CN106172400A - A kind of spraying film-forming type fruit and vegerable or crop bagging composite and preparation and application thereof - Google Patents

A kind of spraying film-forming type fruit and vegerable or crop bagging composite and preparation and application thereof Download PDF

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Publication number
CN106172400A
CN106172400A CN201610539095.3A CN201610539095A CN106172400A CN 106172400 A CN106172400 A CN 106172400A CN 201610539095 A CN201610539095 A CN 201610539095A CN 106172400 A CN106172400 A CN 106172400A
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vegerable
fruit
crop
film
forming type
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CN106172400B (en
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蒋刚彪
刘永林
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South China Agricultural University
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South China Agricultural University
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0237Devices for protecting a specific part of a plant, e.g. roots, trunk or fruits
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10Macromolecular compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/16Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
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    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/04Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aldehyde or keto groups, or thio analogues thereof, directly attached to an aromatic ring system, e.g. acetophenone; Derivatives thereof, e.g. acetals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/06Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
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    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/06Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/24Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/26Meliaceae [Chinaberry or Mahogany family], e.g. mahogany, langsat or neem
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]
    • A01N65/44Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass

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Abstract

The present invention discloses one spraying film-forming type fruit and vegerable or crop bagging composite and preparation and application thereof, belongs to functional composite material and fruit and vegerable or crop bagging field.This material includes following component the most in parts by mass: 5~30 parts of film property materials, 58~94 parts of dispersants, 1~10 part of medicine carrying reinforcing material, 0.1~2 part of insect protected antiviral agents, 0~0.1 part of dyestuff.This material polychrome and have good insect protected disease-resistant performance, sprays after air-drying on fruit and vegerable or crop surface, adheres to fruit and vegerable or crop surface forms thin film, reach the purpose of bagging, it does not affect growth, has no side effect, it is possible to long-acting slow-release goes out insect protected disease-resistance substance.This material preparation method is simple, and cost of material is relatively low;Also can replace Pesticide use, the problem solving pesticide residues, can be used for producing green organic food;Action time is permanent, can maintain 1~3 months;Cannot be only used for fruit and vegerable, it may also be used for the insect protected of crops, flowers, trees etc. is disease-resistant.

Description

A kind of spraying film-forming type fruit and vegerable or crop bagging composite and preparation and application thereof
Technical field
The invention belongs to functional composite material and fruit and vegerable or crop bagging field, be specifically related to a kind of spraying film-forming type fruit Vegetables or crop bagging composite and preparation method and application.
Background technology
Current era, bag fruit and vegetable are increasingly welcome by masses and like, not only due to by protected by bagging Fruit and vegerable mouthfeel is clear and melodious sweet, and bagging contributes to fruit and vegerable and prevents disease pest from encroaching on, and reduces pesticide application number of times, thus reduces pesticide Residual.But the most well received fruit-vegetable covering bag uses and extremely bothers, need artificial ladder or climb up fruit tree fruit and vegerable are overlapped one by one Bag and tie up.By using environment, manpower and the huge restriction of cost, additionally, existing fruit-vegetable covering bag material generally uses nonwoven Cloth, plastics, paper etc., be easily detained rainwater, dew, usually makes to be overlapped in the environment that the fruit and vegerable pricked are in humidity, easily grows Raw phytopathogen, causes diseases of garden stuff, and in order to avoid harmful microorganism is bred, some bagging is in internal layer coating or has soaked long-acting Sustained-release pesticides, adds the risk that fruit and vegerable pesticide seriously remains undoubtedly.Therefore, the fruit vegetable set that property easy to use, safe is good Bag technique needs exploitation badly.This fruit vegetable bagging technique aims to solve the problem that and takes place frequently due to pest and disease damage and domestic labour force reduces day by day Social overall background under, bagging cause not in time fruit and vegerable total crop failure or Quality Down, the problem that economic benefit is badly damaged.
Before spraying pesticide is fruit-vegetable covering bag or Main Means that after bagging, insect protected is disease-resistant, owing to pesticide dosage is big, point Solve slow, easily accumulate in crops, human health is constituted huge threat.And due to the drug resistance of insect, pathogenic bacteria etc. Property be continuously increased, use conventional pesticide insect protected disease resisting effect decline, high-toxic pesticide is continued on, and causes vicious cycle, ring Environment pollution is increasingly serious.Along with the continuous enhancing of health of people idea, the demand of pollution-free food is continuously increased by people, novel not Use pesticide to realize fruit and vegerable and the disease-resistant new tool of crops insect protected, new material are welcome by society deeply.
Agricultural production practice shows, sprays insect repellent agent or to have the plant extract of antibacterial ability be to realize crops The good method of safety and environmental protection that insect protected is disease-resistant.
