CN106187324B - A kind of Imitation Rock Porcelain Tiles and preparation method thereof with three-dimensional decorative effect - Google Patents

A kind of Imitation Rock Porcelain Tiles and preparation method thereof with three-dimensional decorative effect Download PDF

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CN106187324B
CN106187324B CN201510217641.7A CN201510217641A CN106187324B CN 106187324 B CN106187324 B CN 106187324B CN 201510217641 A CN201510217641 A CN 201510217641A CN 106187324 B CN106187324 B CN 106187324B
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porcelain tiles
imitation rock
rock porcelain
fabric
starch adhesive
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CN106187324A (en
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余爱民
夏昌奎
甄燕萍
樊叶利
余剑峰
余惠
朱爱余
曹承鑫
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DEQING NABEL CERAMIC Co Ltd
JIUJIANG NABEL CERAMIC Co Ltd
HANGZHOU NABEL CERAMIC CO Ltd
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DEQING NABEL CERAMIC Co Ltd
JIUJIANG NABEL CERAMIC Co Ltd
HANGZHOU NABEL CERAMIC CO Ltd
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Abstract

The Imitation Rock Porcelain Tiles and preparation method thereof with three-dimensional decorative effect that the invention discloses a kind of, comprising the following steps: (1) prepare Imitation Rock Porcelain Tiles green body powder according to a conventional method;(2) Imitation Rock Porcelain Tiles fabric is prepared;(3) Imitation Rock Porcelain Tiles body preparation;(4) body drying;(5) starch adhesive A is drenched;(6) fabric B is printed;(7) it is dried after applying cloth fabric;(8) spray infiltration ink;(9) it is burnt into;(10) edging.The beneficial effects of the invention are as follows cost increases caused by solving starch adhesive in the prior art and assistant toner dosage greatly, pattern texture lacks the problem of solid grain expression, it solves the show-through inaesthetic technical problem of the deep processings such as existing ceramic brick with permeated pattern fluting, chamfering simultaneously, provides a kind of preparation method of the richer Imitation Rock Porcelain Tiles of more environmentally friendly economy, decorative effect.

Description

A kind of Imitation Rock Porcelain Tiles and preparation method thereof with three-dimensional decorative effect
Technical field
The present invention relates to architectural pottery technical field, more particularly to a kind of Imitation Rock Porcelain Tiles with three-dimensional decorative effect and its Preparation method.
Background technique
Currently, seeping flower porcelain brick product is to achieve the effect that imitation natural stone line or wood grain, " seeping flower " polishing skill is generallyd use Art, and experienced in terms of seeping flower process from the infiltration that silk-screen printing includes soluble-salt and spend liquid to the upgrading of spray infiltration ink.In State patent CN102795892B describes a kind of infiltration flower Imitation Rock Porcelain Tiles and its production method, throws face by drenching porcelain in green body layer surface On the one hand the penetration depth for seeping flower salt can be down to 0.3 ~ 0.5mm from 2 ~ 3mm of traditional pattern permeating tile, expand and seeped flower salt by slurry Using type, pattern is enriched;On the other hand the grinding thichness for reducing polishing process, reduces waste material yield.Assistant toner The use of cooperation ink-jet infiltration ink has been obviously improved the color saturation and lightness of decorative pattern, and clean mark is fine and smooth.However, Single use ink-jet realizes that imitation natural stone line or wood grain make the decoration of ceramic tile be only limited to planar scale, for stone pattern or wood But it is short of the expression of stereoscopic level in the gully of hole and fluctuating in line.In addition, starch adhesive, which is all made of multiple tracks glaze pouring, applies cloth, face It is larger to starch dosage, and the assistant toner of the higher cost accordingly introduced is also on the high side, causes the rising of production cost.
Summary of the invention
Present invention aim to address starch adhesive in the prior art and assistant toner dosage higher cost caused greatly, pattern textures The problem of lacking solid grain expression, provide a kind of preparation method of the richer Imitation Rock Porcelain Tiles of more environmentally friendly economy, decorative effect.
It is a further object of the present invention to provide the Imitation Rock Porcelain Tiles with three-dimensional decorative effect with this method preparation.
