CN105494364A - Bactericide containing azoxystrobin and hymexazol - Google Patents

Bactericide containing azoxystrobin and hymexazol Download PDF

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Publication number
CN105494364A
CN105494364A CN201410561742.1A CN201410561742A CN105494364A CN 105494364 A CN105494364 A CN 105494364A CN 201410561742 A CN201410561742 A CN 201410561742A CN 105494364 A CN105494364 A CN 105494364A
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China
Prior art keywords
fluoxastrobin
bactericide
mould spirit
carrier
disliking
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Pending
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CN201410561742.1A
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Chinese (zh)
Inventor
李建民
刘忠想
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York Agrochemicals Co Ltd
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York Agrochemicals Co Ltd
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Priority to CN201410561742.1A priority Critical patent/CN105494364A/en
Publication of CN105494364A publication Critical patent/CN105494364A/en
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Abstract

A disclosed bactericide containing azoxystrobin and hymexazol contains effective ingredients, an auxiliary agent, a binder and a carrier, the effective ingredients are azoxystrobin and hymexazol, the mass ratio of the raw materials comprise 0.01%-5% of azoxystrobin, 0.1%-15% of hymexazol, 1%-15% of the auxiliary agent, 0.5%-10% of the binder, and the balance being the carrier. Urea, ammonium chloride, ammonium sulfate, potassium sulfate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate and calcium dihydrogenphoshate are employed as the carrier, and are capable of supplementing N, P, K, S, Ca and other nutrients necessary for crops, and the output is further improved when crop damping-off, die-back, root rot and other soil borne diseases are treated.

