CN106353842A - Manufacturing method of microlens - Google Patents

Manufacturing method of microlens Download PDF

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Publication number
CN106353842A
CN106353842A CN201611069237.0A CN201611069237A CN106353842A CN 106353842 A CN106353842 A CN 106353842A CN 201611069237 A CN201611069237 A CN 201611069237A CN 106353842 A CN106353842 A CN 106353842A
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China
Prior art keywords
lenticule
template
microlens
temperature
expansion
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CN201611069237.0A
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Chinese (zh)
Inventor
刘刚
胡玥
熊瑛
侯双月
田扬超
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University of Science and Technology of China USTC
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University of Science and Technology of China USTC
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Priority to CN201611069237.0A priority Critical patent/CN106353842A/en
Publication of CN106353842A publication Critical patent/CN106353842A/en
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B3/00Simple or compound lenses
    • G02B3/0006Arrays
    • G02B3/0012Arrays characterised by the manufacturing method
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B3/00Simple or compound lenses
    • G02B3/0006Arrays
    • G02B3/0012Arrays characterised by the manufacturing method
    • G02B3/0031Replication or moulding, e.g. hot embossing, UV-casting, injection moulding

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

The invention discloses a manufacturing method of a microlens. The manufacturing method comprises the following steps of (1) manufacturing a microlens or a microlens array, and using as a template microlens; (2) pouring a polymer monomer onto the manufactured microlens or microlens array, and heating at certain temperature; (3) after the polymer is cured, cooling to room temperature, removing the template microlens, and obtaining the final microlens or microlens array on the polymer. The manufacturing method has the advantages that the manufacturing of the microlens by the heat expansion of material is proposed for the first time, the surface shape of the microlens is controlled according to the correlation of heat expansion volume change amount and temperature change amount of the material, and the microlenses with different focal lengths are obtained in a micro-copying technology; the manufacturing technology of the microlens is simplified, the repeatability of the technology is improved, the manufacturing cost of the microlens is reduced, and the manufacturing cycle of the microlens is shortened.

