CN1056328C - 制备钯粉和氧化钯粉的气溶胶分解法 - Google Patents
制备钯粉和氧化钯粉的气溶胶分解法 Download PDFInfo
- Publication number
- CN1056328C CN1056328C CN93118602A CN93118602A CN1056328C CN 1056328 C CN1056328 C CN 1056328C CN 93118602 A CN93118602 A CN 93118602A CN 93118602 A CN93118602 A CN 93118602A CN 1056328 C CN1056328 C CN 1056328C
- Authority
- CN
- China
- Prior art keywords
- palladium
- aerosol
- contain
- drop
- particle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title claims abstract description 114
- 229910003445 palladium oxide Inorganic materials 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 52
- 239000000443 aerosol Substances 0.000 title claims abstract description 49
- 229910052763 palladium Inorganic materials 0.000 title claims abstract description 39
- 238000000354 decomposition reaction Methods 0.000 title claims abstract description 24
- 239000000843 powder Substances 0.000 title description 16
- JQPTYAILLJKUCY-UHFFFAOYSA-N palladium(ii) oxide Chemical compound [O-2].[Pd+2] JQPTYAILLJKUCY-UHFFFAOYSA-N 0.000 title 1
- HBEQXAKJSGXAIQ-UHFFFAOYSA-N oxopalladium Chemical compound [Pd]=O HBEQXAKJSGXAIQ-UHFFFAOYSA-N 0.000 claims abstract description 62
- 239000002245 particle Substances 0.000 claims abstract description 57
- 239000002904 solvent Substances 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 12
- 239000000047 product Substances 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 239000006227 byproduct Substances 0.000 claims abstract description 7
- 150000002941 palladium compounds Chemical class 0.000 claims description 30
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims 8
- 239000008367 deionised water Substances 0.000 claims 2
- 229910021641 deionized water Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 abstract description 34
- 229910052751 metal Inorganic materials 0.000 abstract description 32
- 239000012159 carrier gas Substances 0.000 abstract description 26
- 239000000203 mixture Substances 0.000 abstract description 12
- 238000002844 melting Methods 0.000 abstract description 6
- 230000008018 melting Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 18
- 239000003570 air Substances 0.000 description 17
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 8
- 238000002441 X-ray diffraction Methods 0.000 description 8
- 229910044991 metal oxide Inorganic materials 0.000 description 8
- 239000013528 metallic particle Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000000428 dust Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 239000013078 crystal Substances 0.000 description 6
- 150000002940 palladium Chemical class 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 229910052709 silver Inorganic materials 0.000 description 6
- 239000004332 silver Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000000956 alloy Substances 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000003985 ceramic capacitor Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 239000004020 conductor Substances 0.000 description 3
- 238000000280 densification Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 238000009938 salting Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009388 chemical precipitation Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003989 dielectric material Substances 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000004242 micellar liquid chromatography Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- -1 quinhydrones Substances 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000002389 environmental scanning electron microscopy Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000005118 spray pyrolysis Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2301/00—Metallic composition of the powder or its coating
- B22F2301/25—Noble metals, i.e. Ag Au, Ir, Os, Pd, Pt, Rh, Ru
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US95627292A | 1992-10-05 | 1992-10-05 | |
US07/956,272 | 1992-10-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1085474A CN1085474A (zh) | 1994-04-20 |
CN1056328C true CN1056328C (zh) | 2000-09-13 |
Family
ID=25498015
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN93118602A Expired - Lifetime CN1056328C (zh) | 1992-10-05 | 1993-10-05 | 制备钯粉和氧化钯粉的气溶胶分解法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5421854A (ja) |
