Background technology
At present, PCB surface gold-plating technique can comprise the following steps:
A1, the figure that PCB makes gold-plated region and gold plated lead;
A2, stick dry film in non-gold-plated region, then gold-plated in gold-plated region;
A3, make non-gold-plated regional graphics;
A4, other coating operation of surface.
In above-mentioned technique, first making the gold-plated region on PCB, is first time graphic making; then dry film protection is sticked in non-gold-plated region, and gold-plated in the gold-plated region of not sticking dry film, then remove the dry film in non-gold-plated region; making the figure in non-gold-plated region, is second time graphic making.The successively graphic making of twice, by the problem causing gold-plated region and non-gold-plated joint area place to there is the aligning accuracy deviation of 2-4mil, if when there is fine and closely woven circuit in gold-plated region and non-gold-plated joint area place, then cannot at this junction electroplating lead.
Another PCB craft of gilding can comprise the following steps:
B1, with dry film cover non-gold-plated region, gold-plated in gold-plated region;
B2, PCB after gold-plated make figure.
In above-mentioned technique, the poor adhesive force of dry film, non-gold-plated region overlay is tight, causes occurring gold-platedly oozing the problem of crossing, and gold plating quality is poor.
Summary of the invention
For above-mentioned defect, embodiments provide a kind of electrogilding method for printed circuit board (PCB), adopt advanced oxidation processes, prevent from gold-platedly oozing the problem of crossing, and the aligning accuracy at gold-plated region and non-gold-plated joint area place is higher, improve printed circuit board (PCB) quality.
Embodiments provide a kind of electrogilding method for printed circuit board (PCB), comprising:
Printed circuit board (PCB) after electro-coppering prints wet film, and carries out prebake conditions;
Graphic transitions process is carried out to the printed circuit board (PCB) after prebake conditions, to make the gold-plated region obtaining non-gold-plated region and wet film covering in described printed circuit board surface;
Segmentation baking is carried out to described printed circuit board (PCB), to make to generate oxide layer in described non-gold-plated region surface;
Remove the wet film in described printed circuit board surface;
Using the layers of copper under described printed circuit board (PCB) as electroplating lead, to described printed circuit board electroplating;
To described printed circuit board (PCB) microetch, remove the oxide layer of described non-gold-plated region surface.
Further, comprise before described printed circuit board (PCB) after electro-coppering prints wet film: copper electroplating layer on the printed circuit board (PCB) after making internal layer figure, at least thick than the thickness of the preset need 5um of described copper layer thickness.
Particularly, describedly carry out Graphic transitions process to the printed circuit board (PCB) after prebake conditions, the gold-plated region covered to make to obtain non-gold-plated region and wet film in described printed circuit board surface comprises: utilize anti-gold-plated figure egative film exposure copper face to obtain non-gold-plated region on the printed circuit board and development copper face obtains gold-plated region.
As can be seen from the above technical solutions, the electrogilding method for printed circuit board (PCB) that the embodiment of the present invention provides has the following advantages: after the printed circuit board (PCB) being printed with electrogilding stamps wet film, carry out prebake conditions and Graphic transitions process, printed circuit board surface obtains the gold-plated region of non-gold-plated region and wet film covering, and then printed circuit board (PCB) segmentation is toasted, so that printed circuit board (PCB) can deep oxidation, generate oxide layer in above-mentioned non-gold-plated region surface, and gold-plated region can not be oxidized owing to being covered by wet film.Remove the wet film in this printed circuit board surface again; to this printed circuit board electroplating; now; non-gold-plated region surface have protect oxide layer cannot plated with nickel gold; can not cause between gold-plated region and non-gold-plated region and gold-platedly ooze the problem of crossing; the Line-width precision at gold-plated region and non-gold-plated joint area place can be improved, improve printed circuit board (PCB) quality.
Embodiment
Below in conjunction with the accompanying drawing of the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiments providing a kind of electrogilding method for printed circuit board (PCB), for improving the Line-width precision at gold-plated region and non-gold-plated joint area place, improving gold plating quality.
With specific embodiment, the present invention will be described in detail below:
Refer to Fig. 1, the schematic flow sheet of the electrogilding method for printed circuit board (PCB) that Fig. 1 provides for the embodiment of the present invention; As shown in Figure 1, a kind of electrogilding method for printed circuit board (PCB) can comprise:
S101, printed circuit board (PCB) after electro-coppering print wet film, and carries out prebake conditions;
Printed circuit board (PCB) carries out inner figure making, matching board, lamination, boring, heavy copper and plating according to normal flow, copper layer thickness after plating 5um at least thicker in the copper layer thickness of preset need, to guarantee copper layer thickness can not be caused not enough after successive depths is oxidized rear and oxidation removal.
