CN106243834B - 一种打印在棉布上不褪色的墨水及其应用方法 - Google Patents
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Abstract
本发明公开了一种打印在棉布上不褪色的墨水,采用纤维素酶对棉布进行处理,为活性染料的迅速染色创造有利条件;墨水中加入pH调节剂、分散剂和保湿剂为活性染料的高效反应提供条件;反应后迅速进行沸水处理,使沸水失活,打印颜色固定;本发明的打印在棉布上不褪色的墨水具有耐皂洗、耐摩擦、耐光,永不褪色的优点。
Description
技术领域
本发明涉及棉布印花技术领域,尤其涉及一种打印在棉布上不褪色的墨水及其应用方法。
背景技术
数码喷墨印花技术是喷墨打印在工业应用领域的一大拓展。现代计算机喷墨打印技术用于纺织品印花时,可以用各种输入手段如扫描仪、数字摄像机、数字照相机等,把需要的图案以数字式输入计算机,经过各种作图软件印花分色系统处理后,再经过计算机控制的数字喷墨印花机,直接将印花墨水喷射到各种纤维织物上,印制出所需的各种图案,这种印花技术被称为数字喷墨印花。
近年来,数码印花技术得到了迅速的发展。与传统印花相比,数码印花工艺清洁,生产过程灵活,可以进行远程定货,纳入供应链网络,是未来纺织品印花技术发展的方向。
数码印花以无接触方式将墨水准确喷印到织物的表面,因此色牢度相对较低,因此现有技术中,在对织物进行数码印花喷印之前,需要对织物进行上浆前处理,以助于染料的固色率和色牢度等问题,但是这样仍无法达到永不褪色的效果。
发明内容
为了解决背景技术中的问题,本发明提供一种打印在棉布上不褪色的墨水及其应用方法。
一种打印在棉布上不褪色的墨水,包括以下重量百分比的成分:
乙烯砜型活性染料 3-15%
表面活性剂2-5%
pH调节剂1-3%
杀菌剂 0.3-0.7%
分散剂 0.5-1%
保湿剂 8-15%
纤维素酶 2-5%
去离子水 余量。
优选的,所述的表面活性剂为壬基酚聚氧乙烯醚。
优选的,所述的杀菌剂为纳米二氧化钛。
优选的,所述的pH调节剂为碳酸钠。
优选的,所述的分散剂为TEGO Dispers 740W。
优选的,所述的保湿剂为二甘醇。
一种打印在棉布上不褪色的墨水的应用方法,包括以下步骤:
A、采用常规方法对棉布进行漂白、染色处理;
B、将棉布用清水洗净并烘干后,使用打印在棉布上不褪色的墨水进行喷印,喷印后保持15-30s;
C、将棉布放入沸水中处理3-5min,继续进行后整理等其他工序。
棉纤维是由受精胚珠的表皮细胞经伸长、加厚而成的种子纤维,不同于一般的韧皮纤维,它的主要组成物质是纤维素。
纤维素(cellulose)是由葡萄糖组成的大分子多糖。不溶于水及一般有机溶剂,是植物细胞壁的主要成分。纤维素是自然界中分布最广、含量最多的一种多糖,占植物界碳含量的50%以上。棉花的纤维素含量接近100%,为天然的最纯纤维素来源。
纤维素是植物细胞壁的主要结构成分,通常与半纤维素、果胶和木质素结合在一起,其结合方式和程度对植物源食品的质地影响很大。而植物在成熟和后熟时质地的变化则有果胶物质发生变化引起的。人体消化道内不存在纤维素酶,纤维素是一种重要的膳食纤维。自然界中分布最广、含量最多的一种多糖。
本发明的墨水在棉布上达到不褪色的染色效果的原理为:纤维素是由葡萄糖组成的大分子多糖,不溶于水及一般有机溶剂,具有较为稳定的结构,活性染料染色需要特性条件下并处理较长时间,本发明中采用纤维素酶对纤维素进行分解,由于酶是非常高效的催化剂,故纤维素的原有结构在非常短的时间内就被破坏,为活性染料的迅速染色创造有利条件,同时墨水中加入pH调节剂、分散剂和保湿剂为活性染料的高效反应提供条件。
由于纤维素酶对纤维素的分解是持续性的,必须对反应的时间和程度进行控制,防止影响棉纤维的强度和纺织性能,故本发明中对纤维素酶的浓度有严格的控制,并在染色完成后,迅速将棉纤维放入沸水中处理,一方面使纤维素酶失去活性,另一方面使打印颜色固定,防止轻微掉色。
本发明的打印在棉布上不褪色的墨水,采用纤维素酶对棉布进行处理,为活性染料的迅速染色创造有利条件;墨水中加入pH调节剂、分散剂和保湿剂为活性染料的高效反应提供条件;反应后迅速进行沸水处理,使沸水失活,打印颜色固定;本发明的打印在棉布上不褪色的墨水具有耐皂洗、耐摩擦、耐光,永不褪色的优点。
