CN108218644A - A kind of smokeless dulcet cold light firework medicament - Google Patents

A kind of smokeless dulcet cold light firework medicament Download PDF

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Publication number
CN108218644A
CN108218644A CN201810085640.5A CN201810085640A CN108218644A CN 108218644 A CN108218644 A CN 108218644A CN 201810085640 A CN201810085640 A CN 201810085640A CN 108218644 A CN108218644 A CN 108218644A
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CN
China
Prior art keywords
cold light
dulcet
smokeless
light firework
firework medicament
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Pending
Application number
CN201810085640.5A
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Chinese (zh)
Inventor
张永明
王彦君
邓维平
王文斌
刘杰
赖习军
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Luzhou Beifang Chemical Industry Co Ltd
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Luzhou Beifang Chemical Industry Co Ltd
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Application filed by Luzhou Beifang Chemical Industry Co Ltd filed Critical Luzhou Beifang Chemical Industry Co Ltd
Priority to CN201810085640.5A priority Critical patent/CN108218644A/en
Publication of CN108218644A publication Critical patent/CN108218644A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B33/00Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
    • C06B33/08Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide with a nitrated organic compound
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B27/00Compositions containing a metal, boron, silicon, selenium or tellurium or mixtures, intercompounds or hydrides thereof, and hydrocarbons or halogenated hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Medicinal Preparation (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention discloses a kind of smokeless dulcet cold light firework medicaments, belong to fireworks and firecrackers field.Few or even smokeless the technical problem to be solved in the present invention is to provide a kind of combustion fumes, jet power is strong, and spark is full, dulcet cold light firework medicament, includes the component of following mass parts:13~91 parts of nitrocelluloses, 0.2~5 part of ferrocene, 0.5~2.5 part of stabilization agent, 0.5~5 part of essence, 8~80 parts of titanium valves.The present invention is by adjusting nitrocellulose, stabilization agent, ferrocene, essence and titanium valve ratio, make cold light firework medicament sets off non smoke, spark jetting stability and it is full, temperature is low, irritating ammonia odor is not generated after burning, the gas that medicament generates after burning can also be made to give out various fragrance, comfortable adjusts atmosphere, cold light firework medicament of the present invention has a wide range of applications in fireworks and firecrackers field, is worthy to be popularized.