Garlicin, matrine, Camphora, citronella oil, limonoid, the leaf of chinaberry, really, core etc., be long-term existence in from So boundary, effect significant insect protected antiviral agents and efficient anti-feedant, have anthelmintic activity, bactericidal effect, coordinate plant growth etc. many Plant function, and can decompose rapidly in the Nature, be finally decomposed to carbon dioxide and water.And multiple chemical substance in them Synergism, is not easily caused insect and develops immunity to drugs with pathogenic bacteria, can life-time service.Owing to they will not be direct to corresponding insect Poisoning, but control insect biotic population quantity, and the natural enemy that will not kill off the insect pests.They agriculturally extensively should in recent years With, pest and disease damage is had good prevention effect, is low toxicity, low-residual, environment-friendly type insect protected antiviral agents.
The aldehyde materials such as antibacterial antiviral agents cinnamic aldehyde similar to the above, vanillin, anisaldehyde and salicylic acid, sorbic acid, The organic acid such as caffeic acid are the interior natural materials with specific stimulation abnormal smells from the patient and special aroma produced of plant.Industrially It is widely used as anthelmintic, anophelifuge, refrigerator deodorizer, antistaling agent etc.;At field of medicaments, there is sterilizing anticorrosion, anti-routed Infections, antivirus action;It is usually used in flavorant, preservation and antisepsis mildew-resistant etc. in field of food industry;Can be also used for preparing spice Essence, prepares health product etc..These materials are harmless, it is easy to biodegradation, and bacteria resistance function is notable, it is also possible to application Antibacterial disease-resistant in crops.
Polyvinylpyrrolidone (PVP), polyvinyl alcohol (PVA), Polyethylene Glycol (PEG), sodium alginate, chitosan, Guar Glue, carboxymethyl cellulose (CMC), ethyl cellulose (EC), hydroxypropyl cellulose (HPC), hydroxypropyl methyl cellulose (HPMC) Deng macromolecules such as cellulose derivative, starch derivatives, the lignin derivative such as lignosulfonate, nitration of lignin, humic acid Material, is that nature is widely present or through the most complete synthesis or semi-synthetic product obtained, and it is tasteless, odorless, nontoxic Property, have a wide range of applications.They have preferable biological safety, biodegradability etc., are widely used in agricultural, doctor The numerous areas such as the process of medicine, food, chemical industry, cosmetics, water, METAL EXTRACTION and recovery, biochemistry and biomedical engineering.And it There is certain film property, carry the function of this medicine is mild controlled release, be good film forming and controlled release drug carrier materials.
The natural minerals such as kieselguhr, Graphene, graphite, clay, Muscovitum, Kaolin, are that nature exists or passes through The widely used inorganic material that processing obtains.They have, and porosity is big, absorbability is strong, sustained release performance is good, chemical property is steady The feature such as fixed, wear-resisting, heat-resisting, and can toughness reinforcing, strengthen, improve adhesive force, there is bigger pore volume, film can be made to shorten and do The dry time.Have a wide range of applications in fields such as medicine slow release field, feedstuff, papermaking, chemical fillers.Currently used papery, mould The use that the material solid type fruit-vegetable covering bag such as thin film, non-woven fabrics exists is loaded down with trivial details, pesticide residues, easily absorption are detained rain and dew water and are grown pathogenic bacteria It is that needs are urgently to be resolved hurrily etc. problem.
Summary of the invention
In order to overcome the shortcoming of prior art with not enough, the primary and foremost purpose of the present invention is to provide a kind of spraying film-forming type fruit Vegetables or crop bagging composite.This material uses polyvinylpyrrolidone (PVP), sodium alginate, cellulose derivative, really The film property material such as glue, resin, as medicine carrying and reinforcing materials such as base material, comprehensive silicon diatomaceous earth, Graphene, Kaolin, loads Bulbus Allii Element, insect protected antiviral agents and the dyestuff such as matrine, salicylic acid, cinnamic aldehyde, obtain multiple color and there is good insect protected disease resistance The composite of energy, its mixed system solution sprays after air-drying on fruit and vegerable or crop surface, becomes to adhere to fruit and vegerable or crop table The thin film in face, generates novel fruit and vegerable or crop adhesive type thin film bagging, does not affect fruit and vegerable or plant growth, and nontoxic pair is made With, and insect protected disease-resistance substance can be gone out by long-acting slow-release.Traditional fruit-vegetable covering bag technology is simplified by this technology, by membrane type " sack " It is sprayed on required fruit and vegerable by the way of spraying, then condenses film forming, time saving and energy saving.This technology can be in crop surface film forming (being equivalent to crop surface bagging), plays the effect that insect protected is disease-resistant, decreases the use of pesticide to a certain extent, solve crop Pesticide Residue.
Another object of the present invention is to provide above-mentioned spraying film-forming type fruit and vegerable or the preparation side of crop bagging composite Method.
It is yet a further object of the present invention to provide above-mentioned spraying film-forming type fruit and vegerable or the application of crop bagging composite.
The purpose of the present invention is achieved through the following technical solutions:
A kind of spraying film-forming type fruit and vegerable or crop bagging composite, including: film property material.
