CN107069432B - The preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser - Google Patents

The preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser Download PDF

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CN107069432B
CN107069432B CN201710472687.2A CN201710472687A CN107069432B CN 107069432 B CN107069432 B CN 107069432B CN 201710472687 A CN201710472687 A CN 201710472687A CN 107069432 B CN107069432 B CN 107069432B
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layer
preparation
difference frequency
cascade laser
quantum cascade
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CN107069432A (en
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程凤敏
张锦川
贾志伟
赵越
周予虹
刘峰奇
王利军
刘俊岐
刘舒曼
王占国
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Institute of Semiconductors of CAS
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • H01S5/34Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers
    • H01S5/3401Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers having no PN junction, e.g. unipolar lasers, intersubband lasers, quantum cascade lasers
    • H01S5/3402Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers having no PN junction, e.g. unipolar lasers, intersubband lasers, quantum cascade lasers intersubband lasers, e.g. transitions within the conduction or valence bands
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S1/00Masers, i.e. devices using stimulated emission of electromagnetic radiation in the microwave range
    • H01S1/02Masers, i.e. devices using stimulated emission of electromagnetic radiation in the microwave range solid
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • H01S5/34Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers
    • H01S5/343Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
    • H01S5/34306Structure or shape of the active region; Materials used for the active region comprising quantum well or superlattice structures, e.g. single quantum well [SQW] lasers, multiple quantum well [MQW] lasers or graded index separate confinement heterostructure [GRINSCH] lasers in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength longer than 1000nm, e.g. InP based 1300 and 1500nm lasers

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  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Optical Modulation, Optical Deflection, Nonlinear Optics, Optical Demodulation, Optical Logic Elements (AREA)
  • Semiconductor Lasers (AREA)

Abstract

A kind of preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser, includes the following steps: step 1: sequentially growing lower waveguide layer, lower optical confinement layer, the first active layer, wall, the second active layer, upper optical confinement layer and upper ducting layer on a substrate;Step 2: ducting layer in removal, it is radial on upper optical confinement layer to etch a plurality of grating downwards, form the circular grating of a binary cycle;Step 3: regrow upper ducting layer on upper optical confinement layer after etching;Step 4: etching an annular ridge structure downwards on upper ducting layer, etching depth reaches lower optical confinement layer;Step 5: semi-insulating InP:Fe is filled up in the groove of annular ridge structure after etching;Step 6: evaporation front metal electrode in the annular ridge structure of semi-insulating InP:Fe is filled up in the trench, it is gold-plated;Step 7: by substrate thinning, polishing evaporates back metal electrode at the back side of substrate;Step 8: etching metal electrode prepares second level annular surface metal grating, completes preparation.

