CN105503350A - Composting method for efficient degradation of tetracycline antibiotics in livestock and poultry breeding excrement - Google Patents

Composting method for efficient degradation of tetracycline antibiotics in livestock and poultry breeding excrement Download PDF

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Publication number
CN105503350A
CN105503350A CN201511004438.8A CN201511004438A CN105503350A CN 105503350 A CN105503350 A CN 105503350A CN 201511004438 A CN201511004438 A CN 201511004438A CN 105503350 A CN105503350 A CN 105503350A
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China
Prior art keywords
compost
livestock
tetracycline antibiotics
poultry
efficient degradation
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CN201511004438.8A
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Chinese (zh)
Inventor
马晓文
张思学
任传宝
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Zibo Yongchen Environmental Impact Assessment Co Ltd
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Zibo Yongchen Environmental Impact Assessment Co Ltd
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Priority to CN201511004438.8A priority Critical patent/CN105503350A/en
Publication of CN105503350A publication Critical patent/CN105503350A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • C05D9/02Other inorganic fertilisers containing trace elements
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/80Separation, elimination or disposal of harmful substances during the treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Fertilizers (AREA)

Abstract

The invention provides a composting method for efficient degradation of tetracycline antibiotics in livestock and poultry breeding excrement and belongs to the technical field of environment-friendly livestock breeding. Composting raw materials adopted in the method include, by weight, 30-50% of maize straw, 30-50% of wheat straw, 5-15% of peanut shell and 5-15% of sweet potato stem. According to the composting method, the raw materials are wide in source and low in cost, the composting period is relatively short, and the removal rate of the tetracycline antibiotics is very high.

