CN108042389A

CN108042389A - A kind of ferment is without silicone oil shampoo

Info

Publication number: CN108042389A
Application number: CN201711371427.2A
Authority: CN
Inventors: 曾万祥; 覃敢为; 陈海; 黄娜; 曾嘉
Original assignee: Guangzhou Bo Cosmetics Co Ltd
Current assignee: Guangzhou Bo Cosmetics Co Ltd
Priority date: 2017-12-14
Filing date: 2017-12-14
Publication date: 2018-05-18

Abstract

The invention discloses a kind of ferment without silicone oil shampoo, the raw material for preparing of the shampoo includes yeast beta glucan and carboxymethyl beta glucan sodium；The sum of the weight percentage of the yeast beta glucan and carboxymethyl beta glucan sodium in the shampoo is 0.2~2%.Skin of head growth, reparation and protection are promoted using the immunoregulatory activity of two primary yeast extract of yeast beta glucan and carboxymethyl beta glucan sodium in formula of the ferment of the present invention without silicone oil shampoo; improve hair follicle activity; reduce epilation; extend the life cycle of hair; there is apparent facilitation effect for cell Proliferation, there is transdermal penetration and antiallergic anti-inflammatory.

Description

A kind of ferment is without silicone oil shampoo

Technical field

The present invention relates to a kind of shampoo, and in particular to a kind of ferment is without silicone oil shampoo.

Background technology

Shampoo refers to a kind of hair products with cleaning, reparation, anti-dandruff, treatment oil etc..Best in quality washes The dirt grease adhered on scalp and hair can effectively be cleaned by becoming visible, meanwhile, also to the nutrition and protection needed for scalp, to hair It brings soft, smooth and glossy.The species of shampoo is although various currently on the market, but usually cannot all reach profound clear Clean effect, but also it be easy to cause the generation of some side effects such as scalp itch and dry hair tarnish.It is now very much People are for beauty, often hair-waving or hair dyeing so that hair dry up it is impaired serious, along with the environmental pollution being on the rise, Fungi on scalp is more and more, causes the various symptom of scalp, and if dandruff is excessive, hair is short-tempered, alopecia etc..But with the people Improvement of living standard, consumption concept gradually enhance, also higher and higher to the quality requirement of shampoo, and hair and scalp are carried out Profound level, which is cleaned and reached simultaneously, repairs the shampoo urgent need exploitation for nourishing hair, and immune health is lifted by people, enhances People are to the health perception of itself, and the basic function of immune system is exactly to resist alien bacteria, virus and some other cause of disease Disease caused by body, and influenced by theory of traditional Chinese medical science, it is mostly wine that China, which has the product form of the health products early stage of immune health, Form, with further development, capsule, tablet, pulvis became mainstream in recent years, primary raw material still with ganoderma lucidum, ginseng, Based on royal jelly, colostrum, vitamin etc..But these raw materials have limitation when adding in the product, and be not suitable for all Crowd.In recent years with the exploitation of new raw material, the shampoo with immune health influence among research and development, steps into city Field becomes the hot spot of immune health.

In order to make hair submissive in traditional shampoo, add the highly viscous silicon compound of some high molecular weight serve as it is smooth Agent, they can be adsorbed in each hair surface, form very smooth film.At present in shampoo common silicon compound have it is poly- Dimethyl siloxane, amido silicon oil, cyclomethicone etc., in hair-washing hair-care, these silicon-containing compounds can be between hair scale piece Gap fill up, people can be allowed to think that hair sense of touch is very smooth, but due to silicone oil have characteristic not soluble in water, be wrapped in head Silicon on hair and scalp is less susceptible to be cleaned, and enrichment so year in year out, silicone oil can adsorb the meeting on hair It causes that hair is thicker, hair weight becomes weight, reduces the electrostatic interaction of hair, hair is made gradually to lose elasticity, generate disconnected hair, scalp Clogging of pores causes scalp oxygen flow insufficient, papilla may gradual atrophy, scalp just start to occur it is withered and yellow, itch or even alopecia The phenomenon that, and the siliceous oils product of long-time service can be covered because of hair by silicone oil, and the real nutrition subsequently nursed cannot be introduced into And hair quality is made to be deteriorated.In addition these organosilicons are not only not soluble in water but also insoluble in any surfactant, and environment is discharged into after hair washing It is difficult to it is biodegradable, easily cause environmental pollution.

In addition, existing shampoo is mostly using DMDM hydantoin, methylisothiazolinone, methylchloroisothiazandnone As preservative, irritation is larger, and head can be caused to itch and dandruff, and the immediate cause of dandruff is inflammation caused by stimulating.Work as thorn Stimulus, for example, the metabolin of fungi, comb improper, hair care it is improper Skin Cell can then accelerate hyperplasia when causing inflammation, cause dead Skin comes off, that is, our so-called dandruffs.In many cases, the principal element or chlosma amount of dandruff are uneven Weighing apparatus.It is the key that treatment of dandruff to inhibit scalp chlosma amount.But anti-dandruff type shampoo is mostly using one kind currently on the market Or two kinds of anti-dandruff agents or be known as with plant anti-dandruff component, undesirable to eliminating chlosma effect, anti-dandruff effect is poor, especially It is the more oily hair of dandruff, it is more difficult to reach anti-dandruff effect.The synthesis that above shampoo can not meet modern people will It asks.

Application number 201510987599.7 discloses a kind of Chinese medicine ferment shampoo and its preparation method, which matches somebody with somebody Although what is used in side is all crude drug component, there is no use additional anti-dandruff agent, surfactant and hair The ingredients such as conditioner, although various Chinese herb medicine components are no added safely, individual plant extracts cannot but reach deep The sterilization of level is anti-dandruff and nourish, lubrication, conditioning, moisturizing and other effects, and various effect slowly effects；It is used in formula By adding in the prebiotic strain such as acetobacter, distiller's yeast, yeast, it is sealed by fermentation, is obtained by filtration after the completion of fermentation time fermentation in 6 months Ferment, may among obtained ingredient it is impure, therefore the effect of hair is not also understood.

The content of the invention

A kind of ferment is provided without silicone oil shampoo it is an object of the invention to overcome the shortcomings of the prior art part.

To achieve the above object, the technical solution taken of the present invention is：A kind of ferment without silicone oil shampoo include yeast β- Glucan and carboxymethyl R-glucan sodium；The weight of the yeast beta-dextran and carboxymethyl R-glucan sodium in the shampoo It is 0.2~2% to measure the sum of percentage composition.

Yeast extract is exactly the substance that there is immune health to influence for being gradually applied to cosmetic field at present. Yeast after broken wall will the wherein extractings such as protein, nucleic acid, vitamin, then the amino acid rich in small molecule through biological enzymolysis, The pale yellow powder of the active skull cap components such as peptide, nucleotide, vitamin.Wherein amino acid content more than 30%, total protein 50% More than, nucleotide more than 10% is living and other effects with moisturizing, tax in cosmetics.Because amino acid be in keratoderma from The main component of right moisturizing factor (NMF), is easily absorbed by the skin, and the epidermis of aging is made to recover elasticity, delay skin aging.Nucleic acid And nucleotide is the central genetic substance of human body, has the effects that boost metabolism, improves protein aggregate velocity, enhancing is exempted from Epidemic disease function, enhancement of SOD activity, improve skin antiradical activities.In addition, the nutrition such as vitamin and mineral a small amount of in product Element can also provide sufficient nutrition for skin.It is prepared by the therefore yeast extract standard higher applied to cosmetic field Technique is most complicated, and cost is also high.