Description

A kind of lenticular manufacture method
Technical field
The present invention relates to the processing technique of micro-nano technology is and in particular to a kind of lenticular manufacture method.
Background technology
Lenticule and its array as important optical element, in bionic field, wavefront sensing, light cumulative, light shaping etc. It is widely used in modern high and new technology.Developing rapidly with micro-electronic mechanical skill, occurs in that many new lenticulees Array fabrication techniques, including (the ginseng such as nuda rice, photosensitive glass method for hot forming, photoetching ion exchange, compression molding method Examine document bian, r., et al., ultralong focal length microlens array fabricated based On su-8photoresist.appl opt, 2015.54 (16): p.5088-93. and hou, t., et al., fabrication,characterization,and applications of microlenses.appl opt,2015.54 (24):p.7366-76.).
In actual applications it is often necessary to the lenticule of different focal.Using existing process, often make a kind of the micro- of focal length Lens, are required for first designing corresponding curved surface.Because, in manufacturing process, lenticular face shape is affected by process conditions etc., difficult With precise control, so needing the curved surface according to design, carrying out substantial amounts of explorative experiment, exploring suitable process conditions and ginseng Number.Further according to these parameters and process conditions, produce required lenticule.Transfer a pattern to finally by microreplicated technique Stable material, realizes batch production.Traditional microreplicated technique is equal proportion duplication, duplicated lenticule curved surface and making The lenticule curved surface going out is identical.
Therefore using traditional technique it is desirable to obtain the lenticule of different focal it is necessary to redesign parameter, explore real Test condition (h ottevaere, r.c., h pherzig, t miyashita, k naessens, comparing glass and plastic refractive microlenses fabricated with different technologies.).Due to Traditional method makes lenticule and generally requires to carry out substantial amounts of explorative experiment, and fabrication cycle is long, complex technical process, and high cost High, this develops further to lenticule and creates larger restriction.
Content of the invention
The purpose of the present invention is: the present invention proposes a kind of lenticular new method of making, and the thermal expansion using material is carried out Lenticular making, according to the dependency of material thermal volume expansion variable quantity and temperature knots modification, controls lenticular face shape, The lenticule of different focal is obtained in microreplicated technique.
The technical solution used in the present invention is: a kind of lenticular manufacture method, and the method step is:
Step 1) make lenticule or microlens array, as template lenticule;
Step 2) polymer is poured on the lenticule made or microlens array, carry out at a certain temperature adding Heat;
Step 3) after polymer solidification, it is cooled to room temperature, sloughs template lenticule, obtain final micro- on polymer Mirror or microlens array.(accompanying drawing 2)
Step 1 in this method) in template lenticule can be the lenticule that any materials are made, such as photoresist, metal With glass etc..Simply when the material using belongs to high polymer, the change of curvature becomes apparent from.Because the knots modification of material volume with The thermal coefficient of expansion of material is directly proportional, and is directly proportional to temperature knots modification.Compare other materials, the thermal coefficient of expansion of high polymer is relatively Greatly, after being heated, volume change is big.But for the little material of thermal coefficient of expansion, the method for the present invention is still effective, simply curvature Change relatively small.
Meanwhile, template lenticule can be concavees lens can also be convex lenss.If with concavees lens as template, micro- after expansion The curved surface of mirror rises, and curvature increases.Temperature change is more, and mass expansion is more, and the curvature replicating the dimpling lens obtaining is bigger, Focal length is longer;Temperature change is fewer, and mass expansion is fewer, and the curvature replicating the dimpling lens obtaining is relatively small, and focal length changes Relatively small.If with convex lenss as template, in contrast, after expansion, curvature reduces, and temperature change is more, and curvature becomes to get over Little, focal length becomes shorter.Therefore if desired for making concave mirror arrangements, can be with convex lens array as template;As needed convex lenss battle array Row, can be with concave mirror arrangements as template.
Because the lenticule that the present invention makes has controllability, so template lenticule is as far as possible using having controllability Technique makes.Template lenticular face shape is controlled, just makes that the lenticular curvature of template is accurate and controlled, and such present invention is to micro- The control of the curvature of mirror and focal length is also just more meaningful.When template lenticule is unable to effective control face shape, still can measure To template lenticular curved surface face shape, realize effectively controlling.
