CN105625028A - 一种防辐射纺织纤维及其制备方法 - Google Patents

一种防辐射纺织纤维及其制备方法 Download PDF

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CN105625028A
CN105625028A CN201610198556.5A CN201610198556A CN105625028A CN 105625028 A CN105625028 A CN 105625028A CN 201610198556 A CN201610198556 A CN 201610198556A CN 105625028 A CN105625028 A CN 105625028A
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吴林水
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Abstract

本发明公开了一种防辐射纺织纤维，包括如下重量百分比的各组分：纤维材料40-60份、四甲基乙二醇15-20份、乙二醇水杨酸酯8-13份、丙三醇10-18份、聚乙二醇14-25份、邻羟基苯甲醚13-20份、三氟化硼乙醚9-16份、苯甲酸银3-8份、甲烷磺酸银4-9份、2-羟基苯乙酸钠7-12份；本发明通过将纺织纤维材料直接与含有金属离子的溶液相互作用，使金属离子与纤维材料紧密结合，制作成本有所降低，防辐射性能好，使用寿命长。

Description

一种防辐射纺织纤维及其制备方法
技术领域
本发明属于纺织纤维领域，特别涉及一种防辐射纺织纤维及其制备方法。
背景技术
众所周知，自然界中的一切物体，只要温度在绝对温度零度以上，都会以电磁波和粒子的形式时刻不停地向外传送热量，即产生辐射。常见的辐射主要有太阳辐射、电磁辐射、热辐射等，我们日常生活中接触到的电子产品如手机、电视、微波炉、电脑等均会产生辐射。部分辐射会对人体造成不良影响，尤其是对于孕妇这一特殊人群而言，防辐射服显得非常重要。现有的防辐射服主要是通过银纳米线和铜纳米线与纺织纤维结合制得的，制作成本较高且经水洗、皂洗之后防辐射性能大幅度下降。
发明内容
针对现有技术中存在的以上技术问题，本发明提供了一种防辐射纺织纤维及其制备方法，通过将纺织纤维材料直接与含有金属离子的溶液相互作用，使金属离子与纤维材料紧密结合，制作成本有所降低，防辐射性能好，使用寿命长。
技术方案：一种防辐射纺织纤维，包括如下重量百分比的各组分：纤维材料40-60份、四甲基乙二醇15-20份、乙二醇水杨酸酯8-13份、丙三醇10-18份、聚乙二醇14-25份、邻羟基苯甲醚13-20份、三氟化硼乙醚9-16份、苯甲酸银3-8份、甲烷磺酸银4-9份、2-羟基苯乙酸钠7-12份。
优选的，所述纤维材料45-50份、四甲基乙二醇17-19份、乙二醇水杨酸酯10-12份、丙三醇12-16份、聚乙二醇18-22份、邻羟基苯甲醚14-18份、三氟化硼乙醚12-15份、苯甲酸银4-7份、甲烷磺酸银5-8份、2-羟基苯乙酸钠9-11份。
优选的，所述纤维材料48份、四甲基乙二醇18份、乙二醇水杨酸酯11份、丙三醇15份、聚乙二醇19份、邻羟基苯甲醚16份、三氟化硼乙醚13份、苯甲酸银6份、甲烷磺酸银7份、2-羟基苯乙酸钠10份。
优选的，所述纤维材料为面材料、涤纶、腈纶中的任一种。
一种防辐射纺织纤维的制备方法，具体包括如下步骤：
S1：将苯甲酸银3-8份、四甲基乙二醇15-20份和三氟化硼乙醚9-16份在温度30-50℃下微波加热3-7min，得液A；
S2：将甲烷磺酸银4-9份、邻羟基苯甲醚13-20份和聚乙二醇14-25份在温度40-50℃下微波加热2-5min，得液B；
S3：将2-羟基苯乙酸钠7-12份、乙二醇水杨酸酯8-13份和丙三醇10-18份在温度60-80℃下，以350-400r/min的转速搅拌15-20min，得液C；
S4：将纤维材料40-60份依次在液A、液B、液C中加热浸渍1-3h，随后经水洗、烘干后即可得到所述防辐射纺织纤维。
优选的，步骤S1中所述温度为38℃，加热时间为5min。
优选的，步骤S2中温度为46℃，加热时间为3min。
优选的，步骤S3中温度为72℃，转速为380r/min，搅拌时间为18min。
优选的，步骤S4中纤维材料在液A中加热温度为30℃，浸渍1h；纤维材料在液B中加热温度为40℃，浸渍1.5h；纤维材料在液C中加热温度为50℃，浸渍3h。
有益效果：