Yeast beta-dextran can exactly be extracted from yeast and obtained, it is most physiological activity in glucan family One kind is to polymerize the polysaccharide formed by D-Glucose, these natural polysaccharides are present on the cell membrane of cereal, bacterium, fungi etc.. It is a kind of natural cutaneous immunisation accelerating agent, and acting on skin can promote Skin Cell active, strengthen cell Proliferation metabolism, prolong Slow skin aging, efficiently repairs skin.Can also activated macrophage, neutrophils etc., promote the generation of internal antibody, Free radical, radioresistance, dissolving cholesterol are removed, sense caused by preventing hyperlipidemia and resisting filterable virus, fungi, bacterium etc. The effects that dye.Therefore it is excellent immunoactivator, can stimulate the immune system of body comprehensively, can improve skin itself Immunity；Have effects that remove free radical；Damaged tissues can be assisted to accelerate to recover to generate cytokine；It is repaiied in sensitive skin Also there is unique bioactivity in compound face.

Carboxymethyl R-glucan sodium is the carboxyl methylation derivant of yeast beta-dextran, is generally deposited as its sodium salt Because water-soluble less good, so as to greatly limit its application in cosmetic field.By certain chemical modification, It is water-soluble that its can be substantially improved, wherein carboxymethyl-modification is applied than wide, modified to substantially improve water solubility, can with it is big Most cosmetic composition compatibilities, property are stablized, and are safe and reliable, have been put into international cosmetic raw material list (INCI), it is widely used in the various cosmetics of super quality.

It is carried in the formula of shampoo of the present invention using yeast beta-dextran and two primary yeast of carboxymethyl R-glucan sodium The immunoregulatory activity of object is taken to promote skin of head growth, reparation and protection, hair follicle activity is improved, reduces epilation, prolong The life cycle of long hair has apparent facilitation effect for cell Proliferation, has transdermal penetration and the work of antiallergic anti-inflammatory With.When the sum of additive amount especially when yeast beta-dextran and carboxymethyl R-glucan sodium in shampoo is 0.2~2%, The effect of performance is preferable；If additive amount is less than 0.2%, the effect of being difficult to play yeast extract；When additive amount is more than 2%, Then with the increase of additive amount, the utilization ratio increase of yeast extract is not notable.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the yeast beta-dextran and carboxymethyl The weight ratio of beta glucan sodium is：Yeast beta-dextran：Carboxymethyl R-glucan sodium=0.1~1:0.1~1.

, can be mutually synergistic when yeast beta-dextran and carboxymethyl R-glucan sodium use above-mentioned ratio, mutually promote Into playing a role jointly.

As more preferable embodiment of the ferment of the present invention without silicone oil shampoo, the yeast beta-dextran and carboxylic first The weight ratio of base beta glucan sodium is：Yeast beta-dextran：Carboxymethyl R-glucan sodium=1:1.

Especially when yeast beta-dextran and carboxymethyl R-glucan sodium use above-mentioned ratio, the two can play preferably Cooperative synergism effect, it is optimal to hair and scalp nourishes effect.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the raw material for preparing of the shampoo also wraps Isomer containing carbohydrate；The carbohydrate isomer is in the weight percentage prepared in raw material of the shampoo 0.1~1%.

Carbohydrate isomer is colourless or micro- yellow transparency liquid, is a kind of natural guarantor extracted from sugarcane carbohydrate synthesis Humectant has moisturizing, the keratin in moisture content combined with stratum corneum is assisted, to reach moistening effect.Carbohydrate isomer is a kind of Good water-retaining agent and emollients have and repair epidermal layer cells, promote skin moisturizing ability, manufactured via Measurement for Biochemistry Isomerization D- glucans, have and the similar composition structure of human keratinous layer, using on the skin can be with epsilon-amino acid function Group combines, and is firmly combined just as magnetite, long-acting can maintain the hydromagnetic field energy power of skin and can be widely used in all kinds of skins use, hair Among applying some make up.Have good humidity of skin regulatory function and long-acting moisture-keeping function, effect can in skin applies some make up Persistently until cutin peels off naturally, moisturizing is with slowing down stimulation.Carbohydrate isomer is applied in hair washing product by the present invention, Moisture-keeping function and antistatic property can be played, especially under above-mentioned additive amount, carbohydrate isomerism physical efficiency gives full play to its guarantor Wet and anlistatig effect.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the raw material for preparing of the shampoo also wraps Containing plant extracts, the plant extracts is 0.3~3% in the weight percentage prepared in raw material of the shampoo； The plant extracts includes at least one of radix-polygoni multiflori extract, Rhizoma Chuanxiong extract and tea polyphenols.

Radix-polygoni multiflori extract is the dried root of polygonum multiflorum thunb, and main functional component is lecithin, rheum emodin, Rhein and other ingredients.Main function:Anti-aging effects, the influence to immune system, antibacterial action etc..The object of efficacy effect Matter basis is mainly the ingredients such as phosphatide, Anthraquinones, glucose glycoside, has nourishing the blood to expel wind, and the work(of brain tonic and intelligence development has adjusting nerve With the effect of endocrine function and hairy root nourishing, the generation of hair melanin can be promoted, make hair more black.The fleece-flower root also contains There is a much starch, after Starch Hydrolysis, the glucose of generation has well that profit breaking-out is used, and is the good weight for preparing hair conditioner Want raw material.Lecithin contained by the fleece-flower root is the important source material of cell membrane, can promote the metabolism and growth and development of cell, from And delay the aging of cell, it prolongs life.It does not make one in high spirits with the fleece-flower root for a long time, can also promote to have rosy cheeks glossy, As the health medicine of hair, hair can be nourished well, assigned healthy hair deep layer nutrition, made healthy hair is tough to be not easily broken；To blood Poliosis caused by empty essence is lost, alopecia have the effect of fine.

Rhizome of chuanxiong extract, Xin Xiang are apt to rise, and energy uplink head mountain peak top has wind-expelling pain-stopping effect, to control head wind headache key medicine, It can equally be used with asarum, the root of Dahurain angelica, for diseases such as cold headache, migraine and general headaches.Also it can belong to any appropriate through carrying out according to headache Compatibility.If headache caused by for experiencing ailment said due to cold or exposure can schizonepeta, windproof, Rhizoma Et Radix Notopterygii it is equivalent with controlling anemofrigid cold headache；With chrysanthemum stiff silkworm Compatibilities are waited, control headache due to pathogenic wind-heat.And rhizome of chuanxiong energy expanded head capillary, it promotes blood circulation, increases hair nutrition, make hair There is good compliance and be not easy the effect to become fragile, the tensile strength and extensibility of hair can also be improved, can also delay white hair Growth keeps hair lubrication gloss, is easy to comb.It can anti-anti-avulsion so rhizome of chuanxiong is made shampoo, shampoo, liquid for hair-growth etc. Hair, white hair, and effectively treat the effects that having a headache.Tea polyphenols are the general names of Polyphenols of Tea, including flavanol compound, flower Color glycoside, flavonoids, flavonols and phenolic acid class etc..

Tea polyphenols have stronger antioxidation and bacteriostasis, such as to staphylococcus, Escherichia coli, withered grass bar Bacterium etc. has inhibitory action.The removing toxic substances of tea polyphenols isoreactivity substance tool and radiation resistance can effectively stop radioactive substance intrusion Marrow is described as " radiation jinx " by health and medical field.Tea polyphenols can indirectly be realized by adjusting the activity of immunoglobulin The effect of improving human body comprehensive immunocompetence, the antirheumatic factor, anti-bacteria and anti-virus；The release action of inhibition histamine that can be strong, With antiallergic action and anti-cutaneous anaphylaxis effect；Play the role of removing free radical, can inhibit fat oxygen in skin mitochondria Synthase and lipid peroxidation, so as to anti-aging effect.Antioxidant is substantially better than vitamin E, and has with injection Vitamin B_6 Synergy；There is stronger suction-operated to heavy metal, complex compound can be formed with heavy metal and generate precipitation, be conducive to mitigate The toxic action that heavy metal generates human body；It is water-soluble substances, there is disinfection, sterilizing, resisting age of skin, reduce in daylight Ultraviolet radiation is to damage of hair and other effects.In addition, tea polyphenols can also stop ultraviolet light and remove ultraviolet induction from By base.

