CN1378782A - Agricultural bactericide series prepared from raw powder of hymexazol as main raw material - Google Patents
Agricultural bactericide series prepared from raw powder of hymexazol as main raw material Download PDFInfo
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- CN1378782A CN1378782A CN 02101905 CN02101905A CN1378782A CN 1378782 A CN1378782 A CN 1378782A CN 02101905 CN02101905 CN 02101905 CN 02101905 A CN02101905 A CN 02101905A CN 1378782 A CN1378782 A CN 1378782A
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Abstract
An agricultural bactericide series is prepared from hymexazol [chemical name: (3-hydroxy-5-methyl isoxazole, see structural formula(I)], metalaxyl (DL-N-(2,6-dimethyl benzene)-N-(2-methoxyacetyl) amino methyl propionate, see structural formula (II), organic acid and assistant through proportional mixing. Its advantages are low poison, broad spectrum and high effect to several diseases such as rice blast, damping-off frosty mildew, etc..
Description
<one〉technical field
The present invention is that the hymexazol powder that utilizes this school new technology (number of patent application 99115140.2) to produce is the mould clever concentration height of evil of primary raw material preparation, and sterilizing ability is disliked the strong and one group of wider disinfectant use in agriculture of bactericidal range of mould spirit than using separately.
<two〉background technology
One group of disinfectant use in agriculture of the present invention's preparation, we are referred to as 5% organic acid and dislike mould first frost aqua (former %5 Hymexazol-matulaxyl aqua alleged in first to file 99115140.2), be that we screen the prescription that draws through chemical agent screening and field experiment, at home and abroad do not appear in the newspapers.
The object of the present invention is to provide a kind of efficient, low toxicity and than disliking the more bactericide of wide spectrum of mould spirit.Rice blast is had special efficacy, and to sickle-like bacteria, the control of various crop damping off, damping off, banded sclerotial blight and downy mildew that silk capsule Pseudomonas, corticium cause has special efficacy.
<three〉summary of the invention
The mould spirit of the evil (chemical name: 3-hydroxyl 5-methyl-isoxazole, molecular formula C that former ethyl acetoacetate water method is produced
4H
2NO
2, structural formula
) concentration is lower than 3%, can not dislike mould clever concentration greater than 3% mixture in order to preparation, this school invention hydroxylamine hydrochloride, sodium methoxide, methyl acetoacetates etc. go out (the application for a patent for invention number: 99115140.2) of high-load hymexazol powder for main material production, dislike mould clever content greater than 86%, the present invention is exactly to be primary raw material with the hymexazol powder that adopts this patent production technology to produce, dislikes mould first frost aqua with one group of 5% organic acid that metalaxyl, organic matter and water processing are formulated.5% organic acid is disliked mould first frost aqua has special efficacy to the control rice blast, it also is a kind of low toxicity, the bactericide that interior absorption is strong, controls such as the various crop damping off that sickle-like bacteria, basidiomycetes, silk capsule Pseudomonas, corticium are caused, damping off, rice blast, banded sclerotial blight, downy mildew have special efficacy, thereby be a kind of ratio original we research and produce 3% dislike the sterilizing ability that mould Lingshui Spring agent has more efficient more wide spectrum, the prescription that 5% organic acid is disliked mould first frost aqua is our prescription that screening draws of at first filling a prescription again on the basis of carrying out the chemical agent screening test.
