CN106206867A - The infra red radiation light source of Sandwich-shaped superstructure and manufacture method - Google Patents

The infra red radiation light source of Sandwich-shaped superstructure and manufacture method Download PDF

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Publication number
CN106206867A
CN106206867A CN201610576033.XA CN201610576033A CN106206867A CN 106206867 A CN106206867 A CN 106206867A CN 201610576033 A CN201610576033 A CN 201610576033A CN 106206867 A CN106206867 A CN 106206867A
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metal
sandwich
red radiation
superstructure
dielectric layer
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CN106206867B (en
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张志东
闫树斌
崔建功
薛晨阳
张文栋
王瑞兵
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North University of China
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North University of China
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • H01L33/38Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2933/00Details relating to devices covered by the group H01L33/00 but not provided for in its subgroups
    • H01L2933/0008Processes
    • H01L2933/0016Processes relating to electrodes

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The invention belongs to optical field and micro-nano system regions, be specially infra red radiation light source and the manufacture method of a kind of " sandwich " type metal superstructure.The infra red radiation light source of a kind of " sandwich " type metal superstructure: include ITO/IZO substrate, pores array structural metal thin layer at deposition on substrate, dielectric layer and the rectangular-shaped metal array structure prepared on the dielectric layer.Utilize pores array feature optical exception transmission enhancement effect and the coupling of specific morphology micro-nano structure local surface plasmon resonance aerial radiation enhancement effect can strengthen the radiation of surface phasmon MEMS infrared light supply, narrowing of the adjustment to phasmon MEMS infrared source working wave band and live width can be realized by adjusting the geometric parameter of metal array and dielectric layer structure simultaneously.Relate in the present invention surpasses the metal array structure on surface based on metal and has a good extensibility, and processing technology is simply, easily realize.