本发明所述一种防辐射纺织纤维的制备方法，通过将纺织纤维材料直接与含有金属离子的溶液相互作用，通过加热、浸渍等工艺使金属离子与纤维材料紧密结合，避免了银纳米线和铜纳米线较高的制作成本，且可耐水洗、皂洗，防辐射性能好，使用寿命长。该制备方法简便、易操作，适宜于规模化生产。
具体实施方式
实施例1
S1：将苯甲酸银3份、四甲基乙二醇15份和三氟化硼乙醚9份在温度30℃下微波加热3min，得液A；
S2：将甲烷磺酸银4份、邻羟基苯甲醚13份和聚乙二醇14份在温度40℃下微波加热2min，得液B；
S3：将2-羟基苯乙酸钠7份、乙二醇水杨酸酯8份和丙三醇10份在温度60℃下，以350r/min的转速搅拌15min，得液C；
S4：将纤维材料40份在液A中加热温度为30℃，浸渍1h；随后在液B中加热温度为40℃，浸渍1.5h；之后液C中加热温度为50℃，浸渍3h；经水洗、烘干后即可得到所述防辐射纺织纤维。
将所得到的防辐射纺织纤维在相同条件下制备成纺织品，考察其防辐射性能和耐水洗、耐皂洗性能；结果显示：在0MHz~100GHz范围内对电磁波的衰减可达34.9dB，屏蔽率达98.1%且经10次水洗和皂洗后，衰减和屏蔽率几乎无变化。
实施例2
S1：将苯甲酸银8份、四甲基乙二醇20份和三氟化硼乙醚16份在温度50℃下微波加热7min，得液A；
S2：将甲烷磺酸银9份、邻羟基苯甲醚13份和聚乙二醇14份在温度40℃下微波加热2min，得液B；
S3：将2-羟基苯乙酸钠12份、乙二醇水杨酸酯13份和丙三醇18份在温度80℃下，以400r/min的转速搅拌20min，得液C；
S4：将纤维材料60份在液A中加热温度为40℃，浸渍1h；随后在液B中加热温度为50℃，浸渍1.5h；之后液C中加热温度为30℃，浸渍2h；经水洗、烘干后即可得到所述防辐射纺织纤维。
将所得到的防辐射纺织纤维在相同条件下制备成纺织品，考察其防辐射性能和耐水洗、耐皂洗性能；结果显示：在0MHz~100GHz范围内对电磁波的衰减可达31.8dB，屏蔽率达98.5%且经10次水洗和皂洗后，衰减和屏蔽率几乎无变化。
实施例3
S1：将苯甲酸银8份、四甲基乙二醇20份和三氟化硼乙醚16份在温度50℃下微波加热7min，得液A；
S2：将甲烷磺酸银9份、邻羟基苯甲醚13份和聚乙二醇14份在温度40℃下微波加热2min，得液B；
S3：将2-羟基苯乙酸钠9份、乙二醇水杨酸酯10份和丙三醇12份在温度60℃下，以350r/min的转速搅拌15min，得液C；
S4：将纤维材料45份在液A中加热温度为35℃，浸渍2h；随后在液B中加热温度为40℃，浸渍1.5h；之后液C中加热温度为45℃，浸渍3h；经水洗、烘干后即可得到所述防辐射纺织纤维。
将所得到的防辐射纺织纤维在相同条件下制备成纺织品，考察其防辐射性能和耐水洗、耐皂洗性能；结果显示：在0MHz~100GHz范围内对电磁波的衰减可达28.6dB，屏蔽率达98.9%且经10次水洗和皂洗后，衰减和屏蔽率几乎无变化。
实施例4
S1：将苯甲酸银8份、四甲基乙二醇20份和三氟化硼乙醚16份在温度50℃下微波加热7min，得液A；
S2：将甲烷磺酸银9份、邻羟基苯甲醚13份和聚乙二醇14份在温度40℃下微波加热2min，得液B；
S3：将2-羟基苯乙酸钠11份、乙二醇水杨酸酯12份和丙三醇16份在温度80℃下，以400r/min的转速搅拌20min，得液C；
S4：将纤维材料50份在液A中加热温度为40℃，浸渍1h；随后在液B中加热温度为35℃，浸渍3h；之后液C中加热温度为50℃，浸渍1.5h；经水洗、烘干后即可得到所述防辐射纺织纤维。
将所得到的防辐射纺织纤维在相同条件下制备成纺织品，考察其防辐射性能和耐水洗、耐皂洗性能；结果显示：在0MHz~100GHz范围内对电磁波的衰减可达26.4dB，屏蔽率达99.2%且经10次水洗和皂洗后，衰减和屏蔽率几乎无变化。
实施例5
S1：将苯甲酸银6份、四甲基乙二醇18份和三氟化硼乙醚13份在温度38℃下微波加热5min，得液A；
S2：将甲烷磺酸银7份、邻羟基苯甲醚16份和聚乙二醇19份在温度46℃下微波加热3min，得液B；
S3：将2-羟基苯乙酸钠10份、乙二醇水杨酸酯11份和丙三醇15份在温度72℃下，以380r/min的转速搅拌18min，得液C；
S4：将纤维材料48份在液A中加热温度为30℃，浸渍1h；随后在液B中加热温度为40℃，浸渍1.5h；之后液C中加热温度为50℃，浸渍3h；经水洗、烘干后即可得到所述防辐射纺织纤维。
将所得到的防辐射纺织纤维在相同条件下制备成纺织品，考察其防辐射性能和耐水洗、耐皂洗性能；结果显示：在0MHz~100GHz范围内对电磁波的衰减可达25.1dB，屏蔽率达99.8%且经10次水洗和皂洗后，衰减和屏蔽率几乎无变化。

