CN103169631B - A kind of submissive glossy shampoo and preparation method containing Chinese medicine composition - Google Patents
A kind of submissive glossy shampoo and preparation method containing Chinese medicine composition Download PDFInfo
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Abstract
The invention discloses a kind of submissive glossy shampoo and the preparation method that contain Chinese medicine composition, this shampoo is made up of following raw material: laureth ammonium sulfate, ammonium lauryl sulfate, dodecanamide propyl hydroxyl sulphur betanin, glycol distearate, decyl glucoside, coconut oleoyl amine MEA, essence, cetearyl alcohol, citric acid, myristoyl-N-methylaminoacetic acid sodium, polydimethylsiloxane, trideceth-5, acrylic acid esters co-polymer, dimethiconol, dodecylbenzene sodium sulfonate, Silk Amino Acids, Radix Rehmanniae Preparata extracting solution, Fructus Lycii extracting solution, Radix Polygoni Multiflori extracting solution, Radix Angelicae Sinensis extracting solution, Radix Ginseng extractive solution, Polyquaternium-10, palmitamide hydroxypropyltrimonium chloride, triethanolamine, D-panthenol, EDETATE SODIUM, antiseptic and deionized water, the submissive easy comb of hair is made after hair washing washing of the present invention, hair cleaning is pliable and tough and be rich in healthy glow, can nutrition hair, the long-acting moisturizing of deep layer, prevents that hair is withered, bifurcated and water loss.
Description
Technical field
The present invention relates to a kind of shampoo, particularly relate to a kind of shampoo containing Chinese medicine composition.
Background technology
Hair has certain defence and keeps the function of body temperature, the more important thing is to have very strong rhetorical function to human body, and coordination that is correct, facial, that take on cervical region so that whole figure seems particularly important.
Current various shampoo has become people and to have lived indispensable articles for use, and along with growth in the living standard, people are more and more higher for the selection requirements of shampoo.Wish shampoo except while can cleaning hair, also there is the health care to hair and scalp.
Summary of the invention
While the object of this invention is to provide a kind of energy high-efficiency washing hair, scalp, also can strengthen the submissive glossy shampoo containing Chinese medicine composition that nutrition and the deep layer of hair are nourished further.
Second object of the present invention is to provide a kind of preparation method of the submissive glossy shampoo containing Chinese medicine composition.
Technical scheme of the present invention is summarized as follows:
A submissive glossy shampoo containing Chinese medicine composition, be made up of following raw material by mass percentage:
Laureth ammonium sulfate 5%-25%; Ammonium lauryl sulfate 1%-10%; Dodecanamide propyl hydroxyl sulphur betanin 1%-10%; Glycol distearate 0.5%-4%; Decyl glucoside 0.5%-4%; Coconut oleoyl amine MEA0.1%-3% essence 0.1%-1%; Cetearyl alcohol 0.1%-3%; Citric acid 0.1%-1%; Myristoyl-N-methylaminoacetic acid sodium 1%-10%; Polydimethylsiloxane 0.1%-5%; Trideceth-50.1%-5%; Acrylic acid esters co-polymer 0.1%-5%; Dimethiconol 0.1%-5%; Dodecylbenzene sodium sulfonate 0.1%-5%; Silk Amino Acids 0.1%-5%; Radix Rehmanniae Preparata extracting solution 0.1%-5%; Fructus Lycii extracting solution 0.1%-5%; Radix Polygoni Multiflori extracting solution 0.1%-5%; Radix Angelicae Sinensis extracting solution 0.1%-5%; Radix Ginseng extractive solution 0.1%-5%; Polyquaternium-10 0.1%-2%; Palmitamide hydroxypropyltrimonium chloride 0.1%-2%; Triethanolamine 0.1%-2%; D-panthenol 0.1%-2%; EDETATE SODIUM 0.01%-0.5%; Antiseptic 0.01%-0.5%; Deionized water surplus.
Described essence is ice orange essence, flavoring pineapple essence, strawberry essence, osmanthus flower fragrance or Hami melon essence.
Described antiseptic is Methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate.