Described film property material is macromolecular material, preferably sodium alginate, polyvinylpyrrolidone (PVP), various Modified cellulose or modified starch, polyvinyl alcohol, Polyethylene Glycol, pectin, guar gum, agarose, chitosan, arabic gum, Huang Any one or at least two in the materials such as stilbene glue, Lac, oils and fats, resin, this film property material is dispersed in liquid dispersion In system, spray after fruit and vegerable or crop surface air-dry, form the thin film sticking to fruit and vegerable or crop surface, to fruit and vegerable or crop There is physical protection effect, play the purpose of isolation pest and disease damage, thus exist in liquid or gel form before preparing a class solidification Fruit-vegetable covering bag.It is the key technology point of the present invention, is also the innovation point of the present invention, rely on merely them also can obtain relatively Good bagging protection effect.
Described spraying film-forming type fruit and vegerable or crop bagging composite, also comprise the following components: dispersant, medicine carrying strengthen Material, insect protected antiviral agents.
Described spraying film-forming type fruit and vegerable or crop bagging composite, including following component in parts by mass:
5~30 parts of film property materials, 58~94 parts of dispersants, 1~10 part of medicine carrying reinforcing material, 0.1~2 part of insect protected are disease-resistant Agent, 0~0.1 part of dyestuff.
Described dispersant is preferably at least one in water and ethanol;
Described medicine carrying reinforcing material is preferably the mineral such as kieselguhr, Graphene, graphite, clay, Muscovitum and Kaolin In any one or at least two;
Described insect protected antiviral agents is preferably garlicin, matrine, Camphora, citronella oil, limonoid, the leaf of chinaberry, Really, nuclear extract, sorbic acid, salicylic acid, gallic acid, tannic acid, caffeic acid, cinnamic aldehyde, in the material such as vanillin and anisaldehyde Any one or at least two;
Described dyestuff is preferably food colour;More preferably natural edible dyestuff.
Described spraying film-forming type fruit and vegerable or the preparation method of crop bagging composite, comprise the steps of:
(1) film property material is scattered in dispersant, is stirred continuously, obtain viscous solution or the gel of stable homogeneous;
(2) by levigate for medicine carrying reinforcing material, it is fully ground, sieves, mix with insect protected antiviral agents solution, be stirred continuously, add Enter dyestuff, continue stirring mixing, obtain mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, stirs, To spraying film-forming type fruit and vegerable or crop bagging composite.
The condition of the stirring described in step (1) is preferably stirring at normal temperature 0.5h~24h;
200~1000 mesh sieves that sieved preferably described in step (2);
The concentration of the insect protected antiviral agents solution described in step (2) is 0.01~0.1g/mL;
The condition of the stirring described in step (2) is preferably stirring at normal temperature 0.5h~8h;
The condition continuing stirring described in step (2) is preferably room temperature and continues stirring 0.5h~12h;
The condition of the stirring described in step (3) is preferably stirring at normal temperature 0.5h~24h.
Described spraying film-forming type fruit and vegerable or crop bagging composite answering in fruit and vegerable or crop spraying bagging field With.
Spraying film-forming type fruit and vegerable or crop bagging composite are diluted 5~200 times, i.e. can be used for fruit and vegerable or crop spray Execute, air-dry after spraying and stick to fruit and vegetable surfaces film forming, thus obtain the membrane jacket bag with the disease-resistant function of insect protected.
The principle of the present invention is: the present inventor utilizes excellent film forming such as the excellent macromolecular material of biological safety itself Property, as film forming matrix material;Natural insect protected antibacterial substance is carried on clay, porous material that Graphene even load amount is big In, it is mixed with film former, slow releasing function can be played, reach lasting insect protected disease resisting effect.Meanwhile, molecular sieve, Graphene The film property of film former can be increased Deng material, improve film-strength, increase the breathability of film, needed for meeting fruit and vegerable or crop bagging Effect.These material non-toxic are harmless, can form protecting film, without spraying pesticide at fruit and vegerable or crop surface, it is possible to realize anti- Worm is disease-resistant, is to produce green organic fruit and vegerable or a kind of Novel complete bag material of crop.
The present invention, relative to prior art, has such advantages as and effect:
(1) the fruit and vegerable that prepared by the present invention or crop bagging composite, can air-dry film forming at fruit and vegerable or crop surface, tool There is insect protected resistant effect.
(2) the fruit and vegerable that prepared by the present invention or crop bagging composite, using method is simple, utilizes to spray and just can complete really Vegetables or crop bagging, reduce labour force and use.
(3) present invention is with fruit and vegerable that macromolecular material is main preparation or crop bagging composite, good biocompatibility, nothing Poison is harmless.
(4) the fruit and vegerable that prepared by the present invention or crop bagging composite, it is also possible to replace Pesticide use, solve pesticide residues Problem, can be used for produce green organic food.
(5) the fruit and vegerable that prepared by the present invention or crop bagging composite, preparation method is simple, and cost of material is relatively low.
(6) the fruit and vegerable that prepared by the present invention or crop bagging composite, action time is permanent, can maintain 1~3 months.
(7) the fruit and vegerable that prepared by the present invention or crop bagging composite, can be not only used for fruit and vegerable, it is also possible to for farming The insect protected of thing, flowers, trees etc. is disease-resistant.
Accompanying drawing explanation
Fig. 1 is the spraying fruit-vegetable covering bag material design sketch on Fructus Mangifera Indicae of embodiment 23 gained.