Claims (9)

1.一种防辐射纺织纤维，其特征在于，包括如下重量百分比的各组分：纤维材料40-60份、四甲基乙二醇15-20份、乙二醇水杨酸酯8-13份、丙三醇10-18份、聚乙二醇14-25份、邻羟基苯甲醚13-20份、三氟化硼乙醚9-16份、苯甲酸银3-8份、甲烷磺酸银4-9份、2-羟基苯乙酸钠7-12份。
2.根据权利要求1所述的一种防辐射纺织纤维，其特征在于，所述纤维材料45-50份、四甲基乙二醇17-19份、乙二醇水杨酸酯10-12份、丙三醇12-16份、聚乙二醇18-22份、邻羟基苯甲醚14-18份、三氟化硼乙醚12-15份、苯甲酸银4-7份、甲烷磺酸银5-8份、2-羟基苯乙酸钠9-11份。
3.根据权利要求2所述的一种防辐射纺织纤维，其特征在于，所述纤维材料48份、四甲基乙二醇18份、乙二醇水杨酸酯11份、丙三醇15份、聚乙二醇19份、邻羟基苯甲醚16份、三氟化硼乙醚13份、苯甲酸银6份、甲烷磺酸银7份、2-羟基苯乙酸钠10份。
4.根据权利要求1-3任一所述的一种防辐射纺织纤维，其特征在于，所述纤维材料为面材料、涤纶、腈纶中的任一种。
5.一种防辐射纺织纤维的制备方法，其特征在于，具体包括如下步骤：
S1：将苯甲酸银3-8份、四甲基乙二醇15-20份和三氟化硼乙醚9-16份在温度30-50℃下微波加热3-7min，得液A；
S2：将甲烷磺酸银4-9份、邻羟基苯甲醚13-20份和聚乙二醇14-25份在温度40-50℃下微波加热2-5min，得液B；
S3：将2-羟基苯乙酸钠7-12份、乙二醇水杨酸酯8-13份和丙三醇10-18份在温度60-80℃下，以350-400r/min的转速搅拌15-20min，得液C；
S4：将纤维材料40-60份依次在液A、液B、液C中加热浸渍1-3h，随后经水洗、烘干后即可得到所述防辐射纺织纤维。
6.根据权利要求5所述的一种防辐射纺织纤维的制备方法，其特征在于，步骤S1中所述温度为38℃，加热时间为5min。
7.根据权利要求5所述的一种防辐射纺织纤维的制备方法，其特征在于，步骤S2中温度为46℃，加热时间为3min。
8.根据权利要求5所述的一种防辐射纺织纤维的制备方法，其特征在于，步骤S3中温度为72℃，转速为380r/min，搅拌时间为18min。
9.根据权利要求5所述的一种防辐射纺织纤维的制备方法，其特征在于，步骤S4中纤维材料在液A中加热温度为30℃，浸渍1h；纤维材料在液B中加热温度为40℃，浸渍1.5h；纤维材料在液C中加热温度为50℃，浸渍3h。
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