CN105603819B - 一种施胶剂及其制备方法 - Google Patents

一种施胶剂及其制备方法 Download PDF

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CN105603819B
CN105603819B CN201610026976.5A CN201610026976A CN105603819B CN 105603819 B CN105603819 B CN 105603819B CN 201610026976 A CN201610026976 A CN 201610026976A CN 105603819 B CN105603819 B CN 105603819B
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CN105603819A (zh
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余晓飞
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Xuzhou Naili Macromolecule Technology Co Ltd
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Priority to CN201710894976.1A priority patent/CN107558299A/zh
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    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16Sizing or water-repelling agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/22Proteins
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/25Cellulose
    • D21H17/26Ethers thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/28Starch
    • D21H17/29Starch cationic
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/44Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
    • D21H17/45Nitrogen-containing groups
    • DTEXTILES; PAPER
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    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/62Rosin; Derivatives thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
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    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material

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Abstract

本发明公开了一种施胶剂及其制备方法,其中,其原料配方是由如下重量份数的各组分组成:阳离子松香胶10‑15份;硫酸铝20‑30份;阳离子淀粉5‑15份;阳离子聚丙烯酰胺2‑5份;酪蛋白朊1‑3份;羧甲基纤维素钠20‑30份;滑石粉40‑60份。本发明公开了一种施胶剂及其制备方法,本发明的施胶剂附着率高,施胶效果好,强度高,耐久性好。

Description

一种施胶剂及其制备方法
技术领域
本发明涉及抄纸施胶领域,尤其涉及的是一种施胶剂及其制备方法。
背景技术
在造纸,抄纸过程中,经常需要用到施胶剂使纸和纸板具有抗墨、抗水、抗乳液、抗腐蚀等性能以提高平滑度、强度和施用期。现有技术中的施胶剂多种多样,但是普遍存在强度差,耐久性差,施胶效果不理想的问题。
因此,现有技术有待改进。
发明内容
本发明的目的在于提供一种施胶剂及其制备方法,本发明的施胶剂附着率高,施胶效果好,强度高,耐久性好。
本发明的技术方案如下:一种施胶剂,其中,其原料配方是由如下重量份数的各组分组成:
阳离子松香胶 10-15份;
硫酸铝 20-30份;
阳离子淀粉 5-15份;
阳离子聚丙烯酰胺 2-5 份;
酪蛋白朊 1-3份;
羧甲基纤维素钠 20-30份;
滑石粉 40-60份。
所述的施胶剂,其中,其原料配方是由如下重量份数的各组分组成:
阳离子松香胶 12份;
硫酸铝 21份;
阳离子淀粉 10份;
阳离子聚丙烯酰胺 2 份;
酪蛋白朊 1份;
羧甲基纤维素钠 30份;
滑石粉 45份。
所述的施胶剂的制备方法,其中,包括以下步骤:
A1、将阳离子淀粉放入羧甲基纤维素钠溶液中,搅拌20分钟;
A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺,搅拌10分钟,温度为50摄氏度;
A3、加入阳离子松香胶,继续搅拌30分钟,前15分钟搅拌温度为50摄氏度,后15分钟搅拌温度为35摄氏度,然后再次升温至55-60摄氏度保温浸泡30分钟;
A4、加入滑石粉,搅拌直至没有沉淀,得到成品。
本发明的有益效果:本发明公开了一种施胶剂及其制备方法,本发明的施胶剂附着率高,施胶效果好,强度高,耐久性好。
具体实施方式
为使本发明的目的、技术方案及优点更加清楚、明确,以下列举实施例对本发明进一步详细说明。
实施例1
本实施例的施胶剂原料配方是由如下重量份数的各组分组成:
阳离子松香胶 12份;
硫酸铝 21份;
阳离子淀粉 10份;
阳离子聚丙烯酰胺 2 份;
酪蛋白朊 1份;
羧甲基纤维素钠 30份;
滑石粉 45份。
本实施例的施胶剂的制备过程如下:
A1、将阳离子淀粉放入羧甲基纤维素钠溶液中,搅拌20分钟。
A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺,搅拌10分钟,温度为50摄氏度。
A3、加入阳离子松香胶,继续搅拌30分钟,前15分钟搅拌温度为50摄氏度,后15分钟搅拌温度为35摄氏度,然后再次升温至55-60摄氏度保温浸泡30分钟;通过巧妙的采用这种先升温、在降温、最后再升温保温的技术方式,有利于提高施胶剂的附着率和耐久性,同时对温度稳定性强。
A4、加入滑石粉,搅拌直至没有沉淀,得到成品。
本实施例得到的施胶剂附着率高,施胶效果好,强度高,耐久性好。经测试,取本实施例制备的施胶剂1g 进行施胶,胶料附着率达到68%,纸张强度较不施胶提高78%。
实施例2
本实施例基本与实施例1相同,不同的是,本实施例的施胶剂原料配方是由如下重量份数的各组分组成:
阳离子松香胶 10份;
硫酸铝 25份;
阳离子淀粉 10份;
阳离子聚丙烯酰胺 4 份;
酪蛋白朊 2份;
羧甲基纤维素钠 20份;
滑石粉 45份。
本实施例提供的施胶剂比实施例1的效果更好,经测试,取本实施例制备的施胶剂1g ,取本实施例制备的施胶剂1g 进行施胶,胶料附着率达到72%,纸张强度较不施胶的提高86%。
应当理解的是,本发明的应用不限于上述的举例,对本领域普通技术人员来说,可以根据上述说明加以改进或变换,所有这些改进和变换都应属于本发明所附权利要求的保护范围。

