CN105648763A - 一种保温抗菌织物整理剂及其制备方法 - Google Patents

一种保温抗菌织物整理剂及其制备方法 Download PDF

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CN105648763A
CN105648763A CN201610200035.9A CN201610200035A CN105648763A CN 105648763 A CN105648763 A CN 105648763A CN 201610200035 A CN201610200035 A CN 201610200035A CN 105648763 A CN105648763 A CN 105648763A
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沈飞峰
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Wujiang Fuhuiyuan Textile Co Ltd
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Abstract

本发明公开了一种保温抗菌织物整理剂，包括如下重量百分比的各组分：碳酸锌5-10份、氧氯化锆6-15份、硅化镁3-9份、铁锂云母7-12份、二乙醚15-25份、磷酸组胺8-16份、磷酸铵2-8份、氨基甲酸乙酯3-10份、甘油磷酸酯20-30份、蒸馏水80-120份。该整理剂具有良好的蓄热保温作用和抗菌作用，可广泛应用于汽车内饰物、医疗卫生用品、服装鞋帽等行业，能够满足特定场合人们的需求。

Description

一种保温抗菌织物整理剂及其制备方法
技术领域
本发明属于整理剂领域，特别涉及一种保温抗菌织物整理剂及其制备方法。
背景技术
近年来，全球和我国市场对于功能纺织品需求量呈现大幅度增长，各种功能型整理剂蓬勃发展，成为该领域研发的重点。目前现有的纺织品大都不具有蓄热保温功能，人们穿着于身上时无法起到蓄热保温效果，对于需要在寒冷室外穿着较薄衣物的情形无法满足，例如演唱会、跨年夜等外场演出时，演出者极易因受凉而感冒，引起人体不适。此外，现有纺织品整理剂中无法同时具有蓄热保温和抗菌作用，因此开发这样一种整理剂，显得尤为重要。
发明内容
针对现有技术中存在的以上技术问题，本发明提供了一种保温抗菌织物整理剂及其制备方法，该整理剂具有良好的蓄热保温作用和抗菌作用，以满足特定场合人们的需求。
技术方案：一种保温抗菌织物整理剂，包括如下重量百分比的各组分：碳酸锌5-10份、氧氯化锆6-15份、硅化镁3-9份、铁锂云母7-12份、二乙醚15-25份、磷酸组胺8-16份、磷酸铵2-8份、氨基甲酸乙酯3-10份、甘油磷酸酯20-30份、蒸馏水80-120份。
进一步的，所述碳酸锌6-9份、氧氯化锆8-12份、硅化镁5-8份、铁锂云母9-11份、二乙醚17-20份、磷酸组胺10-13份、磷酸铵4-7份、氨基甲酸乙酯5-9份、甘油磷酸酯22-25份、蒸馏水90-100份。
进一步的，所述碳酸锌8份、氧氯化锆10份、硅化镁6份、铁锂云母10份、二乙醚18份、磷酸组胺12份、磷酸铵5份、氨基甲酸乙酯8份、甘油磷酸酯23份、蒸馏水95份。
一种保温抗菌织物整理剂的制备方法，具体包括如下步骤：
（1）将碳酸锌5-10份、氧氯化锆6-15份、硅化镁3-9份和铁锂云母7-12份混合并粉碎至80-120目，得到混合料；
（2）将二乙醚15-25份、甘油磷酸酯20-30份、磷酸铵2-8份和蒸馏水80-120份加入反应器中，将温度升至70-85℃，搅拌30-40min；
（3）将磷酸组胺8-16份滴加至步骤（2）中反应器中，滴加过程中不断搅拌；随后加入氨基甲酸乙酯3-10份，将温度升至100-120℃回流反应1-2h，随后待反应冷却后即可得到所述保温抗菌织物整理剂。
进一步的，步骤（1）中所述目数为100目。
进一步的，步骤（2）中所述温度为78℃，搅拌速率为200-350r/min，搅拌时间35min。
进一步的，步骤（3）中所述滴加时间为10min，温度为115℃，回流反应1.5h。
有益效果：
本发明所述保温抗菌织物整理剂的制备方法，将铁锂云母、磷酸组胺和氧氯化锆通过混合、加热、搅拌等工艺加入制备过程中，得到蓄热保温效果良好且抗菌性能良好的多功能型整理剂；该整理剂可广泛应用于汽车内饰物、医疗卫生用品、服装鞋帽等行业；该制备工艺简便，易操作。
具体实施方式
实施例1
（1）将碳酸锌5份、氧氯化锆6份、硅化镁3份和铁锂云母7份混合并粉碎至80目，得到混合料；
（2）将二乙醚15份、甘油磷酸酯20份、磷酸铵2份和蒸馏水80份加入反应器中，将温度升至70℃，以速率200r/min搅拌30min；
（3）将磷酸组胺8份滴加至步骤（2）中反应器中，滴加过程中不断搅拌，滴加时间为10min；随后加入氨基甲酸乙酯3份，将温度升至100℃回流反应1h，随后待反应冷却后即可得到所述保温抗菌织物整理剂。
对比例1
（1）将碳酸锌5份和硅化镁3份混合并粉碎至80目，得到混合料；
（2）将二乙醚15份、甘油磷酸酯20份、磷酸铵2份和蒸馏水80份加入反应器中，将温度升至70℃，以速率200r/min搅拌30min；
（3）将氨基甲酸乙酯3份加至步骤（2）中反应器中，将温度升至100℃回流反应1h，随后待反应冷却后即可得到整理剂。
实施例2
（1）将碳酸锌10份、氧氯化锆15份、硅化镁9份和铁锂云母12份混合并粉碎至120目，得到混合料；
（2）将二乙醚25份、甘油磷酸酯30份、磷酸铵8份和蒸馏水120份加入反应器中，将温度升至85℃，以速率350r/min搅拌40min；
（3）将磷酸组胺16份滴加至步骤（2）中反应器中，滴加过程中不断搅拌，滴加时间为10min；随后加入氨基甲酸乙酯10份，将温度升至120℃回流反应2h，随后待反应冷却后即可得到所述保温抗菌织物整理剂。
对比例2
（1）将碳酸锌10份和硅化镁9份混合并粉碎至120目，得到混合料；
（2）将二乙醚25份、甘油磷酸酯30份、磷酸铵8份和蒸馏水120份加入反应器中，将温度升至85℃，以速率350r/min搅拌40min；
（3）将氨基甲酸乙酯10份加至步骤（2）中反应器中，将温度升至120℃回流反应2h，随后待反应冷却后即可得到整理剂。
实施例3
（1）将碳酸锌6份、氧氯化锆8份、硅化镁5份和铁锂云母9份混合并粉碎至80目，得到混合料；
（2）将二乙醚17份、甘油磷酸酯22份、磷酸铵4份和蒸馏水90份加入反应器中，将温度升至70℃，以速率200r/min搅拌30min；
（3）将磷酸组胺10份滴加至步骤（2）中反应器中，滴加过程中不断搅拌，滴加时间为10min；随后加入氨基甲酸乙酯5份，将温度升至100℃回流反应2h，随后待反应冷却后即可得到所述保温抗菌织物整理剂。
实施例4
（1）将碳酸锌9份、氧氯化锆12份、硅化镁8份和铁锂云母11份混合并粉碎至120目，得到混合料；
（2）将二乙醚20份、甘油磷酸酯25份、磷酸铵7份和蒸馏水100份加入反应器中，将温度升至85℃，以速率350r/min搅拌40min；
（3）将磷酸组胺13份滴加至步骤（2）中反应器中，滴加过程中不断搅拌，滴加时间为10min；随后加入氨基甲酸乙酯9份，将温度升至120℃回流反应1h，随后待反应冷却后即可得到所述保温抗菌织物整理剂。
实施例5
（1）将碳酸锌8份、氧氯化锆10份、硅化镁6份和铁锂云母10份混合并粉碎至100目，得到混合料；
（2）将二乙醚18份、甘油磷酸酯23份、磷酸铵5份和蒸馏水95份加入反应器中，将温度升至78℃，以速率300r/min搅拌35min；
（3）将磷酸组胺12份滴加至步骤（2）中反应器中，滴加过程中不断搅拌，滴加时间为10min；随后加入氨基甲酸乙酯8份，将温度升至115℃回流反应1.5h，随后待反应冷却后即可得到所述保温抗菌织物整理剂。
测试各个实施例和对比例中得到整理剂的产品性能，结果如下：
实验 蓄热变化率（J/min） 保温变化率（℃/min） 抑菌率%（大肠杆菌）
实施例1 23.5 1.5 80.3
对比例1 43.1 20.4 10.4
实施例2 22.1 1.3 81.4
对比例2 45.0 21.7 11.3
实施例3 20.9 1.1 82.7
实施例4 19.7 0.8 84.6
实施例5 18.4 0.5 86.1