Detailed description of the invention
Below in conjunction with embodiment and accompanying drawing, the present invention is described in further detail, but embodiments of the present invention do not limit In this.
Embodiment 1
(1) being scattered in 580g aqueous solution by 50g polyvinylpyrrolidone, room temperature is stirred continuously 0.5h, obtain homogeneous surely Fixed viscous solution or gel.
(2) by levigate for 10g graphite, it is fully ground, crosses 200 mesh sieves, mix with 10mL 0.1g/mL garlicin solution, room temperature Being stirred continuously 0.5h, be not added with dyestuff, room temperature continues mix and blend 0.5h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 2d, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 2
(1) being scattered in 580g aqueous solution by 50g pectin, room temperature is stirred continuously 1h, obtains the viscous solution of stable homogeneous Or gel.
(2) by levigate for 10g kieselguhr, it is fully ground, crosses 200 mesh sieves, mix with 100mL 0.1g/mL matrine solution, Room temperature is stirred continuously 8h, adds 0.5g food colour, and room temperature continues mix and blend 12h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 0.5h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 3
(1) being scattered in 940g aqueous solution by 50g guar gum, room temperature is stirred continuously 2h, and the thickness obtaining stable homogeneous is molten Liquid or gel.
(2) by levigate for 10g clay, it is fully ground, crosses 200 mesh sieves, mix with 200mL 0.1g/mL Camphora solution, room temperature Being stirred continuously 6h, add 1g food colour, room temperature continues mix and blend 10h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 24h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 4
(1) being scattered in 940g aqueous solution by 50g polyvinyl alcohol, room temperature is stirred continuously 1h, obtains the thickness of stable homogeneous Solution or gel.
(2) by levigate for 10g Muscovitum, it is fully ground, crosses 200 mesh sieves, mix, often with 200mL 0.1g/mL citronella oil solution Temperature is stirred continuously 2h, adds 0.2g food colour, and room temperature continues mix and blend 8h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 24h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 5
(1) being scattered in 900g aqueous solution by 50g sodium alginate, room temperature is stirred continuously 0.5h, obtains the viscous of stable homogeneous Thick solution or gel.
(2) by levigate for 50g graphite, it is fully ground, crosses 200 mesh sieves, with 200mL 0.05g/mL matrine and 0.05g/mL Cinnamic aldehyde solution mixes, and room temperature is stirred continuously 5h, adds 0.2g food colour, and room temperature continues mix and blend 3h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 0.5h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 6
(1) being scattered in 580g aqueous solution by 50g Polyethylene Glycol, room temperature is stirred continuously 0.5h, obtains the viscous of stable homogeneous Thick solution or gel.
(2) by levigate for 50g Graphene, it is fully ground, crosses 200 mesh sieves, mix with 10mL 0.1g/mL limonoid solution Closing, room temperature is stirred continuously 8h, adds 0.2g food colour, and room temperature continues mix and blend 3h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 0.5h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 7
(1) being scattered in 580g aqueous solution by 50g Polyethylene Glycol, room temperature is stirred continuously 0.5h, obtains the viscous of stable homogeneous Thick solution or gel.
(2) by levigate for 50g Graphene, it is fully ground, crosses 200 mesh sieves, mix, often with 10mL 0.1g/mL sorbic acid solutions Temperature is stirred continuously 8h, adds 0.2g food colour, and room temperature continues mix and blend 3h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 0.5h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 8
(1) being scattered in 580g aqueous solution by 50g Polyethylene Glycol, room temperature is stirred continuously 0.5h, obtains the viscous of stable homogeneous Thick solution or gel.
(2) by levigate for 50g Graphene, it is fully ground, crosses 200 mesh sieves, mix with 10mL 0.1g/mL gallic acid solution, Room temperature is stirred continuously 8h, adds 0.2g food colour, and room temperature continues mix and blend 3h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 0.5h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 9
(1) being scattered in 940g aqueous solution by 50g Polyethylene Glycol, room temperature is stirred continuously 0.5h, obtains the viscous of stable homogeneous Thick solution or gel.
(2) by levigate for 50g Graphene, it is fully ground, crosses 200 mesh sieves, mix with 10mL 0.1g/mL tan-liquor, room temperature Being stirred continuously 8h, add 0.2g food colour, room temperature continues mix and blend 3h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 0.5h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 10
(1) being scattered in 940g aqueous solution by 50g agarose, room temperature is stirred continuously 2h, and the thickness obtaining stable homogeneous is molten Liquid or gel.
(2) by levigate for 10g clay, it is fully ground, crosses 200 mesh sieves, mix with 200mL 0.1g/mL Camphora solution, room temperature Being stirred continuously 6h, add 1g food colour, room temperature continues mix and blend 10h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 1h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 11
(1) being scattered in 940g aqueous solution by 50g arabic gum, room temperature is stirred continuously 2h, obtains the thickness of stable homogeneous Solution or gel.