A preparation method for submissive glossy shampoo containing Chinese medicine composition, comprises the steps:
(1) following raw material is taken by mass percentage:
Laureth ammonium sulfate 5%-25%; Ammonium lauryl sulfate 1%-10%; Dodecanamide propyl hydroxyl sulphur betanin 1%-10%; Glycol distearate 0.5%-4%; Decyl glucoside 0.5%-4%; Coconut oleoyl amine MEA0.1%-3% essence 0.1%-1%; Cetearyl alcohol 0.1%-3%; Citric acid 0.1%-1%; Myristoyl-N-methylaminoacetic acid sodium 1%-10%; Polydimethylsiloxane 0.1%-5%; Trideceth-50.1%-5%; Acrylic acid esters co-polymer 0.1%-5%; Dimethiconol 0.1%-5%; Dodecylbenzene sodium sulfonate 0.1%-5%; Silk Amino Acids 0.1%-5%; Radix Rehmanniae Preparata extracting solution 0.1%-5%; Fructus Lycii extracting solution 0.1%-5%; Radix Polygoni Multiflori extracting solution 0.1%-5%; Radix Angelicae Sinensis extracting solution 0.1%-5%; Radix Ginseng extractive solution 0.1%-5%; Polyquaternium-10 0.1%-2%; Palmitamide hydroxypropyltrimonium chloride 0.1%-2%; Triethanolamine 0.1%-2%; D-panthenol 0.1%-2%; EDETATE SODIUM 0.01%-0.5%; Antiseptic 0.01%-0.5%; Deionized water surplus;
(2) apparatus and equipment are carried out sterilization treatment, add in reactor by described deionized water by the quantity specified in formula, rear input EDTA bis-receives, and starts and stirs, and keeps 25-28 to turn/min;
(3) acrylic acid esters co-polymer is dropped in reactor by the quantity that formula specifies, after stirring, add triethanolamine to liquid be even translucent thick after add Polyquaternium-10, warming while stirring, rise to 90 DEG C, after being incubated sterilizing in 10 minutes, start cooling;
(4) coconut oleoyl amine MEA, cetearyl alcohol, glycol distearate, dodecanamide propyl hydroxyl sulphur betanin is added when being cooled to 85 DEG C successively;
(5) 75 DEG C are cooled to, add laureth ammonium sulfate, ammonium lauryl sulfate successively, evacuation, keep vacuum 0.08mpa, air (aerofluxus) two to three times in suction still, after dissolving completely, add palmitamide hydroxypropyltrimonium chloride, 70-68 DEG C of insulation 1 hour;
(6) 45 DEG C are cooled to, add myristoyl-N-methylaminoacetic acid sodium, D-panthenol, decyl glucoside, polydimethylsiloxane, trideceth-5, dimethiconol, dodecylbenzene sodium sulfonate, Silk Amino Acids, Radix Rehmanniae Preparata extract, Fructus Lycii extract, Radix Polygoni Multiflori extract, Radix Angelicae Sinensis extract, Radix Ginseng extract, antiseptic and essence successively, add citric acid and stir;
(7) ON cycle pump, keeps homogenizing 1500rpm, by material by bottom cycle in still, keep system even;
(8) 38 DEG C are cooled to, discharging.
Described essence is ice orange essence, flavoring pineapple essence, strawberry essence, osmanthus flower fragrance or Hami melon essence.
Described antiseptic is Methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate.
Advantage of the present invention:
Can nutrition hair, the long-acting moisturizing of deep layer, can prevent that hair is withered, bifurcated and water loss, submissive easy comb, clean pliable and tough and be rich in healthy glow.
Experiment makes the cleaning of the submissive easy comb of hair, hair pliable and tough and is rich in healthy glow after proving hair washing of the present invention washing; Shampoo energy nutrition hair of the present invention, the long-acting moisturizing of deep layer, can prevent that hair is withered, bifurcated and water loss.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated.
The Radix Rehmanniae Preparata extracting solution that the present invention relates to, Fructus Lycii extracting solution, Radix Polygoni Multiflori extracting solution, Radix Angelicae Sinensis extracting solution, Radix Ginseng extractive solution and Silk Amino Acids are all purchased from Huzhou Zhenlu Biological Products Co., Ltd..