Description

The preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser
Technical field
The present invention relates to infrared semiconductor photoelectric device technical field more particularly to a kind of annular chamber surface launching difference frequency terahertzs The hereby preparation method of quantum cascade laser.The structure is unique in that, epitaxial wafer is circularized double ditch structures, then Second level annular metal grating is made on substrate, on the one hand, substrate second level annular metal grating structure can be in entire annular chamber model Enclose the interior effective extraction for realizing terahertz light;On the other hand, the far field diverging of terahertz light can be improved.
Background technique
Wavelength be 30-300 μm between the infrared THz wave between microwave due to its special spectral position, make its Light spectrum image-forming, radio astronomy, free-space communication, medical treatment and environmental monitoring etc. have broad application prospects.At present The available high-power THz source of tradition is very limited, and some electronic devices are because by electron transit time and parasitic time constant Limitation and be difficult to make the radiation source greater than 1THz, optical device, which is limited by material forbidden bandwidth and is difficult to make, to be less than The radiation source of 10THz forms the Terahertz gap of so-called 1-10THz.Quantum cascade laser has energy band Scalability The characteristics of, so sight is targeted by quantum stage naturally by efficiently portable 1-10THz Terahertz light source, researchers in order to obtain Join laser, it is desirable to realize quantum cascade laser in the lasing of 1-10THz wave band by " cutting " of energy band.Meaning is big within 2002 Sharp scientist R ü degerEt al. successfully produced first lasing in the quantum cascade laser of terahertz wave band, Hereafter Terahertz quantum cascaded laser develops rapidly, and the high-power output for being greater than 1W under low temperature is realized by 2015, still It is increased with operating temperature, power declines quickly, cannot use at room temperature.Close coupling between quantum state in quantum cascade laser Huge nonlinear effect can be generated, theoretically second order nonlinear coefficient can reach 106pm/V, than common nonlinear crystal High four orders of magnitude, furthermore the mid-infrared light based on quantum cascade laser has been carried out the continuous high pumping function of room temperature Rate, so the Terahertz quantum cascaded laser based on the intracavitary difference frequency of middle infrared double-wave length, which becomes, realizes the most promising of room temperature Terahertz light source.M.A.Belkin of Harvard University in 2007 et al. is based on bound state using the matched mode of modal phase Double active area structures to continuous state and alliteration sub-resonance successfully develop first dual wavelength difference frequency terahertz quanta cascade laser Device, but due to second order nonlinear coefficient in practice there is no 106pm/V, in infrared multimode lasing, modal phase mismatch, it is outer Too short etc. reasons of coupling length cause the difference frequency terahertz quantum cascade laser to be not carried out ambient operation and output power Only nanowatt magnitude, by thickness of improvement doping and ducting layer etc., only with one-year age, the group is achieved that difference frequency terahertz The ambient operation of quantum cascade laser, but room temperature output power is still less than 1 μ W.Until Karun in 2012 Vijayraghavan et al. by the way of based on Cerenkov phase matched, in the transfer efficiency of infrared-Terahertz mentioned Height, delivery efficiency are also improved, the difference frequency terahertz quantum cascade laser hereafter based on Cerenkov phase matched mode It rapidly develops.It is up to currently based on the Terahertz light source pulse peak power of dual wavelength difference frequency quantum cascade laser 1.9mW is the active area structure combination Cerenkov that monophone sub-resonance is used by Northwestern Univ USA's M.Razeghi group in 2015 Phase matched scheme obtains, but its outer coupling efficiency is also only 15%, and room temperature is continuously only microwatt magnitude.By in InP Substrate, which is glued silicon strip or extracted terahertz light in the long range of entire chamber using surface two-grade grating, can be improved outer coupling efficiency, But the former substrate still cannot be thinned, device thermal diffusivity is bad, is unfavorable for realizing continuous operation, the latter far field is in ridge wide direction Diverging still can be larger.It is had reached currently based on emitting quantum cascade laser single-mode output infrared in annular chamber 400mW improves far field diverging, this patent based on the small advantage of annular chamber far-field divergence angle in order to improve outer coupling efficiency simultaneously It proposes the effective extraction for realizing terahertz light using annular chamber surface launching mechanism while improving the diverging of its far field.
Summary of the invention
The various problems for causing the outer coupling efficiency of terahertz light lower in summary, this patent propose a kind of annular Cavity surface The preparation method for emitting difference frequency terahertz quantum cascade laser can be improved its outer coupling efficiency and realize the effective of terahertz light It extracts.Structure single mode infrared first in upper ducting layer production first-order optical grating is realized, it is double to do circlewise ridged for epitaxial wafer Ditch structure extracts on the face that substrate production realizes terahertz light for the secondary surface metal grating of terahertz light, makes simultaneously The far-field divergence angle of device reduces.
The present invention provides a kind of preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser, including as follows Step:
Step 1: lower waveguide layer, lower optical confinement layer, the first active layer, wall, second are sequentially grown on a substrate Active layer, upper optical confinement layer and upper ducting layer;