Description

The infra red radiation light source of Sandwich-shaped superstructure and manufacture method
Technical field
The invention belongs to optical field and micro-nano system regions, be specially the infrared of a kind of " sandwich " type metal superstructure Radiating light source and manufacture method.
Background technology
Infra-red radiation has very important application in fields such as military affairs, medical treatment, accident search and rescue, remote sensing surveys, the reddest Outer fight mark can be effectively prevented from friendly troop in combined operation and accidentally injure;In search and rescue action, infrared id signal can Be greatly enhanced rescue and search success rate, the most infrared mark routing indicator, aircraft landing guide, ship piloting, And the Infrared Wireless Communication application aspect such as the recognition and tracking of military target has a good application prospect.Use MEMS at present Novel MEMS infra red radiation light source prepared by technique has high electric light transformation efficiency, multiband spectrum output, volume is little, work can By and the advantage such as can be mass, but, there is also live width the narrowest, wavelength selectivity is poor, grow away from defects such as detecting limitations.
Big for the live width of current MEMS infra red radiation light source, filtering property is poor, grow away from problems such as detecting limitations, the present invention carries Go out the surface phasmon enhancing MEMS infra red radiation light source being combined super surface texture based on ITO/IZO substrate " sandwich " type Structure.
Summary of the invention
The live width that the present invention is directed to current MEMS infra red radiation light source is big, filtering property is poor, grow away from problems such as detecting limitations, carries MEMS infra red radiation light source and the manufacture method of " sandwich " type metal superstructure are supplied.
The present invention adopts the following technical scheme that realization: the infra red radiation light source of " sandwich " type metal superstructure, Including ITO/IZO substrate, pores array structural metal thin layer at deposition on substrate, dielectric layer and at dielectric layer The rectangular-shaped metal array structure of upper preparation, pores array structural metal thin layer, the dielectric layer in middle level and the top of bottom The rectangular-shaped metal array structure of layer constitutes " sandwich " type metal superstructure.Utilize pores array feature optical exception transmission Enhancement effect and the coupling of rectangular-shaped metal array structure local surface plasmon resonance aerial radiation enhancement effect can show Write and strengthen the radiation of MEMS infrared light supply, can be realized by the geometric parameter of adjustment metal array and dielectric layer structure simultaneously The adjustment of MEMS infrared source working wave band and narrowing of live width.Basic functional principle is: " sandwich " type metal superstructure exists Light excites lower generation plasmon resonance, on the one hand, produce local surface phasmon under metal superstructure field excitation outside altogether Shaking and energy accumulating enhanced rad ability occurs, on the other hand, the collective of electronics shakes the heat causing ohmic loss to produce and increases Strong infra-red radiation.Use MEMS technology, utilize surface plasmon resonance structure blackbody radiation spectrum is had enhancing transmission and Characteristic is cut out in filtering, can be made into the phasmon MEMS source of infrared radiation that can launch high-performance, narrow line width regulatable.Therefore, The research work carrying out surface plasmon resonance effect enhancing MEMS infra-red radiation has very important Research Significance and dives In using value.The metal superstructure strengthening infra-red radiation based on surface phasmon is applied to strengthen infra-red radiation have very Good novelty.
The manufacture method of the infra red radiation light source of above-mentioned " sandwich " type metal superstructure, comprises the following steps:
The first step: even one layer of negative photoresist on ITO/IZO substrate;
Second step: use electron-beam exposure system that the negative photoresist on ITO/IZO substrate is exposed, and carry out developing, determining Shadow processes;
3rd step: utilize Magnetron Sputtering Thin Film depositing system to deposition on substrate metallic film;
4th step: the metal removal using Lift off technique photoresist and photoresist to be adhered to above, obtains hole on substrate Hole array structure metal film layer;
5th step: (this dielectric layer is wanted to continue to utilize chemical meteorology deposition method to grow one layer of dielectric layer on ITO/IZO substrate Light transmission is good);
6th step: the evenest one layer of positive photoetching rubber;
7th step: use alignment process the positive photoetching rubber got rid of on the dielectric layer is exposed, to develop, fixing;
8th step: utilize magnetron sputtering metal-coated films again;
9th step: utilize Lift off technique to remove the metal above photoresist and photoresist, obtain rectangular-shaped metal array Structure, finally gives " sandwich " type metal superstructure.
The present invention proposes a kind of infra red radiation light source based on surface phasmon " sandwich " type metal superstructure.Should MEMS infra red radiation light source array structure is by pores array structural metal thin layer-dielectric layer-rectangular-shaped metal array structure Composition, can realize the adjustment to MEMS infra red radiation light source service band, transmission enhancing and line under different array structure parameters Wide narrows.
Accompanying drawing explanation
Fig. 1 is the whole process flow diagram of the present invention.
Fig. 2 is the technological process design sketch of the present invention.
Fig. 3 is the sectional view of single " sandwich " type metal superstructure infra red radiation light source, in figure: 1-ITO/IZO substrate, 2-pores array structural metal thin layer, 3-dielectric layer, the rectangular-shaped metal array structure of 4-.
Fig. 4 is the structural representation of " sandwich " type metal superstructure infra red radiation light source, wherein bottom pores array knot The thickness of structure metal film layer ist, the thickness of interlayer dielectric isd, the thickness of the rectangular-shaped metal array structure of top layer ish, a length ofl, width isw, top layer cuboid metal array structure all around between distance be respectivelyP 2P 1
