CN107604751A - 用于造纸工业的高强度施胶剂的制备方法 - Google Patents

用于造纸工业的高强度施胶剂的制备方法 Download PDF

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CN107604751A
CN107604751A CN201710902530.9A CN201710902530A CN107604751A CN 107604751 A CN107604751 A CN 107604751A CN 201710902530 A CN201710902530 A CN 201710902530A CN 107604751 A CN107604751 A CN 107604751A
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余晓飞
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/22—Proteins
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/25—Cellulose
    • D21H17/26—Ethers thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D21H17/29—Starch cationic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
    • D21H17/45—Nitrogen-containing groups
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/62—Rosin; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material

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  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
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Abstract

本发明公开了用于造纸工业的高强度施胶剂，其原料配方是由如下重量份数的各组分组成：阳离子松香胶12份；硫酸铝22份；阳离子淀粉10份；阳离子聚丙烯酰胺4份；酪蛋白朊3份；羧甲基纤维素钠28份；滑石粉55份；包括以下工艺步骤：A1、将阳离子淀粉放入羧甲基纤维素钠溶液中，搅拌20分钟；A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺，搅拌10分钟，温度为50摄氏度；A3、加入阳离子松香胶，继续搅拌30分钟，前15分钟搅拌温度为50摄氏度，后15分钟搅拌温度为35摄氏度，然后再次升温至55‑60摄氏度保温浸泡30分钟；A4、加入滑石粉，搅拌直至没有沉淀，得到成品。本发明公开了用于造纸工业的高强度施胶剂，本发明的施胶剂附着率高，施胶效果好，强度高，耐久性好。

Description

用于造纸工业的高强度施胶剂的制备方法
技术领域
本申请为分案申请，母案申请日：2016年1月15日，申请号：201610026976.5。本发明涉及抄纸施胶领域，尤其涉及的是用于造纸工业的高强度施胶剂。
背景技术
在造纸，抄纸过程中，经常需要用到施胶剂使纸和纸板具有抗墨、抗水、抗乳液、抗腐蚀等性能以提高平滑度、强度和施用期。现有技术中的施胶剂多种多样，但是普遍存在强度差，耐久性差，施胶效果不理想的问题。因此，现有技术有待改进。
发明内容
本发明的目的在于提供用于造纸工业的高强度施胶剂，本发明的施胶剂附着率高，施胶效果好，强度高，耐久性好。
本发明的技术方案如下：一种用于造纸工业的高强度施胶剂，其中，其原料配方是由如下重量份数的各组分组成：
所述的用于造纸工业的高强度施胶剂，其中，其原料配方是由如下重量份数的各组分组成：
所述的用于造纸工业的高强度施胶剂，其中，其原料配方是由如下重量份数的各组分组成：
所述的用于造纸工业的高强度施胶剂，其中，其原料配方是由如下重量份数的各组分组成：
所述的用于造纸工业的高强度施胶剂的制备方法，其中，包括以下步骤：
A1、将阳离子淀粉放入羧甲基纤维素钠溶液中，搅拌20分钟；
A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺，搅拌10分钟，温度为50摄氏度；
A3、加入阳离子松香胶，继续搅拌30分钟，前15分钟搅拌温度为50摄氏度，后15分钟搅拌温度为35摄氏度，然后再次升温至55-60摄氏度保温浸泡30分钟；
A4、加入滑石粉，搅拌直至没有沉淀，得到成品。
本发明的有益效果：本发明公开了用于造纸工业的高强度施胶剂，本发明的施胶剂附着率高，施胶效果好，强度高，耐久性好。
具体实施方式
为使本发明的目的、技术方案及优点更加清楚、明确，以下列举实施例对本发明进一步详细说明。
实施例1
本实施例的施胶剂原料配方是由如下重量份数的各组分组成：
阳离子松香胶12份；
硫酸铝21份；
阳离子淀粉10份；
阳离子聚丙烯酰胺2份；
酪蛋白朊1份；
羧甲基纤维素钠30份；
滑石粉45份。
本实施例的施胶剂的制备过程如下：
A1、将阳离子淀粉放入羧甲基纤维素钠溶液中，搅拌20分钟。
A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺，搅拌10分钟，温度为50摄氏度。
A3、加入阳离子松香胶，继续搅拌30分钟，前15分钟搅拌温度为50摄氏度，后15分钟搅拌温度为35摄氏度，然后再次升温至55-60摄氏度保温浸泡30分钟；通过巧妙的采用这种先升温、在降温、最后再升温保温的技术方式，有利于提高施胶剂的附着率和耐久性，同时对温度稳定性强。
A4、加入滑石粉，搅拌直至没有沉淀，得到成品。
本实施例得到的施胶剂附着率高，施胶效果好，强度高，耐久性好。经测试，取本实施例制备的施胶剂1g进行施胶，胶料附着率达到68％，纸张强度较不施胶提高78％。
实施例2
实施例2本实施例基本与实施例1相同，不同的是，本实施例的施胶剂原料配方是由如下重量份数的各组分组成：
阳离子松香胶10份；
硫酸铝25份；
阳离子淀粉10份；
阳离子聚丙烯酰胺4份；
酪蛋白朊2份；
羧甲基纤维素钠20份；
滑石粉45份。
本实施例提供的施胶剂比实施例1的效果更好，经测试，取本实施例制备的施胶剂1g，取本实施例制备的施胶剂1g进行施胶，胶料附着率达到72％，纸张强度较不施胶的提高86％。
实施例3
实施例3本实施例基本与实施例1、2相同，不同的是，本实施例的施胶剂原料配方是由如下重量份数的各组分组成：
本实施例提供的施胶剂比实施例1的效果更好，经测试，取本实施例制备的施胶剂1g，取本实施例制备的施胶剂1g进行施胶，胶料附着率达到75％，纸张强度较不施胶的提高88％。
应当理解的是，本发明的应用不限于上述的举例，对本领域普通技术人员来说，可以根据上述说明加以改进或变换，所有这些改进和变换都应属于本发明所附权利要求的保护范围。

