CN106176467B - Children's hair conditioner and preparation method thereof - Google Patents
Children's hair conditioner and preparation method thereof Download PDFInfo
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- CN106176467B CN106176467B CN201610771496.1A CN201610771496A CN106176467B CN 106176467 B CN106176467 B CN 106176467B CN 201610771496 A CN201610771496 A CN 201610771496A CN 106176467 B CN106176467 B CN 106176467B
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Abstract
The invention discloses a kind of children's hair conditioner and preparation method thereof, children's hair conditioner is prepared by following raw materials: water, cetostearyl alcohol, glycerol, cationic surfactant, dimethyl silicone polymer, dipropylene glycol, tip edge bladder-wrack extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract, sorbierite, hydrolysis sericin, ammonia-terminated polydimethylsiloxane, EDETATE SODIUM, essence, DMDM hydantoin, methylchloroisothiazandnone, methylisothiazolinone, lactic acid.Children's hair conditioner of the present invention, contains a variety of natural components, gives the triple loves of child: Shu Rou, moistening, protection, is a mild hair conditioner, and soft and moist hair takees good care of hair, the luminous pool of discount diverging and smooth easy combing.
Description
Technical field
The present invention relates to daily-use chemical industry technical fields, and in particular to a kind of children's hair conditioner and preparation method thereof.
Background technique
With the acceleration of human industryization process, pollutant component becomes more and more in atmosphere, for example, vehicle exhaust and
Chemical component contained in haze is extremely complex, so that hair, the scalp to human body also bring more threats.
Hair conditioner is also known as Rinsing, generally uses in pairs with shampoo, is uniformly applied to appropriate hair conditioner on hair after hair washing,
It gently rubs one minute or so, then with clear water rinsed clean, therefore also someone is known as rinsing conditioner, belongs to hair cosmetic.
It is generally believed that hair has negative electrical charge.It is had one's hair wash with shampoo (mainly anionic detergent, soap also belong to such)
Afterwards, hair can be made with more negative electrical charges, to generate electrostatic, cause combing inconvenient.Hair conditioner has been used, it is therein main
Constituent cation quaternary ammonium salt can neutralize the molecule with anion that remains in hair surface, and leave one layer of uniform unimolecule
Film, this layer of marvellous thing can carry out a series of benefits to hair carry: softness, gloss are easy to comb, are antistatic, and making hair
Mechanical damage and chemistry are scalded, are permed, damage brought by hair dye is by a degree of reparation.
Children's hair conditioner needs profession to develop, and child skin is delicate, cannot use adult cleaning chemical products, otherwise can injure
Skin, and the chemical substance contained in adult cleaning chemical products will affect children's health.
Summary of the invention
Aiming at the above shortcomings existing in the prior art, the first technical problem to be solved by the present invention is to provide a kind of youngster
Virgin hair conditioner.
The two of the technical issues of solution of the invention are to provide a kind of preparation method of children's hair conditioner.
Object of the present invention is to what is be achieved through the following technical solutions:
A kind of children's hair conditioner, is prepared by following raw materials: water, cetostearyl alcohol, glycerol, cation surface activating
Agent, dimethyl silicone polymer, dipropylene glycol, tip edge bladder-wrack extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract, sorb
Alcohol, hydrolysis sericin, ammonia-terminated polydimethylsiloxane, EDETATE SODIUM, essence, DMDM hydantoin, methyl chloride isothiazoline
Ketone, methylisothiazolinone, lactic acid.
A kind of children's hair conditioner, is prepared by the raw material of following weight parts: 15-25 parts of cetostearyl alcohol, glycerol 75-85
Part, 45-55 parts of cationic surfactant, 1-10 parts of dimethyl silicone polymer, 1-10 parts of dipropylene glycol, tip edge bladder-wrack are extracted
1-10 parts of object, 1-10 parts of yellow tang extract, 1-10 parts of Asparagus toxiformis (Delile) Coll et Harv extract of thorn, 5-15 parts of sorbierite, hydrolysis sericin 15-
55 parts, 1-10 parts of ammonia-terminated polydimethylsiloxane, 1-10 parts of EDETATE SODIUM, 0.1-1 parts of essence, DMDM hydantoin 0.05-0.5
Part, 0.05-0.5 parts of methylchloroisothiazandnone, 0.05-0.5 parts of methylisothiazolinone, 1-10 parts of lactic acid, water 300-500
Part.