(2) by levigate for 10g clay, it is fully ground, crosses 200 mesh sieves, mix, often with 2000mL 0.01g/mL Camphora solution Temperature is stirred continuously 6h, adds 1g food colour, and room temperature continues mix and blend 10h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 1h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 12
(1) being scattered in 940g aqueous solution by 50g tragacanth, room temperature is stirred continuously 2h, and the thickness obtaining stable homogeneous is molten Liquid or gel.
(2) by levigate for 10g Kaolin, it is fully ground, crosses 200 mesh sieves, mix, often with 400mL 0.05g/mL Camphora solution Temperature is stirred continuously 6h, adds 1g food colour, and room temperature continues mix and blend 10h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 1h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 13
(1) being scattered in 940g aqueous solution by 100g chitosan, room temperature is stirred continuously 2h, and the thickness obtaining stable homogeneous is molten Liquid or gel.
(2) by levigate for 80g kieselguhr, be fully ground, cross 200 mesh sieves, with the leaf of 200mL 0.1g/mL chinaberry, really, core carries Taking the mixing of thing solution, room temperature is stirred continuously 8h, adds 0.2g food colour, and room temperature continues mix and blend 3h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 12h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 14
(1) being scattered in 580g aqueous solution by 200g oils and fats, room temperature is stirred continuously 20h, and the thickness obtaining stable homogeneous is molten Liquid or gel.
(2) by levigate for 100g Graphene, it is fully ground, crosses 200 mesh sieves, mix with 50mL 0.1g/mL salicylic acid solution, Room temperature is stirred continuously 8h, adds 0.1g food colour, and room temperature continues mix and blend 10h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 12h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 15
(1) being scattered in 700g aqueous solution by 300g sodium alginate, room temperature is stirred continuously 24h, obtains the viscous of stable homogeneous Thick solution or gel.
(2) by levigate for 50g graphite, it is fully ground, crosses 200 mesh sieves, mix with 100mL 0.1g/mL gallic acid solution, Room temperature is stirred continuously 8h, adds 0.1g food colour, and room temperature continues mix and blend 12h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 24h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 16
(1) being scattered in 700g aqueous solution by 300g Lac, room temperature is stirred continuously 24h, and the thickness obtaining stable homogeneous is molten Liquid or gel.
(2) by levigate for 50g clay, it is fully ground, crosses 200 mesh sieves, mix, often with 100mL 0.1g/mL caffeic acid solution Temperature is stirred continuously 8h, adds 0.1g food colour, and room temperature continues mix and blend 12h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 0.5h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 17
(1) being scattered in 940g aqueous solution by 300g sodium alginate, room temperature is stirred continuously 24h, obtains the viscous of stable homogeneous Thick solution or gel.
(2) by levigate for 50g Muscovitum, it is fully ground, crosses 200 mesh sieves, mix, often with 200mL 0.1g/mL cinnamic aldehyde solution Temperature is stirred continuously 2h, adds 0.1g food colour, and room temperature continues mix and blend 3h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 24h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 18
(1) by 50g resin (water-soluble special acrylate polymer), 50g modified cellulose, 50g modified starch, 50g Polyvinyl alcohol, 50g sodium alginate and 50g Polyethylene Glycol are scattered in 940g aqueous solution, and room temperature is stirred continuously 24h, obtain homogeneous Stable viscous solution or gel.
(2) by 10g kieselguhr, 10g Graphene, 10g graphite, 10g clay, 10g Muscovitum is levigate, is fully ground, and crosses 200 mesh Sieve, mixes with 200mL 0.1g/mL vanillin solution, and room temperature is stirred continuously 8h, adds 0.1g food colour, and room temperature continues mixing Stirring 12h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 24h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 19
(1) 100g polyvinyl alcohol, 100g sodium alginate and 100g Polyethylene Glycol being scattered in 940g aqueous solution, room temperature is not Disconnected stirring 24h, obtains viscous solution or the gel of stable homogeneous.
(2) by 20g graphite, 20g clay, 20g Kaolin is levigate, is fully ground, and crosses 200 mesh sieves, with 200mL 0.1g/mL Anisaldehyde solution mixes, and room temperature is stirred continuously 8h, adds 0.1g food colour, and room temperature continues mix and blend 12h, is mixed Liquid;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 24h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 20
(1) being scattered in 940g aqueous solution by 50g polyvinyl alcohol, room temperature is stirred continuously 24h, obtains the thickness of stable homogeneous Solution or gel.
(2) by levigate for 50g graphite, it is fully ground, crosses 200 mesh sieves, with 200mL 0.01g/mL matrine, 0.005g/mL Camphora, 0.005g/mL citronella oil, 0.005g/mL limonoid, the leaf of 0.005g/mL chinaberry, really, nuclear extract, 0.005g/mL salicylic acid, 0.005g/mL gallic acid, 0.005g/mL caffeic acid, 0.005g/mL cinnamic aldehyde, 0.005g/mL is fragrant Oxalaldehyde and the mixing of 0.005g/mL anisaldehyde solution, room temperature is stirred continuously 8h, adds 0.1g food colour, and room temperature continues mixing and stirs Mix 12h, obtain mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 24h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 21
(1) being scattered in 580g aqueous solution by 50g modified cellulose, room temperature is stirred continuously 12h, obtains the viscous of stable homogeneous Thick solution or gel.