When Fig. 5 is for having rectangular-shaped metal array structure and metal array structure rectangular-shaped without top layer, surface etc. is from swashing Unit strengthens the resonance line of infra-red radiation metal superstructure, and result shows to increase the rectangular-shaped metal array structure of top layer can be real Now regulation and control and the enhancing of optical transmission to " sandwich " type metal superstructure infra-red radiation resonance peak position.
Fig. 6 is that the surface phasmon obtained during the thickness adjusting dielectric layer strengthens the humorous of infra-red radiation metal superstructure Shake spectral line, and result shows can realize " sandwich " type metal superstructure infra-red radiation humorous by the thickness of adjustment dielectric layer Shake the adjustment of peak position.
Fig. 7 is that the surface phasmon obtained during the thickness adjusting bottom pores array structural metal thin layer strengthens infrared The resonance line of radiation metal superstructure, result shows that the thickness increasing bottom pores array structural metal thin layer can realize " sandwich " type metal superstructure infra-red radiation work live width is narrowed, but its intensity in transmission can weaken.
Fig. 8 is that the surface phasmon obtained during the size adjusting the rectangular-shaped metal array structure of top layer strengthens infrared spoke Radioglold belongs to the resonance line of superstructure, and result shows, in the case of top layer rectangular-shaped metal structure thickness is certain, to change top Layer rectangular-shaped metal array structure area can realize the adjustment to " sandwich " type metal superstructure resonance peak position and The change of optical transmission intensity.
Fig. 9 is to adjust the surface phasmon enhancing infra-red radiation that the array period of rectangular-shaped metal array structure obtains The resonance line of metal superstructure, result shows that its transmission of increase of the array period along with rectangular-shaped metal array structure is strong Degree reduces, but transmission peaks narrows.
Detailed description of the invention
Below in conjunction with the accompanying drawings the whole machining process of the present invention is described in further detail.
With reference to figure one, figure two, the infra red radiation light source of " sandwich " type metal superstructure: include ITO/IZO substrate, at base On sheet deposition pores array structural metal (Ag) thin layer, dielectric layer and prepare on the dielectric layer rectangular-shaped Metal (Ag) array structure, pores array structural metal thin layer, the dielectric layer in middle level and the top layer of bottom rectangular-shaped Metal array structure constitutes " sandwich " type metal superstructure.Wherein the thickness of underlying metal film layer ist, interlayer dielectric Thickness bed, the thickness of top-level metallic array structure ish, single cuboid metal derby a length ofl, width isw, top layer gold Belong to array structure all around between distance be respectivelyP 2P 1.When metal superstructure parametertdlwP 1P 2In any one When individual parameter changes, surface phasmon strengthens the resonance line of infra-red radiation metal superstructure and all can become therewith Change.Therefore can by reasonably design metal superstructure parameter realize high emission performance, narrow linewidth and tunable etc. from Excimer MEMS infra red radiation light source.
Metal superstructure bottom pores array structural metal thin film layer thickness (t) regulation, whentWhen taking different values, table Face phasmon strengthens the cavity linewidth of infra-red radiation metal superstructure and can change.And along withtThe increase of numerical value, Resonance spectrum live width narrows, but its intensity in transmission weakens.
Metal superstructure dielectric layer thickness (d) regulation, whendWhen taking different values, surface phasmon strengthens infrared The resonance line of radiation metal superstructure can drift about, and along withdThe increase of numerical value, resonance line can occur blue shift.
The regulation of metal superstructure top layer rectangular-shaped metal array structure size, changes the rectangular-shaped metal array of top layer The area of structure can realize " sandwich " type metal superstructure optical transmission intensity and the adjustment of resonance peak position.
When the array period of metal superstructure changes, surface phasmon strengthens the saturating of infra-red radiation metal superstructure Penetrate intensity and resonance spectral line width changes the most therewith.Its resonance spectrum live width of array period increasing metal superstructure can narrow, But intensity in transmission can weaken.
Above-mentioned based on surface phasmon strengthen infra-red radiation " sandwich " type metal superstructure manufacture method, including with Lower step:
The first step: even one layer of negative photoresist on ITO/IZO substrate.
Second step: use electron-beam exposure system that the negative photoresist on ITO/IZO substrate is exposed, and show Shadow, fixing process.
3rd step: utilize Magnetron Sputtering Thin Film depositing system to deposition on substrate metal (Ag) thin film.
4th step: use Lift off technique by photoresist and the metal removal that adheres to above.
5th step: utilize chemical meteorology deposition method to grow one layer of dielectric layer (SiO on ITO/IZO substrate2), and carry out Annealing.
6th step: continue even one layer of positive photoetching rubber on ITO/IZO substrate.
7th step: use alignment process the positive photoetching rubber got rid of on the dielectric layer is exposed, to develop, fixing.
8th step: utilize magnetron sputtering plating (Ag) thin film again.
9th step: utilize Lift off technique to remove photoresist and metal above, obtain " sandwich " type metal superjunction Structure.
" sandwich " type metal superstructure structure, under the resonant excitation of outfield, produces in rectangular-shaped shape metal surface and has The what is called " focus " of high field local, these " focuses " make metal surpass the enhancing of surface texture infra-red radiation, on the other hand, super surface Collective's concussion of upper metal array electronics causes ohmic loss to produce heat radiation, strengthens providing extra energy for infra-red radiation Amount is supplemented.Surface plasmon resonance structure (SPR) is utilized to have enhancing transmission and filtering cutting characteristic to blackbody radiation spectrum, Can be by adjusting geometric parameter and the array period of " sandwich " type metal superstructure, it is achieved high emission performance, narrow linewidth can The phasmon MEMS infra red radiation light source of tuning.