Description

A kind of containing Fluoxastrobin and the bactericide of disliking mould spirit
[technical field]
The present invention relates to a kind of bactericide, particularly a kind of containing Fluoxastrobin and the bactericide of disliking mould spirit.
[background technology]
The chemical name of Fluoxastrobin (Azoxystrobin) is: (E)-[2-[6-(2-cyano-benzene oxygen) pyrimidine-4-yl oxygen] phenyl]-3-methoxy-methyl acrylate; Molecular formula is: C 22h 17n 305it is a kind of bactericide of efficient, wide spectrum, all has good activity to nearly all mycota (Ascomycotina, Basidiomycotina, Mastigomycotina and Deuteromycotina) disease such as powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast etc.The formulation products of Fluoxastrobin is mainly used in control vegetables, diseases of garden stuff, but due to its drug cost high, use not extensive.
Dislike mould spirit (hymexazol), chemical name is 3-hydroxy-5-methyl base isoxazole, and molecular formula is C 4h 5nO 2be a kind of systemic fungicide and plant growth regulator, have significant control efficiency to soil fungi, sickle-like bacteria, root shell bacterium, rhizoctonia, pythium spp, the rotten pathogen such as bacterium, photovoltaicing leather bacteria of seedling, but it be undesirable in field result of use, the dosage needed is large, causes cost to raise.
[summary of the invention]
The object of this invention is to provide a kind of containing Fluoxastrobin and the bactericide of disliking mould spirit, reduce the use cost of this bactericide further.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is:
Containing Fluoxastrobin and a bactericide of disliking mould spirit, it is characterized in that: be made up of active ingredient, auxiliary agent, binding agent, carrier, wherein active ingredient is Fluoxastrobin and dislikes mould spirit.
The described bactericide containing Fluoxastrobin and the mould spirit of evil is made up of the component of following weight percents:
(1) Fluoxastrobin 0.01% ~ 5%
(2) mould clever 0.1% ~ 15% is disliked
(3) auxiliary agent 1% ~ 15%
(4) binding agent 0.5% ~ 10%
(5) carrier is used to complement to 100%.
Described auxiliary agent is one or more combinations in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, fatty alcohol-polyoxyethylene ether, dioctyl sodium sulfosuccinate.
Described binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol, carboxymethyl cellulose.
Described carrier is one or more combinations in White Carbon black, diatomite, active carbon, carclazyte, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulfate, sodium sulphate, calcium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate, talcum powder, river sand, cinder, flyash.
Described containing Fluoxastrobin and dislike mould spirit bactericide preparation method for by formula rate by Fluoxastrobin, dislike mould spirit, auxiliary agent, binding agent and carrier and mix; pulverize; stir after adding water-wet; use screw extruder pelletizer granulation again; sieve after drying, obtain of the present invention containing Fluoxastrobin and the bactericide of disliking mould spirit.
Carry out the control experiment of cucumber fusarium axysporum, according to product estimated cost, test process arranged as follows:
Process 1:5% Fluoxastrobin dislikes mould spirit (2: 3) bactericide 0.5kg/ mu.
Process 2:11% Fluoxastrobin dislikes mould spirit (1: 10) bactericide 0.8kg/ mu.
Process 3:7.5% Fluoxastrobin dislikes mould spirit (1.5: 6) bactericide 0.6kg/ mu.
Process 4:20% Fluoxastrobin dislikes mould spirit (5: 15) bactericide 0.2kg/ mu.
Process 5:5.1% Fluoxastrobin dislikes mould spirit (5: 0.1) bactericide 0.2kg/ mu.
Process 6:13% Fluoxastrobin dislikes mould spirit (3: 10) bactericide 0.4kg/ mu.
Process 7:15.01% Fluoxastrobin dislikes mould spirit (0.01: 15) bactericide 1.5kg/ mu.
Process 8:16% Fluoxastrobin dislikes mould spirit (1: 15) bactericide 0.7kg/ mu.
Process 9:0.25% Fluoxastrobin bactericide 5kg/ mu.
Process 10:10% dislikes mould bactericide 5kg/ mu.
Process 11: blank.
Above-mentioned process is used when cucumber is transplanted, wherein, process 1-process 8 is mixed into sandy soil 4.5kg, 4.2kg, 4.4kg, 4.8kg, 4.8kg, 4.6kg, 3.5kg, 4.3kg respectively and uses after stirring again, within after medicine 60 days, 90 days, carry out the investigation of cucumber fusarium axysporum situation of the harm respectively, carry out determination of yield during cucumber harvesting, final statistics is as shown in the table:
Visible, under the prerequisite that use cost is close, process 1-8 products obtained therefrom to the preventive effect of lawn fusarium wilt obviously than Fluoxastrobin, dislike mould spirit alone time preventive effect high, the lasting period is long, and can make sugarcane yield growth by more than 30%.
Fluoxastrobin is tested the Toxicity Determination of watermelon grafting with the mould spirit of evil and mixture thereof:
Test with Fluoxastrobin, dislike mould clever two kinds of single doses medicament in contrast, and according to No. 5, following proportions mixture No. 1-mixture:
No. 1, mixture: Fluoxastrobin: dislike mould spirit=1: 1500
No. 2, mixture: Fluoxastrobin: dislike mould spirit=1: 20
No. 3, mixture: Fluoxastrobin: dislike mould spirit=1: 1
No. 4, mixture: Fluoxastrobin: dislike mould spirit=4: 1
No. 5, mixture: Fluoxastrobin: dislike mould spirit=50: 1
Test, with watermelon blight, arranges blank, and by Fluoxastrobin, dislike mould spirit and above-mentioned 5 mixtures adopt dip method carry out Toxicological testing and do statistical analysis, final statistics is as shown in the table:
