CN105980343B - 用于制备生物来源的丙烯酸的方法 - Google Patents

用于制备生物来源的丙烯酸的方法 Download PDF

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Publication number
CN105980343B
CN105980343B CN201580009244.9A CN201580009244A CN105980343B CN 105980343 B CN105980343 B CN 105980343B CN 201580009244 A CN201580009244 A CN 201580009244A CN 105980343 B CN105980343 B CN 105980343B
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acrylic acid
stream
column
dehydration
acrolein
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Chinese (zh)
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CN105980343A (zh
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J-F.德沃克斯
M.福科内
S.贾因
S.特拉特利克
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Arkema SA
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Arkema SA
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/58—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201580009244.9A 2014-02-19 2015-02-16 用于制备生物来源的丙烯酸的方法 Active CN105980343B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1451315A FR3017617B1 (fr) 2014-02-19 2014-02-19 Procede de production d'acide acrylique bio-source
FR1451315 2014-02-19
PCT/FR2015/050371 WO2015124856A1 (fr) 2014-02-19 2015-02-16 Procede de production d'acide acrylique bio-source

Publications (2)

Publication Number Publication Date
CN105980343A CN105980343A (zh) 2016-09-28
CN105980343B true CN105980343B (zh) 2018-05-18

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CN201580009244.9A Active CN105980343B (zh) 2014-02-19 2015-02-16 用于制备生物来源的丙烯酸的方法

Country Status (7)

Country Link
US (1) US10029975B2 (enExample)
EP (1) EP3107885A1 (enExample)
JP (1) JP2017509604A (enExample)
KR (1) KR20160124194A (enExample)
CN (1) CN105980343B (enExample)
FR (1) FR3017617B1 (enExample)
WO (1) WO2015124856A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3060000B1 (fr) * 2016-12-08 2020-05-01 Arkema France Procede pour eviter le depot de polymeres dans un procede de purification d'acide (meth)acrylique.
EP3774987B1 (en) * 2018-04-06 2024-06-05 Novomer, Inc. Method of producing a film comprising polypropiolactone, and film so obtained
FR3162750A1 (fr) * 2024-05-30 2025-12-05 Arkema France Procede de purification d’acide (meth)acrylique

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102639479A (zh) * 2009-12-14 2012-08-15 阿肯马法国公司 用于从甘油制造丙烯醛和/或丙烯酸的方法

Family Cites Families (28)

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Publication number Priority date Publication date Assignee Title
DE4238493C1 (de) 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
DE19740253A1 (de) * 1997-09-12 1999-03-18 Basf Ag Verfahren zur fraktionierten Kondensation eines heißen Gasgemisches mit einem hohen Anteil nicht kondensierbarer Komponenten
DE19848208A1 (de) 1998-10-20 2000-04-27 Deg Engineering Gmbh Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
US6498272B1 (en) 1999-03-06 2002-12-24 Basf Aktiengesellschaft Method for producing acrylic acid
DE10019381B4 (de) 2000-04-19 2006-05-18 Daun, Klaus-Dieter, Dipl.-Ing. Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
JP3957298B2 (ja) 2003-06-05 2007-08-15 株式会社日本触媒 アクリル酸の製造方法
US7268254B2 (en) 2003-07-24 2007-09-11 Basf Aktiengesellschaft Preparation of (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed partial oxidation of C3 and/or C4 precursor compounds in a reactor having thermoplate modules
JP5006507B2 (ja) 2004-01-30 2012-08-22 株式会社日本触媒 アクリル酸の製造方法
FR2882053B1 (fr) 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
FR2882052B1 (fr) 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine
TWI438187B (zh) 2005-02-28 2014-05-21 Evonik Degussa Gmbh 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法
FR2884818B1 (fr) 2005-04-25 2007-07-13 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
US20090068440A1 (en) 2005-06-20 2009-03-12 Gunther Bub Production of acrolein, acrylic acid and water-absorbent polymer structures made from glycerine
US7495505B2 (en) 2006-07-18 2009-02-24 Faraday Technology Corp. Low supply voltage band-gap reference circuit and negative temperature coefficient current generation unit thereof and method for supplying band-gap reference current
CN101516820B (zh) 2006-09-15 2012-11-21 阿克马公司 制备丙烯酸的方法
JP2008115103A (ja) 2006-11-02 2008-05-22 Nippon Shokubai Co Ltd アクリル酸の製造方法、アクリル酸製造用装置、およびアクリル酸製造用組成物
FR2909999B1 (fr) 2006-12-19 2009-04-03 Arkema France Procede de preparation d'acide acrylique a partir de glycerol
EP1978009A1 (en) 2007-04-04 2008-10-08 Rohm and Haas Company Method for purification of glycerol
WO2009127889A1 (en) 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
FR2935971B1 (fr) * 2008-09-16 2010-11-19 Arkema France Acide bio-acrylique de grade polymere et son procede de fabrication a partir de glycerol.
EP2179981A1 (en) 2008-10-24 2010-04-28 Arkema France Process for manufacturing acrolein from glycerol
SG172273A1 (en) 2008-12-26 2011-07-28 Nippon Catalytic Chem Ind Process for producing acrylic acid
WO2010140530A1 (ja) 2009-06-01 2010-12-09 株式会社日本触媒 （メタ）アクリル酸の晶析方法および製品（メタ）アクリル酸の重合防止剤含有量の調整方法
FR2948365B1 (fr) 2009-07-22 2011-09-09 Arkema France Procede de fabrication d'acide acrylique bio-ressource a partir de glycerol
FR2948366B1 (fr) * 2009-07-22 2012-08-17 Arkema France Procede de fabrication d'acide acrylique bio-ressource a partir de glycerol
US20130053595A1 (en) 2009-09-18 2013-02-28 Arkema France Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
FR2957594B1 (fr) 2010-03-18 2013-04-26 Arkema France Procede de fabrication d'acide acrylique bio-ressource de grade polymere a partir de glycerol
WO2012101471A1 (en) 2011-01-28 2012-08-02 Arkema France Improved process for manufacturing acrolein/acrylic acid

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102639479A (zh) * 2009-12-14 2012-08-15 阿肯马法国公司 用于从甘油制造丙烯醛和/或丙烯酸的方法

Also Published As

Publication number Publication date
FR3017617A1 (fr) 2015-08-21
US20170166507A1 (en) 2017-06-15
KR20160124194A (ko) 2016-10-26
WO2015124856A1 (fr) 2015-08-27
FR3017617B1 (fr) 2016-02-12
JP2017509604A (ja) 2017-04-06
CN105980343A (zh) 2016-09-28
US10029975B2 (en) 2018-07-24
EP3107885A1 (fr) 2016-12-28

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