Claims (2)

1. the infra red radiation light source of " sandwich " type metal superstructure, it is characterised in that include ITO/IZO substrate, on substrate The pores array structural metal thin layer of deposition, dielectric layer and the rectangular-shaped metal array prepared on the dielectric layer Structure.
2. the manufacture method of the infra red radiation light source of " sandwich " type metal superstructure as claimed in claim 1, its feature exists In comprising the following steps:
The first step: even one layer of negative photoresist on ITO/IZO substrate;
Second step: use electron-beam exposure system that the negative photoresist on ITO/IZO substrate is exposed, and carry out developing, determining Shadow processes;
3rd step: utilize Magnetron Sputtering Thin Film depositing system to deposition on substrate metallic film;
4th step: the metal removal using Lift off technique photoresist and photoresist to be adhered to above, obtains hole on substrate Hole array structure metal film layer;
5th step: continue to utilize chemical meteorology deposition method to grow one layer of dielectric layer on ITO/IZO substrate;
6th step: the evenest one layer of positive photoetching rubber;
7th step: use alignment process the positive photoetching rubber got rid of on the dielectric layer is exposed, to develop, fixing;
8th step: utilize magnetron sputtering metal-coated films again;
9th step: utilize Lift off technique to remove the metal above photoresist and photoresist, obtain rectangular-shaped metal array Structure, finally gives " sandwich " type metal superstructure strengthening infra-red radiation.
CN201610576033.XA 2016-07-21 2016-07-21 The infra red radiation light source and production method of Sandwich-shaped superstructure Expired - Fee Related CN106206867B (en)

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CN108107684A (en) * 2017-12-27 2018-06-01 陕西师范大学 It is a kind of regulate and control circular dichroism it is double-layer nanostructured and preparation method thereof
CN108169171A (en) * 2017-12-08 2018-06-15 苏州大学 A kind of refraction index test based on surface plasmon resonance and preparation method thereof
CN109375477A (en) * 2018-12-07 2019-02-22 中山科立特光电科技有限公司 A kind of preparation method of metal spiral micro-nano structure
CN109901258A (en) * 2019-04-04 2019-06-18 湖南大学 A kind of micro-nano integrated device of Color Full holography and preparation method thereof
CN112436287A (en) * 2020-11-30 2021-03-02 江西师范大学 Electromagnetic super-surface, preparation method thereof and nano broadband notch filter
JP2021100033A (en) * 2019-12-20 2021-07-01 国立研究開発法人物質・材料研究機構 Detection element and light emitting element for infrared light

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CN103308486A (en) * 2013-05-23 2013-09-18 中国科学院长春光学精密机械与物理研究所 Surface-plasma-based infrared photon absorption device of composite resonator
US8987754B1 (en) * 2013-09-16 2015-03-24 Sandia Corporation Highly directional thermal emitter
US11320306B2 (en) * 2014-12-23 2022-05-03 University Of Central Florida Research Foundation, Inc. Optical frequency-selective absorber-based infrared detector, methods, and applications
CN104614077A (en) * 2015-02-05 2015-05-13 电子科技大学 Optical window with high terahertz wave transmission rate and low infrared light transmission rate
CN105355703B (en) * 2015-11-18 2017-03-22 南京大学 Absorption structure of infrared quantum well photoelectric detector

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CN108169171A (en) * 2017-12-08 2018-06-15 苏州大学 A kind of refraction index test based on surface plasmon resonance and preparation method thereof
CN108169171B (en) * 2017-12-08 2020-12-25 苏州大学 Refractive index test based on surface plasmon resonance and manufacturing method thereof
CN108107684A (en) * 2017-12-27 2018-06-01 陕西师范大学 It is a kind of regulate and control circular dichroism it is double-layer nanostructured and preparation method thereof
CN108107684B (en) * 2017-12-27 2020-03-24 陕西师范大学 Double-layer nanostructure for regulating circular dichroism and preparation method thereof
CN109375477A (en) * 2018-12-07 2019-02-22 中山科立特光电科技有限公司 A kind of preparation method of metal spiral micro-nano structure
CN109901258A (en) * 2019-04-04 2019-06-18 湖南大学 A kind of micro-nano integrated device of Color Full holography and preparation method thereof
JP2021100033A (en) * 2019-12-20 2021-07-01 国立研究開発法人物質・材料研究機構 Detection element and light emitting element for infrared light
JP7450912B2 (en) 2019-12-20 2024-03-18 国立研究開発法人物質・材料研究機構 Detection element and light emitting element for infrared light
CN112436287A (en) * 2020-11-30 2021-03-02 江西师范大学 Electromagnetic super-surface, preparation method thereof and nano broadband notch filter
CN112436287B (en) * 2020-11-30 2022-07-29 江西师范大学 Electromagnetic super surface, preparation method thereof and nano broadband notch filter

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