: negative photoresist is exposed and is heated to reflux, make template taking a kind of controllability good template lenticule as a example Nick lens.Below the glass transition temperature less than uncrosslinked part photoresist, nick lens are heated again, photoresist There is not glass transition, but thermal expansion occurs.The photoresist thermal coefficient of expansion of uncrosslinked part is big, and after being heated, volumetric expansion is relatively Many, the photoresist thermal coefficient of expansion of crosslink part is little, and after being heated, volume is basically unchanged.Therefore lenticular curved surface rises, curvature Increase.Nick lens curved surface now is replicated using microreplicated material, just obtains new dimpling lens.Photoresist heat is swollen How much swollen, determined by temperature knots modification and thermal coefficient of expansion.After photoresist is selected, thermal coefficient of expansion no longer changes, this Sample temperature just becomes the single factor changing photoresist swell increment.Temperature change is more, and photoresist expands more, to obtain dimplings The curvature of lens is bigger, and focal length is longer;Temperature change is fewer, and photoresist expansion is fewer, and the curvature of the dimpling lens obtaining is relatively Less, focal length is relatively short.Therefore, adjust the heating-up temperatures different to nick lens, photoresist will be made to have different degrees of Expand, obtain different dimpling lens.Additionally, when the negative photoresist nick lens being obtained using above-mentioned technique are template, by Different from uncrosslinked part thermal coefficient of expansion in crosslink part, the change of curved surface can become apparent from, and Curvature varying is bigger, and obtain is micro- The curvature of convex lenss can be longer.(accompanying drawing 3, accompanying drawing 4)
Additionally, step 1) in using temperature, lenticular face shape is adjusted, the selection of temperature determines the micro- of formation The face shape of lens.For amorphous substance, temperature should control not bringing it about below glass transition, for amorphous material, temperature Degree should control below its fusing point.This ensure that material only occurs thermal expansion, there is no other changes.Otherwise on gravity and surface In the presence of tension force, face shape can change, and still keep the face shape after changing, be so equivalent to template and there occurs not after cooling Reversible change.
This method step 2) in can be using as the material of the in-situ polymerization such as pdms as microreplicated material.Such former Position polymeric material, before there is not polyreaction, is existed with monomeric form, has good mobility, therefore can replicate completely Go out complete curved surface face shape, after polymerization, form stable polymer, can be used as good duplicating material.To thermal coefficient of expansion etc. There is no specific requirement, but when the thermal coefficient of expansion of thermal coefficient of expansion and template microlens material has significant difference, can more hold Easily the lenticule finally giving is separated with template lenticule.This is because after cooling, template lenticule recovers room temperature, pattern is extensive The multiple state under room temperature, and this polymer has replicated the lenticular pattern of template when expanding, now both patterns are not It is completely superposed, separate such that it is able to light.
The thermal expansion of material is mainly utilized in the present invention, using the lenticule face shape of swelling state under polymer replication, when Temperature drops back to room temperature, and template lenticule returns to the face shape before thermal expansion.Because being not related to the change such as melting, lenticule is simply sent out The reversible physical change of life.Lenticule therefore next time makes, and is still with identical lenticule as template, heats up again swollen Swollen, recording surface shape, will not there is any infringement to template lenticule, so template lenticule can be reused.Thermal expansion And replicate that the time of curved surface is relatively short, the techniques such as exposure above need not be repeated, so fabrication cycle greatly shortens.
The principle of the present invention is: material thermal expansion is the change of the scantling and profile being caused due to temperature change Change.Manufactured lenticule is heated, microlens material can occur thermal expansion, lenticular curved surface rises, curvature changes. Lenticule face shape now is got off with another polymer replication, has just obtained new lenticule on the surface of this polymer. Material thermal expansion number determined by the knots modification of temperature and thermal coefficient of expansion.Every kind of material has corresponding thermal coefficient of expansion, After selecting a kind of material, thermal coefficient of expansion determines that.Change experiment in temperature it is possible to control thermal expansion number it is simply that Lenticular curved surface is controlled.Therefore achieve in the present invention in microreplicated technique, for same lenticule, energy Copy the lenticule of multiple curvature and focal length, and there is controllability.(accompanying drawing 1)
Compared with prior art, present invention firstly provides carrying out lenticular making using the thermal expansion of material, according to thing Matter thermal volume expansion variable quantity and the dependency of temperature knots modification, control lenticular face shape it is achieved that in microreplicated technique Obtain the lenticule of different focal.This invention simplifies lenticule processing technology, improve process repeatability, reduce micro- simultaneously Lens cost of manufacture, shortens lenticule fabrication cycle.
Brief description
Fig. 1 is the present invention lenticular manufacture method schematic diagram;
Fig. 2 is the present invention lenticular manufacture method flow chart;