Preferably, the essence is vanillic aldehyde, lemon extract, Mint Essence, lavender oil, flavoring rose essence etc..
Preferably, the cationic surfactant be behenyl base trimethyl ammonium chloride, stearyl trimethyl ammonium chloride,
One or more mixture in decyl trimethyl ammonium chloride.
It is highly preferred that the cationic surfactant is by behenyl base trimethyl ammonium chloride, stearyl trimethyl chlorination
Ammonium, decyl trimethyl ammonium chloride mix, the behenyl base trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, ten alkane
The mass ratio of base trimethyl ammonium chloride is (1-3): (1-3): (1-3).
The present invention also provides the preparation methods of above-mentioned children's hair conditioner, comprising the following steps:
Heat water to 65-85 DEG C, sequentially added under stirring condition cetostearyl alcohol, glycerol, cationic surfactant,
Dimethyl silicone polymer, dipropylene glycol, ammonia-terminated polydimethylsiloxane are uniformly mixed, and are cooled to 45-55 DEG C, then are successively added
Enter sorbierite, EDETATE SODIUM, essence, DMDM hydantoin, methylchloroisothiazandnone, methylisothiazolinone, lactic acid, hydrolysis
Sericin, tip edge bladder-wrack extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract are uniformly mixed to obtain the final product.
Specifically, in the present invention:
Lemon extract, the lemon extract provided using Shanghai bright moon daily use chemicals Co., Ltd in the embodiment of the present invention.
Behenyl base trimethyl ammonium chloride, i.e. INCROQUAT TMC-80, No. CAS: 17301-53-0.
Stearyl trimethyl ammonium chloride, No. CAS: 112-03-8.
Decyl trimethyl ammonium chloride, No. CAS: 10108-87-9.
Glycerol, No. CAS: 56-81-5.
Cetostearyl alcohol, No. CAS: 67762-27-0, it is provided using German BASF (former Corning) in the embodiment of the present invention
Lanette D cetostearyl alcohol.
EDETATE SODIUM, i.e. disodium ethylene diamine tetraacetate, No. CAS: 139-33-3.
Dipropylene glycol, No. CAS: 25265-71-8.
DMDM hydantoin, 1,3- dihydroxymethyl -5,5- Dimethyl Hydan, No. CAS: 6440-58-0.
Lactic acid, No. CAS: 849585-22-4
Dimethyl silicone polymer, No. CAS: 9016-00-6.
Sericin is hydrolyzed, the side of embodiment two in number of patent application 201310511239.0 is used in the embodiment of the present invention
Method preparation.
Ammonia-terminated polydimethylsiloxane, No. CAS: 71750-80-6, the fragrant refined chemical industry in Guangzhou is used in the embodiment of the present invention
The ammonia-terminated polydimethylsiloxane TCN-620 that Co., Ltd provides.
Methylchloroisothiazandnone, No. CAS: 26172-55-4.
Methylisothiazolinone, No. CAS: 2682-20-4.
Sorbierite, also known as D- D-sorbite, No. CAS: 50-70-4.
Tip edge bladder-wrack extract, English name: Fucus Serratus Extrac, from Boulez Brittany area
Tip edge bladder-wrack, locals are known as " gold seaweed ".The algae extract has reinforcing fiber archaeocyte vigor, and protection mitochondria is thin
Born of the same parents promote cutaneous respiration, bring powerful moisture-keeping efficacy for skin, and Cucumber Extract water storage function also can promote regeneration, increase
Cell viability restores skin life, promotes the metabolism of skin, effectively antagonizes free radical, confrontation cell senescence, discharges simultaneously
Active-energy improves dry, prevention microgroove, wrinkle generates, delay skin aging.Tip edge bladder-wrack extract can be prepared or be purchased
It can buy, preparation method can be conventional water extraction or alcohol extracting method, such as according to solid-liquid after tip edge bladder-wrack is cleaned and crush
Immersing mass fraction than (g/ml) 1:10-1:30 is to impregnate 8-12h in 95% ethyl alcohol, be heated to reflux 4-6h, cooling, is filtered, will
After filtrate concentration, it is lyophilized into powder.Tip edge bladder-wrack extract used in the present invention is bought from Nanjing Ze Lang medicine section
Skill Co., Ltd, the 1g tip edge bladder-wrack extract that specification 10:1, i.e. 10g tip edge bladder-wrack are extracted.