(2) by levigate for 50g graphite, it is fully ground, crosses 200 mesh sieves, with 200mL 0.03g/mL matrine, 0.03g/mL water Poplar acid and 0.03g/mL anisaldehyde solution mix, and room temperature is stirred continuously 2h, add 0.1g food colour, and room temperature continues mix and blend 12h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 0.5h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 22
(1) being scattered in 600g aqueous solution by 50g modified starch, room temperature is stirred continuously 12h, obtains the thickness of stable homogeneous Solution or gel.
(2) by levigate for 50g graphite, it is fully ground, crosses 200 mesh sieves, with 200mL 0.01g/mL matrine, 0.01g/mL water Poplar acid and 0.01g/mL anisaldehyde solution mix, and room temperature is stirred continuously 2h, add 0.1g food colour, and room temperature continues mix and blend 12h, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, room temperature mixing is stirred Mix 0.5h, obtain spray film-forming type fruit and vegerable or crop bagging composite.
Embodiment 23
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 5 times, spray application to Fructus Mangifera Indicae Fruit surface, reaches bagging and the disease-resistant effect of insect protected.Effect is as shown in Figure 1.
Embodiment 24
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 20 times, spray application to Fructus Mali pumilae Fruit surface, reaches bagging and the disease-resistant effect of insect protected.
Embodiment 25
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 50 times, spray application to the fruit of pears Real surface, reaches bagging and the disease-resistant effect of insect protected..
Embodiment 26
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 100 times, spray application to Fructus Pruni pseudocerasi Fruit surface, reach bagging and the disease-resistant effect of insect protected.
Embodiment 27
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 200 times, spray application to Fructus Fragariae Ananssae Fruit surface, reach bagging and the disease-resistant effect of insect protected.
Embodiment 28
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 10 times, spray application to Hylocereus undatus Fruit surface, reach bagging and the disease-resistant effect of insect protected.
Embodiment 29
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 5 times, spray application to Fructus Musae Fruit surface, reaches bagging and the disease-resistant effect of insect protected.
Embodiment 30
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 20 times, spray application to Eugenia javanica Lam Fruit surface, reaches bagging and the disease-resistant effect of insect protected.
Embodiment 31
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 20 times, spray application to Sakyamuni Fruit surface, reaches bagging and the disease-resistant effect of insect protected.
Embodiment 32
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 100 times, spray application to Fructus Persicae Fruit surface, reach bagging and the disease-resistant effect of insect protected.
Embodiment 33
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 20 times, spray application to Fructus Chaenomelis Fruit surface, reaches bagging and the disease-resistant effect of insect protected.
Embodiment 34
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 5 times, spray application to Fructus Citri tangerinae Fruit surface, reaches bagging and the disease-resistant effect of insect protected.
Embodiment 35
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 20 times, spray application to Arillus Longan Fruit surface, reaches bagging and the disease-resistant effect of insect protected.
Embodiment 36
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 20 times, spray application to Fructus Litchi Fruit surface, reaches bagging and the disease-resistant effect of insect protected.
Embodiment 37
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 20 times, spray application to Fructus Citri junoris Fruit surface, reaches bagging and the disease-resistant effect of insect protected.
Embodiment 38
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 20 times, spray application to Fructus actinidiae chinensis Fruit surface, reach bagging and the disease-resistant effect of insect protected.
Embodiment 39
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 20 times, spray application to Fructus psidii guajavae immaturus Fruit surface, reach bagging and the disease-resistant effect of insect protected.
Embodiment 40
Spraying film-forming type fruit and vegerable embodiment 1 obtained or crop bagging composite, dilute 100 times, spray application to Chinese date Fruit surface, reach bagging and the disease-resistant effect of insect protected.
Embodiment 41
Spraying film-forming type fruit and vegerable embodiment 1 to embodiment 22 obtained or the mixing of crop bagging composite, dilute 10 Times, spray application to the fruit surface of Fructus Mangifera Indicae, reach bagging and the disease-resistant effect of insect protected.
Embodiment 42
Spraying film-forming type fruit and vegerable embodiment 1 and embodiment 5 obtained or the mixing of crop bagging composite, dilute 100 Times, spray application to, on the vegetable leafs such as Brassica campestris L, Herba Spinaciae, Fructus Lycopersici esculenti or fruit, reach the effect that insect protected is disease-resistant.
Embodiment 43
All spraying film-forming type fruit and vegerable that embodiment 1~embodiment 12 are obtained or the mixing of crop bagging composite, dilute Release 50 times, spray application to, on the vegetable leafs such as Brassica campestris L, Herba Spinaciae, Fructus Lycopersici esculenti or fruit, reach the effect that insect protected is disease-resistant.
Embodiment 44
All spraying film-forming type fruit and vegerable embodiment 1 obtained or the mixing of crop bagging composite, dilute 100 times, spray It is applied on the crop leafs such as Radix Ipomoeae, Semen Tritici aestivi, Oryza sativa L. or fruit, reaches the effect that insect protected is disease-resistant.