Step 2: ducting layer in removal, it is radial on upper optical confinement layer to etch a plurality of grating downwards, form one The circular grating of binary cycle;
Step 3: regrow upper ducting layer on upper optical confinement layer after etching;
Step 4: etching an annular ridge structure downwards on upper ducting layer, etching depth reaches lower optical confinement layer;
Step 5: semi-insulating InP:Fe is filled up in the groove of annular ridge structure after etching;
Step 6: evaporation front metal electrode in the annular ridge structure of semi-insulating InP:Fe is filled up in the trench, it is gold-plated;
Step 7: by substrate thinning, polishing evaporates back metal electrode at the back side of substrate;
Step 8: etched backside metal electrode prepares second level annular surface metal grating, completes preparation.
The beneficial effects of the present invention are:
1, terahertz light is extracted in substrate surface production second level metal grating using annular chamber, it can be along entire chamber Terahertz light is extracted in face can effectively improve outer coupling efficiency.
2, substrate is avoided using production second level metal grating structure on substrate and polishes 20-30 ° of angle bring substrate not Device heat dissipation problem caused by capable of being thinned, the heat dissipation for being conducive to device mutually compatible with device inverse bonding technique improve the continuous function of room temperature Rate, while improving device and being dissipated in the far field of ridge wide direction.
Detailed description of the invention
Feature and effect in order to further illustrate the present invention do more into one the present invention below with reference to examples and drawings The explanation of step, in which:
Fig. 1 is preparation flow figure of the invention;
Fig. 2 is structural schematic diagram of the invention.
Specific embodiment
As shown in Figs.1 and 2, the present invention provides a kind of annular chamber surface launching difference frequency terahertz quantum cascade laser Preparation method, include the following steps:
Step 1: sequentially grown on a substrate 1 lower waveguide layer 2, lower optical confinement layer 3, the first active layer 4, wall 5, Second active layer 6, upper optical confinement layer 7 and upper ducting layer 8, the material of the substrate 1 are the semi-insulating InP of n-type doping, institute The material for the lower waveguide layer 2 stated is the InGaAs of n-type doping, and the material of the lower light limiting layer 3 is the InP of n-type doping, institute The first active layer 4 and the second active layer 6 stated are made of the InGaAs/InAlAs Quantum Well in 20-40 period, this is first active Layer 4 and the corresponding wavelength of the second active layer 6 are 7-11 μm, and the material of the wall 5 is the InGaAs of n-type doping, described The material of upper optical confinement layer 7 is the InGaAs of n-type doping, and the material of the upper ducting layer 8 is the InP of n-type doping.;
Step 2: ducting layer 8 in removal, it is radial on upper optical confinement layer 7 to etch a plurality of grating, preparation one downwards A structure circular grating with binary cycle, the circular grating of the binary cycle are in order to purify wavelength infrared in two, in turn The THz wave that single mode can be obtained, compared with vertical bar type, theoretically two middle infrared waves do not have chamber in annular optical grating construction Area loss, threshold current density is lower, can reduce power consumption;
Step 3: regrow upper ducting layer 8 on upper optical confinement layer 7 after etching, forms the optical grating construction, The material of optical grating construction is InGaAs/InP, which has level-one distributed feedback structure, two periods point of the grating The not other wavelength combination first-order optical grating formula as corresponding to two active layers: λ=2neffΛIt determines, the material of the upper ducting layer 8 For the InP of n-type doping;
Step 4: etching an annular ridge structure downwards on upper ducting layer 8, etching depth reaches lower optical confinement layer 3;
Step 5: semi-insulating InP:Fe is filled up in the groove of annular ridge structure after etching, filling up semi-insulating InP:Fe is In order to which device can preferably radiate;
Step 6: filling up evaporation front metal electrode 9 in the annular ridge structure of semi-insulating InP:Fe, gold-plated, plating in the trench Gold is the heat dissipation characteristics in order to further improve device;
Step 7: substrate 1 being thinned, is polished, evaporates back metal electrode 10 at the back side of substrate 1, substrate 1, which is thinned, also to be had Conducive to the heat dissipation of device;
Step 8: etching metal electrode prepares second level annular metal grating, the second level annular metal grating is by gold Category/air composition, which is Ti/Au, and the period of the second level annular metal grating is by formula:ΛgTHz/(nInP·cos θc) determine, λTHzFor Terahertz wavelength, nInPRefractive index for THz wave in substrate, θcFor Cerenkov radiation angle, system is completed It is standby.The purpose for preparing the two-grade grating is to realize that the substrate of Terahertz goes out light.
Compared with existing difference frequency terahertz quantum cascade laser source, the present invention is had the advantage that
One, substrate goes out light, does not influence the thinned of device, polishing and inverse bonding technique, is conducive to the heat dissipation of device;And it adopts at present The device of 20 ° of -30 ° of light extraction modes is polished with substrate in order to which the more terahertz light substrates of coupling as outer as possible not will do it generally It is thinned, seriously hinders the heat dissipation of device, be unfavorable for the raising of device performance.Structure of the present invention it is possible to prevente effectively from This problem.