Bactericide of the present invention is formulated through processing by hymexazol powder, metalaxyl, organic acid and auxiliary agent, and each constituent content scope is as follows: hymexazol powder 2.5%~30% (weight) metalaxyl 0.5%~30% (weight) organic acid % 0%~30% (weight) auxiliary agent 10%~97% (weight)
The used raw material of the present invention all is the mature industry product, and the market is on sale, following 1, the hymexazol powder of its specification, and purity: 90%, 2, metalaxyl, purity 97%,
Metalaxyl chemical name: DL-N-(2, the 6-dimethyl benzene)-N-(2-methoxy acetyl group) alanine methyl esters molecular formula: C
15H
21NO
4Structural formula:
3, organic acid, purity 97% comprises: R
1COOH, R
2-CH=CH-COOH,
R
1, R
2Be hydrogen base or all kinds of alkyl C
nH
2n+1(n=1-20), R
3, R
4Be included in the F in position, ortho position or the contraposition between phenyl ring, Cl, Br, I, CN, NO
2With all kinds of alkyl C
nH
2n+1(n=1-20).4, auxiliary agent: water, methyl alcohol, ethanol, dimethyl formamide or methyl-sulfoxide.The bacteriocide formula that is mixed with has: prescription one, 3% is disliked mould first frost aqua (former %3 Hymexazol-matulaxyl aqua alleged in first to file 99115140.2)
Metalaxyl (purity 97%) 0.5% (weight)
Hymexazol powder (purity 90%) 2.5% (weight)
Auxiliary agent 97% (weight)
Be metalaxyl (purity 97%)+hymexazol powder (purity 90%)=0.5%+2.5%
Compound method: 1. get former powder 0.50 gram of (97%) metalaxyl and be dissolved in the alcohol of 2.9 grams 95%; 2. getting 90% hymexazol powder, 2.50 grams is dissolved in the 94.1 gram water; 3. the solution with above two kinds of former powder mixes, and stirs and promptly gets the mould first frost of 3% evil aqua.Prescription two, 5% organic acid is disliked mould first frost aqua (No. 2, former %3 Hymexazol-matulaxyl aqua alleged in first to file 99115140.2)
Above-mentioned 3% dislikes mould first frost aqua 98% (weight)
1% organic acid (above-mentioned each organic acid), 1% (weight)
1% hymexazol powder (purity 90%), 1% (weight)
Compound method: get purity and be 90% hymexazol powder 1 gram, above-mentioned organic acid 1 gram joins 98 gram prescriptions one described 3% and dislikes in the mould first frost aqua, and stirring gets final product.Prescription three, 5% organic acid is disliked mould first frost aqua (No. 3, former %3 Hymexazol-matulaxyl aqua alleged in first to file bright 115140.2)
Hymexazol powder (purity 90%) 3% (weight)
Organic acid 2% (weight)
Water 95% (weight)
Compound method: get 90% hymexazol powder, 3 grams, above-mentioned organic acid 2 grams join in the 95 gram water, and stirring gets final product.Prescription four, 5% organic acid is disliked mould first frost aqua (No. 4, former %3 Hymexazol-matulaxyl aqua alleged in first to file 99115140.2)
3% dislikes mould first frost aqua (prescription one) 98% (weight)
Organic acid (above-mentioned each organic acid) 2% (weight)
Compound method: get above-mentioned each organic acid 2 gram and be dissolved in the mould first frost of 98 gram prescriptions, the one described 3% evil aqua, stirring gets final product.The disinfectant use in agriculture that the above formulated of several employings becomes suppresses effect to the Pyricularia oryzae mycelia and sees Table 1.