Radix-polygoni multiflori extract is with the addition of in shampoo of the present invention, three kinds of natural plants of Rhizoma Chuanxiong extract and tea polyphenols are grown Strong hair ingredient is supported, can quickly nourish strong damaged hair.Especially, when three Plant Extracts use above-mentioned additive amount, energy The effect of giving full play to plant extracts plays the preferable effect for nourishing hair.

As more preferable embodiment of the ferment of the present invention without silicone oil shampoo, it is first what the plant extracts includes Black extract, Rhizoma Chuanxiong extract and tea polyphenols；The weight ratio of the radix-polygoni multiflori extract, Rhizoma Chuanxiong extract and tea polyphenols is： Radix-polygoni multiflori extract：Rhizoma Chuanxiong extract：Tea polyphenols=0.1~1:0.1~1:0.1~1.

It when three Plant Extracts use said ratio, can mutually promote, play synergistic effect.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the raw material for preparing of the shampoo also wraps Containing hair conditioner, the hair conditioner includes panthenol, allantoin, Etidronic Acid, EDETATE SODIUM, Anjidew NL50 and silk silk At least one of glue protein.

Panthenol is the precursor of vitamin B5, therefore also known as dexpanthenol, is widely used in medicine, food, cosmetic industry. As there is identical metabolic process in vivo with vitamin B5, in food service industry, as nutritional supplement and hardening agent, Pantothenic acid is converted into human body interior energy, and then synthesizes coacetylase, promotes the metabolism of human body protein, fat, carbohydrate, keeps skin And mucous membrane, improve hair luster, improve immunity, prevent the generation of disease；In cosmetic industry：Nursing role table on skin It is now the moisturizer penetrated deep into, stimulates the growth of epithelial cell, promote wound healing, play antiinflammation；Nursing on hair Effect shows as lasting moisture-keeping functions, it wraps up hair, has and moistens, and moisturizing is smooth, reduces bifurcated, hair is prevented to be damaged, Increase the density of hair, improve the gloss of hair quality.Also small wrinkle, inflammation, solarization, erosion can be prevented, anti-alopecia-stopping promotes life Hair keeps hair moistening, prevents clear-cut and fracture, and enemy initiates protection, repairs, nursing role.

Silk sericin, is the natural polymer fibrin extracted from silk, content account for silk 70~ 80%, containing 18 kinds of amino acid, there is preferable affinity interaction to hair, protectiveness transparent membrane can be formed in hair surface, prevented Only injury of the thioglycolate salt to hair supplements the various nutrients needed for hair, improves the gloss and elasticity of hair, can be effective It prevents hair damage, makes gloss and the slim and graceful softness such as tiffany that hair distributes ripples.Meanwhile silk sericin is to impaired Hair has apparent repairing effect.

Hair conditioner of the present invention is selected to non-stimulated to scalp, can effectively be supplemented the nutrients for scalp and hair Substance.

As more preferable embodiment of the ferment of the present invention without silicone oil shampoo, the hair conditioner includes general Alcohol, allantoin, Etidronic Acid, EDETATE SODIUM, Anjidew NL50 and silk sericin；Raw material is prepared in the shampoo, institute The weight percentage for stating panthenol is 0.5~2.5%；The weight percentage of the allantoin is 0.1~0.5%；The hydroxyl The weight percentage of second diphosphonic acid is 0.05~0.15%；The weight percentage of the EDETATE SODIUM for 0.05~ 0.15%；The weight percentage of the Anjidew NL50 is 0.5~1%；The weight percentage of the silk sericin is 0.3 ~3%.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the raw material for preparing of the shampoo also wraps Containing anti-dandruff and itching-relieving agent, the anti-dandruff and itching-relieving agent is 0.16~1.3% in the weight percentage prepared in raw material of shampoo；Institute It states anti-dandruff and itching-relieving agent and includes azadirachta seed extract, piroctone olamine salt and hexamidine two (isethionic acid) salt.

Azadirachta seed extract possesses the effect of sterilization and antiviral characteristic and desinsection, sterilizing.Piroctone olamine Salt namely anti-dandruff agent OCTO, it is famous due to its bacteriostasis, Plasmodium ovale is particularly can inhibit, parasitizes dandruff, face Deng scurf in.The product is a kind of efficient, nontoxic non-stimulated anti-dandruff agent, can be widely used in anti-dandruff shampoo, hair-nourishing liquid It is washed with hair conditioner etc. in shield class cosmetics.The anti-dandruff and itching-relieving mechanism of OCTO is fundamentally blocked by sterilization and antioxidation The external channel that dandruff generates, so as to effectively effect a radical cure dandruff, stopping head itching rather than temporarily be disappeared from presentation by modes such as degreasings Except dandruff.One of the reason for being better than similar product here it is OCTO anti-dandruff and itching-relievings performance.The substance is identified through external authoritative institution It is very reliable to the security of eyes, skin.Definitely non-toxic, irritation and sensitization.Head will not be damaged in actual use Skin is not in alopecia, disconnected hair.Hexamidine two (isethionic acid) salt (Pf-95) it is a kind of new water solubility sun Ion dandruff-removing itching-relieve agent has broad-spectrum antiseptic and bactericidal property, to various gram-positive bacterias and negative bacterium and various moulds There are very high sterilization and bacteriostasis property with saccharomycete, especially to the pityrosporum ovale for causing dandruff, because of its unique knot Structure has very strong killing effect and to the propionibacterium acnes of acne is caused to have very strong inhibition and sterilization effect.And And very safety is mild, and it is small to skin irritation, it is excellent with the compatibility of common raw material in daily chemical products.Especially because its sun from The suction-operated that sub- property generates hair, be more advantageous to its anti-dandruff effect reinforcement and persistently play, this be other anti-dandruff agents not The characteristic possessed.Have extremely important in cosmetics and other industry and be widely applied.Plant anti-dandruff agent azadirachta seed extracts Object margosa tree possesses the effect of sterilization and antiviral characteristic and desinsection, sterilizing.

Ferment of the present invention without above-mentioned three kinds of anti-dandruff and itching-relieving agents are added in silicone oil shampoo there is preferable sterilization to make With, and plant extracts is non-stimulated to scalp, three play a role jointly achieve the effect that it is anti-dandruff.Anti-dandruff effect is stopped with anti-dandruff Itch agent additive amount increase and increase, but be when anti-dandruff and itching-relieving agent is more than in the additive amount prepared in raw material of the shampoo When 1.3%, the amount of anti-dandruff and itching-relieving agent is further added by, anti-dandruff effect increase is not notable, therefore when anti-dandruff and itching-relieving agent is in the shampoo The weight percentage prepared in raw material be 0.6~1.3% when, could preferably play anti-dandruff effect.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the azadirachta seed extract, pyrrole sieve The weight ratio of gram ketone ethanolamine salt and hexamidine two (isethionic acid) salt is：Azadirachta seed extract, piroctone ethyl alcohol Amine salt：Hexamidine two (isethionic acid) salt=1~5:0.1~3:0.5~5.

