CN106283702A - 一种薄型耐摩擦色牢度的汽车内饰革 - Google Patents

一种薄型耐摩擦色牢度的汽车内饰革 Download PDF

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CN106283702A
CN106283702A CN201610653203.XA CN201610653203A CN106283702A CN 106283702 A CN106283702 A CN 106283702A CN 201610653203 A CN201610653203 A CN 201610653203A CN 106283702 A CN106283702 A CN 106283702A
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郑嗣铣
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Zhejiang Kexin new material Polytron Technologies Inc
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Abstract

本发明公开了一种薄型耐摩擦色牢度的汽车内饰革，包括基布层和面层，所述的面层涂覆于基布层的一面，所述面层为三层级结构，包括水性PU底层、水性PU中间层和水性PU表层，所述水性PU底层、水性PU中间层和水性PU表层三者依次连接，所述面层的厚度为0.25～0.4mm。本发明中基布层采用抗菌、抗紫外线、阻燃的海岛型超细纤维制成，具有抗菌抗紫外线，阻燃的效果，耐磨、耐高温和耐老化性能好；面层皮质感强，且均采用水性聚氨酯乳液为原料，环保性好，强度高、防水透气性强；水性PU表层中还添加了纳米TiO2粉与纳米ZnO粉及多元醇脂肪酸酯，具有较强的有较好的耐光老化性和抗静电效果，采用了道康宁DC‑57有机硅聚醚共聚物，汽车内饰革光滑耐磨，耐摩擦色牢度强。