The raw material of embodiment 1-embodiment 5 takes all by mass percentage:
Embodiment 6
A preparation method for submissive glossy shampoo containing Chinese medicine composition, comprises the steps:
(1) raw material is taken by embodiment 1;
(2) apparatus and equipment are carried out sterilization treatment, add in reactor by described deionized water by the quantity specified in formula, rear input EDTA bis-receives, and starts and stirs, and keeps 25 turns/min; (also can select 28 turns/min, form new embodiment)
(3) acrylic acid esters co-polymer is dropped in reactor by the quantity that formula specifies, after stirring, add triethanolamine to liquid be even translucent thick after add Polyquaternium-10, warming while stirring, rise to 90 DEG C, after being incubated sterilizing in 10 minutes, start cooling;
(4) coconut oleoyl amine MEA, cetearyl alcohol, glycol distearate, dodecanamide propyl hydroxyl sulphur betanin is added when being cooled to 85 DEG C successively;
(5) 75 DEG C are cooled to, add laureth ammonium sulfate, ammonium lauryl sulfate successively, evacuation, keep vacuum 0.08mpa, air (aerofluxus) two to three times in suction still, after dissolving completely, add palmitamide hydroxypropyltrimonium chloride, 70-68 DEG C of insulation 1 hour;
(6) 45 DEG C are cooled to, add myristoyl-N-methylaminoacetic acid sodium, D-panthenol, decyl glucoside, polydimethylsiloxane, trideceth-5, dimethiconol, dodecylbenzene sodium sulfonate, Silk Amino Acids, Radix Rehmanniae Preparata extract, Fructus Lycii extract, Radix Polygoni Multiflori extract, Radix Angelicae Sinensis extract, Radix Ginseng extract, antiseptic and essence successively, add citric acid and stir;
(7) ON cycle pump, keeps homogenizing 1500rpm, by material by bottom cycle in still, keep system even;
(8) 38 DEG C are cooled to, discharging.
Result of use:
The shampoo having 50 people to use the embodiment of the present invention 6 to prepare voluntarily 2 months, within every three days, wash a hair, according to every human hair's length, select 1-3ml not, use shampoo of the present invention to wash hair, make it stop 1-2min at head, rear clear water is rinsed well, treat natural drying, reflect according to user: wash rear submissive easy comb, hair cleaning is pliable and tough and be rich in healthy glow; Shampoo energy nutrition hair of the present invention, the long-acting moisturizing of deep layer, can prevent that hair is withered, bifurcated and water loss.
The formula of embodiment 2-5 also has above-mentioned similar effect with shampoo prepared by the step of embodiment 6 (2)-(8).
Radix Rehmanniae Preparata, has another name called Radix Rehmanniae Preparata or throws oneself on the ground, and belonging to goatweed, is the tuber of Scrophulariaceae Radix Rehmanniae platymiscium Radix Rehmanniae, steams solarization form through processing.Include rehmanin, multiple glycoside material, organic acid and acidic polysaccharose, the effective ingredient such as various trace elements.It is a kind of first-class Chinese crude drug, has YIN nourishing effect of enriching blood, sweet, tepor, yin nourishing of enriching blood, black beard and hair, has the effect improving tyrosinase activity.Radix Rehmanniae Preparata extracting solution makes an addition to hair washing, hair care category in cosmetics, all can play hair blackening, impels hair black pigment to generate, can be used as nutrient and the conditioner of hair.
Radix Rehmanniae Preparata extracting solution, containing iridoid glycosides, the effective ingredient such as aminoacid, enlarged head blood capillary, blood circulation promoting, strengthens pliability, black hair.Make an addition in the hair washing in cosmetics, hair care category product and can impel the melanic generation of hair, make hair blackening.Also can be used as nutrient and the conditioner of hair.
Fructus Lycii is the dry mature fruit of plant of Solanaceae lycium barbarum.Containing alkaloid, coumarin, several amino acids.Another containing effective ingredient such as carotene, B-sitosterol, vitamin B, C, polysaccharide.There is Anti-hair loss, promote that melanin generates.