Several medicaments of table 1 suppress effect to the Pyricularia oryzae mycelia
Prescription | Medicament kind | Concentration of treatment C (ppm) | Average colony diameter (mm) | Relative fungistatic effect (%) |
Prescription two | 5% acrylic acid is disliked mould first frost No. 2 | ????50 | ????38 | ????50 |
????100 | ????28 | ????65.2 | ||
????400 | ????5 | ????100 | ||
Prescription three | 5% acrylic acid is disliked mould first frost No. 3 | ????50 | ????56 | ????22.7 |
????100 | ????46.3 | ????37.4 | ||
????400 | ????5 | ????100 | ||
Prescription four | 5% acrylic acid is disliked mould first frost No. 4 | ????50 | ????46 | ????37.9 |
????100 | ????26.7 | ????67.1 | ||
????400 | ????5 | ????100 | ||
Prescription one | ????5 | ????23 | ????72.7 | |
????50 | ????6.7 | ????97.4 | ||
????400 | ????5 | ????100 | ||
Contrast | 25% tricyclazole | ????400 | ????12 | ????84.4 |
CK | ???????????????????????????????71 |
Average colony diameter contains 5mm rice temperature bacterium bacterium piece.The inhibition effect that several agricultural Hymexazol-matulaxyl bactericide are sprouted magnaporthe grisea spore sees Table 2
The inhibition effect that several medicaments of table 2 are sprouted magnaporthe grisea spore
Prescription | Medicament kind | Concentration of treatment C (ppm) | Check spore sum (individual) | Spore germination number (individual) | Spore germination rate (%) | Spore germination inhibiting rate (%) |
Prescription two | 5% acrylic acid is disliked mould first frost aqua | ????50 | ????117 | ????110 | ????94 | ????6.0 |
????100 | ????258 | ????8 | ????3.1 | ????96.9 | ||
????400 | ????125 | ????2 | ????1.6 | ????98.4 | ||
Prescription three | 5% acrylic acid is disliked mould first frost aqua No. 3 | ????50 | ????158 | ????158 | ????100 | ????0.0 |
????100 | ????139 | ????111 | ????79.9 | ????20.1 | ||
????400 | ????121 | ????2 | ????1.7 | ????98.3 | ||
Prescription four | 5% acrylic acid is disliked mould first frost aqua No. 4 | ????50 | ????127 | ????103 | ????81.1 | ????18.9 |
????100 | ????163 | ????4 | ????2.5 | ????97.5 | ||
????400 | ????114 | ????2 | ????1.8 | ????98.2 | ||
Prescription one | 3% dislikes mould first frost aqua | ????50 | ????105 | ????92 | ????87.6 | ????12.4 |
????100 | ????145 | ????6 | ????4.1 | ????95.6 | ||
????400 | ????106 | ????2 | ????1.9 | ????98.1 | ||
Contrast | 20% tricyclazole | ????400 | ????115 | ????1 | ????0.87 | ????99.1 |
CK | ????299 | ????299 | ????100 |
From The above results fill a prescription one as can be seen, prescription four aquas are better to the inhibition effect of the inhibition of Pyricularia oryzae mycelia and spore germination, further carry out the ED of medicament below
50Measure, record result such as table 3 and table 4
Each medicament of table 3 is to the inhibitory action of rice blast spore germination
The medicament title | Concentration of treatment (ppm) | Spore germination rate (%) | Suppress bright rate of plane (%) | The probability value |
Acrylic acid | ????5.0 ????12.5 ????25.0 ????50.0 ????62.5 | ????97.8 ????69.3 ????32.2 ????14.8 ????1.0 | ????2.2 ????30.7 ????67.8 ????85.2 ????99.0 | ????2.95 ????4.67 ????5.47 ????6.04 ????7.33 |
Metalaxyl | ????100.0 ????200.0 ????400.0 ????800.0 ????1600.0 ????2000.0 | ????99.2 ????93.6 ????85.4 ????80.3 ????2.3 ????0.0 | ????0.8 ????6.4 ????14.6 ????19.7 ????97.7 ????100.0 | ????2.67 ????3.45 ????3.96 ????4.16 ????7.75 ????8.09 |
