CN105647351A - 一种金属防火耐冲击涂料及其制备方法 - Google Patents
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Abstract
本发明涉及一种金属防火耐冲击涂料及其制备方法,涂料由以下质量份的原料组成:水性丙烯酸改性环氧树脂20~30份、氨基树脂10~15份、十二碳醇酯2~4份、聚乙烯醇4~6份、磷酸铝3~5份、磷酸铁5~8份、硅钙粉10~15份、磷酸二氢铵2~4份、硼酸锌2~5份、邻苯二甲酸二乙酯2~5份、亚麻油酸皂1~2份、磷酸三甲苯酯2~4份、聚氧化乙烯1~3份、乙醇3~5份、水30~50份;本发明提供的金属防护涂料,具有优良的耐热性,抗冲击性,附着力好。
Description
技术领域
本发明涉及一种金属防护涂料的制备方法,具体涉及一种金属防火耐冲击涂料及其制备方法,属金属表面防护的研究领域。
背景技术
金属材料受周围介质的作用,在金属界面上发生化学或电化学多相反应,使金属转入氧化(离子)状态而损坏,这会显著降低金属材料的强度、塑性、韧性等力学和使用性能,破坏金属构件的几何形状,缩短设备的使用寿命,甚至造成火灾、泄露等事故。随着现代工业的不断发展,金属表面的防腐保护越来越被各行各业重视。金属表面防腐的方式很多,包括电镀、化学镀、涂层技术等,其中采用涂料涂覆防腐是一种简洁、有效、操作方便的方法。涂料是指涂布于物体表面在一定的条件下能形成薄膜而起保护、装饰或其他特殊功能(绝缘、防锈、防霉、耐热等)的一类液体或固体材料。然而,目前使用的金属防护涂料往往在某些方面存在一定的缺陷,如耐热性、耐冲击性较差,附着力不高等,在诸如化工、冶金等行业等设备防护中难以推广应用。
本发明的目的就是开发一种金属防腐耐冲击涂料及其制备方法,通过在金属表面涂覆一层涂料,形成具有优良的耐热性、柔韧性,抗冲击力强,附着力好的保护层,以提高金属或金属设备的使用性能和寿命。
发明内容
本发明的目的在于提供一种金属防火耐冲击涂料,该涂料是具有优良的耐热性,韧性好,抗冲击,附着力好的金属防护物料。
本发明金属防火耐冲击涂料由以下质量份的原料组成:水性丙烯酸改性环氧树脂20~30份、氨基树脂10~15份、十二碳醇酯2~4份、聚乙烯醇4~6份、磷酸铝3~5份、磷酸铁5~8份、硅钙粉10~15份、磷酸二氢铵2~4份、硼酸锌2~5份、邻苯二甲酸二乙酯2~5份、亚麻油酸皂1~2份、磷酸三甲苯酯2~4份、聚氧化乙烯1~3份、乙醇3~5份、水30~50份。
所述硅钙粉为工业黄磷生产时产生的黄磷炉渣经干燥、研磨至小于300目而得到的物料。
本发明另一目的是提供上述金属防火耐冲击涂料的制备方法,具体步骤如下:
A、将水性丙烯酸改性环氧树脂、氨基树脂、十二碳醇酯、聚乙烯醇加入反应器中,然后加入亚麻油酸皂、磷酸三甲苯酯、聚氧化乙烯、乙醇和水,于常温、4000~5000rpm的搅拌条件下高速分散30~40min,得到混合乳液;
B、在A步骤得到的混合乳液中,加入磷酸铝、磷酸铁、硅钙粉、磷酸二氢铵、硼酸锌、邻苯二甲酸二乙酯,常温下在2000~3000rpm的搅拌条件下高速分散混合30~40min,得到混合均匀的金属防火耐冲击涂料。
本发明具有下列优点和效果:采用上述方案制备得到的金属防护涂料具有优良的耐热性,抗冲击,附着力好,设备要求简单,设备少,操作容易、安全等特点。
具体实施方式
下面通过实施例对本发明作进一步详细说明,但本发明的保护范围不局限于所述内容。
实施例1:本金属防火耐冲击涂料由以下质量份的原料组成:水性丙烯酸改性环氧树脂20份、氨基树脂15份、十二碳醇酯3份、聚乙烯醇4份、磷酸铝3份、磷酸铁8份、硅钙粉10份、磷酸二氢铵4份、硼酸锌2份、邻苯二甲酸二乙酯3份、亚麻油酸皂1份、磷酸三甲苯酯3份、聚氧化乙烯1份、乙醇5份、水50份;硅钙粉为工业黄磷生产时产生的黄磷炉渣经干燥、研磨至小于300目而得到的物料。
上述金属防火耐冲击涂料制备方法如下:将水性丙烯酸改性环氧树脂20kg、氨基树脂15kg、十二碳醇酯3kg、聚乙烯醇4kg加入反应器中,同时依次加入亚麻油酸皂1kg、磷酸三甲苯酯3kg、聚氧化乙烯1kg、乙醇5kg、水50kg,在常温、5000rpm的搅拌条件下高速分散30min,得到混合乳液;然后在得到的混合乳液中,加入磷酸铝3kg、磷酸铁8kg、硅钙粉10kg、磷酸二氢铵4kg、硼酸锌2kg、邻苯二甲酸二乙酯3kg,常温下在2500rpm的搅拌条件下高速分散混合30min,得到混合均匀的物料。