Yellow tang extract, English name: Ascophyllum Nodosum Extract, have it is antitumor, antiviral,
Antibacterial eliminates free radical, anti-oxidation efficacy.Yellow tang extract can be prepared or is commercially available, and preparation method can be conventional
Water extraction or alcohol extracting method, for example immerse mass fraction according to solid-to-liquid ratio (g/ml) 1:10-1:30 after yellow tang is cleaned and crush
Cooling to impregnate 8-12h, being heated to reflux 4-6h in 95% ethyl alcohol, filtering after filtrate is concentrated, is lyophilized into powder.The present invention
Used in yellow tang extract be purchase from Xi'an all places Biotechnology Co., Ltd, specification 10:1, i.e. 10g yellow tang
The 1g yellow tang extract extracted.
Pierce Asparagus toxiformis (Delile) Coll et Harv marine algae extract, English name: Asparagopsis Armata Extract is rich in activated silica, energy
Effectively optimization skin cell metabolism has skin reconstruction, lipolysis, resists oedema, skin quality moisture-keeping efficacy.Pierce Asparagus toxiformis (Delile) Coll et Harv
Marine algae extract can be prepared or is commercially available, and preparation method can be conventional water extraction or alcohol extracting method, for example will pierce Haimen
It is to impregnate 8-12h in 95% ethyl alcohol that winter seaweed, which immerses mass fraction according to solid-to-liquid ratio (g/ml) 1:10-1:30 after cleaning and crush,
It is heated to reflux 4-6h, cooling, filtering after filtrate is concentrated, is lyophilized into powder.Thorn Asparagus toxiformis (Delile) Coll et Harv seaweed used in the present invention mentions
Taking object is beautiful (EXSYMOL) company in purchase self-love west, the 1g that specification 10:1, i.e. 10g thorn Asparagus toxiformis (Delile) Coll et Harv marine algae extract extract
Pierce Asparagus toxiformis (Delile) Coll et Harv marine algae extract.
Children's hair conditioner of the present invention, contains a variety of natural components, gives the triple loves of child: Shu Rou, moistening, protection, be
A mild hair conditioner, soft and moist hair take good care of hair, the luminous pool of discount diverging and smooth easy combing.
Specific embodiment
The present invention will be further explained with reference to the examples below, as described below, is only to preferable implementation of the invention
Example, not limits the present invention, any person skilled in the art is possibly also with the disclosure above
Technology contents be changed to the equivalent embodiment changed on an equal basis.Without departing from the concept of the present invention, according to the present invention
Technical spirit any simple modification or equivalent variations that following embodiment is made, fall within the scope of protection of the present invention.
Embodiment 1
Children's hair conditioner raw material (parts by weight): 20 parts of cetostearyl alcohol, 80 parts of glycerol, 50 parts of cationic surfactant,
2 parts of dimethyl silicone polymer, 5 parts of dipropylene glycol, 4 parts of tip edge bladder-wrack extract, 4 parts of yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv mention
Take 4 parts of object, 10 parts of sorbierite, hydrolysis 35 parts of sericin, 3 parts of ammonia-terminated polydimethylsiloxane, 1 part of EDETATE SODIUM, lemonene
Essence 0.12 part, DMDM hydantoin 0.1,0.06 part of methylchloroisothiazandnone, 0.06 part of methylisothiazolinone, 3 parts of lactic acid,
400 parts of water.
The cationic surfactant is by behenyl base trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, ten alkyl
Trimethyl ammonium chloride is that 1:1:1 is uniformly mixed to obtain in mass ratio.
