CN102020518B - Scintillator for replacing titanium in firework raw material - Google Patents

Scintillator for replacing titanium in firework raw material Download PDF

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Publication number
CN102020518B
CN102020518B CN2010105299859A CN201010529985A CN102020518B CN 102020518 B CN102020518 B CN 102020518B CN 2010105299859 A CN2010105299859 A CN 2010105299859A CN 201010529985 A CN201010529985 A CN 201010529985A CN 102020518 B CN102020518 B CN 102020518B
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China
Prior art keywords
percent
scintillator
raw material
titanium
firework
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Expired - Fee Related
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CN2010105299859A
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Chinese (zh)
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CN102020518A (en
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刘建军
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Individual
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Individual
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Publication of CN102020518B publication Critical patent/CN102020518B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention discloses a scintillator for replacing titanium in a firework raw material. The scintillator comprises the following components: 10-44 percent of white scintillator, 6-26 percent of sulphur, 9-27 percent of aluminum-magnesium alloy, 5-14 percent of aluminum slag, 5-21 percent of sepiolite and 4-29 percent of barium nitrate, wherein the white scintillator comprises 5-15 percent of SrSO4, 30-50 percent of BaSO4, 20-40 percent of Na2SiF6, 5-10 percent of K2Cr2O7 and 5-10 percent of CuO on the basis of total weight. The invention has the advantages of wide raw material source, safe production process, no pollution and low cost, can completely replace metal titanium, changes the dependence of the firework production industry on the metal titanium and the shortage situation of the metal titanium and prevents the potential safety hazard of the metal titanium during production, storage, transportation, selling and firework preparation.

Description

Be used for substituting the scintillator of fireworks raw material titanium
Technical field
The present invention relates to a kind of fireworks raw material.
Background technology
Existing fireworks need metal titanium to be used as a kind of colouring material during fabrication, especially have the fireworks of Hua Xin in the firework display effect, can not lack metal titanium especially in its raw material.Titanium is as a large amount of uses of a kind of precious metal in fireworks are produced source of goods shortage on the one hand, and supply falls short of demand, costs an arm and a leg, and makes present fireworks cost high; Because titanium can be lighted with naked light, and its inflammableness makes it to join in production, accumulating, sale and fireworks system and has potential safety hazard in the process, the security incident that is caused by titanium also happens occasionally in the past on the other hand.Therefore how under the situation that guarantees firework effect, to reduce the fireworks manufacturing cost, and the safe reliability of raising fireworks production all processes is the key subjects that fireworks manufacturer urgently thirsts for solving.
Summary of the invention
The object of the present invention is to provide the scintillator that is used for substituting fireworks raw material titanium that a kind of raw material sources are extensive, with low cost, safety performance is good.
This scintillator that is used for substituting fireworks raw material titanium provided by the invention comprises aluminium slag, the 5-21% sepiolite of aluminum magnesium alloy, the 5-14% of sulphur, the 9-27% of white sudden strain of a muscle agent, the 6-26% of following component: 10-44%, the nitrate of baryta of 4-29%; With white sudden strain of a muscle agent gross weight is radix, and said white sudden strain of a muscle agent contains the SrSO of 5-15% 4, 30-50% BaSO 4, 20-40%Na 2SiF 6, 5-10% K 2Cr 2O 7, 5-10% CuO.
Raw material sources of the present invention are extensive, alternative metals titanium, and production process safety fully, and pollution-free, open firing point does not fire, and needs firework medicament just can light, and can't mingle in the sale, and quality is guaranteed easily.Can be used for multiple fireworks series products such as aerial, ground, indoor stage cold light, its flower shape is bright and glittering, if spray with cold light; Colored type of the present invention is the same with the colored type of titanium, if with the black powder spray, the present invention has 5-6 even more flower; And titanium has only a flower; Will be far superior to the fireworks of prior art with titanium from this point effect of the present invention, this external application scintillator system tobacco blending flower of the present invention is than spending with metal titanium system tobacco blending, and its production cost will reduce more than 10%.Therefore the present invention has not only reduced the fireworks cost; Changed dependence and the metal titanium in short supply present situation of fireworks production industry to metal titanium; Also avoid the potential safety hazard of metal titanium in production, accumulating, sale and fireworks system are joined, thereby promoted the flourishing and development of fireworks industry.
Embodiment
Below be the inventor some embodiment in the short run trial-manufacturing process.
Embodiment one:
The at first white sudden strain of a muscle of preparation agent: all the raw material gross weights to form white sudden strain of a muscle agent are radix, get 5% SrSO 4, 50% BaSO 4, 35%Na 2SiF 6, 5% K 2Cr 2O 7, 5% CuO, these raw materials are mixed forming Powdered white sudden strain of a muscle agent with the pulvis state, subsequent use.
All raw material weights to form scintillator of the present invention are radix; Get 6% sulphur, 27% aluminum magnesium alloy, 21% sepiolite, 18% nitrate of baryta pulverize separately; Mix with 14% aluminium slag and 14% white sudden strain of a muscle agent again, process the scintillator that the present invention is used for substituting fireworks raw material titanium.
Embodiment two:
At first be equipped with the white agent of dodging: all the raw material gross weights to form white sudden strain of a muscle agent are radix, get 15% SrSO 4, 30% BaSO 4, 40%Na 2SiF 6, 5% K 2Cr 2O 7, 10% CuO.These raw material pulverizing are mixed the white sudden strain of a muscle of formation agent, subsequent use.
Get weight percent again and be 26% sulphur, 9% aluminum magnesium alloy,, 21% sepiolite, 29% nitrate of baryta, these raw materials are all pulverized, mix with 5% aluminium slag and 10% white sudden strain of a muscle agent then, get final product.
Embodiment three:
White sudden strain of a muscle agent preparation: get 15% SrSO 4, 45% BaSO 4, 20%Na 2SiF 6, 10% K 2Cr 2O 7, 10% CuO.These raw materials are mixed the Powdered white sudden strain of a muscle agent of formation with the pulvis state, subsequent use.
Get 15% sulphur, 15% aluminum magnesium alloy, 5% sepiolite again, 19% nitrate of baryta is pulverized, add 14% aluminium slag and 28% white sudden strain of a muscle agent mixing then and get final product.
Embodiment four:
White sudden strain of a muscle agent preparation: get 10% SrSO 4, 40% BaSO 4, 36%Na 2SiF 6, 7% K 2Cr 2O 7, 7% CuO.These raw materials are mixed the Powdered white sudden strain of a muscle agent of formation with the pulvis state, subsequent use.
Get 6% sulphur, 27% aluminum magnesium alloy, 5% sepiolite again, 4% nitrate of baryta is pulverized, add 14% aluminium slag and 44% white sudden strain of a muscle agent mixing then and get final product.