S102, Graphic transitions process is carried out to the printed circuit board (PCB) after prebake conditions, to make to obtain in described printed circuit board surface the gold-plated region that non-gold-plated region and wet film cover;
Be understandable that, Graphic transitions process mainly adopts anti-gold-plated figure egative film to printed circuit board to explosure-development.Gold-plated region is transmission region, and do not have gold-plated region to arrange and be in the light a little, the gold-plated region so after development is covered by wet film, and copper face is exposed in non-gold-plated region.
S103, carry out segmentation baking at described printed circuit board (PCB), to make to generate oxide layer in described non-gold-plated region surface;
Deep oxidation is carried out to the printed circuit board (PCB) after Graphic transitions process, specifically segmentation baking is carried out to printed circuit board (PCB).
Enough moisture is had in order to ensure during deep oxidation, before segmentation baking, spray last layer water smoke first on a printed circuit, make the moisture on printed circuit board (PCB) sufficient, meet deep oxidation needs, make the copper of non-gold-plated region surface fully oxidation reaction can occur.
Wherein, segmentation baking from left to right or is from right to left toasted piecemeal, to guarantee that the copper face exposed in the non-gold-plated region after Graphic transitions process can by deep oxidation.
Be understandable that, the materials such as oxygen, carbon dioxide and water in the copper now exposed in the gold-plated region of deep oxidation right and wrong and air react, and generate the oxide of the mixed type copper such as basic copper carbonate, cupric oxide, cuprous oxide.Wherein, reactive chemistry equation is as follows:
7Cu+4O
2+CO
2+2HO
2=2Cu
2(OH)
2CO
3+CuO+Cu
2O
The thickness of mixed copper oxide that deep oxidation generates, at more than 2-3um, can resist general weak acid to wash, due to oxide cannot with nickel generation displacement reaction, protect non-gold-plated region can not plated with gold.
Preferably, the temperature of 80 DEG C can be adopted first to printed circuit board (PCB) segmentation baking 30min, again temperature is elevated to 120 DEG C again to printed circuit board (PCB) segmentation baking 60min, temperature is elevated to 150 DEG C once again afterwards, to printed circuit board (PCB) segmentation baking 60min, finally, then temperature is elevated to 200 DEG C, to printed circuit board (PCB) segmentation baking 30min.
S104, the wet film removed in described printed circuit board surface;
Preferably, can adopt the wet film in alkaline solution removal printed circuit board surface, gold-plated region, can not be oxidized when segmentation is toasted because there is wet film to protect.And alkaline solution can not impact the oxide in non-gold-plated region.
At printed circuit board (PCB) after above-mentioned process, by light contamination and can there is small amounts in the gold-plated region of printed circuit board surface, can adopt weak pickling unavoidably.
S105, using the layers of copper under described printed circuit board (PCB) as electroplating lead, to described printed circuit board electroplating;
Cannot plated with nickel gold due to the protection of non-gold-plated region Cu oxide, only can on gold-plated region plated with nickel gold, then can not to cause between gold-plated region and non-gold-plated region gold-plated oozes the problem of crossing.
S106, to described printed circuit board (PCB) microetch, remove the oxide layer of described non-gold-plated region surface.
Alternatively, the oxide layer generated after stronger microetch liquid medicine can be adopted to get rid of deep oxidation, exposes the layers of copper under non-gold-plated region.
After removal oxide layer, outer graphics making and packaging will be carried out according to normal flow to printed circuit board (PCB).
In the embodiment of the present invention, prebake conditions and Graphic transitions process is carried out after the printed circuit board (PCB) being printed with electrogilding stamps wet film, printed circuit board surface obtains the gold-plated region of non-gold-plated region and wet film covering, and then this printed circuit board (PCB) segmentation is toasted, generate oxide layer in above-mentioned non-gold-plated region surface, and gold-plated region can not be oxidized owing to being covered by wet film.Remove the wet film in this printed circuit board surface again; to this printed circuit board electroplating; now; non-gold-plated region surface have protect oxide layer cannot plated with nickel gold; can not cause between gold-plated region and non-gold-plated region and gold-platedly ooze the problem of crossing, the Line-width precision at gold-plated region and non-gold-plated joint area place can be improved.
Above a kind of electrogilding method for printed circuit board (PCB) provided by the present invention is described in detail, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.