CN109628032A - A kind of flame retardant type based Wood Adhesives - Google Patents
A kind of flame retardant type based Wood Adhesives Download PDFInfo
- Publication number
- CN109628032A CN109628032A CN201811445394.6A CN201811445394A CN109628032A CN 109628032 A CN109628032 A CN 109628032A CN 201811445394 A CN201811445394 A CN 201811445394A CN 109628032 A CN109628032 A CN 109628032A
- Authority
- CN
- China
- Prior art keywords
- parts
- flame retardant
- type based
- based wood
- wood adhesives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of flame retardant type based Wood Adhesives, raw material including following parts by weight, 60-80 parts of phenolic resin, 20-40 parts of epoxy resin, 3-9 parts of polyethanol butyral, 5-8 parts of fire retardant, 15-20 parts of toughener, 0.2-0.8 parts of dispersing agent, the fire retardant is the mixture of bromination distyrene, antimony oxide and dicalcium powder, and the bromination distyrene: antimony oxide: the mass ratio of dicalcium powder is (1~2): (3~5): (2~3).The present invention has anti-flammability, and the release of poison gas and toxic smoke, is not detrimental to health when adhesive being prevented to burn.
Description
Technical field
The present invention relates to based Wood Adhesives technical field, especially a kind of flame retardant type based Wood Adhesives.
Background technique
Based Wood Adhesives are mainly used for wood-based plate manufacture and woodwork produces two big fields, common based Wood Adhesives kind
Multiplicity mainly has urea-formaldehyde resin adhesive, melamine resin adehsive to stick agent, vinyl acetate and its copolymer emulsion adhesive, phenol
Urea formaldehyde adhesive, epoxy resin adhesive, chloroprene rubber adhesive, adhesive for polyurethane, protein adhesive and carbon aquation
Close object adhesive.Common based Wood Adhesives, do not have an anti-flammability, and when burning can discharge poison gas and toxic smoke, are detrimental to health.
Therefore, common based Wood Adhesives, do not have an anti-flammability, and when burning can discharge poison gas and toxic smoke, are detrimental to health.
Summary of the invention
The purpose of the present invention is the provision of a kind of flame retardant type based Wood Adhesives.The present invention has anti-flammability, prevents glue
The release of poison gas and toxic smoke, is not detrimental to health when glutinous agent burning.
Technical solution of the present invention: a kind of flame retardant type based Wood Adhesives, the raw material including following parts by weight, phenolic resin
60-80 parts, 20-40 parts of epoxy resin, 3-9 parts of polyethanol butyral, 5-8 parts of fire retardant, 15-20 parts of toughener, dispersing agent
0.2-0.8 parts.
In a kind of flame retardant type based Wood Adhesives above-mentioned, the raw material including following parts by weight, 70 parts of phenolic resin, asphalt mixtures modified by epoxy resin
30 parts of rouge, 6 parts of polyethanol butyral, 7 parts of fire retardant, 18 parts of toughener, 0.5 part of dispersing agent.
In a kind of flame retardant type based Wood Adhesives above-mentioned, the fire retardant is bromination distyrene, antimony oxide and again
The mixture of calcium powder.
In a kind of flame retardant type based Wood Adhesives above-mentioned, the bromination distyrene: antimony oxide: the quality of dicalcium powder
Than for (1~2): (3~5): (2~3).
In a kind of flame retardant type based Wood Adhesives above-mentioned, the bromination distyrene: antimony oxide: the quality of dicalcium powder
Than for 1.5:4:2.5.
In a kind of flame retardant type based Wood Adhesives above-mentioned, the toughener is dibutyl phthalate and phthalic acid
One or both of dibutyl ester.
In a kind of flame retardant type based Wood Adhesives above-mentioned, the dispersing agent is calgon, sodium pyrophosphate, polyphosphoric acid
One or more of salt, Sodium Polyacrylate or carboxylate.
Compared with the prior art, fire retardant is contained in raw material of the invention, the fire retardant is bromination distyrene, three oxygen
Change the mixture of two antimony and dicalcium powder, the bromination distyrene: antimony oxide: the mass ratio of dicalcium powder is (1~2): (3
~5): (2~3), the fire retardant of said ratio, raw material accounting is small, so that the present invention has anti-flammability, and caking property is strong, film forming
Property is good, and durability is good.The fire retardant is a small amount of organohalogen compounds and inorganic matter, has taken into account flame retardant property and environmental requirement,
The incorporation of dicalcium powder so that cost reduces, while increasing intensity of the invention to a certain extent.The present invention has fire-retardant
Property, the release of poison gas and toxic smoke when adhesive being prevented to burn is not detrimental to health.
Specific embodiment
Below with reference to embodiment, the present invention is further illustrated, but is not intended as the foundation limited the present invention.
Embodiment 1.A kind of flame retardant type based Wood Adhesives, the raw material including following parts by weight, 60 parts of phenolic resin, asphalt mixtures modified by epoxy resin
20 parts of rouge, 3 parts of polyethanol butyral, 5 parts of fire retardant, 15 parts of toughener, 0.2 part of dispersing agent.