Three kinds of anti-dandruff and itching-relieving agents are especially under said ratio, the anti-dandruff best results that reach.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the raw material for preparing of the shampoo also wraps Containing assigning fat agent, described to assign fat agent in the weight percentage prepared in raw material of the shampoo be 1.71~7.5%；The tax Fat agent includes phytosterol Queensland nut oleate, C12-13 alcohol lactate, dipentaerythritol pentaerythritol tetraisostearate, glycerine oil Acid esters and three-C12-13 alkanol citrates；The phytosterol Queensland nut oleate, C12-13 alcohol lactate, dimerization season The weight ratio of penta tetrol pentaerythritol tetraisostearate, glyceryl oleate and three-C12-13 alkanol citrates is：Phytosterol Australia Nut oleate：C12-13 alcohol lactates：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate：Three-C12-13 alkanol lemons Lemon acid esters=0.1~0.6：0.1~0.6：0.5~1：1~5:0.01~0.3.

Because traditional silicone oil is not dissolved in surfactant system, long-time service easily absorption is on hair and is not easy clear It washes, hair is made gradually to lose elasticity for a long time, generates disconnected hair, scalp clogging of pores causes scalp oxygen flow insufficient, and papilla may be by Gradually atrophy, scalp just start to occur it is withered and yellow, itch or even the phenomenon that alopecia.The present invention selects above-mentioned five kinds of substances as tax fat Agent substitutes traditional silicone oil, they are completely soluble in the surfactant system of shampoo, and their structure and skin Lubricant component in skin is all more approximate, therefore correct leatherware has extraordinary nourish to lubricate, and hair can be made salubrious soft after washing Along non-greasy, apparent heavy feeling, softening hair and the gloss for increasing hair are not had.And it is obtained through inventor's test of many times Go out, it is preferable to submissive and scalp the nourishes effect of hair when tax fat agent of the present invention uses said ratio.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the raw material for preparing of the shampoo also wraps Cation conditioner；The cation opsonizing agent the shampoo the weight percentage prepared in raw material for 0.15~ 0.9%；The cation opsonizing agent is guar hydroxypropyltrimonium chloride and Polyquaternium-10；The melon glue hydroxypropyl The weight ratio of base trimethyl ammonium chloride and Polyquaternium-10 is：Guar hydroxypropyltrimonium chloride：Polyquaternium-10 =1~6：0.5~3.

The present invention intersects collocation using two kinds of different type cationic hair conditioner bases, and the deep layer that can highlight shampoo is repaiied Protective function.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the raw material for preparing of the shampoo also wraps Containing surfactant；The surfactant is 19~37% in the weight percentage prepared in raw material of the shampoo； The surfactant includes laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate, Cocoamidopropyl betaine, cocounut oil acyl Amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl disodium glutamate；The laureth sodium sulfovinate, laruyl alcohol sulphur Acid esters sodium, Cocoamidopropyl betaine, coconut oleoyl amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl disodium glutamate Weight ratio be：Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA：Sodium methyl cocoyl taurate：Cocounut oil acyl disodium glutamate=13~18：1~5：2~6：1~2：1~3：1~3.

Surfactant used in the present invention is relatively mild surfactant, can mitigate shampoo to a certain extent Stimulation to scalp reduces and hair is injured.

As preferred embodiment of the ferment of the present invention without silicone oil shampoo, the raw material for preparing of the shampoo also wraps Containing preservative, the preservative is bromo- 2- nitropropanes -1, the 3- glycol of 2- and methylisothiazolinone；The bromo- 2- nitros of 2- Propane -1,3- glycol is 0.001~0.1% in the weight percentage prepared in raw material of the shampoo；The methyl is different Thiazolinone component is 0.01~0.2% in the weight percentage prepared in raw material of the shampoo.

Shampoo of the present invention uses the above-mentioned raw material non-stimulated to scalp and proportioning, plays and makees in shampoo jointly With stablizing shampoo character, effect is complete.

Ferment of the present invention is without silicone oil shampoo, in addition to said components clearly require, in the effect of the lossless present invention In the range of fruit, other adjunct ingredients, such as pH adjusting agent, essence etc. can be added or used to, those skilled in the art can press The common content of more solito standard selection.

Another object of the present invention is to provide preparation method of the above-mentioned ferment without silicone oil shampoo, comprise the following steps：

1st, deionized water is added in ratio in formula in pot is emulsified, 80~85 DEG C is then heated to, according to the weight of raw material Amount percentage weighs raw material, first adds in laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate, methyl cocoyl taurine Sodium, coconut oleoyl amine DEA, allantoin, after being evacuated to -0.06~0.08MPa, under stirring at low speed by 1~15min of its homogeneous extremely Uniformly, the guar hydroxypropyltrimonium chloride that 20 times of cold pure water disperse is added in, adds in the polyquaternary amine that 20 times of cold pure water disperse Salt -10, for 5~10min of homogeneous to uniform, moderate-speed mixer is kept the temperature 30 minutes, is added in glyceryl oleate and is started to drop while stirring Temperature；

2. add in cocounut oil acyl disodium glutamate, panthenol, C12-13 alcohol lactic acid when said components temperature is down to 45~50 DEG C Ester, Etidronic Acid, EDETATE SODIUM stir always to emulsification pot, middling speed；

3. a pair said components cool down, temperature added in when being down to 40~45 DEG C silk sericin, yeast beta-dextran, Carboxymethyl R-glucan sodium, carbohydrate isomer, phytosterol Queensland nut oleate, four isostearic acid of dipentaerythritol Ester, azadirachta seed extract, Anjidew NL50, piroctone olamine salt, radix-polygoni multiflori extract, Rhizoma Chuanxiong extract, three-C12-13 alkane Alcohol citrate, tea polyphenols and (isethionic acid) salt of hexamidine two are to emulsification pot, and 30~45min is to uniform for stirring；

4. weighing acid-base modifier citric acid or sodium hydroxide in ratio in formula, pH to 5.2~5.8 is adjusted；

5. weighing Cocoamidopropyl betaine in ratio in formula, it is added in emulsification pot, adjusting viscosity to 13000~ 18000mp.s reaches after product inner quality standard to get the ferment after testing without silicone oil shampoo.

The beneficial effects of the present invention are：The present invention provides a kind of ferment without silicone oil shampoo, ferment of the present invention The immune tune of two primary yeast extract of yeast beta-dextran and carboxymethyl R-glucan sodium is used in the formula of no silicone oil shampoo Activity is saved to promote skin of head growth, reparation and protection, raising hair follicle is active, reduces epilation, extends the life of hair Cycle has apparent facilitation effect for cell Proliferation, plays an important role of transdermal penetration and antiallergic anti-inflammatory.

Specific embodiment

To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present invention It is described further.

Embodiment 1

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment include following weight Percentage composition prepares raw material：Yeast beta-dextran 0.8%, carboxymethyl R-glucan sodium 0.8%, carbohydrate isomer 0.8%th, plant extracts 1.3%, panthenol 0.9%, allantoin 0.3%, Etidronic Acid 0.1%, EDETATE SODIUM 0.1%, PCA Sodium 0.8%, silk sericin 0.5%, anti-dandruff and itching-relieving agent 1.2%, tax fat agent 4.5%, cation opsonizing agent 0.4%, surface The bromo- 2- nitropropanes -1,3- glycol 0.005% of activating agent 21.9%, 2-, methylisothiazolinone 0.015%, pH adjusting agent 0.3% and the water of surplus.