The preparation method of above-mentioned children's hair conditioner, comprising the following steps:
75 DEG C are heated water to, it is living that cetostearyl alcohol, glycerol, cationic surface are sequentially added under 500 revs/min of stirring conditions
Property agent, dimethyl silicone polymer, dipropylene glycol, ammonia-terminated polydimethylsiloxane are uniformly mixed, and are cooled to 48 DEG C, then successively
Sorbierite, EDETATE SODIUM, lemon extract, DMDM hydantoin, methylchloroisothiazandnone, methylisothiazolinone, cream is added
Acid, hydrolysis sericin, tip edge bladder-wrack extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract are uniformly mixed.It obtains
Children's hair conditioner of embodiment 1.
Embodiment 2
Children's hair conditioner raw material (parts by weight): 20 parts of cetostearyl alcohol, 80 parts of glycerol, 50 parts of cationic surfactant,
2 parts of dimethyl silicone polymer, 5 parts of dipropylene glycol, 6 parts of tip edge bladder-wrack extract, 6 parts of yellow tang extract, 10 parts of sorbierite,
Hydrolyze 35 parts of sericin, 3 parts of ammonia-terminated polydimethylsiloxane, 1 part of EDETATE SODIUM, 0.12 part of lemon extract, acyl in DMDM second
Urea 0.1,0.06 part of methylchloroisothiazandnone, 0.06 part of methylisothiazolinone, 3 parts of lactic acid, 400 parts of water.
The cationic surfactant is by behenyl base trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, ten alkyl
Trimethyl ammonium chloride is that 1:1:1 is uniformly mixed to obtain in mass ratio.
The preparation method of above-mentioned children's hair conditioner, comprising the following steps:
75 DEG C are heated water to, it is living that cetostearyl alcohol, glycerol, cationic surface are sequentially added under 500 revs/min of stirring conditions
Property agent, dimethyl silicone polymer, dipropylene glycol, ammonia-terminated polydimethylsiloxane are uniformly mixed, and are cooled to 48 DEG C, then successively
Sorbierite, EDETATE SODIUM, lemon extract, DMDM hydantoin, methylchloroisothiazandnone, methylisothiazolinone, cream is added
Acid, hydrolysis sericin, tip edge bladder-wrack extract, yellow tang extract are uniformly mixed.Obtain the protector for children of embodiment 2
Hair element.
Embodiment 3
Children's hair conditioner raw material (parts by weight): 20 parts of cetostearyl alcohol, 80 parts of glycerol, 50 parts of cationic surfactant,
2 parts of dimethyl silicone polymer, 5 parts of dipropylene glycol, 6 parts of tip edge bladder-wrack extract, thorn 6 parts of Asparagus toxiformis (Delile) Coll et Harv extract, sorbierite 10
Part, 35 parts of sericin of hydrolysis, 3 parts of ammonia-terminated polydimethylsiloxane, 1 part of EDETATE SODIUM, 0.12 part of lemon extract, in DMDM second
Uride 0.1,0.06 part of methylchloroisothiazandnone, 0.06 part of methylisothiazolinone, 3 parts of lactic acid, 400 parts of water.
The cationic surfactant is by behenyl base trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, ten alkyl
Trimethyl ammonium chloride is that 1:1:1 is uniformly mixed to obtain in mass ratio.
The preparation method of above-mentioned children's hair conditioner, comprising the following steps:
75 DEG C are heated water to, it is living that cetostearyl alcohol, glycerol, cationic surface are sequentially added under 500 revs/min of stirring conditions
Property agent, dimethyl silicone polymer, dipropylene glycol, ammonia-terminated polydimethylsiloxane are uniformly mixed, and are cooled to 48 DEG C, then successively
Sorbierite, EDETATE SODIUM, lemon extract, DMDM hydantoin, methylchloroisothiazandnone, methylisothiazolinone, cream is added
Acid, hydrolysis sericin, tip edge bladder-wrack extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract are uniformly mixed.Obtain the children of embodiment 3
Hair conditioner.
Embodiment 4
Children's hair conditioner raw material (parts by weight): 20 parts of cetostearyl alcohol, 80 parts of glycerol, 50 parts of cationic surfactant,
2 parts of dimethyl silicone polymer, 5 parts of dipropylene glycol, 6 parts of yellow tang extract, thorn 6 parts of Asparagus toxiformis (Delile) Coll et Harv extract, 10 parts of sorbierite, water
Solve 35 parts of sericin, 3 parts of ammonia-terminated polydimethylsiloxane, 1 part of EDETATE SODIUM, 0.12 part of lemon extract, DMDM hydantoin
0.1,0.06 part of methylchloroisothiazandnone, 0.06 part of methylisothiazolinone, 3 parts of lactic acid, 400 parts of water.