3% dislikes mould first frost aqua (prescription one) | ????30.0 ????33.6 ????51.7 ????62.5 ????75.0 ????100.0 ????150.0 | ????99.3 ????97.0 ????90.2 ????50.0 ????11.9 ????1.4 ????0.6 | ????0.7 ????3.0 ????9.8 ????50.0 ????88.1 ????98.6 ????99.4 | ????2.67 ????3.10 ????3.72 ????5.00 ????6.18 ????7.33 ????7.51 |
5% acrylic acid is disliked mould No. 2, first frost aqua (prescription two) | ????25.0 ????36.5 ????51.7 ????100.0 ????150.0 | ????100.0 ????99.0 ????98.0 ????36.4 ????12.9 | ????0.0 ????1.0 ????2.0 ????63.6 ????87.1 | ????0.00 ????2.67 ????2.95 ????5.36 ????6.13 |
5% acrylic acid is disliked mould first frost aqua (prescription four) | ????25.0 ????36.6 ????44.1 ????62.5 ????75.0 ????150.0 | ????99.3 ????91.4 ????58.0 ????25.9 ????3.03 ????0.0 | ????0.7 ????8.6 ????42.0 ????74.1 ????97.0 ????100.0 | ????2.67 ????3.66 ????4.80 ????5.64 ????6.88 ????8.09 |
20% tricyclazole | ????12.5 ????25.0 ????50.0 ????100.0 ????200.0 ????400.0 | ????95.3 ????83.0 ????63.6 ????45.6 ????5.9 ????0.0 | ????4.7 ????17.0 ????36.4 ????54.4 ????94.1 ????100.0 | ????3.36 ????4.05 ????4.63 ????5.10 ????6.55 ????8.09 |
Several medicaments of table 4 are to the virulence of magnaporthe grisea spore
The medicament title | Virulence regression equation | ????ED 50(ppm) | Correlation coefficient |
Metalaxyl | ??Y=10.0632+5.351X | ????659.68 | ????0.9528 |
Acrylic acid | ??Y=0.5881+3.5156X | ????17.99 | ????0.9752 |
20% tricyclazole | ??Y=0.2745+3.0114X | ????56.43 | ????0.9706 |
3% dislikes mould first frost aqua (prescription one) | ??Y=8.7670+7.7122X | ????60.97 | ????0.9538 |
5% acrylic acid is disliked mould first frost aqua (prescription two) | ??Y=9.7064+7.4172X | ????96.10 | ????0.9726 |
5% acrylic acid is disliked mould first frost aqua (prescription four) | ??Y=10.1580+9.0164X | ????47.99 | ????0.9908 |
3% dislike mould first frost aqua (prescription one) as seen from Table 3,5% acrylic acid is disliked mould first frost aqua (prescription four) and in the 6-150ppm concentration range magnaporthe grisea spore is sprouted the inhibitory action that all has in various degree, spore germination suppresses to increase with the increase of concentration, wherein dislikes mould first frost aqua No. 4 (prescriptions four) with 5% acrylic acid and suppresses best results.As can be seen from Table 4: each medicament is to the virulence of Pyricularia oryzae plane order: acrylic acid (DE
50=17.99)>5% acrylic acid is disliked mould first frost aqua (prescription four) (ED
50=47.99) tricyclazole wettable powder (ED>20%
50=56.43)>3% dislike mould first frost aqua (prescription one) (ED
50=60.97)>5% acrylic acid is disliked mould first frost aqua (prescription two).(ED
50=96.10)>metalaxyl (ED
50=659.68).It is best to the virulence of rice blast spore to dislike mould first frost aqua (prescription four) with 5% acrylic acid in three kinds of prescriptions.
5% acrylic acid dislike mould first frost aqua (prescription four) to the comparison of leaf blast in rice control efficiency and 5% acrylic acid dislike mould first frost aqua (prescription four) to the leaf blast control efficiency relatively (the 21 day result) see Table 5 and table 6
Table 5 5% Hymexazol-matulaxyl aqua (prescription four) to the leaf blast in rice control efficiency relatively
