CN1074250C - Application of diniconazole emulsion in preventing and treating sigatoka - Google Patents
Application of diniconazole emulsion in preventing and treating sigatoka Download PDFInfo
- Publication number
- CN1074250C CN1074250C CN99102988A CN99102988A CN1074250C CN 1074250 C CN1074250 C CN 1074250C CN 99102988 A CN99102988 A CN 99102988A CN 99102988 A CN99102988 A CN 99102988A CN 1074250 C CN1074250 C CN 1074250C
- Authority
- CN
- China
- Prior art keywords
- emulsion
- sigatoka
- preventing
- diniconazole
- alkene azoles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 15
- 230000003405 preventing effect Effects 0.000 title abstract description 8
- FBOUIAKEJMZPQG-BLXFFLACSA-N diniconazole-M Chemical compound C1=NC=NN1/C([C@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1Cl FBOUIAKEJMZPQG-BLXFFLACSA-N 0.000 title abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- 150000001336 alkenes Chemical class 0.000 claims description 21
- 150000003851 azoles Chemical class 0.000 claims description 21
- 201000010099 disease Diseases 0.000 abstract description 11
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 11
- 235000018290 Musa x paradisiaca Nutrition 0.000 abstract description 8
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 239000002904 solvent Substances 0.000 abstract description 7
- 239000003995 emulsifying agent Substances 0.000 abstract description 6
- 239000000080 wetting agent Substances 0.000 abstract description 6
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 239000003899 bactericide agent Substances 0.000 abstract description 3
- 240000005561 Musa balbisiana Species 0.000 abstract 1
- 230000000149 penetrating effect Effects 0.000 abstract 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 15
- 206010039509 Scab Diseases 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 241000234295 Musa Species 0.000 description 10
- 244000052769 pathogen Species 0.000 description 10
- 230000001717 pathogenic effect Effects 0.000 description 9
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 8
- 230000003449 preventive effect Effects 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 6
- 230000000740 bleeding effect Effects 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical group CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 3
- 235000021015 bananas Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009313 farming Methods 0.000 description 3
- 230000001408 fungistatic effect Effects 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000004563 wettable powder Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 239000005739 Bordeaux mixture Substances 0.000 description 1
- 241001157813 Cercospora Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000005802 Mancozeb Substances 0.000 description 1
- 206010027146 Melanoderma Diseases 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000005822 Propiconazole Substances 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000005842 Thiophanate-methyl Substances 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 241000228452 Venturia inaequalis Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000005078 fruit development Effects 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000011173 large scale experimental method Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000008223 sterile water Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an application of diniconazole emulsion for preventing and treating banana leaf spot disease, which uses diniconazole as a bactericide and is added with an emulsifier, a wetting agent, a penetrating agent and a solvent to prepare the emulsion.
Description
The present invention relates to a kind of alkene azoles alcohol emulsion and preventing and treating the application of sigatoka.
Sigatoka is one of main disease of harm banana, and this disease belongs to fungal disease, according to reports, found 6 kinds of pathogens, with the difference of region and weather, the main disease species in each producing region is different, the blade of this disease main harm banana, the various scab of the initial generation of the blade of being injured becomes large stretch of scab thereafter gradually, last full leaf is withered, lose physiological function, when the blade of being injured increased, functional leaf reduced, fruit development can not be full, causes the underproduction even cause losing receipts comprehensively.
The specific drug of preventing and treating sigatoka at present is 25% enemy's power demulsification oil Tilt that Switzerland-Novartis Co.,Ltd produces, chemical name is a propiconazole, and also have 25% of Israel-A Gan chemical company production must pounce on your missible oil with a kind of commercial goods of chemical composition, can reach 80% to the anti-efficient of sigatoka, in addition, also has widely used thiophanate methyl wetting powder, carbendazol wettable powder, the Te Keduo wetting powder, the tpn wetting powder, mancozeb wettable powder is for woods ammonium aqua, green newborn copper, bordeaux mixture, though these kinds also have certain preventive and therapeutic effect to sigatoka, preventive effect is lower, generally only be 30-70%, the anti-usefulness that has reaches more than 80%, but costs an arm and a leg, and the control cost is high.
Purpose of the present invention is being prevented and treated the application of sigatoka for the shortcoming that overcomes above-mentioned prior art provides a kind of pointed high a kind of alkene azoles alcohol emulsion of efficient of preventing and treating with deficiency just, thereby can reach effectively preventing banana disease, obtain the high yield good harvest.