The technical scheme is that a kind of preparation method of the Imitation Rock Porcelain Tiles with three-dimensional decorative effect, including following step It is rapid:
(1) Imitation Rock Porcelain Tiles green body powder is prepared according to a conventional method, it is spare;
(2) Imitation Rock Porcelain Tiles fabric is prepared, the Imitation Rock Porcelain Tiles fabric of use is divided into starch adhesive A and two kinds of fabric B, starch adhesive A and fabric B's Siccative chemical composition is consistent, similar to green body powder in step (1), but wherein K2O+Na2O:6 ~ 8%, impurity≤4%(are weight Percentage);The siccative of starch adhesive A and starch adhesive B are all made of feldspar poor material and kaolin families plastic raw material carries out ingredient, two kinds of faces It is 325 mesh sieve margins within 0.5% that the slurry of material, which controls fineness, and specific gravity is 1.60 ~ 1.90g/cm3, wherein starch adhesive A's is dry Material and auxiliary additive wet ball grinding apply the slurry of performance requirement at satisfaction leaching, and the siccative and auxiliary additive of fabric B is wet Method ball milling is dried after meeting size performance requirement, and dry powder is made in 800 DEG C ~ 1000 DEG C calcinings, and mixes with stamp-pad ink, auxiliary additive Preparation meets the printing fabric of printing performance, spare;
(3) Imitation Rock Porcelain Tiles body preparation: by Imitation Rock Porcelain Tiles green body powder obtained in step (1) according to designed pattern line Reason carries out multitube cloth, cloth is then spread in brick machine die cavity, under the pressure of 20 ~ 50MPa, by Imitation Rock Porcelain Tiles green body powder pressure Imitation Rock Porcelain Tiles green compact are made;
(4) body drying: Imitation Rock Porcelain Tiles green compact prepared by step (3) are dried at 150 ~ 300 DEG C in dry kiln;
(5) it drenches starch adhesive A: the Imitation Rock Porcelain Tiles starch adhesive A of step (2) preparation is applied into the Imitation Rock Porcelain Tiles life of cloth after the drying with glaze pouring Base surface, the weight of the applied starch adhesive of unit area are 400 ~ 800g/m2
(6) it prints fabric B: Imitation Rock Porcelain Tiles fabric B prepared by step (2) being applied into cloth with printing technology and was drenching starch adhesive A's Billet surface;
(7) it is dried after applying cloth fabric: the Imitation Rock Porcelain Tiles green compact for applying fabric is dried at 150 ~ 300 DEG C in dry kiln again It is dry;
(8) it spray infiltration ink: is sprayed on Imitation Rock Porcelain Tiles green body, is cooperated by designed pattern using Digital ink-jet printer Blank pattern texture, so that brick body surface and green body have similar texture and quality;
(9) it is burnt into: the Imitation Rock Porcelain Tiles green compact that step (8) is jetted through infiltration ink being placed in roller kilns and are burnt using conventional Imitation Rock Porcelain Tiles At temperature schedule, pressure regime and atmosphere system, once-firing, firing temperature is 1150 ~ 1250 DEG C, firing period is 40 ~ Imitation Rock Porcelain Tiles semi-finished product are made in 90min;
(10) edging: using conventional edging process equipment, double of finished bricks carries out edging processing, and being made has three-dimensional dress Adorn the Imitation Rock Porcelain Tiles finished product of effect.
It is all not add special instruction in above step, all use conventional control means in the prior art.
To complete second goal of the invention, using the porcelain with three-dimensional decorative effect by above-mentioned steps preparation Brick.
Contain kaolin families plastic raw material in the formula of the prior art, printing fabric is directly prepared into, easily because of plasticity Raw material sticky net and influence printing performance, in step (2) of the present invention will starch adhesive A it is dry after calcine, can effectively reduce starch adhesive A's The plasticity of plastic raw material, preferably solves problems in siccative.
Great soil group raw material and suitable water form walk after being kneaded, and this walk generates deformation under the action of certain external force But it does not crack, after external force is removed, is still able to maintain its shape invariance, this property is known as plasticity.The height that the present invention uses Ridge great soil group raw material belongs to double-layer structure silicate mineral from structure, crystallization, and each layer crystal series of strata are by one layer of oxygen-octahedron It is linked together with one layer of alumina octahedral by shared oxygen atom, and adjacent two crystal layer passes through octahedral hydroxyl and another The tetrahedral oxygen of layer is associated with hydrogen bond, thus the binding force between them is weaker, and stratification is easily cracked and slides, due to moisture The wedge of son, which splits effect, so that particle is destroyed, and increase specific surface area, and oxygen and hydroxyl can be with the water by near surface on particle surface Molecule is bonded by hydrogen bond.Kaolin families raw particles (referred to as " great soil group particle ") surface negative charge has one in its vicinity Electrostatic field aligns polar water molecules, and great soil group particle surface adsorbs the hydrone aligned from level to level, and formation has The great soil group particle of hydration shell, adjacent great soil group particle are combined by the hydrogen bond action of hydration shell, finally show great soil group raw material Plasticity.