Medicament and consumption | Repeat | Disease refers to (%) before the medicine | Behind the medicine | ||||
14 days | 21 days | ||||||
Disease refers to (%) | Preventive effect (%) | Disease refers to (%) | Preventive effect (%) | ||||
5% Hymexazol-matulaxyl aqua (prescription four) * ml/ mu | ??30 | ????1 | ????3.5 | ????1.94 | ????63.32 | ????2.16 | ????71.24 |
????2 | ????3.7 | ????2.08 | ????60.20 | ????2.20 | ????69.69 | ||
????3 | ????1.2 | ????2.44 | ????58.64 | ????2.66 | ????71.09 | ||
????4 | ????4.1 | ????2.25 | ????63.96 | ????2.88 | ????66.76 | ||
??? X | ????3.9 | ????61.53 | ????68.93 | ||||
??80 | ????1 | ????4.2 | ????1.82 | ????72.00 | ????2.30 | ????74.46 | |
????2 | ????3.9 | ????1.75 | ????67.43 | ????1.66 | ????75.35 | ||
????3 | ????4.1 | ????1.77 | ????70.75 | ????1.61 | ????80.37 | ||
????4 | ????3.7 | ????1.96 | ????65.14 | ????1.59 | ????79.67 | ||
??? X | ????4.0 | ????68.75 | ????77.59 | ||||
??10 ??0 | ????1 | ????4.1 | ????1.28 | ????79.35 | ????1.16 | ????86.78 | |
????2 | ????4.2 | ????1.29 | ????77.71 | ????1.14 | ????86.12 | ||
????3 | ????3.9 | ????1.02 | ????81.38 | ????4.12 | ????85.64 | ||
????4 | ????4.2 | ????1.43 | ????77.64 | ????1.13 | ????87.27 | ||
??? X | ????4.1 | ????79.25 | ????86.25 | ||||
Tricyclazole 100 gram/mus | ????1 | ????3.7 | ????2.5 | ????55.30 | ????2.76 | ????65.14 | |
????2 | ????3.6 | ????2.12 | ????57.26 | ????2.30 | ????67.33 | ||
????3 | ????4.0 | ????2.34 | ????58.36 | ????2.70 | ????66.25 | ||
????4 | ????3.6 | ????2.58 | ????56.28 | ????2.85 | ????64.52 | ||
??? X | ????3.8 | ????56.75 | ????65.72 | ||||
Metalaxyl 10 gram/mus | ????1 | ????3.9 | ????3.94 | ????33.14 | ????4.91 | ????41.16 | |
????2 | ????4.2 | ????3.98 | ????31.22 | ????5.22 | ????36.44 | ||
????3 | ????4.1 | ????3.95 | ????33.05 | ????5.04 | ????38.54 | ||
????4 | ????4.2 | ????4.38 | ????31.51 | ????5.87 | ????33.88 | ||
??? X | ????4.2 | ????32.50 | ????37.50 | ||||
Organic acid 10 gram/mus | ????1 | ????4.5 | ????2.44 | ????64.13 | ????2.95 | ????68.88 | |
????2 | ????4.3 | ????2.43 | ????58.98 | ????3.18 | ????62.18 | ||
????3 | ????4.8 | ????2.18 | ????63.05 | ????3.45 | ????59.88 | ||
????4 | ????4.4 | ????2.55 | ????61.99 | ????3.18 | ????62.12 | ||
??? X | ????4.4 | ????62.03 | ????63.39 | ||||
Dislike mould clever 10 gram/mus | ????1 | ????3.9 | ????2.55 | ????56.75 | ????3.11 | ????62.73 | |
????2 | ????4.5 | ????2.69 | ????55.82 | ????2.75 | ????68.75 | ||
????3 | ????4.3 | ????2.80 | ????53.65 | ????3.16 | ????63.25 | ||
????4 | ????4.2 | ????2.89 | ????54.81 | ????2.97 | ????66.54 | ||
??? X | ????4.2 | ????55.26 | ????65.32 | ||||
Clear water (CK) | ????1 | ????4.3 | ????6.5 | ????9.2 | |||
????2 | ????4.5 | ????6.2 | ????8.8 | ||||
????3 | ????4.2 | ????5.9 | ????8.4 | ||||
????4 | ????4.4 | ????6.7 | ????9.3 | ||||
??? X | ????4.4 | ????6.8 | ????8.9 |
Table 6 5% Hymexazol-matulaxyl aqua (prescription four) compares (the 21 day result) to the leaf blast control efficiency
Medicament | District's group preventive effect arcsine value | ???Tr | ??X | New antinucleus difference test | Inverse transform % | ||||||
??I | ??II | ???III | ???IV | Handle | The significance of difference | ||||||
??5% | ?X | ||||||||||
5% Hymexazol-matulaxyl aqua (prescription four) ml/ mu | 30 | ??57.54 | ??56.54 | ???67.45 | ???54.32 | ???225.58 | ??56.47 | ???65.41 | ??a | ?A | ??86.50 |