Wherein, the plant extracts is radix-polygoni multiflori extract, Rhizoma Chuanxiong extract and tea polyphenols, and the fleece-flower root extracts The weight ratio of object, Rhizoma Chuanxiong extract and tea polyphenols is：Radix-polygoni multiflori extract：Rhizoma Chuanxiong extract：Tea polyphenols=5:5:3；

The anti-dandruff and itching-relieving agent is azadirachta seed extract, piroctone olamine salt and hexamidine two (isethionic acid) Salt；The weight ratio of the azadirachta seed extract, piroctone olamine salt and hexamidine two (isethionic acid) salt is：Print Spend chinaberry seed extract：Piroctone olamine salt：Hexamidine two (isethionic acid) salt=2:5:5；

It is different that the tax fat agent includes phytosterol Queensland nut oleate, C12-13 alcohol lactate, dipentaerythritol four Stearate, glyceryl oleate and three-C12-13 alkanol citrates；The phytosterol Queensland nut oleate, C12-13 Alcohol lactate, dipentaerythritol pentaerythritol tetraisostearate, the weight ratio of glyceryl oleate and three-C12-13 alkanol citrates For：Phytosterol Queensland nut oleate：C12-13 alcohol lactates：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate： Three-C12-13 alkanols citrate=0.3：0.3：0.8：3:0.1；

The cation opsonizing agent is guar hydroxypropyltrimonium chloride and Polyquaternium-10；The melon glue hydroxyl The weight ratio of hydroxypropyltrimonium chloride and Polyquaternium-10 is：Guar hydroxypropyltrimonium chloride：Polyquaternium- 10=3：1；

The surfactant includes laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate, cocamidopropyl propyl amide beet Alkali, coconut oleoyl amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl disodium glutamate；The laureth sodium sulfovinate, Laruyl alcohol sodium sulfovinate, Cocoamidopropyl betaine, coconut oleoyl amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl paddy The weight ratio of propylhomoserin disodium is：Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocoamidopropyl betaine：Coconut palm Oleamide DEA：Sodium methyl cocoyl taurate：Cocounut oil acyl disodium glutamate=13：2：3：1.5：1.2：1.2.

Preparation method of the ferment described in the present embodiment without silicone oil shampoo, comprises the following steps：

1. pair all production apparatus are washed with water and disinfected, emulsification pot is carried out at autoclave sterilization Reason；Deionized water is added in ratio in formula in pot is emulsified, 80~85 DEG C are then heated to, according to the weight percent of raw material Raw material is weighed, first adds in laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate, sodium methyl cocoyl taurate, cocounut oil acyl Amine DEA, allantoin, after being evacuated to -0.06~0.08MPa, by 1~15min of its homogeneous to uniform, addition under stirring at low speed The guar hydroxypropyltrimonium chloride that 20 times of cold pure water disperse adds in the Polyquaternium-10 that 20 times of cold pure water disperse, homogeneous For 5~10min to uniform, moderate-speed mixer is kept the temperature 30 minutes, is added in glyceryl oleate and is started to cool down while stirring；

Embodiment 2

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment include following weight Percentage composition prepares raw material：Yeast beta-dextran 0.5%, carboxymethyl R-glucan sodium 1%, carbohydrate isomer 1%, plant Object extract 2%, panthenol 1.5%, allantoin 0.3%, Etidronic Acid 0.08%, EDETATE SODIUM 0.08%, Anjidew NL50 0.6%, Silk sericin 2%, anti-dandruff and itching-relieving agent 0.6%, assign fat agent 4.6%, cation opsonizing agent 0.8%, surfactant 30%, The bromo- 2- nitropropanes -1,3- glycol 0.005% of 2-, methylisothiazolinone 0.015%, pH adjusting agent 0.3% and surplus Water.

Wherein, the plant extracts is radix-polygoni multiflori extract, Rhizoma Chuanxiong extract and tea polyphenols, and the fleece-flower root extracts The weight ratio of object, Rhizoma Chuanxiong extract and tea polyphenols is：Radix-polygoni multiflori extract：Rhizoma Chuanxiong extract：Tea polyphenols=3:1:5；

The anti-dandruff and itching-relieving agent is azadirachta seed extract, piroctone olamine salt and hexamidine two (isethionic acid) Salt；The weight ratio of the azadirachta seed extract, piroctone olamine salt and hexamidine two (isethionic acid) salt is：Print Spend chinaberry seed extract, piroctone olamine salt：Hexamidine two (isethionic acid) salt=2:1:0.5；

It is different that the tax fat agent includes phytosterol Queensland nut oleate, C12-13 alcohol lactate, dipentaerythritol four Stearate, glyceryl oleate and three-C12-13 alkanol citrates；The phytosterol Queensland nut oleate, C12-13 Alcohol lactate, dipentaerythritol pentaerythritol tetraisostearate, the weight ratio of glyceryl oleate and three-C12-13 alkanol citrates For：Phytosterol Queensland nut oleate：C12-13 alcohol lactates：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate： Three-C12-13 alkanols citrate=0.1：0.1：1：1:0.01；

The cation opsonizing agent is guar hydroxypropyltrimonium chloride and Polyquaternium-10；The melon glue hydroxyl The weight ratio of hydroxypropyltrimonium chloride and Polyquaternium-10 is：Guar hydroxypropyltrimonium chloride：Polyquaternium- 10=1：3；

The surfactant includes laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate, cocamidopropyl propyl amide beet Alkali, coconut oleoyl amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl disodium glutamate；The laureth sodium sulfovinate, Laruyl alcohol sodium sulfovinate, Cocoamidopropyl betaine, coconut oleoyl amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl paddy The weight ratio of propylhomoserin disodium is：Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocoamidopropyl betaine：Coconut palm Oleamide DEA：Sodium methyl cocoyl taurate：Cocounut oil acyl disodium glutamate=18：1：4：1：3：3；

Preparation method of the ferment described in the present embodiment without silicone oil shampoo is same as Example 1.

Embodiment 3

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment include following weight Percentage composition prepares raw material：Yeast beta-dextran 1%, carboxymethyl R-glucan sodium 0.1%, carbohydrate isomer 0.5%, Plant extracts 2%, panthenol 2.3%, allantoin 0.2%, Etidronic Acid 0.05%, EDETATE SODIUM 0.05%, Anjidew NL50 0.6%th, silk sericin 0.8%, anti-dandruff and itching-relieving agent 1.2%, tax fat agent 5%, cation opsonizing agent 0.5%, surface-active Agent 19%, the bromo- 2- nitropropanes -1,3- glycol 0.005% of 2-, methylisothiazolinone 0.015%, 0.3% and of pH adjusting agent The water of surplus.

Wherein, the plant extracts is radix-polygoni multiflori extract, Rhizoma Chuanxiong extract and tea polyphenols, and the fleece-flower root extracts The weight ratio of object, Rhizoma Chuanxiong extract and tea polyphenols is：Radix-polygoni multiflori extract：Rhizoma Chuanxiong extract：Tea polyphenols=1:0.5:0.5；

The anti-dandruff and itching-relieving agent is azadirachta seed extract, piroctone olamine salt and hexamidine two (isethionic acid) Salt；The weight ratio of the azadirachta seed extract, piroctone olamine salt and hexamidine two (isethionic acid) salt is：Print Spend chinaberry seed extract, piroctone olamine salt：Hexamidine two (isethionic acid) salt=5:0.1:0.5；

It is different that the tax fat agent includes phytosterol Queensland nut oleate, C12-13 alcohol lactate, dipentaerythritol four Stearate, glyceryl oleate and three-C12-13 alkanol citrates；The phytosterol Queensland nut oleate, C12-13 Alcohol lactate, dipentaerythritol pentaerythritol tetraisostearate, the weight ratio of glyceryl oleate and three-C12-13 alkanol citrates For：Phytosterol Queensland nut oleate：C12-13 alcohol lactates：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate： Three-C12-13 alkanols citrate=0.1：0.1：0.8：5:0.01；

The cation opsonizing agent is guar hydroxypropyltrimonium chloride and Polyquaternium-10；The melon glue hydroxyl The weight ratio of hydroxypropyltrimonium chloride and Polyquaternium-10 is：Guar hydroxypropyltrimonium chloride：Polyquaternium- 10=5：0.8；

The surfactant includes laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate, cocamidopropyl propyl amide beet Alkali, coconut oleoyl amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl disodium glutamate；The laureth sodium sulfovinate, Laruyl alcohol sodium sulfovinate, Cocoamidopropyl betaine, coconut oleoyl amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl paddy The weight ratio of propylhomoserin disodium is：Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocoamidopropyl betaine：Coconut palm Oleamide DEA：Sodium methyl cocoyl taurate：Cocounut oil acyl disodium glutamate=13：1：2：1：1：1；

Embodiment 4

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The difference of the additive amount that the difference is that only the yeast beta-dextran and carboxymethyl R-glucan sodium of embodiment 1, this reality It applies in example, the yeast beta-dextran is 1% in the weight percentage prepared in raw material of the shampoo, the carboxymethyl Beta glucan sodium is 1% in the weight percentage prepared in raw material of the shampoo.