Medical research shows, it contains carotene, betanin, vitamin A, vitamin B1, vitamin B2, vitamin C and calcium, phosphorus, ferrum etc., has the pharmacological action increasing leukocyte activity, promote hepatocyte new life, also can blood pressure lowering, blood sugar lowering, blood fat.Fructus Lycii is also strengthening the body resistance, and spermatogenesis mends the good medicine of marrow, enriching yin and nourishing kidney, benefiting vital QI for tranquillizing, building body, slow down aging, evident in efficacy to chronic hepatitis, central serous chorioretinopathy, optic atrophy etc.; Also good therapeutic effect is had to diabetes, pulmonary tuberculosis etc.; To antitumor, protect the liver, blood pressure lowering, blood sugar lowering and old people's organ failure ageing disorders have very strong improvement result.As tonic invigorator treatment suffer from a deficiency of the kidney each disease and hepatorenal disease curative effect excellent, plasma testosterone cellulose content in human body can be significantly improved, reach the effect of keeping fit.Modern medicine study shows, Fructus Lycii has obvious inhibitory action to cancer cell in vitro, can be used for preventing the diffusion of cancerous cell and strengthening the immunologic function of human body.
Radix Polygoni Multiflori, property is bitter, sweet, puckery, taste temperature.Containing nutritional labelings such as lecithin, have effect of nourishing blood to expel wind, scalable nerve and endocrine function and hairy root nourishing, hair black pigment can be impelled to generate, and is hair blackening.Containing chrysophanol and much starch, there is good hair care effect.
The Radix Polygoni Multiflori can invigorating the liver and kidney, benefiting essence-blood, black beard and hair, bone and muscle strengthening, empty etc. for blood deficiency and yellow complexion, vertigo and tinnitus, early whitening of beard and hair, soreness of the waist and knees, numb limbs and tense tendons, bleeding not during menses, chronic malaria body.
Famous defying age prescription " Radix Polygoni Multiflori pill ", " Qibao Meiran Dan ", " Song Shan polygonic multiflori tea " are exactly be that principal agent is made with Radix Polygoni Multiflori Preparata.The old and feeble sign of middle-aged and elderly people can be improved with the Radix Polygoni Multiflori, as poliosis, dedentition, senile plaque etc., the raising of body immunity can be promoted, suppress to allow " lipofuscin " deposition in organ of people's aging.The Radix Polygoni Multiflori can also expand the coronary artery of heart, blood fat reducing, promotes erythrocytic generation, so to coronary heart disease, hyperlipidemia, old anemia, brain degeneration, senilism sign etc., have preventive effect.The alone amount of the Radix Polygoni Multiflori is every day 10 ~ 15 grams.Caulis Polygoni Multiflori.For the rattan of Polygonaceae herbaceos perennial Radix Polygoni Multiflori.Caulis Polygoni Multiflori has another name called Caulis Polygoni Multiflori.
Ming Dynasty Li Shizhen (1518-1593 A.D.) Compendium of Material Medica is recorded, and the Radix Polygoni Multiflori can " nourish blood the liver benefiting, controlling nocturnal emission with astringent drugs kidney tonifying, muscle reinforcing and bone strengthening, black beard and hair, is tonic medicine, and cold not dry, merit is on Radix Rehmanniae, all medicines of Radix Asparagi ".
The Radix Polygoni Multiflori is the tuber of polygonum multiflorum thunb, main containing anthraquinone substance, lecithin, crude fat, starch etc.It is a kind ofly to nourish blood, tonifying liver, controlling nocturnal emission with astringent drugs, kidney tonifying, bone and muscle strengthening, black beard and hair body-building tonic medicine.
Radix Polygoni Multiflori extracting solution is containing lecithin, and the effective ingredient such as starchy material, hairy root nourishing, promotes that melanin generates, black hair hair care.Hair blackening can be made, can be used as hair nutritional agent and conditioner and antibacterial, for hair care, hair care or hair tonic cosmetic, have good therapeutical effect for juvenile canities disease.
Radix Angelicae Sinensis is the root of umbellifer Radix Angelicae Sinensis, includes multiple volatile oil, sucrose, vitamin B12 and retinoid material.Cupreol is had containing in Palmic acid, stearic acid, myristic acid and unsaturated oleic acid, linoleic acid, not saponification composition in the saponification part of root.Enrich blood and invigorate blood circulation, menstruction regulating and pain relieving, loosening bowel to relieve constipation.For blood deficiency and yellow complexion, dizzy cardiopalmus, menoxenia, amenorrhea dysmenorrhea, asthenia cold abdominalgia, dryness of the intestine constipation, rheumatic arthralgia, injury from falling down, ulcer sores.Radix Angelicae Sinensis (processed with wine) promoting blood circulation to restore menstrual flow.For amenorrhea dysmenorrhea, rheumatic arthralgia, injury from falling down.
