CN102763672A - Granula containing ivermectin and clothianidin - Google Patents
Granula containing ivermectin and clothianidin Download PDFInfo
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- CN102763672A CN102763672A CN2012102867394A CN201210286739A CN102763672A CN 102763672 A CN102763672 A CN 102763672A CN 2012102867394 A CN2012102867394 A CN 2012102867394A CN 201210286739 A CN201210286739 A CN 201210286739A CN 102763672 A CN102763672 A CN 102763672A
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Abstract
The invention relates to granula containing ivermectin and clothianidin. The granula is composed of active ingredients, auxiliaries, binder and carriers. The granula comprises, by weight, 0.01%-5% of ivermectin, 0.01%-10% of clothianidin, 1%-15% of auxiliaries, 0.5%-10% of binder and the balance carriers. The granula containing the ivermectin and the clothianidin is wide in an insecticidal spectrum, not only can effectively prevent and control injurious insects such as borers, aphids and thrips on the ground, but also is good in effect on injurious insects such as nematodes and grubs under the ground. The composite of the ivermectin and clothianidin is remarkable in synergistic effect, good in product preventive effect and long in a validity period.
Description
Technical field
The present invention relates to the granular pesticide field, specifically is the granule that contains ivermectin and thiophene worm amine.
Background technology
Ivermectin; Have another name called Ivermectin HCL; English name: Ivermectin; Be the semi-synthetic macrolides multicomponent antibiotic that is produced by the Avid kyowamycin fermentation, high-efficiency broad spectrum can effectively be controlled insects such as Lepidoptera, diptera and thrips; Insect to coleoptera, orthoptera, Hymenoptera, Isoptera, Siphonaptera, Dermaptera and psocopteran some particular types also has certain toxic action simultaneously, can be used for numerous crop pest controls such as sugarcane, paddy rice, wheat, corn, fruit tree, vegetables, cotton, tobacco.
Thiophene worm amine belongs to second generation nicotinic insecticide, has characteristics such as low toxicity, active height, tagging property and interior absorption are strong, is applicable to foliar spray, soil treatment.
Chinese patent 200910018515.3 discloses a kind of clothianidin sustained and controlled release granule composite, is processed by thiophene worm amine, carrier and seed coating medicine etc., uses anti-insect such as eliminate aphis at crop root.Chinese patent 201110426804.4 discloses that a kind of said composition can be processed granule with fipronil bisamide and the composite composition of thiophene worm amine, is mainly used in control lepidoptera pest and homoptera pest.Foregoing invention is mainly used in the homoptera pest and the lepidoptera pest of control overground part, and relatively poor for root-knot nematode, these two kinds main soil insect preventive effects of grub, can not satisfy the demand of peasant household.
Utilize ivermectin to process granule control soil insect and do not retrieve open file.Ivermectin and thiophene worm amine compounded combination are not seen open yet.
Summary of the invention
The purpose of this invention is to provide a kind of granule that contains ivermectin and thiophene worm amine, solve the problem that present granular pesticide insecticidal spectrum can not satisfy peasant household's demand, when being implemented in prevention and control overground part insect, doublely control main soil insects such as root-knot nematode, grub.
The present invention solves the problems of the technologies described above the technical scheme of being taked: the granule that contains ivermectin and thiophene worm amine; Form by active ingredient, auxiliary agent, binding agent, carrier; The granule prescription is made up of following components in weight percentage: ivermectin 0.01%～5%, thiophene worm amine 0.01%～10%, auxiliary agent 1%～15%; Binding agent 0.5%～10%, carrier complements to 100%.
Described auxiliary agent is calcium lignosulfonate, sodium lignin sulfonate, magnesium lignosulfonate, naphthalenesulfonate formaldehyde condensation compound, alkylnaphthalene sulfonate formaldehyde condensation products, polycarboxylate, draw back one or more the combination in powder, lauryl sodium sulfate, AEO, APES, calcium dodecyl benzene sulfonate, azone, thiophene ketone, the maleic acid di-sec-octyl sodium sulfonate.