The cationic surfactant is by behenyl base trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, ten alkyl
Trimethyl ammonium chloride is that 1:1:1 is uniformly mixed to obtain in mass ratio.
The preparation method of above-mentioned children's hair conditioner, comprising the following steps:
75 DEG C are heated water to, it is living that cetostearyl alcohol, glycerol, cationic surface are sequentially added under 500 revs/min of stirring conditions
Property agent, dimethyl silicone polymer, dipropylene glycol, ammonia-terminated polydimethylsiloxane are uniformly mixed, and are cooled to 48 DEG C, then successively
Sorbierite, EDETATE SODIUM, lemon extract, DMDM hydantoin, methylchloroisothiazandnone, methylisothiazolinone, cream is added
Acid, hydrolysis sericin, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract are uniformly mixed.Obtain children's hair care of embodiment 4
Element.
Embodiment 5
Substantially the same manner as Example 1, difference is only in that: the cationic surfactant is by stearyl trimethyl chlorine
Change ammonium, decyl trimethyl ammonium chloride is that 1:1 is uniformly mixed to obtain in mass ratio.Obtain children's hair conditioner of embodiment 5.
Embodiment 6
Substantially the same manner as Example 1, difference is only in that: the cationic surfactant is by behenyl base trimethyl chlorine
Change ammonium, decyl trimethyl ammonium chloride is that 1:1 is uniformly mixed to obtain in mass ratio.Obtain children's hair conditioner of embodiment 6.
Embodiment 7
Substantially the same manner as Example 1, difference is only in that: the cationic surfactant is by behenyl base trimethyl chlorine
Change ammonium, stearyl trimethyl ammonium chloride is that 1:1 is uniformly mixed to obtain in mass ratio.Obtain children's hair conditioner of embodiment 7.
Test case 1
According to method disclosed in " foundation and application study of the anti-dandruff effect detection evaluation method of shampoo " to embodiment
Hair conditioner made from 1-7 carries out inhibition zone diameter test, evaluates anti-dandruff effect of hair conditioner product.Inhibition zone diameter is got over
Greatly, anti-dandruff effect is better.Test data is shown in Table 1.
Wherein, " foundation and application study of the anti-dandruff effect detection evaluation method of shampoo ", where, Wang Tan, Jia Zebao, flood
Know roc, Peng Jin, research and development department, Si Bao daily use chemicals Co., Ltd, household chemicals science, o. 11th in 2009.
Table 1: anti-dandruff efficacy test tables of data
| Inhibition zone diameter, mm | |
| Embodiment 1 | 22.1 |
| Embodiment 2 | 17.5 |
| Embodiment 3 | 17.9 |
| Embodiment 4 | 18.2 |
| Embodiment 5 | 19.7 |
| Embodiment 6 | 19.2 |
| Embodiment 7 | 19.4 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (tip edge bladder-wrack extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv
Extract compounding) anti-dandruff effect is substantially better than embodiment 2-4 (tip edge bladder-wrack extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv mentions
Take both any compounding in object)；Comparing embodiment 1 and embodiment 5-7, embodiment 1 (behenyl base trimethyl ammonium chloride, stearyl
Trimethyl ammonium chloride, decyl trimethyl ammonium chloride compounding) anti-dandruff effect is substantially better than embodiment 5-7 (behenyl base trimethyl chlorine
Change ammonium, stearyl trimethyl ammonium chloride, both any compounding in decyl trimethyl ammonium chloride).