Claims (1)

1. scintillator that is used for substituting fireworks raw material titanium, this scintillator is composed of the following components by weight percentage: the aluminum magnesium alloy of the white sudden strain of a muscle agent of 10-44%, the sulphur of 6-26%, 9-27%, the aluminium slag of 5-14%, the sepiolite of 5-21%, the nitrate of baryta of 4-29%; With white sudden strain of a muscle agent gross weight is radix, and said white sudden strain of a muscle agent is by the SrSO of 5-15% 4, 30-50% BaSO 4, 20-40%Na 2SiF 6, 5-10% K 2Cr 2O 7, 5-10% CuO form.
CN2010105299859A 2010-11-03 2010-11-03 Scintillator for replacing titanium in firework raw material Expired - Fee Related CN102020518B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010105299859A CN102020518B (en) 2010-11-03 2010-11-03 Scintillator for replacing titanium in firework raw material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010105299859A CN102020518B (en) 2010-11-03 2010-11-03 Scintillator for replacing titanium in firework raw material

Publications (2)

Publication Number Publication Date
CN102020518A CN102020518A (en) 2011-04-20
CN102020518B true CN102020518B (en) 2012-01-11

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102898259A (en) * 2012-09-25 2013-01-30 北京理工大学 White snowflake tail combined firework and method for preparing same
CN110204405A (en) * 2019-05-10 2019-09-06 湖南出入境检验检疫局检验检疫技术中心 A kind of cladding fireworks material, celestial body medicament and its preparation and application

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5515784A (en) * 1994-08-09 1996-05-14 The Ensign-Bickford Company Signal transmission devices and detonation systems using the same
CN1317465A (en) * 2001-06-07 2001-10-17 潘小秋 Safety agent for multi-color flashing fireworks and firecrackers
CN1936492A (en) * 2005-09-21 2007-03-28 浏阳市大瑶棠花出口花炮厂 Fireworks with fan-shape white flash-flower-bundle firing effect and its firing chemicals
CN100999429A (en) * 2007-01-09 2007-07-18 浏阳市庆典烟花有限公司 Glowing ray flash star for fireworks and its making method
DE102008063907A1 (en) * 2008-12-19 2010-07-01 Weco Pyrotechnische Fabrik Gmbh Pyrotechnic body, useful as firecracker, preferably China firecrackers and cannon firecrackers and as flashbang mixture, comprises a pyrotechnic mixture comprising a base mixture and titanium

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5515784A (en) * 1994-08-09 1996-05-14 The Ensign-Bickford Company Signal transmission devices and detonation systems using the same
CN1317465A (en) * 2001-06-07 2001-10-17 潘小秋 Safety agent for multi-color flashing fireworks and firecrackers
CN1936492A (en) * 2005-09-21 2007-03-28 浏阳市大瑶棠花出口花炮厂 Fireworks with fan-shape white flash-flower-bundle firing effect and its firing chemicals
CN100999429A (en) * 2007-01-09 2007-07-18 浏阳市庆典烟花有限公司 Glowing ray flash star for fireworks and its making method
DE102008063907A1 (en) * 2008-12-19 2010-07-01 Weco Pyrotechnische Fabrik Gmbh Pyrotechnic body, useful as firecracker, preferably China firecrackers and cannon firecrackers and as flashbang mixture, comprises a pyrotechnic mixture comprising a base mixture and titanium

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Granted publication date: 20120111

Termination date: 20121103