Described binding agent is one or more the combination in starch, sucrose, polyvinyl alcohol, the carboxymethyl cellulose.
Described carrier is one or more the combination in river sand, kaolin, diatomite, bentonite, white carbon, gypsum, sodium sulphate, ammonium sulfate, calcium carbonate, ammonium dihydrogen phosphate (ADP), potassium dihydrogen phosphate, ammonium chloride, potassium chloride, the urea.
The described preparation method who contains the granule of ivermectin and thiophene worm amine is: ivermectin, thiophene worm amine, auxiliary agent, binding agent and carrier are mixed the back pulverize; Stir after adding water-wet; Be that core carrier carries out dressing with river sand or diatomite again; Sieve after the drying, promptly get the granule that contains ivermectin and thiophene worm amine of the present invention.
The granule that contains ivermectin and thiophene worm amine of the present invention; Be used to prevent and treat soil insect, nematode and the ground insect of crops such as sugarcane, corn, banana, peanut, vegetables, tobacco, forest, comprise grub, mole cricket, cutworm, chafer, root-knot nematode, aphid, snout moth's larva, thrips etc.
The present invention has following beneficial effect:
(1) active ingredient of the present invention is mixed by ivermectin and thiophene worm amine and forms, and the two synergistic function is obvious, and prevention effect is good; Lasting period is long; Can reduce spraying times and formulation rate, reduce drug cost, delay the resistance development of ivermectin and thiophene worm amine simultaneously.
(2) insecticidal spectrum of the present invention is wide, effective insects such as the snout moth's larva of prevention and control overground part, aphid, thrips, and excellent to insect effects such as the nematode of underground part, grubs.
(3) during as carrier, can supply nutrient components such as the required N of crop, P, K, S, Ca with sodium sulphate, ammonium sulfate, calcium carbonate, ammonium dihydrogen phosphate (ADP), potassium dihydrogen phosphate, ammonium chloride, potassium chloride, urea, further improve output.
Embodiment
Embodiment 1 0.02% ivermectin thiophene worm amine granule
Prescription: ivermectin 0.01kg, thiophene worm amine 0.01kg, sodium lignin sulfonate 0.5kg, lauryl sodium sulfate 0.5kg, polyvinyl alcohol 0.5kg, ammonium sulfate 20kg, potassium dihydrogen phosphate 15kg, kaolin 5kg, white carbon 5kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 0.02% ivermectin thiophene worm amine granule.
Embodiment 2 0.1% ivermectin thiophene worm amine granules
Prescription: ivermectin 0.03kg, thiophene worm amine 0.07kg, magnesium lignosulfonate 2kg, lauryl sodium sulfate 0.5kg, polycarboxylate 0.5kg, polyvinyl alcohol 3kg, ammonium dihydrogen phosphate (ADP) 25kg, kaolin 20kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 0.1% ivermectin thiophene worm amine granule.
Embodiment 3 0.3% ivermectin thiophene worm amine granules
Prescription: ivermectin 0.1kg, thiophene worm amine 0.2kg, calcium lignosulfonate 2kg, lauryl sodium sulfate 1kg, polycarboxylate 0.5kg, starch 5kg, potassium dihydrogen phosphate 15kg, ammonium chloride 25kg, kaolin 10kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 0.3% ivermectin thiophene worm amine granule.
Embodiment 4 0.5% ivermectin thiophene worm amine granules
Prescription: ivermectin 0.3kg, thiophene worm amine 0.2kg, naphthalenesulfonate formaldehyde condensation compound 1.5kg draws back powder 1kg, lauryl sodium sulfate 1kg, starch 10kg, gypsum 20kg, bentonite 20kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 0.5% ivermectin thiophene worm amine granule.