Embodiment 45
All spraying film-forming type fruit and vegerable that embodiment 1~embodiment 12 are obtained or the mixing of crop bagging composite, dilute Release 50 times, spray application to, on Semen Maydis, Semen arachidis hypogaeae, Soybean and Other Crops blade or fruit, reach the effect that insect protected is disease-resistant.
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention are not by above-described embodiment Limit, the change made under other any spirit without departing from the present invention and principle, modify, substitute, combine, simplify, All should be the substitute mode of equivalence, within being included in protection scope of the present invention.

Claims (10)

1. spraying film-forming type fruit and vegerable or crop bagging composite, it is characterised in that including: film property material;Described one-tenth Film material be sodium alginate, polyvinylpyrrolidone, various modified cellulose or modified starch, polyvinyl alcohol, Polyethylene Glycol, In pectin, guar gum, agarose, chitosan, arabic gum, tragacanth, Lac, oils and fats, resin any one or at least Two kinds.
Spraying film-forming type fruit and vegerable the most according to claim 1 or crop bagging composite, it is characterised in that: also include as Lower component: dispersant, medicine carrying reinforcing material, insect protected antiviral agents.
Spraying film-forming type fruit and vegerable the most according to claim 2 or crop bagging composite, it is characterised in that: described spray Mist film-forming type fruit and vegerable or crop bagging composite, including following component in parts by mass:
5~30 parts of film property materials, 58~94 parts of dispersants, 1~10 part of medicine carrying reinforcing material, 0.1~2 part of insect protected antiviral agents, 0 ~0.1 part of dyestuff.
4. according to the spraying film-forming type fruit and vegerable described in Claims 2 or 3 or crop bagging composite, it is characterised in that: described Medicine carrying reinforcing material be any one or at least two in kieselguhr, Graphene, graphite, clay, Muscovitum and Kaolin.
5. according to the spraying film-forming type fruit and vegerable described in Claims 2 or 3 or crop bagging composite, it is characterised in that: described Insect protected antiviral agents be garlicin, matrine, Camphora, citronella oil, limonoid, the leaf of chinaberry, really, nuclear extract, Pyrusussuriensis Acid, salicylic acid, gallic acid, tannic acid, caffeic acid, cinnamic aldehyde, any one or at least two in vanillin and anisaldehyde.
Spraying film-forming type fruit and vegerable the most according to claim 3 or crop bagging composite, it is characterised in that: described divides Powder is at least one in water and ethanol;
Described dyestuff is food colour.
7. the spraying film-forming type fruit and vegerable described in any one of claim 3~6 or the preparation method of crop bagging composite, it is special Levy and be to comprise the steps of:
(1) film property material is scattered in dispersant, is stirred continuously, obtain viscous solution or the gel of stable homogeneous;
(2) by levigate for medicine carrying reinforcing material, it is fully ground, sieves, mix with insect protected antiviral agents solution, be stirred continuously, add dye Material, continues stirring mixing, obtains mixed liquor;
(3) the mixed liquor mixing that viscous solution step (1) obtained or gel and step (2) obtain, stirs, is sprayed Mist film-forming type fruit and vegerable or crop bagging composite.
Preparation method the most according to claim 7, it is characterised in that:
The condition of the stirring described in step (1) is stirring at normal temperature 0.5h~24h;
The condition of the stirring described in step (2) is stirring at normal temperature 0.5h~8h;
The condition continuing stirring described in step (2) is that room temperature continues stirring 0.5h~12h;
The condition of the stirring described in step (3) is stirring at normal temperature 0.5h~24h.
Preparation method the most according to claim 7, it is characterised in that:
Sieving as crossing 200~1000 mesh sieves described in step (2);
The concentration of the insect protected antiviral agents solution described in step (2) is 0.01~0.1g/mL.
10. spraying film-forming type fruit and vegerable or crop bagging composite described in any one of claim 1~6 spray at fruit and vegerable or crop Application in mist bagging field.