80 | ??59.67 | ??60.27 | ???63.72 | ???63.22 | ???246.88 | ??61.72 | ???61.72 | ??b | ?B | ??77.60 | |
100 | ??65.70 | ??68.11 | ???67.70 | ???69.12 | ???273.63 | ??68.4 | ???56.47 | ??c | ?C | ??69.00 | |
25 triazoles, 00 gram/mu | ??63.79 | ??55.12 | ???54.51 | ???51.43 | ???216.85 | ??54.19 | ???54.19 | ??cd | ?CD | ??65.80 | |
Metalaxyl 10 gram/mus | ??39.93 | ??37.11 | ???38.35 | ???35.61 | ???151.00 | ??37.75 | ???53.94 | ??cd | ?CD | ??65.40 | |
Acrylic acid 10 gram/mus | ??56.42 | ??52.12 | ???50.71 | ???52.00 | ???211.25 | ??52.81 | ???52.81 | ??d | ?D | ??63.50 | |
Dislike mould clever 10 gram/mus | ??52.36 | ??56.04 | ???52.71 | ???54.63 | ???215.74 | ??53.94 | ???37.75 | ??e | ?E | ??37.50 | |
?∑ | ??388.41 | ??385.31 | ???385.18 | ???382.33 | ???T ??1541.33 | ??SE=0.8913 |
According to table 5 and table 6 as can be known:
1, to dislike mould first frost aqua (prescription four) be the effective agent of control rice blast to 5% acrylic acid, 20% tricyclazole wettable powder that is better than participating in the experiment and single agent metalaxyl, acrylic acid, the mould spirit of evil.
2, in the Shui Dao Fen Tiller phase, spray 1-2 time 5% acrylic acid and dislike mould first frost aqua (prescription four), can effectively control the harm of leaf blast.
3, the control rice blast is advisable with every mu of 80-100ml/ mu (50 kilograms of spouting liquids), and control can reach 77.60%-86.50%.Effect is remarkable.
4, spray 5% acrylic acid and dislike mould first frost aqua, to rice growth, ecotope, beneficial organism all has no adverse effects.
This method except that the preparation aqua, but also be suitable for being processed into different formulations than wet-milling, can ooze powder or pulvis emulsion, colloidal suspending agent etc.
<four〉embodiment 1,3% is disliked mould first frost aqua (prescription one)
Adding purity and be 97% former powder 0.5 gram of metalaxyl in a 200ml beaker is dissolved in the alcohol of 2.9 grams 95%; Take by weighing purity then and be 90% hymexazol powder 2.50 grams, be dissolved in the 94.1 gram water; The solution of above two kinds of former powder is mixed, and water-bath control temperature stirs in 50 ℃, promptly get 3% and dislikes the white aqua of mould first.2,5% acrylic acid is disliked mould first frost aqua (prescription two)
In a 200ml beaker, add 98 grams above-mentioned 3% and dislike mould first frost aquas (prescription 1), take by weighing purity then and be 90% hymexazol powder 1 gram, acrylic acid 1 gram.Water-bath control temperature stirs in 50 ℃, 5% acrylic acid be disliked mould first frost No. 2, aqua (promptly filling a prescription two).3,5% acrylic acid is disliked mould first frost aqua No. 3 (prescription three))
In a 200ml beaker, add 95 gram water, take by weighing purity then and be 90% hymexazol powder 3 grams, acrylic acid 2 grams.Water-bath control temperature stirs to such an extent that 5% acrylic acid is disliked mould first frost aqua (promptly filling a prescription three) in 50 ℃.4,5% acrylic acid is disliked mould first frost aqua (prescription four))
In a 200ml beaker, add 98.00 grams above-mentioned 3% and dislike mould first frost aqua (prescription 1), add acrylic acid 2 grams then.Water-bath control temperature stirs in 50 ℃, 5% acrylic acid be disliked mould first frost aqua (promptly filling a prescription four).