And after being calcined to the fabric containing great soil group raw material, the hydroxyl in kaolin families raw material mix is due to heating power work With departing from the constraint of original structure bonding force, two hydroxy combinings become a hydrone discharge, leave an oxygen atom, make It obtains constitution water gradually to remove, destroys the original structure of great soil group particle, and great soil group raw material shows the architectural source of plasticity just It is that the oxygen on particle surface can be bonded with the hydrone by near surface by hydrogen bond with hydroxyl, so by calcined Great soil group particle can not be bonded with the hydrone by near surface by hydrogen bond again, and hydration shell can not be formed, and reduce great soil group afterwards The plasticity of raw material.
It include auxiliary colorant ZnO, TiO in the auxiliary additive of fabric B in step (2)2One of or a variety of, starch adhesive ZnO, TiO are not included in the auxiliary additive of A2Etc. auxiliary colorants.
As further technical solution, the auxiliary additive additive amount of fabric B is calculated as in step (2) with fabric siccative ZnO is 0.2 ~ 1%, TiO2It is 0.2 ~ 5%.
As further technical solution, silk-screen printing or glue roller printing is can be used in the printing surface sizing process in step (6).
As further technical solution, ink-jet surface thickness is 0.3 ~ 1.0mm in step (8).
Polishing or soft throwing process can be used after the processing of step (10) edging as further technical solution.If right Imitation Rock Porcelain Tiles surface prepared by the present invention is processed by shot blasting, can be obtained a kind of with the ceramic polished of three-dimensional decorative effect Brick.It is handled according to soft throwing, that is, obtains a kind of porcelain matt brick with three-dimensional decorative effect.
Compared with the prior art of the reports such as patent document CN102795892B, the present invention has following several respects advantage:
1, material is saved
The prior art is to reach suitable surface thickness, the technique for mostly using the identical starch adhesive of leaching twice in actual operation, And a certain proportion of auxiliary colorant is introduced in starch adhesive, to cooperate subsequent ink-jetting pattern, enhance the hair color effect of ink. Different, the present invention applies in first of starch adhesive A of cloth and does not add ZnO, TiO2Etc. auxiliary colorants, with prior art phase Than reducing the dosage of auxiliary colorant, reducing production cost.The second fabric that the present invention applies cloth does not use leaching starch adhesive then Technique, but dried after the siccative of fabric B and auxiliary additive wet ball grinding are met size performance requirement, it is made after calcining dry Powder, and the printing fabric for meeting printing performance is mixed with stamp-pad ink, auxiliary additive, fabric B is printed by the way of printing The billet surface for having drenched starch adhesive A is brushed, leaching starch adhesive compared with prior art, fabric B can be greatly reduced using printing technology Precoat thickness saves the dosage of starch adhesive.
2, loss is reduced
The leaching starch adhesive process of the prior art, starch adhesive Chang Yin are trapped in recovering tray or are adhered in conveyor belt and cause to waste And loss, waste are about 20% or so of starch adhesive total amount, and the present invention when applying cloth second fabric using printer Skill, then can substantially reduce the waste of fabric, and fabric utilization rate is up to 95% or more.
3, texture-rich
Existing ink-jet seeps flower Imitation Rock Porcelain Tiles and generally uses pure color green body, and texture is only limitted to the ink-jetting pattern of billet surface, decoration Effect is dull, and the present invention forms certain decoration line by the way that green body powder is carried out multitube cloth by designed pattern texture Road, and digital ink-jet infiltration technology is combined, so that incrustation and green body texture organically combine, greatly enrich conventional ink-jet infiltration The decorative effect of flower Imitation Rock Porcelain Tiles.