Test case 2
By children's hair conditioner made from embodiment 1-7, carried out respectively with dark brown vial it is filling, open wide bottle cap, be placed in
Preservation 90 days under 40 DEG C of environment temperature, 85% environment of relative humidity, staphylococcus aureus (ATCC 6538) bacterium colony is then carried out
Sum test, measures referring to GBT 4789.2-2008 microbiological test of food hygiene total plate count.Specific test result is shown in Table
2。
Table 2: total plate count tests table
| S. aureus colonies sum, cfu/g | |
| Embodiment 1 | 231 |
| Embodiment 2 | 752 |
| Embodiment 3 | 774 |
| Embodiment 4 | 781 |
| Embodiment 5 | 565 |
| Embodiment 6 | 558 |
| Embodiment 7 | 572 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (tip edge bladder-wrack extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv
Extract compounding) antiseptic property be substantially better than embodiment 2-4 (tip edge bladder-wrack extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv mention
Take both any compounding in object)；Comparing embodiment 1 and embodiment 5-7, embodiment 1 (behenyl base trimethyl ammonium chloride, stearyl
Trimethyl ammonium chloride, decyl trimethyl ammonium chloride compounding) antiseptic property is substantially better than embodiment 5-7 (behenyl base trimethyl chlorine
Change ammonium, stearyl trimethyl ammonium chloride, both any compounding in decyl trimethyl ammonium chloride).
Claims (2)
1. a kind of children's hair conditioner, which is characterized in that be prepared by the raw material of following weight parts: 15-25 parts of cetostearyl alcohol,
75-85 parts of glycerol, 45-55 parts of cationic surfactant, 1-10 parts of dimethyl silicone polymer, 1-10 parts of dipropylene glycol, tip edge
1-10 parts of bladder-wrack extract, 1-10 parts of yellow tang extract, 1-10 parts of Asparagus toxiformis (Delile) Coll et Harv extract of thorn, 5-15 parts of sorbierite, hydrolysis
15-55 parts of sericin, 1-10 parts of ammonia-terminated polydimethylsiloxane, 1-10 parts of EDETATE SODIUM, 0.1-1 parts of essence, in DMDM second
0.05-0.5 parts of uride, 0.05-0.5 parts of methylchloroisothiazandnone, 0.05-0.5 parts of methylisothiazolinone, lactic acid 1-10
Part, 300-500 parts of water；
The cationic surfactant is by behenyl base trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, ten alkyl front threes
Ammonium chloride mixes, the behenyl base trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, decyl trimethyl ammonium chloride
Mass ratio be (1-3): (1-3): (1-3).
2. the preparation method of children's hair conditioner as described in claim 1, which comprises the following steps:
65-85 DEG C is heated water to, cetostearyl alcohol, glycerol, cationic surfactant, poly- two are sequentially added under stirring condition
Methylsiloxane, dipropylene glycol, ammonia-terminated polydimethylsiloxane are uniformly mixed, and are cooled to 45-55 DEG C, sequentially add mountain
Pears alcohol, EDETATE SODIUM, essence, DMDM hydantoin, methylchloroisothiazandnone, methylisothiazolinone, lactic acid, hydrolysis silk gum
Albumen, tip edge bladder-wrack extract, yellow tang extract, thorn Asparagus toxiformis (Delile) Coll et Harv extract are uniformly mixed to obtain the final product.
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| CN107714505A (en) * | 2017-11-29 | 2018-02-23 | 桂林华诺威生物科技有限公司 | A kind of collagen hair conditioner |
| CN108498446A (en) * | 2018-07-11 | 2018-09-07 | 佛山皖阳生物科技有限公司 | A kind of hair conditioner and preparation method thereof for preventing hair quality impaired |
| EP3902513A4 (en) * | 2018-12-28 | 2022-10-12 | Henkel AG & Co. KGaA | Solid hair conditioning composition |
| CN110643054A (en) * | 2019-10-19 | 2020-01-03 | 浙江溶力新材料科技有限公司 | Methyl silicone oil emulsion and preparation method thereof |
| CN117487168A (en) * | 2023-11-01 | 2024-02-02 | 广州安迪化工有限公司 | Preparation method of modified siloxane and hair conditioner containing modified siloxane |
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| CN104095792A (en) * | 2014-07-22 | 2014-10-15 | 广州好迪集团有限公司 | Hair conditioner capable of nourishing hair and repairing damage |
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| CN104095792A (en) * | 2014-07-22 | 2014-10-15 | 广州好迪集团有限公司 | Hair conditioner capable of nourishing hair and repairing damage |
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