Description

A kind of smokeless dulcet cold light firework medicament
Technical field
The invention belongs to fireworks and firecrackers fields, and in particular to a kind of smokeless dulcet cold light firework medicament.
Background technology
Cold light firework, which is called, makees cool flame fire, and common fireworks burning point easily causes human body at 500 DEG C~800 DEG C, burning Injury, and cool flame fire burning point is at 60 DEG C~80 DEG C, 30 DEG C~50 DEG C of external temperature, to human body fanout free region.Cool flame fire is suitable for room Inside and outside to set off, brightness is high when setting off, smog is small, pollution is few, can play the role of strong setting off rendering by contrast to live atmosphere.It is various The cold light firework product of shape-designing is suitble to different places to set off, such as outdoor dragon dance performance and indoor stage performance.
The medicament of presently commercially available cold light firework is generally using the mixture of single original washing powder, titanium valve and oxidant.Single original washing powder is to adopt With retired military single-base gun propellant hygrometric state it is broken prepared by yellow powder fiber, cigarette and residue are few during burning.Oxidant Generally use ammonium perchlorate, potassium hyperchlorate etc., the cold light firework containing ammonium perchlorate, potassium hyperchlorate can generate NH setting off4、HCl、 Cl2, they can cause pungent smell and a certain amount of smog, be a kind of cool flame fire of micro- cigarette.Chinese patent CN1059400A A kind of smoke less fire cracker and manufacturing method are disclosed, belongs to cool flame fire scope, drug ingedient range is (by weight):Nitrocellulose 75 ~90%, magnalium cerium alloy 4~15%, Titanium 5~15% and shellac 5~10%.Interior is seted off, not only smokelessly but also with fireworks Effect.But by the medicament of this trial-production, loaded on being seted off after paper web, fireworks jet power is weaker, and spark level is dull, smog Still it is larger.
Invention content
Technical problem solved by the invention is to provide that a kind of combustion fumes are few or even smokeless, and jet power is strong, and spark is satisfied It is full, dulcet cold light firework medicament.
There is provided a kind of smokeless dulcet cold light cigarettes for technological means used by the present invention solves above-mentioned technical problem Anther agent includes the component of following mass parts:13~91 parts of nitrocelluloses, 0.2~5 part of ferrocene, 0.5~2.5 part of peace Determine agent, 0.5~5 part of essence, 8~80 parts of titanium valves.
Wherein, in smokeless dulcet cold light firework medicament described above, the degree of nitration of the nitrocellulose is not small In 175mL/g.
Wherein, in the cold light firework medicament of smokeless no ammonia odor described above, the stabilization agent is diphenylamines, in No. I Determine at least one of agent or No. II centralite.
Wherein, in the cold light firework medicament of smokeless no ammonia odor described above, the titanium valve for Titanium, yellow light titanium, At least one of titanium sponge or titantium hydride.
Wherein, in the cold light firework medicament of smokeless no ammonia odor described above, the granularity of the titanium valve is 20~200 Mesh.
Wherein, in the cold light firework medicament of smokeless no ammonia odor described above, the essence can be natural perfume material tune The essence that the essence of sum or artificial synthesized fragrance reconcile.
Wherein, in the cold light firework medicament of smokeless no ammonia odor described above, the odor type of the essence can select the fragrance of a flower Type, non-flowery scent, Fruity type, wine odor type or cigarette odor type etc..
The present invention also provides the preparation method of smokeless dulcet cold light firework medicament described above, this method includes Following steps:By each component be uniformly mixed to get.
In addition, the answering in fireworks and firecrackers the present invention also provides smokeless dulcet cold light firework medicament described above With.
Beneficial effects of the present invention:
The present invention makes setting off for cold light firework medicament by adjusting nitrocellulose, stabilization agent, ferrocene and titanium valve ratio Non smoke, spark jetting stability and it is full, temperature is low, irritating ammonia odor is not generated after burning;Essence addition is adjusted again, It is made not influence medicament combustibility, and the gas that medicament can be made to be generated after burning gives out various fragrance, comfortable is adjusted Atmosphere;Without potassium hyperchlorate or ammonium perchlorate in medicament of the present invention, and the jet power for using the combustion-supporting generation of ferrocene enough, reach Outstanding firework display effect, safety and reliability;Cold light firework medicament of the present invention has a wide range of applications in fireworks and firecrackers field, is worth It promotes.