Existing ink-jet seeps flower Imitation Rock Porcelain Tiles using leaching twice starch adhesive technique, and starch adhesive all covers billet surface, can only be simple Supporting body of the ground as subsequent i alphakjet pattern, starch adhesive layer are confined to two-dimension plane structure, it is difficult to realize the decoration effect of stereo concave-convex Fruit.And the present invention can realize different lines textures using printing web process as needed, really realize that point-line-face is more Kind the texture even combination of Z-Correct bump mapping Z-correct.
In addition, the present invention prints web process can print using part is uneven.Due to common printed glaze fire degree is lower, The lines of printing easily melt, and have Self-leveling effect, and filament texture is easily filled and led up because glaze melts, so that printing lines are confined to Thick line texture, decoration texture are not fine and smooth enough.Compared with common printed glaze, the fiery degree of fabric of the present invention is high, glass phase is few, does not have Have a temperature flowing of common glaze, thus a printable stria, stria since fiery degree height will not soften collapsing in firing, And remain to after firing processing, therefore decoration texture is finer and smoother, and the ditch of stereoscopic three-dimensional level can be formed after firing processing The hole of gully and a small amount of uneven distribution, to more realistically reproduce the crackle of lithotome and the sagging line of stomata or wood grain Road and hole etc..
Compared with prior art, present invention beneficial effect obtained is that solve starch adhesive in the prior art and assistant toner use The problem of higher cost caused by amount is big, pattern texture lacks solid grain expression, while solving existing ceramic brick with permeated pattern and opening The show-through inaesthetic technical problem of the deep processings such as slot, chamfering.Printing fabric mode has not only significantly saved the consume of fabric dosage, drop Low production cost, while fabric Gao Huodu property still to be able to maintain original lines texture after burning, and realizes 3 D stereo level Decorative effect, matched with green body entire body cloth texture, realize the reproduction true to nature of stone pattern or wood texture.
Specific embodiment
Embodiment 1
(1) Imitation Rock Porcelain Tiles green body powder is prepared according to a conventional method, and it is spare to deploy 4 kinds of color powders;
(2) prepare Imitation Rock Porcelain Tiles fabric, fabric A and fabric B be all made of feldspar poor material and kaolin families plastic raw material into Row ingredient, but auxiliary colorant is introduced in fabric B, wet ball grinding, it is 325 mesh sieve margins that the slurry of two kinds of fabrics, which controls fineness, Within 0.5%, specific gravity 1.8g/cm3, wherein the siccative of starch adhesive A and auxiliary additive wet ball grinding are applied performance at satisfaction leaching and are wanted The slurry asked, the siccative and auxiliary additive wet ball grinding of fabric B are dried after meeting size performance requirement, 800 DEG C of calcinings Dry powder is made, and is mixed with the printing fabric for meeting printing performance with stamp-pad ink, auxiliary additive, it is spare.The change of two kinds of fabrics Learning compositing range is (parts by weight): SiO2: 62%, Al2O3: 19%, MgO+CaO:2.0%, K2O+Na2O:7%, surplus are impurity, face Additional ZnO 0.9%, TiO are also needed in material B2 4%。
(3) Imitation Rock Porcelain Tiles body preparation: by Imitation Rock Porcelain Tiles green body powder obtained in step (1) according to designed pattern line Reason, carry out multitube cloth, then spread cloth in brick machine die cavity, under the pressure of 30MPa, by Imitation Rock Porcelain Tiles green body powder pressing at Imitation Rock Porcelain Tiles green compact;
(4) Imitation Rock Porcelain Tiles green compact prepared by step (3) are dried at 150 DEG C in dry kiln;
(5) it drenches starch adhesive A: the Imitation Rock Porcelain Tiles starch adhesive A of step (2) preparation is applied into the Imitation Rock Porcelain Tiles life of cloth after the drying with glaze pouring Base surface, the weight of the applied starch adhesive of unit area are 400g/m2
(6) it prints fabric B: Imitation Rock Porcelain Tiles fabric B prepared by step (2) being applied into cloth with silk-screen printing technique and was drenching starch adhesive The billet surface of A;
(7) it is dried after applying cloth fabric: the Imitation Rock Porcelain Tiles green compact for applying fabric is dried at 200 DEG C in dry kiln again;
(8) it spray infiltration ink: is sprayed on Imitation Rock Porcelain Tiles green body, is cooperated by designed pattern using Digital ink-jet printer Blank pattern texture, so that brick body surface and green body have similar texture and quality, ink jet layer is with a thickness of 0.5mm;
(9) it is burnt into: the Imitation Rock Porcelain Tiles green compact that step (8) is jetted through infiltration ink being placed in roller kilns and are burnt using conventional Imitation Rock Porcelain Tiles At temperature schedule, pressure regime and atmosphere system, once-firing, firing temperature is 1170 DEG C, firing period 80min, is made Imitation Rock Porcelain Tiles semi-finished product;
(10) edging: using conventional edging process equipment, double of finished bricks carries out edging processing, that is, obtaining one kind has The Imitation Rock Porcelain Tiles finished product of the natural surface of three-dimensional decorative effect.