The objective of the invention is to realize by following technical proposal:
Prevent and treat sigatoka alkene azoles alcohol emulsion, the emulsion that it is made by following heavy percentage raw material:
Alkene azoles alcohol 10-40%
Emulsifier 5-15%
Wetting agent 2-10%
Bleeding agent 0-2%
The solvent surplus
Emulsifier is one or more combination of farming breast 2201, agricultural newborn 0203B, agricultural newborn 0204C, above-mentioned component; Wetting agent is fatty alcohol-polyoxyethylene ether, diisooctyl succinic acid sodium sulfonate, the group of one or more of above-mentioned component; Bleeding agent is an azone; Solvent is methyl alcohol, dimethyl formamide, dimethyl sulfoxide (DMSO), the combination of one or more of above-mentioned component.
The agricultural chemicals preparation method is characterized in that it is undertaken by following step:
A) take by weighing raw material by following percentage by weight; Alkene azoles alcohol 10-40%, emulsifier 5-15%, wetting agent 2-10%, bleeding agent 0-2%, solvent surplus
B) earlier alkene azoles alcohol, bleeding agent, wetting agent, emulsifier and 2/3 solvent are added container for stirring 10-20 minute, make it whole dissolvings;
C) at last with continuing to stir 40-60 minute in 1/3 solvent adding (b) material, be the finished product agriculture chemicals.
The alkene azoles alcohol that the present invention adopts is bactericide, alkene azoles alcohol English name diniconzale, Chinese name (E)-1-(2,4)-dichlorophenyl)-4,4 ,-dimethyl-2 (1,2, the 4-triazol-1-yl) 1-amylene-3-alcohol, molecular formula is C
15H
17Cl
12N
3O, structural formula is:
This product is mainly used in the powdery mildew of control wheat, yellow rust, leaf rust, black stem rust, moire disease, leaf blight, maize head smut, the cercospora brown spot of peanut, black spot, powder disease, rust and the pear scab of apple, by screening, find that alkene azoles alcohol has very strong inhibitory action to sigatoka to the bulk sterilization agent.
This bactericide and wetting agent, bleeding agent, emulsifier and solvent are made emulsion, can be used for preventing and treating sigatoka, have carried out the indoor bacteriostatic experiment and the large scale experiment of banana garden for this reason, contrast with 25% enemy's power demulsification oil, and its result is as follows:
1, suppress the pathogen test:
Select the topmost pathogen of sigatoka to carry out indoor antibacterial test, observe the fungistatic effect of each medicament.
Concrete grammar is: gather disease leaf standard specimen from the field, earlier isolate pathogen with tissue isolation, the back is carried out purifying with the monospore partition method and is cultivated, the monospore fungus strain that is separated to is through indoor, after outdoor inoculation test proves the pathogen of sigatoka, move into the PDA medium and carry out enlarged culture, cultivated 7 days down at 28-30 ℃, with sterile water the conidium of pathogen is washed, be made under 100 times of light microscopics each visual field and contain the suspension of 300 pathogen spores, pour in 15 ℃ the PDA medium every 150ml PDA medium then into and add 10ml pathogen conidial suspension and shake up, pour in the culture dish that diameter is 90mm.Every ware is poured 10ml into and is contained the conidial PDA liquid medium of pathogen, after treating culture medium solidifying, the filter paper circle butterfly that it is 5mm that a diameter is put at the middle part of every culture dish, soup by the concentration of required test is added on the filter paper circle butterfly at culture dish middle part at leisure, and each pesticide-treated concentration is done 4 repetitions.Install, tighten with plastic sack then, be put in 28-30 ℃ the greenhouse and cultivate, at the 3rd day that cultivates, measure the diameter of the inhibition zone that occurs in each culture dish, the mm of unit the results are shown in Table 1
Inhibition effect table 1 to the sigatoka pathogen
Concentration inhibition zone size (mm) experimental pharmacy mean
(extension rate) I II III IV (mm) 25% alkene azoles alcohol missible oil 2,000 38 37 40 38 38.2525% enemy's power demulsification oil 1,500 32 36 35 37 35.00
Experimental result shows, emulsion of the present invention to fungistatic effect greater than enemy's power demulsification oil.
2, the leaf spot scab is suppressed experiment:
Concrete grammar is: every chemicals treatment 3 strain bananas, whenever select good strains in the field for seed and get 1 on first morbidity leaf, the width of the length of mark and the first morbidity of measurement spot on leaf, 50 big scabs of the grain of rice of every leaf mark, the mark scab is 150 altogether, after the dispenser 15 days, measure the length and the width of institute's mark scab, more various medicaments are to the inhibition effect of scab size.The results are shown in Table 2
Table 2
Concentration scab length scab width experimental pharmacy (extension rate) is (mm) 25% alkene azoles alcohol missible oil 2,000 9.76 1.2825% enemy's power demulsification oil 1,500 10.54 1.50 (mm)
Data are 150 mean values of investigation scab in the table.Experimental result shows that emulsion of the present invention is better than opposing power demulsification oil to leaf spot scab fungistatic effect.