Claims (1)

1.一种用于造纸工业的高强度施胶剂的制备方法，其特征在于，其原料配方是由如下重量份数的各组分组成：阳离子松香胶12份；硫酸铝22份；阳离子淀粉10份；阳离子聚丙烯酰胺4份；酪蛋白朊3份；羧甲基纤维素钠28份；滑石粉55份；
包括以下工艺步骤：A1、将阳离子淀粉放入羧甲基纤维素钠溶液中，搅拌20分钟；A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺，搅拌10分钟，温度为50摄氏度；A3、加入阳离子松香胶，继续搅拌30分钟，前15分钟搅拌温度为50摄氏度，后15分钟搅拌温度为35摄氏度，然后再次升温至55-60摄氏度保温浸泡30分钟；A4、加入滑石粉，搅拌直至没有沉淀，得到成品。
CN201710902530.9A 2016-01-15 2016-01-15 用于造纸工业的高强度施胶剂的制备方法 Pending CN107604751A (zh)

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CN106702815A (zh) * 2016-12-09 2017-05-24 苏州艾博迈尔新材料有限公司 一种复合表面施胶剂及其制备方法
CN106638140A (zh) * 2016-12-10 2017-05-10 钦州学院 一种施胶剂及其制备方法
CN107724173A (zh) * 2017-09-18 2018-02-23 芜湖米诺环保科技有限公司 一种高强度瓦楞纸用的表面抗潮剂
CN112976740A (zh) * 2021-04-09 2021-06-18 湖北银河彩印包装有限公司 一种防潮抗挤压瓦楞纸板
CN113718550B (zh) * 2021-08-26 2022-04-22 浙江百斯特化工有限公司 一种松香施胶剂及其制备方法

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Application publication date: 20180119