Description

一种薄型耐摩擦色牢度的汽车内饰革
【技术领域】
本发明涉及合成革的技术领域，特别涉及一种薄型耐摩擦色牢度的汽车内饰革。
【背景技术】
由于人口增长、环境保护和社会需求的不断增加，真皮已经无法满足人们日常生活的需求，真皮在加工过程中造成的环境污染及天然资源短缺，促使了合成皮革的发展。人造皮革作为天然皮革的替代品，不仅能够克服真皮利用率低、耐磨性差、撕裂强度低、质地不匀和难以裁剪等缺点，而且解决了真皮资源日趋紧张及其在加工过程中对环境造成极大污染的问题
人造皮革因具有手感柔软，纹路清晰、自然，成品色牢度好，易清洗，阻燃性和散热性好，易于机械打孔等优点而被广泛用于汽车内饰领域。随着中国汽车产量的不断提高，汽车用革量也在大幅提高。PVC合成革由于其与基布的粘结性差、手感僵硬、柔软度差、透气性低、环保性较差等问题，逐渐被PU合成革取代，而溶剂型聚氨酯在加工生产过程中，会带来有机溶剂的挥发和污染问题，同时影响工作人员的健康，为了解决上述问题，同时增强汽车内饰革的耐摩擦色牢度，有必要提出一种薄型耐摩擦色牢度的汽车内饰革。
【发明内容】
本发明的目的在于克服上述现有技术的不足，提供一种薄型耐摩擦色牢度的汽车内饰革，其旨在解决现有技术中汽车内饰革的生产环保性较低，且耐摩擦色牢度较低的技术问题。
为实现上述目的，本发明提出了一种薄型耐摩擦色牢度的汽车内饰革，包括基布层和面层，所述的面层涂覆于基布层的一面，所述的面层为三层级结构，包括水性PU底层、水性PU中间层和水性PU表层，所述的水性PU底层、水性PU中间层和水性PU表层三者依次连接，所述的水性PU底层与基布层的一面贴合粘接，所述的面层的厚度为0.25～0.4mm。
作为优选，所述的基布层采用抗菌、抗紫外线、阻燃的海岛型超细纤维制成。
作为优选，所述的水性PU底层由以下质量份数的原料制备而成：水性聚氨酯乳液75～85份、固化剂2～3份、增稠剂2～3份、交联剂2～3份、增粘剂1.2～1.5份、流平剂0.2～0.5份。
作为优选，所述的水性PU中间层由以下质量份数的原料制备而成：水性聚氨酯乳液75～85份、增稠剂2～3份、交联剂2～3份、增粘剂0.5～1份、流平剂0.2～0.5份、固化剂0.5～1份、偶联剂4～5份，所述的偶联剂为KH-550硅烷偶联剂。
作为优选，所述的水性PU表层由以下质量份数的原料制备而成：水性聚氨酯乳液75～85份、增稠剂2～3份、交联剂2～3份、增粘剂0.5～1份、流平剂0.2～0.5份、固化剂2.5～3.5份、抗紫外剂1.2～2.8份、抗静电剂0.3～0.5份、爽滑剂3.5～5.5份，所述的抗紫外剂为纳米TiO2粉与纳米ZnO粉的混合物，所述的抗静电剂为多元醇脂肪酸酯，所述的爽滑剂为道康宁DC-57有机硅聚醚共聚物。
作为优选，所述的水性聚氨酯乳液由以下原料制备而成：多元醇、二异氰酸酯、亲水剂扩链剂、丙酮、中和成盐剂、扩链剂、去离子水，所述的水性聚氨酯乳液固含量为35～45％。
作为优选，所述的多元醇包括聚醚多元醇、聚酯多元醇、聚碳酸酯多元醇，所述的二异氰酸酯采用TDI、MDI、HDI、IPDI中的一种或多种，所述的亲水剂扩链剂采用DMPA，所述的中和成盐剂采用TEA，所述的扩链剂采用EDA。
作为优选，所述的聚醚多元醇、聚酯多元醇、聚碳酸酯多元醇三者的质量之比为5：3：2。
作为优选，所述的增稠剂为聚氨酯类增稠剂或纤维素类增稠剂，交联剂为F-818异氰酸酯交联剂，增粘剂为萜烯树脂，流平剂为机硅聚合物或丙烯酸酯聚合物，固化剂为水性环氧树脂固化剂。
本发明的有益效果：与现有技术相比，本发明提供的一种薄型耐摩擦色牢度的汽车内饰革，结构合理，基布层采用抗菌、抗紫外线、阻燃的海岛型超细纤维制成，具有抗菌，抗紫外线，阻燃的效果，耐磨、耐高温和耐老化性能好；采用水性PU底层、水性PU中间层和水性PU表层形成三层级结构的面层，皮质感强，且均采用水性聚氨酯乳液为原料进行涂层，环保性好，强度高、防水透气性强；水性PU表层中还添加了纳米TiO2粉与纳米ZnO粉及多元醇脂肪酸酯，具有较强的有较好的耐光老化性和抗静电效果，采用了道康宁DC-57有机硅聚醚共聚物，汽车内饰革光滑耐磨，耐摩擦色牢度强。