3, to young leaves protection experiment:
Concrete grammar is: every chemicals treatment 21 strain bananas, and complete stool spray medicine three times, dispenser is spaced apart for the first time and at interval 15 days for the second time, for the second time with at interval 20 days for the third time.
Reinstate urushoil mark plant top position during from first time dispenser, total number of sheets of 20 days inquiry agency marks after the dispenser for the third time, the morbidity number of sheets has been calculated the leaf rate, the results are shown in Table 3:
The new number of sheets of the table 3 experimental pharmacy concentration young leaves sum morbidity good leaf rate of the number of sheets of not falling ill
(extension rate) (opening) (opening) (opening) be 25% alkene azoles alcohol missible oil, 2,000 238 19 219 92.0225% enemy's power demulsifications oil 1,500 254 38 216 85.04 (%)
Experimental result shows: missible oil of the present invention is better than 25% enemy's power demulsification oil to banana young leaves protection effect.
4, the sigatoka preventive effect is tested:
Concrete grammar is: every chemicals treatment 7 strain bananas, repeat for 4 times, complete stool spray medicine 3 times, dispenser at interval: at interval 15 days for the first time and for the second time, for the second time with at interval 20 days for the third time.
The total leafiness number of investigation records, the sick number of sheets and sick leaf-size class number before each dispenser.Investigated total leafiness number of plant for the third time after the dispenser in 20 days, the morbidity number of sheets and sick level, calculate disease index and preventive effect:
The stage division of sick leaf:
0 grade-anosis,
1 grade-scab distribution blade face is below 1/6,
2 grades-scab distribution blade face 1/6-1/3,
3 grades-scab distribution blade face 1/3-1/2,
4 grades-scab distribution blade face is more than 1/2,
The results are shown in Table 4
Table 4
Concentration disease index preventive effect
Experimental pharmacy (extension rate) is (%) (mm)
25% alkene azoles alcohol missible oil 2,000 3.77 91.0
25% enemy's power demulsification oil 1,500 5.82 86.10
Experimental result shows: missible oil of the present invention is better than opposing power demulsification oil to the sigatoka preventive effect.
5, banana garden preventive effect experiment: select Pubei County, Guangxi banana garden
Experimental result: see Table 5
Table 5
The average preventive effect of concentration and preventing effect (%) experimental pharmacy
(extension rate) I II III IV (%) 6% alkene azoles alcohol missible oil 1,000 82.9 89.1 85.4 86.3 85.912% alkene azoles alcohol missible oil 1,500 88.9 88.5 86.3 85.1 87.225% alkene azoles alcohol missible oil 2,000 90.8 92.1 89.4 93.2 91.4 experimental results show, missible oil of the present invention prevent and treat efficient all at 85.9-91.4%, have significant bactericidal effect.
In sum, it is effective that compared with the prior art the present invention has the bacterium of stopping, and can reach 90%, and sigatoka is had special efficacy, and product cost is low, and the preparation method is simple, and the no three wastes are pollution-free.
Embodiment 1:
Alkene azoles alcohol 10kg, fatty alcohol-polyoxyethylene ether 2kg, farming breast 2201 and agricultural each 2.51kg of newborn 0203B, 35kg methyl alcohol, the 20kg dimethyl formamide, add in the container, stirred 15 minutes, and added methyl alcohol 18kg again, dimethyl formamide 10kg, continue again to stir 60 minutes, obtain sterilizing emulsion of the present invention.
Embodiment 2:
Alkene azoles alcohol 25kg, diisooctyl succinic acid sodium sulfonate 6kg, azone 1kg and agricultural newborn 0204C10kg, dimethyl formamide 38kg adds in the container, stirs 15 minutes, adds dimethyl formamide 20kg again and continues to stir 50 minutes, promptly obtains sterilizing emulsion of the present invention.
Embodiment 3:
Alkene azoles alcohol 40kg, poly alkyl alcohol vinyl chloride ether 5kg, diisooctyl fourth acetate sodium sulfonate 5kg, azone 2kg, the newborn 0203B of farming and agricultural each 7.5kg of newborn 0204C, methyl alcohol 22kg, add in the container, stirred 20 minutes, add dimethyl sulfoxide (DMSO) 11kg again, continue to stir 40 minutes, promptly get sterilizing emulsion of the present invention.