EP (1) | EP0591881B1 (ja) |
JP (1) | JP2650838B2 (ja) |
KR (1) | KR960010247B1 (ja) |
CN (1) | CN1056328C (ja) |
DE (1) | DE69317846T2 (ja) |
TW (1) | TW256798B (ja) |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5429657A (en) * | 1994-01-05 | 1995-07-04 | E. I. Du Pont De Nemours And Company | Method for making silver-palladium alloy powders by aerosol decomposition |
US5861136A (en) * | 1995-01-10 | 1999-01-19 | E. I. Du Pont De Nemours And Company | Method for making copper I oxide powders by aerosol decomposition |
US5616165A (en) * | 1995-08-25 | 1997-04-01 | E. I. Du Pont De Nemours And Company | Method for making gold powders by aerosol decomposition |
DE19545455C1 (de) * | 1995-12-06 | 1997-01-23 | Degussa | Verfahren zur Herstellung von Edelmetallpulvern |
JP3277823B2 (ja) * | 1996-09-25 | 2002-04-22 | 昭栄化学工業株式会社 | 金属粉末の製造方法 |
US5847327A (en) * | 1996-11-08 | 1998-12-08 | W.L. Gore & Associates, Inc. | Dimensionally stable core for use in high density chip packages |
US6660680B1 (en) | 1997-02-24 | 2003-12-09 | Superior Micropowders, Llc | Electrocatalyst powders, methods for producing powders and devices fabricated from same |
CA2280865C (en) * | 1997-02-24 | 2008-08-12 | Superior Micropowders Llc | Aerosol method and apparatus, particulate products, and electronic devices made therefrom |
US6699304B1 (en) * | 1997-02-24 | 2004-03-02 | Superior Micropowders, Llc | Palladium-containing particles, method and apparatus of manufacture, palladium-containing devices made therefrom |
US6103393A (en) * | 1998-02-24 | 2000-08-15 | Superior Micropowders Llc | Metal-carbon composite powders, methods for producing powders and devices fabricated from same |
US6159267A (en) * | 1997-02-24 | 2000-12-12 | Superior Micropowders Llc | Palladium-containing particles, method and apparatus of manufacture, palladium-containing devices made therefrom |
US6679937B1 (en) * | 1997-02-24 | 2004-01-20 | Cabot Corporation | Copper powders methods for producing powders and devices fabricated from same |
US7097686B2 (en) * | 1997-02-24 | 2006-08-29 | Cabot Corporation | Nickel powders, methods for producing powders and devices fabricated from same |
US6780350B1 (en) | 1997-02-24 | 2004-08-24 | Superior Micropowders Llc | Metal-carbon composite powders, methods for producing powders and devices fabricated from same |
US6338809B1 (en) * | 1997-02-24 | 2002-01-15 | Superior Micropowders Llc | Aerosol method and apparatus, particulate products, and electronic devices made therefrom |
US20050097987A1 (en) * | 1998-02-24 | 2005-05-12 | Cabot Corporation | Coated copper-containing powders, methods and apparatus for producing such powders, and copper-containing devices fabricated from same |
US6967183B2 (en) | 1998-08-27 | 2005-11-22 | Cabot Corporation | Electrocatalyst powders, methods for producing powders and devices fabricated from same |
US7066976B2 (en) * | 1998-02-24 | 2006-06-27 | Cabot Corporation | Method for the production of electrocatalyst powders |
US6753108B1 (en) * | 1998-02-24 | 2004-06-22 | Superior Micropowders, Llc | Energy devices and methods for the fabrication of energy devices |
US7517606B2 (en) * | 1998-02-24 | 2009-04-14 | Cabot Corporation | Fuel cells and batteries including metal-carbon composite powders |
DE19912733A1 (de) | 1999-03-20 | 2000-09-21 | Degussa | Verfahren zur Herstellung von Wasserstoffperoxid durch Direktsynthese |
SG94805A1 (en) * | 2000-05-02 | 2003-03-18 | Shoei Chemical Ind Co | Method for preparing metal powder |
WO2002037990A2 (en) * | 2000-11-10 | 2002-05-16 | Vector Tobacco Ltd. | Method and product for removing carcinogens from tobacco smoke |
US6679938B1 (en) | 2001-01-26 | 2004-01-20 | University Of Maryland | Method of producing metal particles by spray pyrolysis using a co-solvent and apparatus therefor |
DE10120484A1 (de) * | 2001-04-25 | 2002-10-31 | Degussa | Verfahren und Vorrichtung zur thermischen Behandlung von pulverförmigen Stoffen |
JP2005508648A (ja) * | 2001-11-09 | 2005-04-07 | ベクター・タバコ・インコーポレーテッド | 炭でフィルターされた巻きタバコのメントール化のための組成物及び方法 |
EP1455609A2 (en) * | 2001-12-19 | 2004-09-15 | Vector Tobacco Inc. | Method and compositions for imparting cooling effect to tobacco products |
DE60215385T2 (de) * | 2001-12-19 | 2007-10-25 | Vector Tobacco Inc.(N.D.Ges.D.Staates Virginia) | Verfahren und zusammensetzung zur mentholanreicherung von zigaretten |