Embodiment 5 1% ivermectin thiophene worm amine granules
Prescription: ivermectin 0.8kg, thiophene worm amine 0.2kg, maleic acid di-sec-octyl sodium sulfonate 2kg, naphthalenesulfonate formaldehyde condensation compound 5kg; Polycarboxylate 1kg, calcium dodecyl benzene sulfonate 1.5kg, carboxymethyl cellulose 5kg; Calcium carbonate 20kg, diatomite 25kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 1% ivermectin thiophene worm amine granule.
Embodiment 6 1.5% ivermectin thiophene worm amine granules
Prescription: ivermectin 0.1kg, thiophene worm amine 1.4kg, alkylnaphthalene sulfonate formaldehyde condensation products 5kg, AEO 3kg, carboxymethyl cellulose 3kg, calcium carbonate 20kg, kaolin 25kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient except that diatomite being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with diatomite, sieves after the drying, promptly gets 1.5% ivermectin thiophene worm amine granule.
Embodiment 7 2% ivermectin thiophene worm amine granules
Prescription: ivermectin 0.5kg, thiophene worm amine 1.5kg, naphthalenesulfonate formaldehyde condensation compound 8kg, calcium lignosulfonate 7kg, carboxymethyl cellulose 2kg, sucrose 8kg, gypsum 10kg, ammonium sulfate 15kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 2% ivermectin thiophene worm amine granule.
Embodiment 8 3% ivermectin thiophene worm amine granules
Prescription: ivermectin 1kg, thiophene worm amine 2kg, azone 3kg, naphthalenesulfonate formaldehyde condensation compound 2kg, calcium lignosulfonate 5kg, APES 2kg, starch 8kg, calcium carbonate 20kg, gypsum 15kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 3% ivermectin thiophene worm amine granule.
Embodiment 9 5% ivermectin thiophene worm amine granules
Prescription: ivermectin 3kg, thiophene worm amine 2kg, thiophene ketone 2kg, naphthalenesulfonate formaldehyde condensation compound 3kg, calcium lignosulfonate 4kg, sucrose 8kg, carboxymethyl cellulose 2kg, gypsum 20kg, sodium sulphate 10kg, potassium chloride 5kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient except that diatomite being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with diatomite, sieves after the drying, promptly gets 5% ivermectin thiophene worm amine granule.
Embodiment 10 5.01% ivermectin thiophene worm amine granules
Prescription: ivermectin 5kg, thiophene worm amine 0.01kg, calcium lignosulfonate 3kg, polycarboxylate 2.5kg, AEO 3kg, polyvinyl alcohol 5kg, calcium carbonate 20kg, bentonite 15kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 5.01% ivermectin thiophene worm amine granule.
Embodiment 11 6% ivermectin thiophene worm amine granules
Prescription: ivermectin 1kg, thiophene worm amine 5kg, azone 3kg, naphthalenesulfonate formaldehyde condensation compound 5kg, calcium lignosulfonate 1kg, lauryl sodium sulfate 2kg, starch 8kg, calcium carbonate 10kg, kaolin 20kg, urea 5kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient except that diatomite being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with diatomite, sieves after the drying, promptly gets 6% ivermectin thiophene worm amine granule.
Embodiment 12 9% ivermectin thiophene worm amine granules
Prescription: ivermectin 3kg, thiophene worm amine 6kg, naphthalenesulfonate formaldehyde condensation compound 2kg, lauryl sodium sulfate 1kg, polyvinyl alcohol 3kg, ammonium chloride 15kg, kaolin 20kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient except that diatomite being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with diatomite, sieves after the drying, promptly gets 9% ivermectin thiophene worm amine granule.
Embodiment 13 10.01% ivermectin thiophene worm amine granules
Prescription: ivermectin 0.01kg, thiophene worm amine 10kg, thiophene ketone 2kg, calcium lignosulfonate 5kg, polycarboxylate 2kg, polyvinyl alcohol 2kg, sucrose 5kg, gypsum 20kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 10.01% ivermectin thiophene worm amine granule.