Claims (7)

1.一种保温抗菌织物整理剂，其特征在于，包括如下重量百分比的各组分：碳酸锌5-10份、氧氯化锆6-15份、硅化镁3-9份、铁锂云母7-12份、二乙醚15-25份、磷酸组胺8-16份、磷酸铵2-8份、氨基甲酸乙酯3-10份、甘油磷酸酯20-30份、蒸馏水80-120份。
2.根据权利要求1所述的一种保温抗菌织物整理剂，其特征在于，所述碳酸锌6-9份、氧氯化锆8-12份、硅化镁5-8份、铁锂云母9-11份、二乙醚17-20份、磷酸组胺10-13份、磷酸铵4-7份、氨基甲酸乙酯5-9份、甘油磷酸酯22-25份、蒸馏水90-100份。
3.根据权利要求2所述的一种保温抗菌织物整理剂，其特征在于，所述碳酸锌8份、氧氯化锆10份、硅化镁6份、铁锂云母10份、二乙醚18份、磷酸组胺12份、磷酸铵5份、氨基甲酸乙酯8份、甘油磷酸酯23份、蒸馏水95份。
4.一种保温抗菌织物整理剂的制备方法，其特征在于，具体包括如下步骤：
（1）将碳酸锌5-10份、氧氯化锆6-15份、硅化镁3-9份和铁锂云母7-12份混合并粉碎至80-120目，得到混合料；
（2）将二乙醚15-25份、甘油磷酸酯20-30份、磷酸铵2-8份和蒸馏水80-120份加入反应器中，将温度升至70-85℃，搅拌30-40min；
（3）将磷酸组胺8-16份滴加至步骤（2）中反应器中，滴加过程中不断搅拌；随后加入氨基甲酸乙酯3-10份，将温度升至100-120℃回流反应1-2h，随后待反应冷却后即可得到所述保温抗菌织物整理剂。
5.根据权利要求4所述一种保温抗菌织物整理剂的制备方法，其特征在于，步骤（1）中所述目数为100目。
6.根据权利要求4所述一种保温抗菌织物整理剂的制备方法，其特征在于，步骤（2）中所述温度为78℃，搅拌速率为200-350r/min，搅拌时间35min。
7.根据权利要求4所述一种保温抗菌织物整理剂的制备方法，其特征在于，步骤（3）中所述滴加时间为10min，温度为115℃，回流反应1.5h。
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