Radix Angelicae Sinensis extracting solution contains volatile oil, aminoacid, vitamin, the effective ingredient such as trace element.Its function mainly contain brighten, defying age.There is protective effect to hair, promote scalp cells growth, Anti-hair loss, moisten, anti-yellow hair poliosis, make that hair is pitch-black glossyly has the clean skin effect of speckle dispelling simultaneously.
Radix Ginseng is the root of Araliaceae Radix Ginseng, and containing multiple ginsenoside in root, low molecular peptide, aminoacid, the effective ingredient such as vitamin, increase hair intensity, prevent alopecia and poliosis regeneration.
Radix Ginseng plays regulatory role nerve system of human body, endocrine and blood circulation, can be widely used in the skin protection cosmeticss such as cream frost, emulsion and make nourishing additive agent.Because it has various nutrients, can cell viability be increased, and the effect circulated with peripheral vessel that can enhance metabolism.For in skin care item, skin smooth, soft flexible, slow down aging can be made, also can the generation of check melanin.Be used in hair products, can improve the intensity of hair, prevent the usefulness of alopecia and poliosis regeneration, life-time service makes hair pitch-black glossy.
Silk Amino Acids is natural silk cellulose hydrolysate, includes 17 seed amino acids.There is very strong permeability to skin, be applied to skin very easily through the epidermal keratinocyte of skin and hair, and then be that skin absorbs.Therefore have skin nutrition, strengthen epidermis cell vigor, the function of delaying skin aging is outstanding especially.Silk Amino Acids has good water absorption, can strengthen skin elasticity, prevents xerosis cutis crowfoot cracks, and can suppress the melanic generation in skin.For shampoo and hair conditioner, hair can be made flexible, there is gloss, soft and smooth, enhancing hair conditioning.Good compatibility is had to cosmetics such as cream frost, emulsion, hair-washing hair-care, bath foam.To human non-toxic, to skin and eye conjunctiva non-stimulated.
Polyquaternium-10 is flocculation antibacterial.As non-oxydizing sterilization algicide, can have higher content of cationic monomer, itself and anion also have good compatibility simultaneously, are easy to infiltration and are absorbed by hair, reach best hair assimilation effect.It has outstanding hair conditioning, can provide better conditioning effect to hair, the wet cardability that hair is had a distinctive style, improves the affinity of skin and the glossy of hair quality.
Suppress hair electrostatic, increase hair soft, improve wet comb property, reduce hair and tangle; Its lipophile film can keep hair lubricity, prevents water loss
Polyquaternary ammonium salt is that toxicity is less, and more gentle being suitable for of bactericidal action is applied to the antibacterial of personal-care supplies.
Claims (6)
1. the submissive glossy shampoo containing Chinese medicine composition, is characterized in that being made up of following raw material by mass percentage: laureth ammonium sulfate 5%-25%; Ammonium lauryl sulfate 1%-10%; Dodecanamide propyl hydroxyl sulphur betanin 1%-10%; Glycol distearate 0.5%-4%; Decyl glucoside 0.5%-4%; Coconut oleoyl amine MEA0.1%-3%; Essence 0.1%-1%; Cetearyl alcohol 0.1%-3%; Citric acid 0.1%-1%; Myristoyl-N-methylaminoacetic acid sodium 1%-10%; Polydimethylsiloxane 0.1%-5%; Trideceth-50.1%-5%; Acrylic acid esters co-polymer 0.1%-5%; Dimethiconol 0.1%-5%; Dodecylbenzene sodium sulfonate 0.1%-5%; Silk Amino Acids 0.1%-5%; Radix Rehmanniae Preparata extracting solution 0.1%-5%; Fructus Lycii extracting solution 0.1%-5%; Radix Polygoni Multiflori extracting solution 0.1%-5%; Radix Angelicae Sinensis extracting solution 0.1%-5%; Radix Ginseng extractive solution 0.1%-5%; Polyquaternium-10 0.1%-2%; Palmitamide hydroxypropyltrimonium chloride 0.1%-2%; Triethanolamine 0.1%-2%; D-panthenol 0.1%-2%; EDETATE SODIUM 0.01%-0.5%; Antiseptic 0.01%; Deionized water surplus.