Description

The compost method of tetracycline antibiotics in a kind of efficient degradation livestock and poultry cultivation ight soil
Technical field
The present invention relates to herding environment-protecting cultivation technical field, specifically, is the compost method about tetracycline antibiotics in a kind of efficient degradation livestock and poultry cultivation ight soil.
Background technology
Along with the fast development of the intensive livestock and poultry breeding industry of China and the continuous expansion of management mode, livestock breeding wastewater pollution problem is increasingly outstanding.The nitrogen contained in livestock breeding wastewater, phosphorus, microbiotic (as sulfamido, Macrolide and tetracyclines) are low with heavy metal (copper, arsenic, zinc, lead and nickel etc.) isoconcentration is but the high pollutent endangered, and constitutes huge potential threat to human health.The portion report of America NI H is pointed out, in livestock and poultry breeding industry, antibiotic application may be the major reason causing super resistant organism to occur and propagate.In view of antibiotic harm, European Union has completely forbidden and used microbiotic for the purpose of growth promoting effects in agricultural at the beginning of 2006, and U.S.'s restricted mechanism is in this respect also more and more stricter.China is antibiotic production and uses big country, and in livestock and poultry breeding industry, the phenomenon of Irrational usage of antibiotics is very general.In recent years, State General Administration for Quality Supervision, once to a large amount of sample detecting of the dairy products in northern market, finds that antibiotic remains exceeds standard and occupies defective item first.
At present, antibiotic removal mainly contains Ozonation, Fenton reagent method, free oxychlorination method etc., but above-mentioned three kinds of methods are generally applicable in livestock breeding wastewater, the general method adopting compost removed by microbiotic for feces of livestock and poultry, and the microbiotic how in low cost, short period of time, efficient degradation feces of livestock and poultry is our current main direction of studying.
Summary of the invention
The object of the present invention is to provide the compost method of tetracycline antibiotics in a kind of efficient degradation livestock and poultry cultivation ight soil, the clearance of this compost method to tetracyclines is high, and composting material source is wide, and cost is low, and the cycle is short.
For achieving the above object, the present invention by the following technical solutions: the compost method of tetracycline antibiotics in a kind of efficient degradation feces of livestock and poultry, is characterized in that, comprise the steps:
(1) prepare composting material: maize straw, wheat stalk, Pericarppium arachidis hypogaeae and sweet potato seedling mixed according to weight percent and pulverize, regulate the humidity of fertilizer, make water content reach 65-75%;
(2) FeSO is added by composting material 4, and mix, obtain compost fertilizer;
(3) compost fertilizer and feces of livestock and poultry are mixed according to the ratio of 1:1-2, load in fermentation unit, and carry out UV-irradiation;
(4) in composting process, every 24h once ventilates, and compost is about 20-30 days, terminates compost.
Further, in described composting material, the weight percent of each component is: maize straw 30-50%, wheat stalk 30-50%, Pericarppium arachidis hypogaeae 5-15%, sweet potato seedling 5-15%.
Further, described FeSO 4addition be 2-4 ‰.
Further, the compost temperature in described composting process is 40-50 DEG C.
Further, described compost method is 89.0-92.0% to the clearance of tsiklomitsin hydrochloric acid, is 85.0-89.0% to the clearance of tetramycin hydrochloride, is 79.0-84.0% to the clearance of Chlortetracycline HCl.
The invention has the beneficial effects as follows: 1. composting material source is wide, and cost is low; 2. composting cycle is relatively short; 3. very high clearance is have to the antibiosis of tetracyclines.
Embodiment
The following detailed description of specific embodiment of the invention; what be necessary to herein means out is; below implement just to further illustrate for of the present invention; the restriction to invention protection domain can not be interpreted as; some nonessential improvement and adjustment that this art skilled person makes the present invention according to the invention described above content, still belong to protection scope of the present invention.
Embodiment 1
In efficient degradation feces of livestock and poultry, a compost method for tetracycline antibiotics, comprises the steps:
(1) prepare composting material: take weight fraction be 30% maize straw, the wheat stalk of 40%, the Pericarppium arachidis hypogaeae of 15% and 15% sweet potato seedling mix and pulverize, adjustment fertilizer humidity, make water content reach 65%;
(2) FeSO of 2 ‰ will be added in composting material 4, and mix, obtain compost fertilizer;
(3) compost fertilizer and feces of livestock and poultry are mixed according to the ratio of 1:2, load in fermentation unit, and carry out UV-irradiation;
(4) in composting process, compost temperature remains on 40-50 DEG C, and every 24h once ventilates, compost about 25 days, terminates compost.
Wherein, this compost method is 89.2% to the clearance of tsiklomitsin hydrochloric acid, is 85.7% to the clearance of tetramycin hydrochloride, is 80.0% to the clearance of Chlortetracycline HCl.
Embodiment 2
In efficient degradation feces of livestock and poultry, a compost method for tetracycline antibiotics, comprises the steps:
(1) prepare composting material: take weight fraction be 45% maize straw, the wheat stalk of 45%, the Pericarppium arachidis hypogaeae of 5% and 5% sweet potato seedling mix and pulverize, adjustment fertilizer humidity, make water content reach 70%;
(2) FeSO of 3 ‰ will be added in composting material 4, and mix, obtain compost fertilizer;
(3) compost fertilizer and feces of livestock and poultry are mixed according to the ratio of 1:1.5, load in fermentation unit, and carry out UV-irradiation;
(4) in composting process, compost temperature remains on 40-50 DEG C, and every 24h once ventilates, compost about 27 days, terminates compost.
Wherein, this compost method is 91.3% to the clearance of tsiklomitsin hydrochloric acid, is 87.7% to the clearance of tetramycin hydrochloride, is 82.2% to the clearance of Chlortetracycline HCl.
Embodiment 3
In efficient degradation feces of livestock and poultry, a compost method for tetracycline antibiotics, comprises the steps:
(1) prepare composting material: take weight fraction be 40% maize straw, the wheat stalk of 35%, the Pericarppium arachidis hypogaeae of 15% and 10% sweet potato seedling mix and pulverize, adjustment fertilizer humidity, make water content reach 75%;
(2) FeSO of 4 ‰ will be added in composting material 4, and mix, obtain compost fertilizer;
(3) compost fertilizer and feces of livestock and poultry are mixed according to the ratio of 1:1, load in fermentation unit, and carry out UV-irradiation;
(4) in composting process, compost temperature remains on 40-50 DEG C, and every 24h once ventilates, compost about 30 days, terminates compost.
Wherein, this compost method is 91.9% to the clearance of tsiklomitsin hydrochloric acid, is 89.0% to the clearance of tetramycin hydrochloride, is 83.7% to the clearance of Chlortetracycline HCl.
Be not intended to limit the scope of the invention to the description of embodiment disclosed in the present invention, but for describing the present invention.Correspondingly, scope of the present invention not by the restriction of above embodiment, but is limited by claim or its equivalent.