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CN109328786A (en) * 2018-11-01 2019-02-15 卢国政 A kind of preparation method of liquid fruit bag
CN109362438A (en) * 2018-10-25 2019-02-22 慕善斌 A kind of chitosan degradable biological fruit bagging film spray liquid and preparation method thereof
CN109362444A (en) * 2018-11-20 2019-02-22 青岛睿鸿鑫环保科技有限公司 The method that securing plant blade face is injured from salt fog
CN109618775A (en) * 2018-12-24 2019-04-16 靖西市秀美边城农业科技有限公司 A kind of mango special bagging with impairment effect
CN111165235A (en) * 2019-12-31 2020-05-19 赵梓权 Photocatalytic spray type insect-proof antibacterial fresh-keeping liquid and preparation method thereof
CN111296505A (en) * 2020-04-01 2020-06-19 佳木斯大学 Slow-release pesticide preparation and preparation method and application thereof
CN111393976A (en) * 2020-04-27 2020-07-10 朱亚林 Fruit liquid bagging glue solution and preparation method thereof
CN111820057A (en) * 2020-07-28 2020-10-27 中国热带农业科学院南亚热带作物研究所 Fruit and vegetable bagging composite material and preparation method and application thereof
CN112293435A (en) * 2020-11-02 2021-02-02 成都子之源绿能科技有限公司 Spray and preparation method and application thereof
CN112980253A (en) * 2021-02-25 2021-06-18 陕西品物皆春生态科技有限公司 Humic acid type fruit bagging-free film agent and using method thereof
CN113293604A (en) * 2021-04-16 2021-08-24 珠海市华纶无纺布有限公司 Antibacterial and hydrophilic non-woven fabric and preparation method and application thereof
CN113563770A (en) * 2021-08-10 2021-10-29 佛山市蓝启科技有限公司 Macromolecular plant bionic liquid film for preventing and treating litchi fruit borers and preparation method and application thereof
CN113575243A (en) * 2021-07-27 2021-11-02 中国热带农业科学院南亚热带作物研究所 Liquid fruit bagging material, preparation method and application thereof
CN113929529A (en) * 2021-11-17 2022-01-14 漯河鑫禾生物科技有限公司 Disease-resistant liquid fertilizer and preparation method thereof

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CN104738156A (en) * 2014-12-25 2015-07-01 天津北洋百川生物技术有限公司 Edible fruit and vegetable preservative and using method thereof
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CN1899600A (en) * 2005-07-22 2007-01-24 上海高科联合生物技术研发有限公司 Antibiotic peptide spray film forming agent and its preparing method
CN103694049A (en) * 2013-12-20 2014-04-02 广西大学 Plant protection product
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CN106758490A (en) * 2016-12-13 2017-05-31 广州市极合技术咨询有限公司 A kind of double-deck humidity fruit bag and preparation method thereof
CN106804281A (en) * 2017-04-06 2017-06-09 青岛农业大学 A kind of technology for improving strawberry fruit quality
CN107099200A (en) * 2017-06-06 2017-08-29 仲恺农业工程学院 It is a kind of to be used for pest-resistant packaging film of antibacterial before fruit is adopted and preparation method thereof
CN109362438A (en) * 2018-10-25 2019-02-22 慕善斌 A kind of chitosan degradable biological fruit bagging film spray liquid and preparation method thereof
CN109328786A (en) * 2018-11-01 2019-02-15 卢国政 A kind of preparation method of liquid fruit bag
CN109258254A (en) * 2018-11-20 2019-01-25 青岛睿鸿鑫环保科技有限公司 Application of the water soluble polymer in the plant protection product that preparation securing plant blade face is injured from salt fog
CN109362444A (en) * 2018-11-20 2019-02-22 青岛睿鸿鑫环保科技有限公司 The method that securing plant blade face is injured from salt fog
CN109618775A (en) * 2018-12-24 2019-04-16 靖西市秀美边城农业科技有限公司 A kind of mango special bagging with impairment effect
CN111165235A (en) * 2019-12-31 2020-05-19 赵梓权 Photocatalytic spray type insect-proof antibacterial fresh-keeping liquid and preparation method thereof
CN111296505A (en) * 2020-04-01 2020-06-19 佳木斯大学 Slow-release pesticide preparation and preparation method and application thereof
CN111393976A (en) * 2020-04-27 2020-07-10 朱亚林 Fruit liquid bagging glue solution and preparation method thereof
CN111820057A (en) * 2020-07-28 2020-10-27 中国热带农业科学院南亚热带作物研究所 Fruit and vegetable bagging composite material and preparation method and application thereof
CN111820057B (en) * 2020-07-28 2022-05-27 中国热带农业科学院南亚热带作物研究所 Fruit and vegetable bagging composite material and preparation method and application thereof
CN112293435A (en) * 2020-11-02 2021-02-02 成都子之源绿能科技有限公司 Spray and preparation method and application thereof
CN112980253A (en) * 2021-02-25 2021-06-18 陕西品物皆春生态科技有限公司 Humic acid type fruit bagging-free film agent and using method thereof
CN112980253B (en) * 2021-02-25 2022-01-07 陕西品物皆春生态科技有限公司 Humic acid type fruit bagging-free film agent and using method thereof
CN113293604A (en) * 2021-04-16 2021-08-24 珠海市华纶无纺布有限公司 Antibacterial and hydrophilic non-woven fabric and preparation method and application thereof
CN113575243A (en) * 2021-07-27 2021-11-02 中国热带农业科学院南亚热带作物研究所 Liquid fruit bagging material, preparation method and application thereof
CN113563770A (en) * 2021-08-10 2021-10-29 佛山市蓝启科技有限公司 Macromolecular plant bionic liquid film for preventing and treating litchi fruit borers and preparation method and application thereof
CN113563770B (en) * 2021-08-10 2022-06-21 佛山市蓝启科技有限公司 Macromolecular plant bionic liquid film for preventing and treating litchi fruit borers and preparation method and application thereof
CN113929529A (en) * 2021-11-17 2022-01-14 漯河鑫禾生物科技有限公司 Disease-resistant liquid fertilizer and preparation method thereof

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