Embodiment 5

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The difference of the additive amount that the difference is that only the yeast beta-dextran and carboxymethyl R-glucan sodium of embodiment 1, this reality It applies in example, the yeast beta-dextran is 0.1% in the weight percentage prepared in raw material of the shampoo, the carboxylic first Base beta glucan sodium is 0.1% in the weight percentage prepared in raw material of the shampoo.

Embodiment 6

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The yeast beta-dextran of embodiment 1 is identical with carboxymethyl R-glucan sodium total amount of adding, the present embodiment it is different from embodiment 1 it Place is only that yeast beta-dextran is different with the weight ratio of carboxymethyl R-glucan sodium, yeast beta-dextran and carboxylic in the present embodiment The weight ratio of methyl beta glucan sodium is 2:1.

Embodiment 7

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The yeast beta-dextran of embodiment 1 is identical with carboxymethyl R-glucan sodium total amount of adding, the present embodiment it is different from embodiment 1 it Place is only that yeast beta-dextran is different with the weight ratio of carboxymethyl R-glucan sodium, yeast beta-dextran and carboxylic in the present embodiment The weight ratio of methyl beta glucan sodium is 1:2.

Embodiment 8

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The difference that the difference is that only plant extract species of embodiment 1, plant extracts is fleece-flower root extraction in the present embodiment Object.

Embodiment 9

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The difference that the difference is that only plant extract species of embodiment 1, plant extracts is rhizome of chuanxiong extract in the present embodiment.

Embodiment 10

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The difference that the difference is that only plant extract species of embodiment 1, plant extracts is tea polyphenols in the present embodiment.

Embodiment 11

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The difference that the difference is that only plant extract species of embodiment 1, plant extracts is fleece-flower root extraction in the present embodiment The weight ratio of object and tea polyphenols, the radix-polygoni multiflori extract and tea polyphenols is：Radix-polygoni multiflori extract：Tea polyphenols=5:3.

Embodiment 12

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The difference that the difference is that only plant extract species of embodiment 1, plant extracts is rhizome of chuanxiong extract in the present embodiment And tea polyphenols, the weight ratio of the rhizome of chuanxiong extract and tea polyphenols are：Rhizome of chuanxiong extract：Tea polyphenols=5:3.

Embodiment 13

A kind of embodiment of the ferment of the present invention without silicone oil shampoo, shampoo described in the present embodiment prepare raw material with The difference that the difference is that only plant extract species of embodiment 1, plant extracts is fleece-flower root extraction in the present embodiment The weight ratio of object and rhizome of chuanxiong extract, the radix-polygoni multiflori extract and rhizome of chuanxiong extract is：Radix-polygoni multiflori extract：Rhizome of chuanxiong extracts Object=1:1.

Comparative example 1

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only yeast beta-dextran and carboxymethyl R-glucan sodium of embodiment 1 is free of ferment in this comparative example Female beta glucan, the carboxymethyl R-glucan sodium are 1.6% in the weight percentage prepared in raw material of the shampoo.

Preparation method of the ferment described in this comparative example without silicone oil shampoo is same as Example 1.

Comparative example 2

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only yeast beta-dextran and carboxymethyl R-glucan sodium of embodiment 1 is free of carboxylic in this comparative example Methyl beta glucan sodium, the yeast beta-dextran are 1.6% in the weight percentage prepared in raw material of the shampoo.

Comparative example 3

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only yeast beta-dextran and carboxymethyl R-glucan sodium of embodiment 1 is free of carboxylic in this comparative example Methyl beta glucan sodium and yeast beta-dextran.

Comparative example 4

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only carbohydrate isomer of embodiment 1 is free of carbohydrate isomer in this comparative example.

Comparative example 5

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only plant extracts of embodiment 1 is free of plant extracts in this comparative example.

Comparative example 6

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only anti-dandruff and itching-relieving agent of embodiment 1 is free of anti-dandruff and itching-relieving agent in this comparative example.

Comparative example 7

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only anti-dandruff and itching-relieving agent of embodiment 1 contains only azadirachta seed extract in this comparative example.

Comparative example 8

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only anti-dandruff and itching-relieving agent of embodiment 1, anti-dandruff and itching-relieving agent contains only piroctone described in this comparative example Ethanolamine salt.

Comparative example 9

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only anti-dandruff and itching-relieving agent of embodiment 1, anti-dandruff and itching-relieving agent described in this comparative example contain only hexamidine two (isethionic acid) salt.

Comparative example 10

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only anti-dandruff and itching-relieving agent of embodiment 1, anti-dandruff and itching-relieving agent described in this comparative example carry for azadirachta seed Take object and hexamidine two (isethionic acid) salt；The weight of the azadirachta seed extract and hexamidine two (isethionic acid) salt The ratio between be：Azadirachta seed extract：Hexamidine two (isethionic acid) salt=2:5.

Comparative example 11

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only anti-dandruff and itching-relieving agent of embodiment 1, anti-dandruff and itching-relieving agent described in this comparative example are piroctone second Alcohol amine salt and hexamidine two (isethionic acid) salt；The piroctone olamine salt and hexamidine two (isethionic acid) salt Weight ratio is：Piroctone olamine salt：Hexamidine two (isethionic acid) salt=1:1.

Comparative example 12

A kind of comparative example of the ferment of the present invention without silicone oil shampoo, shampoo described in this comparative example prepare raw material with The difference that the difference is that only anti-dandruff and itching-relieving agent of embodiment 1, anti-dandruff and itching-relieving agent described in this comparative example carry for azadirachta seed Take object and piroctone olamine salt；The azadirachta seed extract and the weight ratio of piroctone olamine salt are：India Chinaberry seed extract：Piroctone olamine salt=2:5.

Embodiment 14

Physico-chemical tests are carried out to 1~13 shampoo of embodiment, gained Testing index is as follows：

1st, character detects

1~13 shampoo of embodiment is suitable for viscosity, has good stability, and fragrant is charming, and silk profit is smooth, carefully Greasy uniform yellow transparent shampoo.

2nd, pH value detects

1~13 shampoo of embodiment is sampled, is measured with pH meter, measures pH value as 5.2~5.8.

3rd, viscosity number detects

1~13 shampoo of embodiment is sampled, is measured with viscosimeter, measures viscosity number 13000~18000.

4th, Detection of Stability

1~13 shampoo of embodiment is sampled, is encapsulated in transparence cosmetic bottle, is respectively placed in quartzy light According to, -15 DEG C, 5 DEG C, 25 DEG C, under 48 DEG C of experiment conditions, 3 by a definite date are carried out to appearance, fragrance, pH value, viscosity and sundry item The continuance test of the moon, sees whether the bad phenomenons such as bleed, layering, separation, precipitation, discoloration, peculiar smell, demulsification occur, detection knot Fruit show more than bad result do not appear in test process, illustrate that it has good stability.