The fire retardant is the mixture of bromination distyrene, antimony oxide and dicalcium powder.
The bromination distyrene: antimony oxide: the mass ratio of dicalcium powder is 1:3:2.
The toughener is the mixture of dibutyl phthalate and o-phthalic acid dibutyl ester, the phthalic acid
The mass ratio of dibutyl ester and o-phthalic acid dibutyl ester is 1:1.
The dispersing agent is the mixture of calgon, sodium pyrophosphate, Sodium Polyacrylate, the calgon, coke
Sodium phosphate, Sodium Polyacrylate mass ratio be 1:1:2.
Embodiment 2.A kind of flame retardant type based Wood Adhesives, the raw material including following parts by weight, 80 parts of phenolic resin, asphalt mixtures modified by epoxy resin
40 parts of rouge, 9 parts of polyethanol butyral, 8 parts of fire retardant, 20 parts of toughener, 0.8 part of dispersing agent.
The fire retardant is the mixture of bromination distyrene, antimony oxide and dicalcium powder.
The bromination distyrene: antimony oxide: the mass ratio of dicalcium powder is 2:5:3.
The toughener is dibutyl phthalate.
The dispersing agent is calgon.
Embodiment 3.A kind of flame retardant type based Wood Adhesives include the raw material of following parts by weight, and 70 parts of phenolic resin, asphalt mixtures modified by epoxy resin
30 parts of rouge, 6 parts of polyethanol butyral, 7 parts of fire retardant, 18 parts of toughener, 0.5 part of dispersing agent.
The fire retardant is the mixture of bromination distyrene, antimony oxide and dicalcium powder.
The bromination distyrene: antimony oxide: the mass ratio of dicalcium powder is 1.5:4:2.5.
The toughener is o-phthalic acid dibutyl ester.
The dispersing agent is calgon and Sodium Polyacrylate, the mass ratio of the calgon and Sodium Polyacrylate
For 1:1.
Certainly, the present invention can also have other various embodiments, without deviating from the spirit and substance of the present invention, ripe
It knows those skilled in the art and makes various corresponding changes and modifications, but these corresponding changes and change in accordance with the present invention
Shape all should fall within the scope of protection of the appended claims of the present invention.
Claims (7)
1. a kind of flame retardant type based Wood Adhesives, it is characterised in that: the raw material including following parts by weight, 60-80 parts of phenolic resin, ring
20-40 parts of oxygen resin, 3-9 parts of polyethanol butyral, 5-8 parts of fire retardant, 15-20 parts of toughener, 0.2-0.8 parts of dispersing agent.
2. a kind of flame retardant type based Wood Adhesives according to claim 1, it is characterised in that: the original including following parts by weight
Material, 70 parts of phenolic resin, 30 parts of epoxy resin, 6 parts of polyethanol butyral, 7 parts of fire retardant, 18 parts of toughener, dispersing agent 0.5
Part.
3. a kind of flame retardant type based Wood Adhesives according to claim 1 or 2, it is characterised in that: the fire retardant is bromination
The mixture of distyrene, antimony oxide and dicalcium powder.
4. a kind of flame retardant type based Wood Adhesives according to claim 3, it is characterised in that: the bromination distyrene: three
Aoxidize two antimony: the mass ratio of dicalcium powder is (1~2): (3~5): (2~3).
5. a kind of flame retardant type based Wood Adhesives according to claim 4, it is characterised in that: the bromination distyrene: three
Aoxidize two antimony: the mass ratio of dicalcium powder is 1.5:4:2.5.
6. a kind of flame retardant type based Wood Adhesives according to claim 1 or 2, it is characterised in that: the toughener is adjacent benzene
One or both of dibutyl carboxylic acid and o-phthalic acid dibutyl ester.
7. a kind of flame retardant type based Wood Adhesives according to claim 1 or 2, it is characterised in that: the dispersing agent is six inclined
One or more of sodium phosphate, sodium pyrophosphate, polyphosphate, Sodium Polyacrylate or carboxylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811445394.6A CN109628032A (en) | 2018-11-29 | 2018-11-29 | A kind of flame retardant type based Wood Adhesives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811445394.6A CN109628032A (en) | 2018-11-29 | 2018-11-29 | A kind of flame retardant type based Wood Adhesives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109628032A true CN109628032A (en) | 2019-04-16 |
Family
ID=66070180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811445394.6A Pending CN109628032A (en) | 2018-11-29 | 2018-11-29 | A kind of flame retardant type based Wood Adhesives |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109628032A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111395000A (en) * | 2019-05-16 | 2020-07-10 | 佛山市三水中信达地毯制品有限公司 | Special fireproof flame retardant for carpet and preparation method thereof |
-
2018
- 2018-11-29 CN CN201811445394.6A patent/CN109628032A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111395000A (en) * | 2019-05-16 | 2020-07-10 | 佛山市三水中信达地毯制品有限公司 | Special fireproof flame retardant for carpet and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190416 |