DE10249521B4 (de) * | 2002-10-23 | 2004-11-04 | W. C. Heraeus Gmbh & Co. Kg | Verfahren zur Herstellung von zumindest nahezu palladiumoxidfreiem Palladium, insbesondere Palladiumschwamm |
US7842181B2 (en) * | 2006-12-06 | 2010-11-30 | Saudi Arabian Oil Company | Composition and process for the removal of sulfur from middle distillate fuels |
CN101778684B (zh) * | 2007-09-07 | 2015-11-25 | E.I.内穆尔杜邦公司 | 包含银以及至少两种含非银的单质的多元素合金粉末 |
US8142646B2 (en) | 2007-11-30 | 2012-03-27 | Saudi Arabian Oil Company | Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds |
US8157886B1 (en) | 2008-02-19 | 2012-04-17 | Sandia Corporation | Bulk synthesis of nanoporous palladium and platinum powders |
EP2250129A2 (en) | 2008-02-21 | 2010-11-17 | Saudi Arabian Oil Company | Catalyst to attain low sulfur gasoline |
US9005432B2 (en) | 2010-06-29 | 2015-04-14 | Saudi Arabian Oil Company | Removal of sulfur compounds from petroleum stream |
CA2819321A1 (en) * | 2010-12-28 | 2012-07-05 | Chevron U.S.A. Inc. | Predicting droplet populations in piping flows |
US8535518B2 (en) | 2011-01-19 | 2013-09-17 | Saudi Arabian Oil Company | Petroleum upgrading and desulfurizing process |
US10752847B2 (en) | 2017-03-08 | 2020-08-25 | Saudi Arabian Oil Company | Integrated hydrothermal process to upgrade heavy oil |
US10703999B2 (en) | 2017-03-14 | 2020-07-07 | Saudi Arabian Oil Company | Integrated supercritical water and steam cracking process |
SG11202001238YA (en) * | 2017-08-17 | 2020-03-30 | Saudi Arabian Oil Co | Aerosol processing method for controlled coating of surface species to generate catalysts |
US10526552B1 (en) | 2018-10-12 | 2020-01-07 | Saudi Arabian Oil Company | Upgrading of heavy oil for steam cracking process |
CN116000306A (zh) * | 2022-12-30 | 2023-04-25 | 上海交通大学 | 一种生成单分散球形金属气溶胶颗粒的装置和方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS621807A (ja) * | 1985-06-26 | 1987-01-07 | Shoei Kagaku Kogyo Kk | 金属粉末の製造方法 |
JPH01192709A (ja) * | 1988-01-28 | 1989-08-02 | Tdk Corp | 超電導酸化物セラミクスの原料粉体、粉体および焼結体の製造方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1461176A (en) * | 1974-04-11 | 1977-01-13 | Plessey Inc | Method of producing powdered materials |
DE2929630C2 (de) * | 1979-07-21 | 1983-12-15 | Dornier System Gmbh, 7990 Friedrichshafen | Verfahren zur Herstellung von Silberpulver |
JPS622404A (ja) * | 1985-06-26 | 1987-01-08 | 昭栄化学工業株式会社 | 厚膜ペ−スト |
JPS62280308A (ja) * | 1986-05-30 | 1987-12-05 | Mitsui Mining & Smelting Co Ltd | 銀−パラジウム合金微粉末の製造方法 |
US4994107A (en) * | 1986-07-09 | 1991-02-19 | California Institute Of Technology | Aerosol reactor production of uniform submicron powders |
JPS6331522A (ja) * | 1986-07-25 | 1988-02-10 | Kao Corp | 吸湿剤 |
JPH0254704A (ja) * | 1988-08-19 | 1990-02-23 | Tanaka Kikinzoku Kogyo Kk | 貴金属粒子の製造方法 |
JPH0368484A (ja) * | 1989-08-08 | 1991-03-25 | Shinji Hasegawa | 排水管の清掃工法 |
US5250101A (en) * | 1991-04-08 | 1993-10-05 | Mitsubishi Gas Chemical Company, Inc. | Process for the production of fine powder |
JPH05311212A (ja) * | 1992-05-01 | 1993-11-22 | Tanaka Kikinzoku Kogyo Kk | Ag−Pd合金微粉末の製造方法 |
-
1993
- 1993-09-29 TW TW082108025A patent/TW256798B/zh not_active IP Right Cessation
- 1993-10-02 DE DE69317846T patent/DE69317846T2/de not_active Expired - Lifetime
- 1993-10-02 EP EP93115959A patent/EP0591881B1/en not_active Expired - Lifetime
- 1993-10-05 CN CN93118602A patent/CN1056328C/zh not_active Expired - Lifetime
- 1993-10-05 JP JP5249233A patent/JP2650838B2/ja not_active Expired - Lifetime
- 1993-10-05 KR KR1019930020519A patent/KR960010247B1/ko not_active IP Right Cessation
-
1994
- 1994-04-08 US US08/225,366 patent/US5421854A/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS621807A (ja) * | 1985-06-26 | 1987-01-07 | Shoei Kagaku Kogyo Kk | 金属粉末の製造方法 |
JPH01192709A (ja) * | 1988-01-28 | 1989-08-02 | Tdk Corp | 超電導酸化物セラミクスの原料粉体、粉体および焼結体の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
JP2650838B2 (ja) | 1997-09-10 |
CN1085474A (zh) | 1994-04-20 |
DE69317846D1 (de) | 1998-05-14 |
KR940008786A (ko) | 1994-05-16 |
JPH06235007A (ja) | 1994-08-23 |
EP0591881A1 (en) | 1994-04-13 |
US5421854A (en) | 1995-06-06 |
DE69317846T2 (de) | 1998-07-30 |
KR960010247B1 (ko) | 1996-07-26 |
EP0591881B1 (en) | 1998-04-08 |
TW256798B (ja) | 1995-09-11 |
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