Two, surface two-grade grating can extract terahertz light along entire device architecture, and terahertz light is with Cerenkov circular cone To external radiation, the light for extracting only 50% from one side can be collected, and consider further that the coupling efficiency of two-grade grating is 80%- 90%, theoretically the outer coupling efficiency of terahertz light can reach 40%-45%;And current difference frequency terahertz quantum cascade laser Outer coupling efficiency too it is low be also cause its output power lower one of reason, [Lu Q, Razeghi reported at present M.Recent advances in room temperature, high-power terahertz quantum cascade laser sources based on difference-frequency generation[C]/ Photonics.Multidisciplinary Digital Publishing Institute, 2016,3 (3): 42.] highest The pulse power peak value of difference frequency terahertz quantum cascade laser is 1.9mW, and room temperature continuous power is 14 μ W, but described in it Outer coupling efficiency is also only 15%.In terms of international development trend, everybody accepts difference frequency terahertz quanta cascade substantially at present Laser is that thz laser Material Field 1THz frequencies above uniquely being capable of the continuously adjustable electric pump semiconductor of working and room temperature THz source, so any its outer coupling efficiency and the structure of output power of can be improved all is worth studied.The present invention provides Structural theory on the outer coupling efficiency of terahertz light can be improved to 40%-45%, terahertz light can be effectively improved Photoelectric conversion efficiency.
Three, what annular light-emitting window in surface of the present invention can be done is wider much larger than Terahertz wavelength, such one side Terahertz Wave will not be leaked from two sides, on the other hand can be improved the far field diverging of device, be improved the beam quality of terahertz light.
So far, attached drawing comparative illustration advantage of the invention is had been combined.According to above description, those skilled in the art are answered When having clear understanding to a kind of annular chamber surface launching difference frequency terahertz quantum cascade laser structure of the present invention.
To the purpose of the present invention, technical solution and have according to structure of the invention described in claims, and below Beneficial effect has been further described, it should be understood that being only of the invention substantially real described in following claims Example is applied, is not intended to restrict the invention, all within the spirits and principles of the present invention, any modification for being made equally is replaced It changes, improve, should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser, includes the following steps:
Step 1: lower waveguide layer, lower optical confinement layer, the first active layer, wall, second active is sequentially grown on a substrate Layer, upper optical confinement layer and upper ducting layer;
Step 2: ducting layer in removal, it is radial on upper optical confinement layer to etch a plurality of grating downwards, form a double week The circular grating of phase;
Step 3: regrow upper ducting layer on upper optical confinement layer after etching;
Step 4: etching an annular ridge structure downwards on upper ducting layer, etching depth reaches lower optical confinement layer;
Step 5: semi-insulating InP:Fe is filled up in the groove of annular ridge structure after etching;
Step 6: evaporation front metal electrode in the annular ridge structure of semi-insulating InP:Fe is filled up in the trench, it is gold-plated;
Step 7: by substrate thinning, polishing evaporates back metal electrode at the back side of substrate;
Step 8: etched backside metal electrode prepares second level annular surface metal grating, completes preparation.
2. the preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser according to claim 1, wherein institute The material for the substrate stated is semi-insulating InP.
3. the preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser according to claim 1, wherein institute The material for the lower waveguide layer stated is the InGaAs of n-type doping.
4. the preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser according to claim 1, wherein institute The material for the lower optical confinement layer stated is the InP of n-type doping.
5. the preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser according to claim 1, wherein institute The first active layer and the second active layer stated are made of the InGaAs/InAlAs Quantum Well in 20-40 period, first active layer Wavelength corresponding with the second active layer is 7-11 μm.
6. the preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser according to claim 1, wherein institute The material for stating wall is the InGaAs of n-type doping.
7. the preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser according to claim 1, wherein institute The material for the upper optical confinement layer (7) stated is the InGaAs of n-type doping, described to prepare on upper optical confinement layer (7) Optical grating construction be InGaAs/InP, the optical grating construction have level-one distributed feedback structure.
8. the preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser according to claim 1, wherein institute The material for the upper ducting layer stated is the InP of n-type doping;The material of the front metal electrode is Au/Ge/Ni/Au.
9. the preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser according to claim 1, wherein institute The material for the back metal electrode stated is Ti/Au.
10. the preparation method of annular chamber surface launching difference frequency terahertz quantum cascade laser according to claim 1, wherein institute The second level annular metal grating stated is made of metal/air, which is Ti/Au, the period of the second level annular metal grating By formula: ΛgTHz/(nInP·cosθc) determine, wherein λTHzFor Terahertz wavelength, nInPFor THz wave substrate refraction Rate, θcFor Cerenkov radiation angle.
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CN108923258B (en) * 2018-07-12 2020-11-03 华南师范大学 Design method of trap type double-phonon active region energy level structure in terahertz quantum cascade laser
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