Fig. 3 is with negative photoresist concavees lens for producing principle figure during template;
Fig. 4 is with negative photoresist concavees lens for Making programme figure during template.
Specific embodiment
With reference to example, the detailed process of lenticule processing technology is illustrated further.
Example 1, the making of convex cylindrical lens array
The planar structure of convex cylindrical lens array is optical grating construction, can be by the selection of grating structural parameter, photoresist Select and corresponding process conditions selection realizing the effective control to lenticule pattern.With array period for 180 microns As a example, select su-8 negative photoresist and pdms to make convex cylindrical lens array.
Provide the size of planar structure first: the cycle is 180 microns of optical grating construction, dutycycle is 1:1, line length is 1 centimetre.
It is produced as follows:
1) according to the above-mentioned size providing, process corresponding optical mask;
2) clean si substrate, 180 degree thermal station dry 20 minutes, cold remove rear spin coating su-8 photoresist, with thermal station 65 degree bakings 5 points Clock, then it is warmed up to 95 degree of bakings 20 minutes.The su-8 photoresist layer that thickness is 100 microns is obtained after cooling;
3) uv-exposure, i line, exposure dose 240mj/cm are carried out using the optical mask processing2
4) sample thermal station is dried 5 minutes at 65 degree, then is warmed up to 95 degree of bakings 10 minutes, places natural cooling under room temperature;
5) prepare pdms, solvent is mixed by 10:1 volume ratio with firming agent.Pdms is poured on sample, at 35 degree Dry 24 hours in thermal station.Take off from su-8 photoresist after pdms solidification, convex lenticule is obtained on pdms.
Using step instrument, to template, recessed cylindrical mirror and the convex cylindrical lens array being finally obtained measure: the recessed cylindrical mirror of template Radius of curvature is 205 microns, and the radius of curvature of convex cylindrical mirror is 295 microns, illustrates to make different curvature based on the present invention Lenticule;The radius of curvature difference of different convex cylindrical mirrors is less than 5%, illustrate to have based on present invention making lenticule very high Process repeatability.
Example 2, the making of convex honeycomb lens arra
The planar structure of convex honeycomb lens arra is honeycomb texture, can pass through selection, the photoresist of honeycomb texture parameter Selection and corresponding process conditions selection realizing the effective control to lenticule pattern.With array period for 55 microns As a example, select su-8 negative photoresist and pdms to make convex honeycomb lens arra.
Provide the size of planar structure first: the cycle is 55 microns of honeycomb texture, in order to improve lens arra to light source Utilization rate, the hem width degree of honeycomb texture is 5 microns.
It is produced as follows:
1) according to the above-mentioned size providing, process corresponding optical mask;
2) clean si substrate, 180 degree thermal station dry 20 minutes, cold remove rear spin coating su-8 photoresist, with thermal station 65 degree bakings 5 points Clock, then it is warmed up to 95 degree of bakings 20 minutes.The su-8 photoresist layer that thickness is 100 microns is obtained after cooling;
3) uv-exposure, i line, exposure dose 240mj/cm are carried out using the optical mask processing2
4) sample thermal station is dried 5 minutes at 65 degree, then is warmed up to 95 degree of bakings 10 minutes.Natural cooling is placed under room temperature;
5) prepare pdms, solvent is mixed by 10:1 volume ratio with firming agent.Pdms is poured on sample, at 50 degree Dry 24 hours in thermal station.Take off from su-8 photoresist after pdms solidification, convex lenticule is obtained on pdms.
Using step instrument, template recessed honeycomb lens arra and finally prepared convex honeycomb lens arra are measured: template The radius of curvature of recessed honeycomb lens is 24.19 microns, and the radius of curvature of convex honeycomb lens is 402 microns, illustrates to be based on the present invention The lenticule of different curvature can be made;The radius of curvature difference of different convex honeycomb lens is less than 5%, illustrates to be based on system of the present invention As lenticule, there is very high process repeatability.
Example 3, the making of recessed cylindrical lens array
Az9260 positive photoresist and pdms is selected to make recessed cylindrical lens array.Provide the chi of planar structure first Very little: a diameter of 300 microns, the cycle is 600 microns of optical grating construction.
It is produced as follows:
1) according to the above-mentioned size providing, process corresponding optical mask;
2) clean si substrate, 180 degree thermal station dry 20 minutes, cold remove rear spin coating az9260 photoresist, with thermal station 65 degree bakings 90 minutes.The az9260 photoresist layer that thickness is 15 microns is obtained after cooling;
3) uv-exposure, i line, exposure dose 510mj/cm are carried out using the optical mask processing2
4) development 200s in the developer solution preparing put into by sample, is rinsed using deionized water;
5) sample thermal station is dried 60 minutes at 75 degree, then is warmed up to 120 degree of bakings 50 minutes.Natural cooling is placed under room temperature Afterwards, the convex cylindrical microlenses of template are obtained;
6) prepare pdms, solvent is mixed by 10:1 volume ratio with firming agent.Pdms is poured on sample, at 50 degree Dry 24 hours in thermal station.Take off after pdms solidification, recessed lenticule is obtained on pdms.
Non-elaborated part of the present invention belongs to the known technology of those skilled in the art.