Specific embodiment
Specifically, a kind of smokeless dulcet cold light firework medicament, include the component of following mass parts:13~91 parts of nitre Cellulose, 0.2~5 part of ferrocene, 0.5~2.5 part of stabilization agent, 0.5~5 part of essence, 8~80 parts of titanium valves.
The present invention using the degree of nitration be not less than 175mL/g nitrocellulose, come ensure burning generate gas can will Titanium valve particle sprays, and forms appreciation effect;It is a plurality of types of that Titanium, yellow light titanium, titanium sponge or titantium hydride etc. can be used in titanium valve Titanium valve derives from a wealth of sources;It is sufficiently mixed for the ease of each component, reaches excellent combustion efficiency, the granularity of titanium valve will in the present invention It asks as 20~200 mesh;Stabilization agent is diphenylamines, at least one of No. I centralite or No. II centralite.
Essence can be the essence that natural perfume material reconciles or the essence that artificial synthesized fragrance reconciles in the present invention, and odor type can To select floral type, non-flowery scent, Fruity type, wine odor type, cigarette odor type etc.;After making addition essence, medicament is not influenced Firework display effect, while ensure that medicament fragrance is suitable, 0.5~5 mass parts of essence position in the present invention.
The preparation method of smokeless dulcet cold light firework medicament of the invention is simple, safe efficient, each component is mixed equal It is even to get.
Smokeless dulcet cold light firework medicament provided by the invention has extensive use in fireworks and firecrackers, such as by medicament After plastotype, packaging, cake cool flame fire, hand-held cold light fireworks, wedding celebration cold light fireworks etc. can be used as, firework display effect is good, safe to use.
The present invention is described in further detail below by embodiment, but is not therefore limited the scope of the present invention Among the embodiment described range.
Embodiment 1
The smokeless dulcet cold light firework medicament of apple fragrance type:Weigh 85 mass of nitrocellulose of degree of nitration 190mL/g Part, 1 mass parts of diphenylamines, 2 mass parts of ferrocene, 3 mass parts of flavoring apple essence, 9 mass of spongy titanium powder of 120~140 mesh of granularity Part, by above-mentioned raw material be uniformly mixed to get.
16 millimeters of powder columns of diameter are made in above-mentioned medicament, stage property is seted off in loading, and when setting off, spark sprays upwards, smokelessly, nothing Pungent taste, gas has light apple aroma after burning, and no residue is fallen, and top is divided into spark, and lower part flame is suitable for inserting It is seted off on cake, increases celebration atmosphere.
Embodiment 2
The smokeless dulcet cold light firework medicament of rose scent:Weigh 70 mass of nitrocellulose of degree of nitration 210mL/g Part, No. I 1 mass parts of centralite, 3 mass parts of ferrocene, 5 mass parts of flavoring rose essence, 120 mesh~140 mesh metallic titanium powder, 21 mass Part, by above-mentioned raw material be uniformly mixed to get.
25 millimeters of powder columns of diameter are made in above-mentioned medicament, stage property is seted off in loading, when setting off, sets off height for 2.5m~3m, Red carpet both sides are can be placed on, smoke-free and tasteless generates the gas of rose scent, increases romantic atmosphere for wedding celebration without slag when setting off, fire Flame is bright and colourful.
Embodiment 3
The smokeless dulcet cold light firework medicament of Rum odor type:Weigh 86 matter of nitrocellulose of degree of nitration 180mL/g Measure part, 1 mass parts of diphenylamines, 0.5 mass parts of ferrocene, 2.5 mass parts of rum essence, the mesh hydride powder 10 of 180 mesh~200 Mass parts, by above-mentioned raw material be uniformly mixed to get.
5 millimeters of powder columns of diameter are made in above-mentioned medicament, outer surface applies flame retardant paint, and insertion is seted off in stage property, is placed on wine bottle cover Upper end is seted off, and smoke-free and tasteless generates the gas of Rum fragrance, increases ardent atmosphere for dinner party, flame is gorgeous without slag when setting off It is beautiful colorful.
By above-described embodiment it is found that the smokeless dulcet cold light firework medicament of the present invention is seted off smokelessly, without pungent smell, The gas generated after burning gives out various fragrance, spark jetting stability and full, and temperature is low, securely and reliably, has in life It is widely used.