Experimental results show that acrylic acid dislikes several prescriptions of mould first cream composition rice blast is all had the obvious suppression effect, it is best wherein to dislike mould first frost aqua (prescription four) effect with 5% acrylic acid.The quality of 5%-60% Hymexazol-matulaxyl aqua product is as follows, and wherein disliking mould clever content is 2.5-30%, and metalaxyl content is 0.5-30%, and organic acid content is 0-30%, and auxiliary agent 10~97% specifically sees the following form:
The project concentration range
Hymexazol powder 2.5%~30% (weight)
Metalaxyl 0.5%~30% (weight)
Organic acid % 0%~30% (weight)
Auxiliary agent 10%~97% (weight)
This method except that the preparation aqua, but also be suitable for being processed into wet-milling, soluble powder or pulvis, emulsion, the colloidal suspending agent of different proportionings.
Claims (13)
1, a kind of is the disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, and formulated through processing by hymexazol powder, metalaxyl, organic acid and auxiliary agent, each constituent content scope is as follows:
Hymexazol powder (3-hydroxy-5-methyl-isoxazole, content 2.5%~30% (weight); Metalaxyl (DL-N-(2, the 6-dimethyl benzene)-N-(2-methoxy acetyl group) alanine methyl esters, structural formula:
), content 0.5%~30% (weight); Organic acid is: R
1COOH, R
2-CH=CH-COOH,
Or
R, R
2Be hydrogen base or all kinds of alkyl C
nH
2n+1(n=1-20), R, R
1Be the Cl in position, ortho position or contraposition between phenyl ring, Br, I, NO
2With all kinds of alkyl C
nH
2n+1(n=1-20), content 0%~30% (weight); Auxiliary agent is water, methyl alcohol, ethanol or dimethyl formamide, content 10%~97% (weight).
2, according to claim 1 is the disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that each constituent content prescription of this disinfectant use in agriculture is:
Metalaxyl (purity 97%) 0.5% (weight)
Hymexazol powder (purity 90%) 2.5% (weight)
Auxiliary agent 97% (weight).
3, according to claim 1 is the disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that each constituent content prescription of this disinfectant use in agriculture is:
Above-mentioned 3% dislikes mould first frost aqua 98% (weight)
1% organic acid (above-mentioned each organic acid), 1% (weight)
1% hymexazol powder (purity 90%), 1% (weight).
4, according to claim 1 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that each constituent content prescription of this disinfectant use in agriculture is:
Hymexazol powder (purity 90%) 3% (weight)
Organic acid 2% (weight)
Water 95% (weight).
5, according to claim 1 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that each constituent content prescription of this disinfectant use in agriculture is:
3% dislikes mould first frost aqua (prescription one) 98% (weight)
Organic acid (above-mentioned each organic acid) 2% (weight).
6, described according to claim 3-5 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that the organic acid in this disinfectant use in agriculture is R
1COOH, R
2-CH=CH-COOH, R
1, R
2Be hydrogen base or all kinds of alkyl C
nH
2n+1(n=1-20).
7, according to claim 6 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that the organic acid in this disinfectant use in agriculture is R
2-CH=CH-COOH, R
2Be hydrogen base or all kinds of alkyl C
nH
2n+1(n=1-20).
8, according to claim 7 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that the organic acid in this disinfectant use in agriculture is an acrylic acid.
9, according to claim 1 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that the auxiliary agent in this disinfectant use in agriculture is a water.
10, according to claim 1 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that the auxiliary agent in this disinfectant use in agriculture is methyl alcohol, ethanol or dimethyl formamide.
11, according to claim 1 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that the auxiliary agent in this disinfectant use in agriculture is methyl alcohol or ethanol.
12, according to claim 1 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that the auxiliary agent in this disinfectant use in agriculture is a dimethyl formamide.
13, according to claim 1 is one group of disinfectant use in agriculture of primary raw material preparation with the hymexazol powder, it is characterized in that this disinfectant use in agriculture both had been suitable for aqua, but also is suitable for being processed into the wet-milling of different proportion, soluble powder or pulvis, emulsion, colloidal suspending agent.