Claims (1)
1, alkene azoles alcohol emulsion, prevent and treat the application of sigatoka.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99102988A CN1074250C (en) | 1999-03-17 | 1999-03-17 | Application of diniconazole emulsion in preventing and treating sigatoka |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99102988A CN1074250C (en) | 1999-03-17 | 1999-03-17 | Application of diniconazole emulsion in preventing and treating sigatoka |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1229582A CN1229582A (en) | 1999-09-29 |
| CN1074250C true CN1074250C (en) | 2001-11-07 |
Family
ID=5271079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99102988A Expired - Fee Related CN1074250C (en) | 1999-03-17 | 1999-03-17 | Application of diniconazole emulsion in preventing and treating sigatoka |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1074250C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013209293A (en) * | 2010-07-28 | 2013-10-10 | Nippon Nohyaku Co Ltd | Method for controlling sigatoka disease |
| CN104969768B (en) * | 2015-07-31 | 2017-06-16 | 王振华 | Prevent and treat the implantation methods of sigatoka |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4291047A (en) * | 1978-07-21 | 1981-09-22 | Bayer Aktiengesellschaft | Combating fungi with α-azolyl-β-hydroxy-ketones |
| US4554007A (en) * | 1979-03-20 | 1985-11-19 | Sumitomo Chemical Company, Limited | Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant |
-
1999
- 1999-03-17 CN CN99102988A patent/CN1074250C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4291047A (en) * | 1978-07-21 | 1981-09-22 | Bayer Aktiengesellschaft | Combating fungi with α-azolyl-β-hydroxy-ketones |
| US4554007A (en) * | 1979-03-20 | 1985-11-19 | Sumitomo Chemical Company, Limited | Geometrical isomer of 1-substituted-1-triazolylstyrenes, and their production and use as fungicide, herbicide and/or plant growth regulant |
Non-Patent Citations (4)
| Title |
|---|
| 农药剂 型加工技术 1998.10.1 刘步林主编化工出版社 * |
| 农药剂 型及助剂应用 1995.10.1 张保民主编，中原农民出版社 * |
| 国外新农药品种手册 1992.10.1 沙家骏，徐敏恒，姜雅君等编化工出版社 * |
| 国外新农药品种手册 1992.10.1 沙家骏，徐敏恒，姜雅君等编化工出版社;农药剂 型及助剂应用 1995.10.1 张保民主编，中原农民出版社;农药剂 型加工技术 1998.10.1 刘步林主编化工出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1229582A (en) | 1999-09-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1847200A (en) | Pollution-less pesticide fertilizer for preventing and controlling blight and its production process | |
| CN101036459A (en) | Eugenol micro-emulsion | |
| CN101057586A (en) | Bactericide for agricultural and forestry crops (except leguminous plants) | |
| CN103039491A (en) | Composition containing chitosan oligosaccharide and prochloraz | |
| CN102037963B (en) | Bavachalcone compounds and bavachin mixed preparation for preventing and controlling plant diseases | |
| CN104604945B (en) | A kind of Pesticidal combination containing green muscardine fungus and jervine and its application in prevention and treatment rice disease | |
| CN108294014B (en) | Seed coating agent for preventing and treating root rot and preparation method and application thereof | |
| CN103493828B (en) | Microbicide compositions containing chitosan oligomer | |
| CN101036461A (en) | Eugenol, osthol complex biological bactericide | |
| CN110800739B (en) | Strawberry powdery mildew prevention and treatment medicament and preparation method and application thereof | |
| CN1074250C (en) | Application of diniconazole emulsion in preventing and treating sigatoka | |
| CN1918988A (en) | Sterilizing and insecticidal composition | |
| CN104351180B (en) | A kind of micro-capsule suspension for preventing and treating rice green smut | |
| CN103444721A (en) | Sterilization pesticide composition, pesticide preparation and application of pesticide preparation | |
| CN113575602B (en) | Powdery mildew resistant bactericidal active agent | |
| CN1810115A (en) | Flusilazole-and kresoxim methyl bactericide composition and its prepn process | |
| CN112913844B (en) | Sterilization composition for preventing and treating powdery mildew | |
| CN116267928A (en) | Sterilization composition containing bronopol | |
| CN107333792A (en) | By rosickyite azoles and the bactericide of the preventing and treating rice blast of miaow chaff azoles compounding | |
| CN1613847A (en) | Aromatic diamidine compound with bactericidal activity and application thereof | |
| CN107333791A (en) | By rosickyite azoles and the bactericide of the preventing and treating rice blast of OIT compounding | |
| CN109832273B (en) | Application of branched chain amino acid in preparation of rice disease control agent | |
| CN1185901A (en) | A new agricultural chemicals against gray mould | |
| CN1565182A (en) | Bactericidal compositions of flumorph and enostroburin and synergist | |
| CN1319447C (en) | Drought resishing aphicide and its use |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20011107 Termination date: 20150317 |
|
| EXPY | Termination of patent right or utility model |