Embodiment 2
(1) Imitation Rock Porcelain Tiles green body powder is prepared according to a conventional method, and it is spare to deploy 5 kinds of color powders;
(2) prepare Imitation Rock Porcelain Tiles fabric, fabric A and fabric B be all made of feldspar poor material and kaolin families plastic raw material into Row
Ingredient, but auxiliary colorant is introduced in fabric B, wet ball grinding, it is 325 mesh that the slurry of two kinds of fabrics, which controls fineness, Screen over-size is within 0.5%, specific gravity 1.7g/cm3, wherein the siccative of starch adhesive A and auxiliary additive wet ball grinding are applied at leaching is met The slurry of performance requirement, the siccative and auxiliary additive wet ball grinding of fabric B are dried after meeting size performance requirement, and 900 Dry powder is made in DEG C calcining, and the printing fabric for meeting printing performance is mixed with stamp-pad ink, auxiliary additive, spare.Two kinds of faces The chemical composition range of material is (parts by weight): SiO2: 64%, Al2O3: 17%, MgO+CaO:2.0%, K2O+Na2O:6%, surplus are miscellaneous Matter also needs additional ZnO 0.4%, TiO in fabric B2 2%。
(3) Imitation Rock Porcelain Tiles body preparation: by Imitation Rock Porcelain Tiles green body powder obtained in step (1) according to designed pattern line Reason, carry out multitube cloth, then spread cloth in brick machine die cavity, under the pressure of 50MPa, by Imitation Rock Porcelain Tiles green body powder pressing at Imitation Rock Porcelain Tiles green compact;
(4) Imitation Rock Porcelain Tiles green compact prepared by step (3) are dried at 300 DEG C in dry kiln;
(5) it drenches starch adhesive A: the Imitation Rock Porcelain Tiles starch adhesive A of step (2) preparation is applied into the Imitation Rock Porcelain Tiles life of cloth after the drying with glaze pouring Base surface, the weight of the applied starch adhesive of unit area are 800g/m2
(6) it prints fabric B: Imitation Rock Porcelain Tiles fabric B prepared by step (2) being applied into cloth with silk-screen printing technique and was drenching starch adhesive The billet surface of A;
(7) it is dried after applying cloth fabric: the Imitation Rock Porcelain Tiles green compact for applying fabric is dried at 200 DEG C in dry kiln again;
(8) it spray infiltration ink: is sprayed on Imitation Rock Porcelain Tiles green body, is cooperated by designed pattern using Digital ink-jet printer Blank pattern texture, so that brick body surface and green body have similar texture and quality, ink jet layer is with a thickness of 0.9mm;
(9) it is burnt into: the Imitation Rock Porcelain Tiles green compact that step (8) is jetted through infiltration ink being placed in roller kilns and are burnt using conventional Imitation Rock Porcelain Tiles At temperature schedule, pressure regime and atmosphere system, once-firing, firing temperature is 1210 DEG C, firing period 58min, is made Imitation Rock Porcelain Tiles semi-finished product;
(10) edging and polishing: using conventional edging process equipment, double of finished bricks carries out edging processing, then to porcelain Brick surface is processed by shot blasting, that is, obtains a kind of polished brick in porcelain character finished product with three-dimensional decorative effect.