Priority Applications (1)
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CN 02101905 CN1378782A (en) | 2002-01-08 | 2002-01-08 | Agricultural bactericide series prepared from raw powder of hymexazol as main raw material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02101905 CN1378782A (en) | 2002-01-08 | 2002-01-08 | Agricultural bactericide series prepared from raw powder of hymexazol as main raw material |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN99115140A Division CN1101132C (en) | 1999-09-14 | 1999-09-14 | Hymexazol producing process and farm germicides compounded by using hymexazol as main material |
Publications (1)
Publication Number | Publication Date |
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CN1378782A true CN1378782A (en) | 2002-11-13 |
Family
ID=4739621
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN 02101905 Pending CN1378782A (en) | 2002-01-08 | 2002-01-08 | Agricultural bactericide series prepared from raw powder of hymexazol as main raw material |
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CN (1) | CN1378782A (en) |
Cited By (8)
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WO2004073401A3 (en) * | 2003-02-20 | 2004-11-25 | Bayer Cropscience Sa | Fungicide composition comprising fenamidone and hymexazol |
CN1306874C (en) * | 2004-11-18 | 2007-03-28 | 上海工程技术大学 | Nuisance free seed additive for preventing vegetable sprout term disease |
CN100415096C (en) * | 2004-11-18 | 2008-09-03 | 上海工程技术大学 | Nuisance free seed coating agent for gourd vegetable crop and preparation method thereof |
CN103190432A (en) * | 2013-03-19 | 2013-07-10 | 本溪经济开发区壮苗科技开发有限公司 | Bactericide composition |
CN105265448A (en) * | 2014-07-22 | 2016-01-27 | 刘仑贤 | Bactericide capable of radical treatment of root rot and black shank of tobacco products |
CN105494364A (en) * | 2014-10-15 | 2016-04-20 | 济南约克农化有限公司 | Bactericide containing azoxystrobin and hymexazol |
CN105638681A (en) * | 2014-11-17 | 2016-06-08 | 武汉凌科达科技有限公司 | A preparing method of a plant-sourced composite pesticide |
CN115380906A (en) * | 2021-05-25 | 2022-11-25 | 北京建佳农科技发展有限责任公司 | Efficient compound bactericidal pesticide for preventing and treating anthracnose root rot and preparation and use methods thereof |
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2002
- 2002-01-08 CN CN 02101905 patent/CN1378782A/en active Pending
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004073401A3 (en) * | 2003-02-20 | 2004-11-25 | Bayer Cropscience Sa | Fungicide composition comprising fenamidone and hymexazol |
CN1307877C (en) * | 2003-02-20 | 2007-04-04 | 拜尔农科股份有限公司 | Fungicide composition comprising fenamidone and hymexazol |
CN1306874C (en) * | 2004-11-18 | 2007-03-28 | 上海工程技术大学 | Nuisance free seed additive for preventing vegetable sprout term disease |
CN100415096C (en) * | 2004-11-18 | 2008-09-03 | 上海工程技术大学 | Nuisance free seed coating agent for gourd vegetable crop and preparation method thereof |
CN103190432A (en) * | 2013-03-19 | 2013-07-10 | 本溪经济开发区壮苗科技开发有限公司 | Bactericide composition |
CN103190432B (en) * | 2013-03-19 | 2014-06-04 | 本溪经济开发区壮苗科技开发有限公司 | Bactericide composition |
CN105265448A (en) * | 2014-07-22 | 2016-01-27 | 刘仑贤 | Bactericide capable of radical treatment of root rot and black shank of tobacco products |
CN105494364A (en) * | 2014-10-15 | 2016-04-20 | 济南约克农化有限公司 | Bactericide containing azoxystrobin and hymexazol |
CN105638681A (en) * | 2014-11-17 | 2016-06-08 | 武汉凌科达科技有限公司 | A preparing method of a plant-sourced composite pesticide |
CN115380906A (en) * | 2021-05-25 | 2022-11-25 | 北京建佳农科技发展有限责任公司 | Efficient compound bactericidal pesticide for preventing and treating anthracnose root rot and preparation and use methods thereof |
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