具体实施方法
实施例1
一种打印在棉布上不褪色的墨水,包括以下重量百分比的成分:
乙烯砜型活性染料 12%
表面活性剂4%
pH调节剂2%
杀菌剂 0.5%
分散剂 0.8%
保湿剂 12%
纤维素酶 3%
去离子水 余量。
所述的表面活性剂为壬基酚聚氧乙烯醚。
所述的杀菌剂为纳米二氧化钛。
所述的pH调节剂为碳酸钠。
所述的分散剂为TEGO Dispers 740W。
所述的保湿剂为二甘醇。
实施例2
一种打印在棉布上不褪色的墨水,包括以下重量百分比的成分:
乙烯砜型活性染料 3%
表面活性剂5%
pH调节剂1%
杀菌剂0.7%
分散剂 0.5%
保湿剂 15%
纤维素酶 2%
去离子水 余量。
所述的表面活性剂为壬基酚聚氧乙烯醚。
所述的杀菌剂为纳米二氧化钛。
所述的pH调节剂为碳酸钠。
所述的分散剂为TEGO Dispers 740W。
所述的保湿剂为二甘醇。
实施例3
一种打印在棉布上不褪色的墨水,包括以下重量百分比的成分:
乙烯砜型活性染料 15%
表面活性剂2%
pH调节剂3%
杀菌剂 0.3%
分散剂1%
保湿剂 8%
纤维素酶 5%
去离子水 余量。
所述的表面活性剂为壬基酚聚氧乙烯醚。
所述的杀菌剂为纳米二氧化钛。
所述的pH调节剂为碳酸钠。
所述的分散剂为TEGO Dispers 740W。
所述的保湿剂为二甘醇。
实施例4
一种打印在棉布上不褪色的墨水的应用方法,包括以下步骤:
A、采用常规方法对棉布进行漂白、染色处理;
B、将棉布用清水洗净并烘干后,使用打印在棉布上不褪色的墨水进行喷印,喷印后保持20s;
C、将棉布放入沸水中处理3.5min,继续进行后整理等其他工序。
对实施例1-3的打印在棉布上不褪色的墨水采用实施例4的工艺进行喷印,测试织物的耐皂洗色牢度、耐摩擦色牢度、耐光色牢度进行测试,结果见表1。
表1:
实施例1 | 实施例2 | 实施例3 | |
耐皂洗色牢度(50次) | 5级 | 5级 | 5级 |
耐干摩擦色牢度 | 5级 | 5级 | 5级 |
耐湿摩擦色牢度 | 5级 | 5级 | 5级 |
耐光色牢度(20h) | 5级 | 5级 | 5级 |
由测试数据可以知道,本发明制成的印花墨水,色牢度高,即使经过多次清洗,仍能不褪色、掉色,保持原有的色彩和鲜艳度。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。
Claims (6)
1.一种打印在棉布上不褪色的墨水的应用方法,其特征在于,墨水包括以下重量百分比的成分:
乙烯砜型活性染料 3-15%
表面活性剂 2-5%
pH调节剂 1-3%
杀菌剂 0.3-0.7%
分散剂 0.5-1%
保湿剂 8-15%
纤维素酶 0.5-1%
去离子水 余量;
所述的打印在棉布上不褪色的墨水的应用方法,包括以下步骤:
A、采用常规方法对棉布进行漂白、染色处理;
B、将棉布用清水洗净并烘干后,使用打印在棉布上不褪色的墨水进行喷印,喷印后保持15-30s;
C、将棉布放入沸水中处理3-5min,继续进行后整理及其他工序。
2.根据权利要求1所述的打印在棉布上不褪色的墨水的应用方法,其特征在于,所述的表面活性剂为壬基酚聚氧乙烯醚。
3.根据权利要求1所述的打印在棉布上不褪色的墨水的应用方法,其特征在于,所述的杀菌剂为纳米二氧化钛。
4.根据权利要求1所述的打印在棉布上不褪色的墨水的应用方法,其特征在于,所述的pH调节剂为碳酸钠。
5.根据权利要求1所述的打印在棉布上不褪色的墨水的应用方法,其特征在于,所述的分散剂为TEGO Dispers 740W。
6.根据权利要求1所述的打印在棉布上不褪色的墨水的应用方法,其特征在于,所述的保湿剂为二甘醇。
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CN104372686A (zh) * | 2014-08-06 | 2015-02-25 | 福建省华奇环保印花有限公司 | 四分色印花染料墨水配方、制备及其应用方法 |
CN104233825A (zh) * | 2014-09-03 | 2014-12-24 | 长兴国圆印染有限公司 | 一种环保真丝印花方法 |
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