Embodiment 14 10% ivermectin thiophene worm amine granules
Prescription: ivermectin 2kg, thiophene worm amine 8kg, azone 3kg, naphthalenesulfonate formaldehyde condensation compound 3kg, calcium lignosulfonate 5kg, lauryl sodium sulfate 1kg, starch 6kg, calcium carbonate 15g, kaolin 25kg, river sand complements to 100kg.
Above-mentioned recipe ingredient except that river sand being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with the river sand, sieves after the drying, promptly gets 10% ivermectin thiophene worm amine granule.
Embodiment 15 15% ivermectin thiophene worm amine granules
Prescription: ivermectin 5kg, thiophene worm amine 10kg, calcium lignosulfonate 4kg, AEO 2kg, polyvinyl alcohol 1kg, gypsum 20kg, bentonite 10kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient except that diatomite being mixed the back pulverize, stir after adding water-wet, is that core carrier carries out dressing again with diatomite, sieves after the drying, promptly gets 15% ivermectin thiophene worm amine granule.
Invention application implementation example 1
Carry out the control of sugarcane moth borer with embodiment 1-5 products obtained therefrom,, will test to handle being provided with as follows according to the product estimated cost:
Handle 1:0.02% ivermectin thiophene worm amine granule 33kg/ mu.
Handle 2:0.1% ivermectin thiophene worm amine granule 7.7kg/ mu.
Handle 3:0.3% ivermectin thiophene worm amine granule 2.5kg/ mu.
Handle 4:0.5% ivermectin thiophene worm amine granule 1.2kg/ mu.
Handle 5:1% ivermectin thiophene worm amine granule 0.5kg/ mu.
Handle 6:0.5% ivermectin granule 1kg/ mu.
Handle 7:1% thiophene worm amine granule 1kg/ mu.
Handle 8: blank.
Above-mentioned processing is used when sugarcane is sowed, and carries out the sugarcane moth borer condition survey of causing harm behind the medicine in 60 days, 90 days respectively, carries out determination of yield during the sugarcane harvesting, and final statistics is as shown in the table:
It is thus clear that under the approaching prerequisite of use cost, embodiment 1-5 products obtained therefrom is obviously high than ivermectin, the preventive effect of thiophene worm amine list time spent to the preventive effect of sugarcane moth borer, the lasting period is long, and can make the sugarcane yield growth more than 20%.
Invention application implementation example 2
Carry out the control of peanut grub and peanut aphid with embodiment 6-10 products obtained therefrom,, will test to handle being provided with as follows according to the product estimated cost:
Handle 1:1.5% ivermectin thiophene worm amine granule 3kg/ mu.
Handle 2:2% ivermectin thiophene worm amine granule 2kg/ mu.
Handle 3:3% ivermectin thiophene worm amine granule 1.2kg/ mu.
Handle 4:5% ivermectin thiophene worm amine granule 0.6kg/ mu.
Handle 5:5.01% ivermectin thiophene worm amine granule 0.5kg/ mu.
Handle 6:0.5% ivermectin granule 5kg/ mu.
Handle 7:1% thiophene worm amine granule 5kg/ mu.
Handle 8: blank.
Above-mentioned processing is used when peanut seeding, and 30 days " Invest, Then Investigate " peanut aphids situation that causes harm is gathered in the crops after 100 days and carried out the investigation of peanut grub insect population number and peanut yield is measured, and final statistics is as shown in the table:
It is thus clear that under the approaching prerequisite of use cost, embodiment 6-10 products obtained therefrom is aspect control peanut aphid and peanut grub, all obviously than ivermectin, the preventive effect of thiophene worm amine list time spent height, the lasting period is long, and can make peanut yield increase more than 20% for preventive effect.