Process ATI TTI Co-toxicity coefficient
Fluoxastrobin 8839.7 - -
Dislike mould spirit 100 - -
No. 1, mixture 1392.5 310.7 128.3
No. 2, mixture 2178.2 516.2 422
No. 3, mixture 18215.2 4469.9 407.5
No. 4, mixture 16839.2 6742.5 257.1
No. 5, mixture 8450.6 9745.2 135.7
Toxicity Determination result shows, Fluoxastrobin and dislike mould spirit and be all greater than 120 according to above-mentioned 5 the different co-toxicity coefficients of ratio mixture to watermelon grafting, this Fluoxastrobin is described and dislikes mould clever mixture to have synergistic function.
The present invention has following beneficial effect:
(1) active ingredient of the present invention by Fluoxastrobin, dislike mould spirit and form, two kinds of component synergistic functions are obvious, and prevention effect is good, and the lasting period is long, reduce spraying times and formulation rate, reduction drug cost.
(2) the present invention can not only realize the generation of prevention and control disease effectively, and can significantly improve the prevention effect of crop to fusarium wilt and root rot, promotes that crop tuber is grown and plant strain growth simultaneously, improves the yield and quality of crop.
(3) using urea, ammonium chloride, ammonium sulfate, potassium sulfate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate as carrier, the nutrient components such as N, P, K, S, the Ca needed for crop can be supplied, improve output further.
[embodiment]
The following examples just for describing the present invention in detail, and limit the protection domain of invention never in any form.
(1) embodiment one
5% Fluoxastrobin dislikes mould bactericide
Formula: Fluoxastrobin 2kg, dislike mould clever 3kg, sodium lignin sulfonate 6kg, fatty alcohol-polyoxyethylene ether 4kg, sodium butylnaphthalenesulfonate 5kg, carboxymethyl cellulose 3kg, starch 5kg, potassium sulfate 15kg, calcium dihydrogen phosphate 10kg, carrier complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverizes, stir after adding water-wet, then use screw extruder pelletizer granulation, sieve after drying and obtain 5% Fluoxastrobin and dislike mould bactericide.
(2) embodiment two
11% Fluoxastrobin dislikes mould bactericide
Formula: Fluoxastrobin 1kg, dislike mould clever 10kg, calcium lignosulfonate 5kg, fatty alcohol-polyoxyethylene ether 3kg, polyvinyl alcohol 5kg, starch 5kg, kaolin 15kg, talcum powder 5kg, carrier complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverizes, stir after adding water-wet, then use screw extruder pelletizer granulation, sieve after drying and obtain 11% Fluoxastrobin and dislike mould bactericide.
(3) embodiment three
7.5% Fluoxastrobin dislikes mould bactericide
Formula: Fluoxastrobin 1.5kg, dislike mould clever 6kg, calcium lignosulfonate 3kg, fatty alcohol-polyoxyethylene ether 4kg, polyvinyl alcohol 2kg, starch 6kg, potassium sulfate 10kg, active carbon 10kg, carrier complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverizes, stir after adding water-wet, then use screw extruder pelletizer granulation, sieve after drying and obtain 7.5% Fluoxastrobin and dislike mould bactericide.
(4) embodiment four
20% Fluoxastrobin dislikes mould bactericide
Formula: Fluoxastrobin 5kg, dislike mould clever 15kg, calcium lignosulfonate 4kg, fatty alcohol-polyoxyethylene ether 5kg, polyvinyl alcohol 6kg, sucrose 3kg, kaolin 15kg, calcium carbonate 8kg, carrier complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverizes, stir after adding water-wet, then use screw extruder pelletizer granulation, sieve after drying and obtain 20% Fluoxastrobin and dislike mould bactericide.
(5) embodiment five
5.1% Fluoxastrobin dislikes mould bactericide
Formula: Fluoxastrobin 5kg, dislike mould clever 0.1kg, calcium lignosulfonate 3kg, sodium butylnaphthalenesulfonate 4kg, carboxymethyl cellulose 3kg, sucrose 6kg, kaolin 10kg, urea 15kg, carrier complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverizes, stir after adding water-wet, then use screw extruder pelletizer granulation, sieve after drying and obtain 5.1% Fluoxastrobin and dislike mould bactericide.
(6) embodiment six
13% Fluoxastrobin dislikes mould bactericide
Formula: Fluoxastrobin 3kg, dislike mould clever 10kg, calcium lignosulfonate 5kg, fatty alcohol-polyoxyethylene ether 3kg, polyvinyl alcohol 3kg, sucrose 5kg, kaolin 10kg, potassium dihydrogen phosphate 15kg, carrier complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverizes, stir after adding water-wet, then use screw extruder pelletizer granulation, sieve after drying and obtain 13% Fluoxastrobin and dislike mould bactericide.
(7) embodiment seven
15.01% Fluoxastrobin dislikes mould bactericide
Formula: Fluoxastrobin 0.01kg, dislike mould clever 15kg, chitin 10kg, calcium lignosulfonate 5kg, sodium butylnaphthalenesulfonate 5kg, polyvinyl alcohol 6kg, starch 4kg, bentonite 10kg, calcium carbonate 10kg, carrier complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverizes, stir after adding water-wet, then use screw extruder pelletizer granulation, sieve after drying and obtain 15.01% Fluoxastrobin and dislike mould bactericide.
(8) embodiment eight
16% Fluoxastrobin dislikes mould bactericide
Formula: Fluoxastrobin 1kg, dislike mould clever 15kg, sodium butylnaphthalenesulfonate 5kg, dioctyl sodium sulfosuccinate 2kg, carboxymethyl cellulose 3kg, sucrose 6kg, kaolin 15kg, sodium sulphate 5kg, carrier complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverizes, stir after adding water-wet, then use screw extruder pelletizer granulation, sieve after drying and obtain 16% Fluoxastrobin and dislike mould bactericide.