5th, centrifugation detection

To 1~13 sampling described in embodiment, it is encapsulated in centrifuge tube under 3000r/min and centrifuges 30min, observation is Dispersion component, testing result do not show not dispersion component do not occur for no appearance, illustrate that its Combination is good.

6th, anaphylaxis is stimulated to detect

1~13 shampoo of embodiment is sampled, it is applied to the volunteer that 300 age brackets are 18-58 Sui in right amount On neck, 30min is observed, sees whether it phenomena such as redness, dermexanthesis, blistering occurs, observation indicate that, own in 30min Volunteer does not occur above-mentioned ill symptoms, illustrates that this product will not generate stimulation and allergy sex chromosome mosaicism to skin.

7th, comprehensive using effect detection

Using opinion poll point system, washed by the way that volunteer is asked to try out respectively described in embodiment 1~13 and comparative example 1~12 It becomes visible, and fills in table on probation and carry out overall merit its using effect.Every group of embodiment sample chooses the aspiration in all ages and classes stage Person 300 (volunteer 150 and the volunteer 150 of 38~58 age levels that age level is 18~38) is as on probation pair As hair washing in every two days once, is used continuously three months, fills in table on probation after on probation and scores.It is every in grade form to use effect Fruit total score is 5 points：5 points are best results, are represented very satisfied；4 points are preferable, are relatively satisfied with；3 points are that can receive；3 points It is below the scope that cannot receive, every using effect average situation is as shown in table 1：

1~12 shampoo items using effect average situation of 1 embodiment 1~13 of table and comparative example

As it can be seen from table 1 embodiment 1~13 and 1~12 shampoo of comparative example show as non-stimulated, cleannes Well, from the comparison of embodiment 1,4,5 and comparative example 1~3 as can be seen that yeast beta-dextran and carboxymethyl R-glucan sodium Addition can make shampoo have the effect of antiallergic anti-inflammatory, and antiallergic anti-inflammatory effects when two primary yeast extracts add simultaneously Better than the effect for only adding one of which；With the increase of yeast beta-dextran and the amount of carboxymethyl R-glucan sodium, shampoo Antiallergic anti-inflammatory effects increase, but the additive amount increase of yeast beta-dextran and carboxymethyl R-glucan sodium resists to a certain extent The effect of quick anti-inflammatory increases unobvious, and total amount of adding is controlled within 2%, the utilization rate higher of yeast extract；From embodiment 1 Comparison with embodiment 6,7 can be seen that under yeast beta-dextran and carboxymethyl R-glucan sodium additive amount unanimous circumstances, ferment The weight ratio of female beta glucan and carboxymethyl R-glucan sodium is 1:When 1, antiallergic anti-inflammatory effects are more preferably.From embodiment 1 and comparison The moisture retention comparison of example 4 is as can be seen that carbohydrate isomerism physical efficiency makes shampoo have preferable moistening effect.Embodiment 1, reality The comparison of the nourishes effect of example 8~13 and comparative example 5 is applied as can be seen that the addition of plant extracts can make shampoo have hair There is preferable nourishes effect, and under plant extracts total addition level unanimous circumstances, add the effect of three Plant Extracts Better than one of which or two kinds of effect is only added, illustrate that three Plant Extracts can compound, play synergistic effect.From The addition that the anti-dandruff Contrast on effect of embodiment 1 and comparative example 6~12 can be seen that anti-dandruff and itching-relieving agent can significantly improve shampoo Anti-dandruff effect, and under the additive amount unanimous circumstances of anti-dandruff and itching-relieving agent, when plant anti-dandruff agent and chemical anti-dandruff agent are used cooperatively It is anti-dandruff it is with obvious effects be better than using one of which or two kinds of anti-dandruff effect, illustrate chemical anti-dandruff agent and plant anti-dandruff agent phase With reference to, its stimulation to scalp is not only reduced, while best anti-dandruff effect can be reached again, highlight multiple anti-dandruff effect.

Embodiment 15

Hair compliance test is carried out to the commercially available shampoo of embodiment 1 and three kind of brand, test method is as follows：

1st, Asia human hair is taken, length 23cm is one group per 3g.By the laruyl alcohol sulphur for each group Hair grooming 3% chosen Acid esters ammonium salt solution is cleaned, and then each group hair is put into diethyl ether solution, observes each group hair hair squamous cell under the microscope Structure destroys situation and counts, marks.By the sodium dodecyl sulfate solution of big topknot (Asia human hair) mass concentration 3% After cleaning, impregnated in ether 24 it is small when, will be each by ether treated topknot the is made long 23cm of multi beam, the small topknot of weight 3g After small topknot is soaked with distilled water, rubbed with the sodium dodecyl sulfate solution 2g of mass concentration 3% wash 2~3 minutes respectively, then It is rinsed well with flowing water, naturally dry is for use.

2nd, wet comb resistance measurement：Each 3 grams of the commercially available shampoo sample of embodiment 1 and three kind of brand is respectively used to rub and washes one The small topknot of beam step 1 treated long 23cm, weight 3g are rubbed and wash the time as 5 minutes, then respectively with 40 DEG C of constant streams flushings 2 minutes, four washed beam Hair grooming Texture instruments (BROOKFIELD, CT3-2K) are tested.

3rd, comb resistance measurement is done：3 grams of the commercially available shampoo of embodiment 1 and three kind of brand is respectively used to rub and washes a branch of step The small topknot of 1 treated long 23cm, weight 3g are rubbed and wash the time as 5 minutes, then respectively with 40 DEG C of constant streams flushings 2 minutes, Four beam Hair grooming Texture instruments (BROOKFIELD, CT3-2K) of drying are tested hair dryer by reusable heat hair-dryer after.

Test result is shown in Table 2 and table 3.

The wet comb resistance (unit of table 2：Newton)

The dry comb resistance (unit of table 3：Newton)

Sample	Embodiment 1	Commercially available shampoo A	Commercially available shampoo B	Commercially available shampoo C
					Resistance	41	60	65	70

It can be seen that from the result of table 2 and table 3.Shampoo of the present invention can make head compared with common commercially available shampoo Dry, the wet comb drop in resistance of hair, can greatly improve the compliance of hair.

Embodiment 16

Hair damage recovery test is carried out to 1~13 shampoo of embodiment, test method is as follows：

1st, Asia human hair is taken, length 10cm, every 10 are one group, totally 15 groups.By each group Hair grooming 3% chosen Bay alcohol sulfuric ester ammonium salt solution is cleaned, and machinery rubbing 5min is carried out to each group hair, observes each group hair hair under the microscope Squamous cell structure destroys situation and counts, marks.

2nd, above-mentioned each group hair is soaked in respectively in 1~13 shampoo solution of embodiment, and constantly stirred, respectively It takes out, is rinsed 3 times, each 1min with clear water, then naturally dry after 5min, 10min, 15min, 20min.

3rd, each group hair after drying is observed under the microscope respectively, and the hair surface marked in counting step 1 is damaged Hair scale piece eucaryotic cell structure repairs situation and calculates repair rate：

Hair surface is damaged hair scale piece cell repair rate and is shown in Table 4.

The hair surface of 4 embodiment of table, 1~13 shampoo is damaged hair scale piece cell repair rate

It is respectively provided with and preferably repaiies from table 4, it can be seen that shampoo of the present invention is damaged hair surface a mao squamous cell Reactivation power.