Claims (6)

1. a kind of lenticular manufacture method it is characterised in that: the method step is:
Step 1) make lenticule or microlens array, as template lenticule;
Step 2) polymer monomer is poured on the lenticule made or microlens array, carry out at a certain temperature adding Heat;
Step 3) polymer solidification after, be cooled to room temperature, slough template lenticule, obtain on polymer final lenticule or Microlens array.
2. a kind of lenticular manufacture method according to claim 1 it is characterised in that: step 1) in template lenticule can To be the lenticule that any materials are made, photoresist, metal or glass can be selected.
3. a kind of lenticular manufacture method according to claim 1 it is characterised in that: step 1) in template lenticule can Be concavees lens can also be convex lenss;If with concavees lens as template, after expansion, lenticular curved surface rises, and curvature increases;Temperature Degree change is more, and mass expansion is more, and the curvature replicating the dimpling lens obtaining is bigger, and focal length is longer;Temperature changes fewer, thing The curvature that matter expands the dimpling lens fewer, duplication obtains is relatively small, and focal length changes relatively small;If with convex lenss as mould Plate, then in contrast, after expansion, curvature reduces, and temperature change is more, and curvature becomes less, and focal length becomes shorter;Therefore as needed Concave mirror arrangements to be made, can be with convex lens array as template;As needed convex lens array, can be with concave mirror arrangements as mould Plate.
4. a kind of lenticular manufacture method according to claim 1 it is characterised in that: step 1) in using temperature to micro- The face shape of lens is adjusted, and the selection of temperature determines the lenticular face shape of formation;For amorphous substance, temperature should control Do not bringing it about below glass transition, for amorphous material, temperature should control below its fusing point;This ensure that material Only there is thermal expansion, there is no other changes;Otherwise in the presence of gravity and surface tension, face shape can change, after cooling Still keep the face shape after changing, be so equivalent to template and there occurs irreversible change.
5. a kind of lenticular manufacture method according to claim 1 it is characterised in that: step 2) in as microreplicated Material can use the material of in-situ polymerization, and in-situ polymerization material, before there is not polyreaction, is existed with monomeric form, has Good mobility, therefore can copy complete curved surface face shape completely, form stable polymer after polymerization, can conduct Good duplicating material;There is no specific requirement to thermal coefficient of expansion etc., but when thermal coefficient of expansion and template microlens material When thermal coefficient of expansion has significant difference, can be easier to separate the lenticule finally giving with template lenticule;This is because it is cold But, after, template lenticule recovers room temperature, the state under shape recovery to room temperature, and this polymer has replicated mould when expanding The lenticular pattern of plate, now both patterns not exclusively overlap, separate such that it is able to light.
6. a kind of lenticular manufacture method according to claim 1 it is characterised in that: mainly utilize material in the method Thermal expansion, using the lenticule face shape of swelling state under polymer replication, when temperature drops back to room temperature, template lenticule returns to Face shape before thermal expansion, template lenticule can be reused.
CN201611069237.0A 2016-11-29 2016-11-29 Manufacturing method of microlens Pending CN106353842A (en)

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN107934911A (en) * 2017-11-14 2018-04-20 西安交通大学 Liquid microarray preparation method based on template-mediated self assembly
CN108594596A (en) * 2018-04-28 2018-09-28 广西民族大学 A method of making dimpling lens using PDMS
CN111399092A (en) * 2020-02-28 2020-07-10 上海大学 Silicon wafer template for preparing micro-lens array structure, preparation method of micro-lens array structure and protective film
CN112034541A (en) * 2020-10-15 2020-12-04 苏州苏纳光电有限公司 Method and system for preparing silicon microlens product by photoresist hot melting method
CN113419301A (en) * 2021-07-21 2021-09-21 上海芯物科技有限公司 Preparation method of micro-lens array and wafer
CN114611221A (en) * 2020-12-07 2022-06-10 长春理工大学 Method for designing limit deviation of mold core and mold in precision glass molding process

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107934911A (en) * 2017-11-14 2018-04-20 西安交通大学 Liquid microarray preparation method based on template-mediated self assembly
CN108594596A (en) * 2018-04-28 2018-09-28 广西民族大学 A method of making dimpling lens using PDMS
CN111399092A (en) * 2020-02-28 2020-07-10 上海大学 Silicon wafer template for preparing micro-lens array structure, preparation method of micro-lens array structure and protective film
CN111399092B (en) * 2020-02-28 2021-10-15 上海大学 Preparation method of micro-lens array structure and protective film
CN112034541A (en) * 2020-10-15 2020-12-04 苏州苏纳光电有限公司 Method and system for preparing silicon microlens product by photoresist hot melting method
CN114611221A (en) * 2020-12-07 2022-06-10 长春理工大学 Method for designing limit deviation of mold core and mold in precision glass molding process
CN114611221B (en) * 2020-12-07 2024-05-24 长春理工大学 Mold core and mold limit deviation design method in precision glass molding process
CN113419301A (en) * 2021-07-21 2021-09-21 上海芯物科技有限公司 Preparation method of micro-lens array and wafer

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