Claims (9)

1. smokeless dulcet cold light firework medicament, it is characterised in that:Include the component of following mass parts:13~91 parts of nitrifications are fine Tie up element, 0.2~5 part of ferrocene, 0.5~2.5 part of stabilization agent, 0.5~5 part of essence, 8~80 parts of titanium valves.
2. smokeless dulcet cold light firework medicament according to claim 1, it is characterised in that:The nitrocellulose The degree of nitration is not less than 175mL/g.
3. the smokelessly cold light firework medicament without ammonia odor according to claim 1, it is characterised in that:The stabilization agent is two At least one of aniline, No. I centralite or No. II centralite.
4. smokeless dulcet cold light firework medicament according to claim 1, it is characterised in that:The titanium valve is metal At least one of titanium, yellow light titanium, titanium sponge or titantium hydride.
5. according to the smokeless dulcet cold light firework medicament of Claims 1 to 4 any one of them, it is characterised in that:The titanium The granularity of powder is 20~200 mesh.
6. smokeless dulcet cold light firework medicament according to claim 1, it is characterised in that:The essence can be day The essence that the essence or artificial synthesized fragrance that right fragrance reconciles reconcile.
7. smokeless dulcet cold light firework medicament according to claim 6, it is characterised in that:The odor type of the essence is Floral type, non-flowery scent, Fruity type, wine odor type or cigarette odor type.
8. the preparation method of the smokeless dulcet cold light firework medicament of claim 1~7 any one of them, it is characterised in that: By each component be uniformly mixed to get.
9. claim 1~7 any one of them smokelessly application of the dulcet cold light firework medicament in fireworks and firecrackers.
CN201810085640.5A 2018-01-29 2018-01-29 A kind of smokeless dulcet cold light firework medicament Pending CN108218644A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108981486A (en) * 2018-08-30 2018-12-11 浏阳象形精品烟花出口制造有限公司 A kind of anaerobic agent cold light cake firework
CN110963867A (en) * 2019-12-03 2020-04-07 江西吉润花炮新材料科技有限公司 Smokeless sulfur-free bright green indoor setting-off type cold firework explosive and preparation method thereof
CN111018639A (en) * 2019-12-10 2020-04-17 江西吉润花炮新材料科技有限公司 Smokeless and sulfur-free cold firework medicament and preparation method thereof
CN113357969A (en) * 2021-07-16 2021-09-07 湖南恒达烟花有限公司 Fireworks are touched off in high altitude with waterproof function

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040782A (en) * 1989-09-26 1990-03-28 江西省万载县黄茅出口花炮厂 The manufacturing of small green snake fireworks
CN1059400A (en) * 1991-05-03 1992-03-11 浏阳县沿溪鞭炮烟花公司花炮厂 Smoke less fire cracker and manufacture method
CN103664425A (en) * 2012-09-12 2014-03-26 李桂华 Nitrified maize-core smokeless fireworks powder
CN107619364A (en) * 2016-11-30 2018-01-23 湖北航天化学技术研究所 A kind of red bright pearl material of few cigarette and its preparation method and application

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040782A (en) * 1989-09-26 1990-03-28 江西省万载县黄茅出口花炮厂 The manufacturing of small green snake fireworks
CN1059400A (en) * 1991-05-03 1992-03-11 浏阳县沿溪鞭炮烟花公司花炮厂 Smoke less fire cracker and manufacture method
CN103664425A (en) * 2012-09-12 2014-03-26 李桂华 Nitrified maize-core smokeless fireworks powder
CN107619364A (en) * 2016-11-30 2018-01-23 湖北航天化学技术研究所 A kind of red bright pearl material of few cigarette and its preparation method and application

Non-Patent Citations (1)

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Title
全国注册安全工程师执业资格考试辅导教材编审委员会: "《安全生产技术》", 30 June 2005, 煤炭工业出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108981486A (en) * 2018-08-30 2018-12-11 浏阳象形精品烟花出口制造有限公司 A kind of anaerobic agent cold light cake firework
CN110963867A (en) * 2019-12-03 2020-04-07 江西吉润花炮新材料科技有限公司 Smokeless sulfur-free bright green indoor setting-off type cold firework explosive and preparation method thereof
CN111018639A (en) * 2019-12-10 2020-04-17 江西吉润花炮新材料科技有限公司 Smokeless and sulfur-free cold firework medicament and preparation method thereof
CN113357969A (en) * 2021-07-16 2021-09-07 湖南恒达烟花有限公司 Fireworks are touched off in high altitude with waterproof function

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Application publication date: 20180629

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