本发明的特征及优点将通过实施例结合附图进行详细说明。
【附图说明】
图1是本发明实施例一种薄型耐摩擦色牢度的汽车内饰革的结构示意图。
图中：1-基布层、2-面层、21-水性PU底层、22-水性PU中间层、23-水性PU表层。
【具体实施方式】
为使本发明的目的、技术方案和优点更加清楚明了，下面通过附图中及实施例，对本发明进行进一步详细说明。但是应该理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限制本发明的范围。此外，在以下说明中，省略了对公知结构和技术的描述，以避免不必要地混淆本发明的概念。
参阅图1，本发明实施例提供一种薄型耐摩擦色牢度的汽车内饰革，包括基布层1和面层2，所述的面层2涂覆于基布层1的一面，所述的面层2为三层级结构，包括水性PU底层21、水性PU中间层22和水性PU表层23，所述的水性PU底层21、水性PU中间层22和水性PU表层23三者依次连接，所述的水性PU底层21与基布层1的一面贴合粘接，所述的面层2的厚度为0.25～0.4mm。
其中，所述的基布层1采用抗菌、抗紫外线、阻燃的海岛型超细纤维制成。
进一步地，所述的水性PU底层21由以下质量份数的原料制备而成：水性聚氨酯乳液75～85份、固化剂2～3份、增稠剂2～3份、交联剂2～3份、增粘剂1.2～1.5份、流平剂0.2～0.5份，所述的水性PU中间层22由以下质量份数的原料制备而成：水性聚氨酯乳液75～85份、增稠剂2～3份、交联剂2～3份、增粘剂0.5～1份、流平剂0.2～0.5份、固化剂0.5～1份、偶联剂4～5份，所述的偶联剂为KH-550硅烷偶联剂，所述的水性PU表层23由以下质量份数的原料制备而成：水性聚氨酯乳液75～85份、增稠剂2～3份、交联剂2～3份、增粘剂0.5～1份、流平剂0.2～0.5份、固化剂2.5～3.5份、抗紫外剂1.2～2.8份、抗静电剂0.3～0.5份、爽滑剂3.5～5.5份，所述的抗紫外剂为纳米TiO2粉与纳米ZnO粉的混合物，所述的抗静电剂为多元醇脂肪酸酯，所述的爽滑剂为道康宁DC-57有机硅聚醚共聚物，所述的水性聚氨酯乳液由以下原料制备而成：多元醇、二异氰酸酯、亲水剂扩链剂、丙酮、中和成盐剂、扩链剂、去离子水，所述的水性聚氨酯乳液固含量为35～45％。
更进一步地，所述的多元醇包括聚醚多元醇、聚酯多元醇、聚碳酸酯多元醇，所述的二异氰酸酯采用TDI、MDI、HDI、IPDI中的一种或多种，所述的亲水剂扩链剂采用DMPA，所述的中和成盐剂采用TEA，所述的扩链剂采用EDA，所述的聚醚多元醇、聚酯多元醇、聚碳酸酯多元醇三者的质量之比为5：3：2，所述的增稠剂为聚氨酯类增稠剂或纤维素类增稠剂，交联剂为F-818异氰酸酯交联剂，增粘剂为萜烯树脂，流平剂为机硅聚合物或丙烯酸酯聚合物，固化剂为水性环氧树脂固化剂。
在本发明实施例中，水性PU底层21、水性PU中间层22和水性PU表层23中均采用水性环氧树脂为固化剂，对水性聚氨酯乳液进行改性的同时，具有优良的粘接性能，使面层2具有高模量、高强度和耐化学性，水性PU中间层22采用了KH-550硅烷偶联剂进行改性，水性聚氨酯乳液的耐水性、力学性能都有显著提高，此外，还可在水性PU底层21、水性PU中间层22和水性PU表层23的原料中添加适量的水性染料和固色剂，改善合成革的外观效果。
本发明提供的一种薄型耐摩擦色牢度的汽车内饰革，基布层1采用抗菌、抗紫外线、阻燃的海岛型超细纤维制成，具有抗菌，抗紫外线，阻燃的效果，耐磨、耐高温和耐老化性能好；采用水性PU底层21、水性PU中间层22和水性PU表层23形成三层级结构的面层2，皮质感强，且均采用水性聚氨酯乳液为原料进行涂层，环保性好，强度高、防水透气性强；水性PU表层23中还添加了纳米TiO2粉与纳米ZnO粉及多元醇脂肪酸酯，具有较强的有较好的耐光老化性和抗静电效果，采用了道康宁DC-57有机硅聚醚共聚物，汽车内饰革光滑耐磨，耐摩擦色牢度强。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内所作的任何修改、等同替换或改进等，均应包含在本发明的保护范围之内。