Claims (6)

1. containing Fluoxastrobin and a bactericide of disliking mould spirit, it is characterized in that: be made up of active ingredient, auxiliary agent, binding agent, carrier, wherein active ingredient is Fluoxastrobin and dislikes mould spirit.
2. according to claim 1 a kind of containing Fluoxastrobin and the bactericide of disliking mould spirit, it is characterized in that: the described Fluoxastrobin that contains is made up of the component of following weight percents with the bactericide of disliking mould spirit:
(1) Fluoxastrobin 0.01% ~ 5%
(2) mould clever 0.1% ~ 15% is disliked
(3) auxiliary agent 1% ~ 15%
(4) binding agent 0.5% ~ 10%
(5) carrier is used to complement to 100%.
3. according to claim 1 a kind of containing Fluoxastrobin and the bactericide of disliking mould spirit, it is characterized in that: described auxiliary agent is one or more combinations in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, fatty alcohol-polyoxyethylene ether, dioctyl sodium sulfosuccinate.
4. according to claim 1 a kind of containing Fluoxastrobin and the bactericide of disliking mould spirit, it is characterized in that: described binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol, carboxymethyl cellulose.
5. according to claim 1 a kind of containing Fluoxastrobin and the bactericide of disliking mould spirit, it is characterized in that: described carrier is one or more combinations in White Carbon black, diatomite, active carbon, carclazyte, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulfate, sodium sulphate, calcium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate, talcum powder, river sand, cinder, flyash.
6. according to claim 1 a kind of containing Fluoxastrobin and the bactericide of disliking mould spirit; it is characterized in that: described containing Fluoxastrobin and dislike mould spirit bactericide preparation method for by formula rate by Fluoxastrobin, dislike mould spirit, auxiliary agent, binding agent and carrier and mix; pulverize; stir after adding water-wet; use screw extruder pelletizer granulation again; sieve after drying, obtain of the present invention containing Fluoxastrobin and the bactericide of disliking mould spirit.
CN201410561742.1A 2014-10-15 2014-10-15 Bactericide containing azoxystrobin and hymexazol Pending CN105494364A (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106857564A (en) * 2017-02-16 2017-06-20 广东中迅农科股份有限公司 The method for controlling plant root disease
CN108283183A (en) * 2018-01-31 2018-07-17 广西壮族自治区药用植物园 Improve seed coat agent of malania oleifera percentage of seedgermination and preparation method thereof and application method
CN109874806A (en) * 2019-03-19 2019-06-14 陈爱昌 A kind of inorganic agent and its method of administration for preventing and treating celery root rot
CN115868396A (en) * 2022-12-16 2023-03-31 广西南亚热带农业科学研究所 Ecological seedling raising substrate for macadamia nuts
CN115868396B (en) * 2022-12-16 2024-05-24 广西南亚热带农业科学研究所 Ecological seedling raising substrate for macadimia nuts

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1378782A (en) * 2002-01-08 2002-11-13 贵州大学 Agricultural bactericide series prepared from raw powder of hymexazol as main raw material
CN103120166A (en) * 2011-11-18 2013-05-29 深圳诺普信农化股份有限公司 Hymexazol-containing sterilizing composition
CN103265371A (en) * 2013-05-30 2013-08-28 南宁市德丰富化工有限责任公司 Bactericide fertilizer containing hymexazol and propamocarb and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1378782A (en) * 2002-01-08 2002-11-13 贵州大学 Agricultural bactericide series prepared from raw powder of hymexazol as main raw material
CN103120166A (en) * 2011-11-18 2013-05-29 深圳诺普信农化股份有限公司 Hymexazol-containing sterilizing composition
CN103265371A (en) * 2013-05-30 2013-08-28 南宁市德丰富化工有限责任公司 Bactericide fertilizer containing hymexazol and propamocarb and application thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106857564A (en) * 2017-02-16 2017-06-20 广东中迅农科股份有限公司 The method for controlling plant root disease
CN108283183A (en) * 2018-01-31 2018-07-17 广西壮族自治区药用植物园 Improve seed coat agent of malania oleifera percentage of seedgermination and preparation method thereof and application method
CN109874806A (en) * 2019-03-19 2019-06-14 陈爱昌 A kind of inorganic agent and its method of administration for preventing and treating celery root rot
CN115868396A (en) * 2022-12-16 2023-03-31 广西南亚热带农业科学研究所 Ecological seedling raising substrate for macadamia nuts
CN115868396B (en) * 2022-12-16 2024-05-24 广西南亚热带农业科学研究所 Ecological seedling raising substrate for macadimia nuts

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Application publication date: 20160420

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