Embodiment 3
(1) Imitation Rock Porcelain Tiles green body powder is prepared according to a conventional method, and it is spare to deploy 3 kinds of color powders;
(2) prepare Imitation Rock Porcelain Tiles fabric, fabric A and fabric B be all made of feldspar poor material and kaolin families plastic raw material into Row ingredient, but auxiliary colorant is introduced in fabric B, wet ball grinding, it is 325 mesh sieve margins that the slurry of two kinds of fabrics, which controls fineness, Within 0.5%, specific gravity 1.9g/cm3, wherein the siccative of starch adhesive A and auxiliary additive wet ball grinding are applied performance at satisfaction leaching and are wanted The slurry asked, the siccative and auxiliary additive wet ball grinding of fabric B are dried after meeting size performance requirement, 1000 DEG C of calcinings Dry powder is made, and is mixed with the printing fabric for meeting printing performance with stamp-pad ink, auxiliary additive, it is spare.The change of two kinds of fabrics Learning compositing range is (parts by weight): SiO2: 60%, Al2O3: 20%, MgO+CaO:2.0%, K2O+Na2O:8%, surplus are impurity, face Additional ZnO 0.6%, TiO are also needed in material B2 5%。
(3) Imitation Rock Porcelain Tiles body preparation: by Imitation Rock Porcelain Tiles green body powder obtained in step (1) according to designed pattern line Reason, carry out multitube cloth, then spread cloth in brick machine die cavity, under the pressure of 40MPa, by Imitation Rock Porcelain Tiles green body powder pressing at Imitation Rock Porcelain Tiles green compact;
(4) Imitation Rock Porcelain Tiles green compact prepared by step (3) are dried at 220 DEG C in dry kiln;
(5) it drenches starch adhesive A: the Imitation Rock Porcelain Tiles starch adhesive A of step (2) preparation is applied into the Imitation Rock Porcelain Tiles life of cloth after the drying with glaze pouring Base surface, the weight of the applied starch adhesive of unit area are 600g/m2
(6) it prints fabric B: Imitation Rock Porcelain Tiles fabric B prepared by step (2) being applied into cloth with roller printing technique and was drenching starch adhesive The billet surface of A;
(7) it is dried after applying cloth fabric: the Imitation Rock Porcelain Tiles green compact for applying fabric is dried at 300 DEG C in dry kiln again;
(8) it spray infiltration ink: is sprayed on Imitation Rock Porcelain Tiles green body, is cooperated by designed pattern using Digital ink-jet printer Blank pattern texture, so that brick body surface and green body have similar texture and quality, ink-jet surface thickness is 0.3mm;
(9) it is burnt into: the Imitation Rock Porcelain Tiles green compact that step (8) is jetted through infiltration ink being placed in roller kilns and are burnt using conventional Imitation Rock Porcelain Tiles At temperature schedule, pressure regime and atmosphere system, once-firing, firing temperature is 1230 DEG C, firing period 50min, is made Imitation Rock Porcelain Tiles semi-finished product;
(10) edging and soft throwing: using conventional edging process equipment, double of finished bricks carries out edging processing, then to porcelain Brick surface carries out soft throwing processing, that is, obtains a kind of porcelain matt brick finished product with three-dimensional decorative effect.
The above embodiments are merely illustrative of the technical scheme of the present invention and are not intended to be limiting thereof, although referring to preferred embodiment pair The present invention is described in detail, those of ordinary skills in the art should understand that.It still can be to the specific reality of invention The mode of applying is modified or some technical features can be equivalently replaced, without departing from the spirit of the technical scheme of the invention, It should all cover within the scope of the technical scheme claimed by the invention.