2. a kind of submissive glossy shampoo containing Chinese medicine composition according to claim 1, is characterized in that described essence is ice orange essence, flavoring pineapple essence, strawberry essence, osmanthus flower fragrance or Hami melon essence.
3. a kind of submissive glossy shampoo containing Chinese medicine composition according to claim 1, is characterized in that described antiseptic is Methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate.
4. a preparation method for the submissive glossy shampoo containing Chinese medicine composition, is characterized in that comprising the steps:
(1) following raw material is taken by mass percentage:
Laureth ammonium sulfate 5%-25%; Ammonium lauryl sulfate 1%-10%; Dodecanamide propyl hydroxyl sulphur betanin 1%-10%; Glycol distearate 0.5%-4%; Decyl glucoside 0.5%-4%; Coconut oleoyl amine MEA0.1%-3%; Essence 0.1%-1%; Cetearyl alcohol 0.1%-3%; Citric acid 0.1%-1%; Myristoyl-N-methylaminoacetic acid sodium 1%-10%; Polydimethylsiloxane 0.1%-5%; Trideceth-50.1%-5%; Acrylic acid esters co-polymer 0.1%-5%; Dimethiconol 0.1%-5%; Dodecylbenzene sodium sulfonate 0.1%-5%; Silk Amino Acids 0.1%-5%; Radix Rehmanniae Preparata extracting solution 0.1%-5%; Fructus Lycii extracting solution 0.1%-5%; Radix Polygoni Multiflori extracting solution 0.1%-5%; Radix Angelicae Sinensis extracting solution 0.1%-5%; Radix Ginseng extractive solution 0.1%-5%; Polyquaternium-10 0.1%-2%; Palmitamide hydroxypropyltrimonium chloride 0.1%-2%; Triethanolamine 0.1%-2%; D-panthenol 0.1%-2%; EDETATE SODIUM 0.01%-0.5%; Antiseptic 0.01%; Deionized water surplus;
(2) apparatus and equipment are carried out sterilization treatment, described deionized water is added in reactor by the quantity specified in formula, rear input EDETATE SODIUM, start and stir, keep 25-28 to turn/min;
(3) acrylic acid esters co-polymer is dropped in reactor by the quantity that formula specifies, after stirring, add triethanolamine to liquid be even translucent thick after add Polyquaternium-10, warming while stirring, rise to 90 DEG C, after being incubated sterilizing in 10 minutes, start cooling;
(4) coconut oleoyl amine MEA, cetearyl alcohol, glycol distearate, dodecanamide propyl hydroxyl sulphur betanin is added when being cooled to 85 DEG C successively;
(5) be cooled to 75 DEG C, add laureth ammonium sulfate, ammonium lauryl sulfate successively, evacuation, keep vacuum 0.08mpa, air two to three times in suction still, after dissolving completely, add palmitamide hydroxypropyltrimonium chloride, 70-68 DEG C of insulation 1 hour;
(6) 45 DEG C are cooled to, add myristoyl-N-methylaminoacetic acid sodium, D-panthenol, decyl glucoside, polydimethylsiloxane, trideceth-5, dimethiconol, dodecylbenzene sodium sulfonate, Silk Amino Acids, Radix Rehmanniae Preparata extract, Fructus Lycii extract, Radix Polygoni Multiflori extract, Radix Angelicae Sinensis extract, Radix Ginseng extract, antiseptic and essence successively, add citric acid and stir;
(7) ON cycle pump, keeps homogenizing 1500rpm, by material by bottom cycle in still, keep system even;
(8) 38 DEG C are cooled to, discharging.
5. the preparation method of a kind of submissive glossy shampoo containing Chinese medicine composition according to claim 4, is characterized in that described essence is ice orange essence, flavoring pineapple essence, strawberry essence, osmanthus flower fragrance or Hami melon essence.
6. the preparation method of a kind of submissive glossy shampoo containing Chinese medicine composition according to claim 4, is characterized in that described antiseptic is Methylisothiazolinone or iodine propilolic alcohol butyl mephenesin Carbamate.
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CN111956587B (en) * | 2020-09-16 | 2021-05-04 | 孙开军 | Black-hair and bright-hair shampoo and preparation method thereof |
CN112494418A (en) * | 2020-12-08 | 2021-03-16 | 任世元 | Traditional Chinese medicine fermented shampoo and preparation method thereof |
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