Claims (2)

1.一种施胶剂,其特征在于,其原料配方是由如下重量份数的各组分组成:
阳离子松香胶 12份;
硫酸铝 21份;
阳离子淀粉 10份;
阳离子聚丙烯酰胺 2 份;
酪蛋白朊 1份;
羧甲基纤维素钠 30份;
滑石粉 45份。
2.一种如权利要求1所述的施胶剂的制备方法,其特征在于,包括以下步骤:
A1、将阳离子淀粉放入羧甲基纤维素钠溶液中,搅拌20分钟;
A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺,搅拌10分钟,温度为50摄氏度;
A3、加入阳离子松香胶,继续搅拌30分钟,前15分钟搅拌温度为50摄氏度,后15分钟搅拌温度为35摄氏度,然后再次升温至55-60摄氏度保温浸泡30分钟;
A4、加入滑石粉,搅拌直至没有沉淀,得到成品。
CN201610026976.5A 2016-01-15 2016-01-15 一种施胶剂及其制备方法 Expired - Fee Related CN105603819B (zh)

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CN201710902565.2A CN107503235A (zh) 2016-01-15 2016-01-15 用于造纸工业的高强度施胶剂
CN201710825178.3A CN107558298A (zh) 2016-01-15 2016-01-15 一种施胶剂及其制备方法
CN201610026976.5A CN105603819B (zh) 2016-01-15 2016-01-15 一种施胶剂及其制备方法
CN201710894976.1A CN107558299A (zh) 2016-01-15 2016-01-15 高耐久性施胶剂
CN201710902530.9A CN107604751A (zh) 2016-01-15 2016-01-15 用于造纸工业的高强度施胶剂的制备方法

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CN201710825178.3A Division CN107558298A (zh) 2016-01-15 2016-01-15 一种施胶剂及其制备方法
CN201710902530.9A Division CN107604751A (zh) 2016-01-15 2016-01-15 用于造纸工业的高强度施胶剂的制备方法
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CN106702815A (zh) * 2016-12-09 2017-05-24 苏州艾博迈尔新材料有限公司 一种复合表面施胶剂及其制备方法
CN106638140A (zh) * 2016-12-10 2017-05-10 钦州学院 一种施胶剂及其制备方法
CN107724173A (zh) * 2017-09-18 2018-02-23 芜湖米诺环保科技有限公司 一种高强度瓦楞纸用的表面抗潮剂
CN112976740A (zh) * 2021-04-09 2021-06-18 湖北银河彩印包装有限公司 一种防潮抗挤压瓦楞纸板
CN113718550B (zh) * 2021-08-26 2022-04-22 浙江百斯特化工有限公司 一种松香施胶剂及其制备方法

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JP4224746B2 (ja) * 1999-08-30 2009-02-18 ハリマ化成株式会社 製紙用サイズ剤
CN101255668B (zh) * 2008-04-09 2010-12-22 广西壮族自治区化工研究院 高稳定性阳离子分散松香胶及其制备方法
CN101319026A (zh) * 2008-06-18 2008-12-10 江苏飞翔化工股份有限公司 松香施胶剂中辅助松香分散的阳离子聚合物的制备方法
CN101787662B (zh) * 2010-01-14 2011-10-19 镇江大东纸业有限公司 计算机直接制印版衬纸的生产方法
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