Claims (5)

1. the compost method of tetracycline antibiotics in efficient degradation feces of livestock and poultry, is characterized in that, comprise the steps:
(1) prepare composting material: maize straw, wheat stalk, Pericarppium arachidis hypogaeae and sweet potato seedling mixed according to weight percent and pulverize, regulate the humidity of fertilizer, make water content reach 65-75%;
(2) FeSO is added by composting material 4, and mix, obtain compost fertilizer;
(3) compost fertilizer and feces of livestock and poultry are mixed according to the ratio of 1:1-2, load in fermentation unit, and carry out UV-irradiation;
(4) in composting process, every 24h once ventilates, and compost is about 25-30 days, terminates compost.
2. the compost method of tetracycline antibiotics in efficient degradation feces of livestock and poultry according to claim 1, it is characterized in that, in described composting material, the weight percent of each component is: maize straw 30-50%, wheat stalk 30-50%, Pericarppium arachidis hypogaeae 5-15%, sweet potato seedling 5-15%.
3. the compost method of tetracycline antibiotics in efficient degradation feces of livestock and poultry according to claim 1, is characterized in that, described FeSO 4addition be 2-4 ‰.
4. the compost method of tetracycline antibiotics in efficient degradation feces of livestock and poultry according to claim 1, it is characterized in that, the compost temperature in described composting process is 40-50 DEG C.
5. the compost method of tetracycline antibiotics in efficient degradation feces of livestock and poultry according to claim 1, it is characterized in that, described compost method is 89.0-92.0% to the clearance of tsiklomitsin hydrochloric acid, is 85.0-89.0% to the clearance of tetramycin hydrochloride, is 79.0-84.0% to the clearance of Chlortetracycline HCl.
CN201511004438.8A 2015-12-29 2015-12-29 Composting method for efficient degradation of tetracycline antibiotics in livestock and poultry breeding excrement Pending CN105503350A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107952783A (en) * 2017-11-27 2018-04-24 北京观澜科技有限公司 A kind of processing method and its application containing antibiotic substance
CN108911800A (en) * 2018-08-28 2018-11-30 倪晓燕 A kind of method for producing compost
CN108911801A (en) * 2018-08-28 2018-11-30 倪晓燕 A kind of anaerobic composting device of fast degradation feces of livestock and poultry tetracycline antibiotics

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101928163A (en) * 2009-06-19 2010-12-29 中国科学院生态环境研究中心 Controlled composting system for removing teracycline antibiotic residues from livestock manures
CN102757280A (en) * 2011-04-27 2012-10-31 北京师范大学 Composting method for rapid degrading veterinary antibiotic and organic fertilizer
CN104230417A (en) * 2014-08-21 2014-12-24 东北林业大学 Method for rapidly preparing organic fertilizer additive used in low-temperature areas by using cow dung and straw and applications of organic fertilizer additive
CN105170605A (en) * 2015-08-30 2015-12-23 常州思宇环保材料科技有限公司 Method for efficiently treating antibiotics in poultry excrement of breeding industry

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101928163A (en) * 2009-06-19 2010-12-29 中国科学院生态环境研究中心 Controlled composting system for removing teracycline antibiotic residues from livestock manures
CN102757280A (en) * 2011-04-27 2012-10-31 北京师范大学 Composting method for rapid degrading veterinary antibiotic and organic fertilizer
CN104230417A (en) * 2014-08-21 2014-12-24 东北林业大学 Method for rapidly preparing organic fertilizer additive used in low-temperature areas by using cow dung and straw and applications of organic fertilizer additive
CN105170605A (en) * 2015-08-30 2015-12-23 常州思宇环保材料科技有限公司 Method for efficiently treating antibiotics in poultry excrement of breeding industry

Non-Patent Citations (3)

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Title
冯福鑫等: "四环素高效降解酵母菌 Trichosporon mycotoxinivorans XPY-10 降解特性", 《环境工程学报》 *
张树清等: "高温堆肥对畜禽粪中抗生素降解和重金属钝化的作用", 《中国农业科学》 *
沈颖等: "猪粪中四环素类抗生素残留物的生物降解", 《过程工程学报》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107952783A (en) * 2017-11-27 2018-04-24 北京观澜科技有限公司 A kind of processing method and its application containing antibiotic substance
CN108911800A (en) * 2018-08-28 2018-11-30 倪晓燕 A kind of method for producing compost
CN108911801A (en) * 2018-08-28 2018-11-30 倪晓燕 A kind of anaerobic composting device of fast degradation feces of livestock and poultry tetracycline antibiotics

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