Claims (7)

1. a kind of preparation method of the Imitation Rock Porcelain Tiles with three-dimensional decorative effect, it is characterised in that it the following steps are included:
(1) Imitation Rock Porcelain Tiles green body powder is prepared according to a conventional method, it is spare;
(2) Imitation Rock Porcelain Tiles fabric is prepared, the Imitation Rock Porcelain Tiles fabric of use is divided into starch adhesive A and two kinds of fabric B, the siccative of starch adhesive A and fabric B Chemical composition is consistent, similar to green body powder in step (1), but wherein K by weight percentage2O+Na2O:6~8%, impurity≤ 4%;The siccative of starch adhesive A and fabric B are all made of feldspar poor material and kaolin families plastic raw material carries out ingredient, starch adhesive A and fabric It is 325 mesh sieve margins within 0.5% that the slurry of B, which controls fineness, and specific gravity is 1.60~1.90, wherein the siccative of starch adhesive A and auxiliary It helps additive wet ball grinding to apply the slurry of performance requirement at satisfaction leaching, does not include in the auxiliary additive of starch adhesive A and assist Toner ZnO, TiO2, the siccative of fabric B and auxiliary additive wet ball grinding dry after meeting size performance requirement, and fabric B's is auxiliary It helps in additive comprising auxiliary colorant ZnO, TiO2One of or it is a variety of, 800 DEG C~1000 DEG C calcinings are made dry powder, and with Stamp-pad ink, auxiliary additive are mixed with the printing fabric for meeting printing performance, spare;
(3) Imitation Rock Porcelain Tiles body preparation: by Imitation Rock Porcelain Tiles green body powder obtained in step (1) according to designed pattern texture, into Row multitube cloth, then spread cloth in brick machine die cavity, under the pressure of 20~50MPa, by Imitation Rock Porcelain Tiles green body powder pressing at Imitation Rock Porcelain Tiles green compact;
(4) body drying: Imitation Rock Porcelain Tiles green compact prepared by step (3) are dried at 150~300 DEG C in dry kiln;
(5) it drenches starch adhesive A: starch adhesive A prepared by step (2) is applied into the Imitation Rock Porcelain Tiles green surface of cloth after the drying with glaze pouring, it is single The weight of the applied starch adhesive of plane product is 400~800g/m2
(6) it prints fabric B: fabric B prepared by step (2) is applied into cloth in the billet surface for having drenched starch adhesive A with printing technology;
(7) apply dry after cloth Imitation Rock Porcelain Tiles fabric: will apply the Imitation Rock Porcelain Tiles green compact of Imitation Rock Porcelain Tiles fabric again in dry kiln in 150~ It is dried at 300 DEG C;
(8) it spray infiltration ink: is sprayed on Imitation Rock Porcelain Tiles green body using Digital ink-jet printer by designed pattern, cooperates green body Pattern texture, so that brick body surface and green body have similar texture and quality;
(9) it is burnt into: the Imitation Rock Porcelain Tiles green compact that step (8) is jetted through infiltration ink being placed in roller kilns and are burnt into temperature using conventional Imitation Rock Porcelain Tiles Degree system, pressure regime and atmosphere system, once-firing, firing temperature be 1150~1250 DEG C, firing period be 40~ Imitation Rock Porcelain Tiles semi-finished product are made in 90min;
(10) edging: using conventional edging process equipment, double of finished bricks carries out edging processing, and being made has stereo decoration effect The Imitation Rock Porcelain Tiles finished product of fruit.
2. the preparation method of the Imitation Rock Porcelain Tiles with three-dimensional decorative effect as described in claim 1, it is characterised in that: the auxiliary Additive additive amount is calculated as ZnO with fabric siccative as 0.2~1%, TiO2It is 0.2~5%.
3. the preparation method of the Imitation Rock Porcelain Tiles with three-dimensional decorative effect as described in claim 1, it is characterised in that: step (6) In printing web process use silk-screen printing or glue roller printing.
4. the preparation method of the Imitation Rock Porcelain Tiles with three-dimensional decorative effect as described in claim 1, it is characterised in that: step (6) It is middle to be printed using part is uneven, so that stereo decoration texture is more life-like.
5. the preparation method of the Imitation Rock Porcelain Tiles with three-dimensional decorative effect as described in claim 1, it is characterised in that: step (8) Ink-jet surface thickness is 0.3~1.0mm.
6. the preparation method of the Imitation Rock Porcelain Tiles with three-dimensional decorative effect as described in claim 1, it is characterised in that: step (10) After edging processing, handled using polishing process.
7. having solid as prepared by the preparation method of any Imitation Rock Porcelain Tiles with three-dimensional decorative effect of claim 1~6 The Imitation Rock Porcelain Tiles of decorative effect.
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CN111018543B (en) * 2020-01-02 2022-04-01 杭州诺贝尔陶瓷有限公司 Once-fired ultra-large specification thin porcelain plate and production method thereof

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CN104325823A (en) * 2014-10-10 2015-02-04 德清诺贝尔陶瓷有限公司 Glazed porcelain polished tile and production method thereof
CN105036814A (en) * 2015-06-24 2015-11-11 佛山市东鹏陶瓷有限公司 Production method for natural travertine-imitated glazed brick, and obtained green brick structure

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CN105036814A (en) * 2015-06-24 2015-11-11 佛山市东鹏陶瓷有限公司 Production method for natural travertine-imitated glazed brick, and obtained green brick structure

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