Embodiment 17

In order to verify the fungistatic effect of anti-dandruff and itching-relieving agent of the present invention, following fungistatic effect testing experiment is carried out：

1st, according to United States Pharmacopeia USP32 and Guangzhou microbiological analysis inspection center《The structure of cosmetics protective system and Its efficiency evaluation》, prepare bacterium and fungi bacteria suspension；

2nd, prepare the sample of embodiment 1 and comparative example 6~12, aseptically weigh 100g and be placed in aseptic bottle, it is waiting Kind；

3rd, bacterium 72h experiments are once added：Bacteria suspension is added in into sample, is inoculated with, makes in sample by 1% volume of product quality The bacteria containing amount concentration of bacterium and fungi is 10⁵-10⁶(cfu/g).With connecing the of bacterium after glass bar stirring or vortex oscillation mixing 0h, 1h, 2h, 4h, for 24 hours, 48h, 72h when sampling detection bacterium amount, record data；

4th, above-mentioned plus bacterium sample 5g is weighed under aseptic condition, addition extremely the 45ml physiological saline containing sterilizing and bead In 100ml triangular flasks, after fully vibrating mixing, counting method is poured into using tablet and is diluted to successively suitable for gradient in 10 times of ratios, Each gradient dilution liquid 1ml is taken to add in plate, then pours into and is cooled to 40-45 DEG C or so culture medium, in 37 DEG C of Bacteria Cultures 2 days and Fungal culture counts after 3 days, and fungistatic effect is shown in Table 5.

The antibacterial test result of 5 embodiment 1 of table and comparative example 6~12

As it can be seen from table 1 the sum of bacterium, mould and yeast is just greatly reduced in embodiment 1 in 1h, illustrate this The shampoo is invented with preferable fungistatic effect.This is can be seen that from the fungistatic effect of embodiment 1 and comparative example 6~12 The anti-dandruff and itching-relieving agent is invented with apparent fungistatic effect, and under the additive amount unanimous circumstances of anti-dandruff and itching-relieving agent, plant Anti-dandruff agent and chemical anti-dandruff agent cooperation are substantially better than with the fungistatic effect of the proportioning in embodiment 1 using one of which or two kinds Fungistatic effect, illustrate that chemical anti-dandruff agent is combined with plant anti-dandruff agent, fungistatic effect is more preferably.

Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, those of ordinary skill in the art should Understand, technical scheme can be modified or replaced equivalently, without departing from the essence of technical solution of the present invention And scope.

Claims

1. a kind of ferment is without silicone oil shampoo, which is characterized in that the shampoo prepare raw material include yeast beta-dextran and Carboxymethyl R-glucan sodium；The weight percent of the yeast beta-dextran and carboxymethyl R-glucan sodium in the shampoo contains The sum of amount is 0.2~2%.

2. ferment as described in claim 1 is without silicone oil shampoo, which is characterized in that the yeast beta-dextran and carboxymethyl β-Portugal The weight ratio of glycan sodium is：Yeast beta-dextran：Carboxymethyl R-glucan sodium=0.1~1:0.1~1；Preferably, the ferment The weight ratio of female beta glucan and carboxymethyl R-glucan sodium is：Yeast beta-dextran：Carboxymethyl R-glucan sodium=1:1.

3. ferment as described in claim 1 is without silicone oil shampoo, which is characterized in that the shampoo prepares raw material also comprising sugar Class isomer；The carbohydrate isomer the shampoo the weight percentage prepared in raw material for 0.1~ 1%.

4. ferment as described in claim 1 is without silicone oil shampoo, which is characterized in that the shampoo prepares raw material also comprising plant Object extract, the plant extracts are 0.3~3% in the weight percentage prepared in raw material of the shampoo；It is described Plant extracts includes at least one of radix-polygoni multiflori extract, Rhizoma Chuanxiong extract and tea polyphenols；Preferably, the plant extract Object includes radix-polygoni multiflori extract, Rhizoma Chuanxiong extract and tea polyphenols；The weight of the radix-polygoni multiflori extract, Rhizoma Chuanxiong extract and tea polyphenols Amount the ratio between be：Radix-polygoni multiflori extract：Rhizoma Chuanxiong extract：Tea polyphenols=0.1~1:0.1~1:0.1~1.

5. ferment as described in claim 1 is without silicone oil shampoo, which is characterized in that preparing in raw material for the shampoo also includes Hair conditioner, the hair conditioner include panthenol, allantoin, Etidronic Acid, EDETATE SODIUM, Anjidew NL50 and silk silk gum At least one of albumen；Preferably, the hair conditioner includes panthenol, allantoin, Etidronic Acid, EDETATE SODIUM, PCA Sodium and silk sericin；Raw material is prepared in the shampoo, the weight percentage of the panthenol is 0.5~2.5%； The weight percentage of the allantoin is 0.1~0.5%；The weight percentage of the Etidronic Acid for 0.05~ 0.15%；The weight percentage of the EDETATE SODIUM is 0.05~0.15%；The weight percentage of the Anjidew NL50 is 0.5 ~1%；The weight percentage of the silk sericin is 0.3~3%.

6. ferment as described in claim 1 is without silicone oil shampoo, which is characterized in that the shampoo prepares raw material also comprising going Consider antipruritic to be worth doing, the anti-dandruff and itching-relieving agent is 0.16~1.3% in the weight percentage prepared in raw material of shampoo；It is described to go It considers antipruritic to be worth doing and includes azadirachta seed extract, piroctone olamine salt and hexamidine two (isethionic acid) salt.

7. ferment as described in claim 1 is without silicone oil shampoo, which is characterized in that the azadirachta seed extract, piroctone The weight ratio of ethanolamine salt and hexamidine two (isethionic acid) salt is：Azadirachta seed extract：Piroctone olamine salt： Hexamidine two (isethionic acid) salt=1~5:0.1~3:0.5~5.

8. ferment as described in claim 1 is without silicone oil shampoo, which is characterized in that the shampoo prepares raw material also comprising tax Fat agent, described to assign fat agent in the weight percentage prepared in raw material of the shampoo be 1.71~7.5%；The tax fat agent Include phytosterol Queensland nut oleate, C12-13 alcohol lactate, dipentaerythritol pentaerythritol tetraisostearate, glyceryl oleate With three-C12-13 alkanol citrates；The phytosterol Queensland nut oleate, C12-13 alcohol lactate, dimerization Ji Wusi The weight ratio of alcohol pentaerythritol tetraisostearate, glyceryl oleate and three-C12-13 alkanol citrates is：Phytosterol Queensland nut Oleate：C12-13 alcohol lactates：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate：Three-C12-13 alkanol citric acids Ester=0.1~0.6：0.1~0.6：0.5~1：1~5:0.01~0.3.

9. ferment is without silicone oil shampoo as any one of claim 1~8, which is characterized in that the preparation of the shampoo Raw material also includes cation opsonizing agent；The cation opsonizing agent the shampoo prepare raw material in weight percentage For 0.15~0.9%；The cation opsonizing agent is guar hydroxypropyltrimonium chloride and Polyquaternium-10；The melon The weight ratio of youngster's glue hydroxypropyl-trimethyl ammonium chloride and Polyquaternium-10 is：Guar hydroxypropyltrimonium chloride：Poly- season Ammonium salt -10=1~6：0.5~3.

10. ferment as claimed in claim 9 is without silicone oil shampoo, which is characterized in that the raw material for preparing of the shampoo also includes Surfactant；The surfactant is 19~37% in the weight percentage prepared in raw material of the shampoo；Institute It states surfactant and includes laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate, Cocoamidopropyl betaine, coconut oleoyl amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl disodium glutamate；The laureth sodium sulfovinate, laruyl alcohol sulfuric acid Ester sodium, Cocoamidopropyl betaine, coconut oleoyl amine DEA, sodium methyl cocoyl taurate and cocounut oil acyl disodium glutamate Weight ratio is：Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA： Sodium methyl cocoyl taurate：Cocounut oil acyl disodium glutamate=13~18：1~5：2~6：1~2：1~3：1~3.