实施例2:本金属防火耐冲击涂料由以下质量份的原料组成:水性丙烯酸改性环氧树脂30份、氨基树脂12份、十二碳醇酯4份、聚乙烯醇5份、磷酸铝5份、磷酸铁6份、硅钙粉15份、磷酸二氢铵2份、硼酸锌4份、邻苯二甲酸二乙酯2份、亚麻油酸皂2份、磷酸三甲苯酯4份、聚氧化乙烯3份、乙醇3份、水40份;硅钙粉为工业黄磷生产时产生的黄磷炉渣经干燥、研磨至小于300目而得到的物料。
上述金属防火耐冲击涂料制备方法如下:将水性丙烯酸改性环氧树脂30kg、氨基树脂12kg、十二碳醇酯4kg、聚乙烯醇5kg加入反应器中,同时依次加入亚麻油酸皂2kg、磷酸三甲苯酯4kg、聚氧化乙烯3kg、乙醇3kg、水40kg,在常温、4000rpm的搅拌条件下高速分散40min,得到混合乳液;然后在得到的混合乳液中,加入磷酸铝5kg、磷酸铁6kg、硅钙粉15kg、磷酸二氢铵2kg、硼酸锌4kg、邻苯二甲酸二乙酯2kg,常温下在3000rpm的搅拌条件下高速分散混合30min,得到混合均匀的物料。
实施例3:本金属防火耐冲击涂料由以下质量份的原料组成:水性丙烯酸改性环氧树脂24份、氨基树脂14份、十二碳醇酯2份、聚乙烯醇6份、磷酸铝4份、磷酸铁5份、硅钙粉12份、磷酸二氢铵3份、硼酸锌5份、邻苯二甲酸二乙酯4份、亚麻油酸皂1.5份、磷酸三甲苯酯2份、聚氧化乙烯2份、乙醇4份、水30份;硅钙粉为工业黄磷生产时产生的黄磷炉渣经干燥、研磨至小于300目而得到的物料。
上述金属防火耐冲击涂料制备方法如下:将水性丙烯酸改性环氧树脂24kg、氨基树脂14kg、十二碳醇酯2kg、聚乙烯醇6kg加入反应器中,同时依次加入亚麻油酸皂1.5kg、磷酸三甲苯酯2kg、聚氧化乙烯2kg、乙醇4kg、水30kg,在常温、4400rpm的搅拌条件下高速分散35min,得到混合乳液;然后在得到的混合乳液中,加入磷酸铝4kg、磷酸铁5kg、硅钙粉12kg、磷酸二氢铵3kg、硼酸锌5kg、邻苯二甲酸二乙酯4kg,常温下在2000rpm的搅拌条件下高速分散混合40min,得到混合均匀的物料。
实施例4:本金属防火耐冲击涂料由以下质量份的原料组成:水性丙烯酸改性环氧树脂28份、氨基树脂10份、十二碳醇酯4份、聚乙烯醇4份、磷酸铝3份、磷酸铁7份、硅钙粉14份、磷酸二氢铵4份、硼酸锌3份、邻苯二甲酸二乙酯5份、亚麻油酸皂2份、磷酸三甲苯酯3份、聚氧化乙烯2.5份、乙醇4份、水35份;硅钙粉为工业黄磷生产时产生的黄磷炉渣经干燥、研磨至小于300目而得到的物料。
上述金属防火耐冲击涂料制备方法如下:将水性丙烯酸改性环氧树脂28kg、氨基树脂10kg、十二碳醇酯4kg、聚乙烯醇4kg加入反应器中,同时依次加入亚麻油酸皂2kg、磷酸三甲苯酯3kg、聚氧化乙烯2.5kg、乙醇4kg、水35份,在常温、4000rpm的搅拌条件下高速分散40min,得到混合乳液;然后在得到的混合乳液中,加入磷酸铝3kg、磷酸铁7kg、硅钙粉14kg、磷酸二氢铵4kg、硼酸锌3kg、邻苯二甲酸二乙酯5kg,常温下在2800rpm的搅拌条件下高速分散混合35min,得到混合均匀的物料。
检测结果
上述实施例1~实施例4的金属防火耐冲击涂料的技术性能指标检测结果如下:
。
Claims (3)
1.一种金属防火耐冲击涂料,其特征在于由以下质量份的原料组成:水性丙烯酸改性环氧树脂20~30份、氨基树脂10~15份、十二碳醇酯2~4份、聚乙烯醇4~6份、磷酸铝3~5份、磷酸铁5~8份、硅钙粉10~15份、磷酸二氢铵2~4份、硼酸锌2~5份、邻苯二甲酸二乙酯2~5份、亚麻油酸皂1~2份、磷酸三甲苯酯2~4份、聚氧化乙烯1~3份、乙醇3~5份、水30~50份。
2.根据权利要求1所述的金属防火耐冲击涂料,其特征在于:硅钙粉为工业黄磷生产时产生的黄磷炉渣经干燥、研磨至小于300目而得到的物料。
3.权利要求1所述的金属防火耐冲击涂料的制备方法,其特征在于按如下步骤进行:
A、将水性丙烯酸改性环氧树脂、氨基树脂、十二碳醇酯、聚乙烯醇加入反应器中,然后加入亚麻油酸皂、磷酸三甲苯酯、聚氧化乙烯、乙醇和水,于常温、4000~5000rpm的搅拌条件下高速分散30~40min,得到混合乳液;
B、在A步骤得到的混合乳液中,加入磷酸铝、磷酸铁、硅钙粉、磷酸二氢铵、硼酸锌、邻苯二甲酸二乙酯,常温下在2000~3000rpm的搅拌条件下高速分散混合30~40min,得到混合均匀的金属防火耐冲击涂料。
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