Claims (9)

1.一种薄型耐摩擦色牢度的汽车内饰革，包括基布层(1)和面层(2)，所述的面层(2)涂覆于基布层(1)的一面，其特征在于：所述的面层(2)为三层级结构，包括水性PU底层(21)、水性PU中间层(22)和水性PU表层(23)，所述的水性PU底层(21)、水性PU中间层(22)和水性PU表层(23)三者依次连接，所述的水性PU底层(21)与基布层(1)的一面贴合粘接，所述的面层(2)的厚度为0.25～0.4mm。
2.如权利要求1所述的一种薄型耐摩擦色牢度的汽车内饰革，其特征在于：所述的基布层(1)采用抗菌、抗紫外线、阻燃的海岛型超细纤维制成。
3.如权利要求1所述的一种薄型耐摩擦色牢度的汽车内饰革，其特征在于：所述的水性PU底层(21)由以下质量份数的原料制备而成：水性聚氨酯乳液75～85份、固化剂2～3份、增稠剂2～3份、交联剂2～3份、增粘剂1.2～1.5份、流平剂0.2～0.5份。
4.如权利要求1所述的一种薄型耐摩擦色牢度的汽车内饰革，其特征在于：所述的水性PU中间层(22)由以下质量份数的原料制备而成：水性聚氨酯乳液75～85份、增稠剂2～3份、交联剂2～3份、增粘剂0.5～1份、流平剂0.2～0.5份、固化剂0.5～1份、偶联剂4～5份，所述的偶联剂为KH-550硅烷偶联剂。
5.如权利要求1所述的一种薄型耐摩擦色牢度的汽车内饰革，其特征在于：所述的水性PU表层(23)由以下质量份数的原料制备而成：水性聚氨酯乳液75～85份、增稠剂2～3份、交联剂2～3份、增粘剂0.5～1份、流平剂0.2～0.5份、固化剂2.5～3.5份、抗紫外剂1.2～2.8份、抗静电剂0.3～0.5份、爽滑剂3.5～5.5份，所述的抗紫外剂为纳米TiO2粉与纳米ZnO粉的混合物，所述的抗静电剂为多元醇脂肪酸酯，所述的爽滑剂为道康宁DC-57有机硅聚醚共聚物。
6.如权利要求3至5中任意一项所述的一种薄型耐摩擦色牢度的汽车内饰革，其特征在于：所述的水性聚氨酯乳液由以下原料制备而成：多元醇、二异氰酸酯、亲水剂扩链剂、丙酮、中和成盐剂、扩链剂、去离子水，所述的水性聚氨酯乳液固含量为35～45％。
7.如权利要求6所述的一种薄型耐摩擦色牢度的汽车内饰革，其特征在于：所述的多元醇包括聚醚多元醇、聚酯多元醇、聚碳酸酯多元醇，所述的二异氰酸酯采用TDI、MDI、HDI、IPDI中的一种或多种，所述的亲水剂扩链剂采用DMPA，所述的中和成盐剂采用TEA，所述的扩链剂采用EDA。
8.如权利要求7所述的一种薄型耐摩擦色牢度的汽车内饰革，其特征在于：所述的聚醚多元醇、聚酯多元醇、聚碳酸酯多元醇三者的质量之比为5：3：2。
9.如权利要求3至5中任意一项所述的一种薄型耐摩擦色牢度的汽车内饰革，其特征在于：所述的增稠剂为聚氨酯类增稠剂或纤维素类增稠剂，交联剂为F-818异氰酸酯交联剂，增粘剂为萜烯树脂，流平剂为机硅聚合物或丙烯酸酯聚合物，固化剂为水性环氧树脂固化剂。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114318877A (zh) * 2022-01-25 2022-04-12 广东溢达纺织有限公司 具有仿皮革手感的织带及其制备方法
CN116144167A (zh) * 2023-03-13 2023-05-23 无锡市曼优丽新型复合材料有限公司 一种汽车内饰用的防紫外皮革及其制备工艺

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1176267C (zh) * 2002-08-30 2004-11-17 山东科特乐股份有限公司 一种超细纤维沙发革的制备方法
JP2007107112A (ja) * 2005-10-11 2007-04-26 Achilles Corp ポリプロピレン系合成皮革
CN104420283A (zh) * 2013-08-24 2015-03-18 江阴立臣实业有限公司 防辐射保暖多功能人造革
CN103255640B (zh) * 2013-04-19 2015-03-25 晋江市闽高纺织科技有限公司 一种环保阻燃聚氨酯合成革、制备方法及其制品
JP5731086B1 (ja) * 2013-06-27 2015-06-10 東洋紡株式会社 合成皮革

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1176267C (zh) * 2002-08-30 2004-11-17 山东科特乐股份有限公司 一种超细纤维沙发革的制备方法
JP2007107112A (ja) * 2005-10-11 2007-04-26 Achilles Corp ポリプロピレン系合成皮革
CN103255640B (zh) * 2013-04-19 2015-03-25 晋江市闽高纺织科技有限公司 一种环保阻燃聚氨酯合成革、制备方法及其制品
JP5731086B1 (ja) * 2013-06-27 2015-06-10 東洋紡株式会社 合成皮革
CN104420283A (zh) * 2013-08-24 2015-03-18 江阴立臣实业有限公司 防辐射保暖多功能人造革

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
代少俊等: "《涂料与黏合剂》", 31 August 2014, 江苏大学出版社 *
马兴元等: "《合成革化学与工艺学》", 30 November 2015, 中国轻工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114318877A (zh) * 2022-01-25 2022-04-12 广东溢达纺织有限公司 具有仿皮革手感的织带及其制备方法
CN116144167A (zh) * 2023-03-13 2023-05-23 无锡市曼优丽新型复合材料有限公司 一种汽车内饰用的防紫外皮革及其制备工艺

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