Invention application implementation example 3
Carry out the control of banana root-knot nematode with embodiment 11-15 products obtained therefrom,, will test to handle being provided with as follows according to the product estimated cost:
Handle 1:6% ivermectin thiophene worm amine granule 1.4kg/ mu.
Handle 2:9% ivermectin thiophene worm amine granule 0.8kg/ mu.
Handle 3:10.01% ivermectin thiophene worm amine granule 1kg/ mu.
Handle 4:10% ivermectin thiophene worm amine granule 0.8kg/ mu.
Handle 5:15% ivermectin thiophene worm amine granule 0.5kg/ mu.
Handle 6:0.5% ivermectin granule 10kg/ mu.
Handle 7:1% thiophene worm amine granule 10kg/ mu.
Handle 8: blank.
Above-mentioned processing is used when the banana field planting, carries out the root-knot nematode investigation of causing harm behind the medicine in 45 days, 90 days respectively, carries out determination of yield during results, and final statistics is as shown in the table:
It is thus clear that under the approaching prerequisite of use cost, embodiment 11-15 products obtained therefrom is obviously high than ivermectin, the preventive effect of thiophene worm amine list time spent to the preventive effect of banana root-knot nematode, the lasting period is long, and can make the banana production growth more than 30%.
Ivermectin, thiophene worm amine and be mixed to the indoor joint toxicity measuring test of Meloidogyne incognita:
Test with ivermectin, two kinds of single agent of thiophene worm amine as the contrast medicament, and according to No. 5, No. 1-mixture of following ratio preparation mixture:
No. 1, mixture: ivermectin: thiophene worm amine=1:1
No. 2, mixture: ivermectin: thiophene worm amine=1:2
No. 3, mixture: ivermectin: thiophene worm amine=1:3
No. 4, mixture: ivermectin: thiophene worm amine=1:4
No. 5, mixture: ivermectin: thiophene worm amine=1:5
Test is the examination worm with the Meloidogyne incognita, and blank is set, and adopts dip method to carry out toxicity test and do statistical analysis ivermectin, thiophene worm amine and above-mentioned 5 mixtures, and final statistics is as shown in the table:
Toxicity Determination result shows, ivermectin, thiophene worm amine are mixed co-toxicity coefficient to Meloidogyne incognita all greater than 120 according to above-mentioned 5 different ratios, explains that these two kinds of active ingredients are mixed and have synergistic function.
Ivermectin, thiophene worm amine and be mixed to the indoor joint toxicity measuring test of corn borer:
Test with ivermectin, two kinds of single agent of thiophene worm amine as the contrast medicament, and according to No. 10, No. 6-mixture of following ratio preparation mixture:
No. 6, mixture: ivermectin: thiophene worm amine=500:1
No. 7, mixture: ivermectin: thiophene worm amine=4:1
No. 8, mixture: ivermectin: thiophene worm amine=3:2
No. 9, mixture: ivermectin: thiophene worm amine=3:7
No. 10, mixture: ivermectin: thiophene worm amine=1:1000
Test is the examination worm with the corn borer, and blank is set, and adopts dip method to carry out toxicity test and do statistical analysis ivermectin, thiophene worm amine and above-mentioned 5 mixtures, and final statistics is as shown in the table:
Toxicity Determination result shows, ivermectin, thiophene worm amine are mixed co-toxicity coefficient to corn borer all greater than 120 according to above-mentioned 5 different ratios, explains that these two kinds of active ingredients are mixed and have synergistic function.
Claims (5)
1. the granule that contains ivermectin and thiophene worm amine; Be made up of active ingredient, auxiliary agent, binding agent, carrier, it is characterized in that, the granule prescription is made up of following components in weight percentage: ivermectin 0.01%～5%; Thiophene worm amine 0.01%～10%; Auxiliary agent 1%～15%, binding agent 0.5%～10%, carrier complements to 100%.
2. the granule that contains ivermectin and thiophene worm amine according to claim 1 is characterized in that described ivermectin percentage by weight is 0.1%～1%, and thiophene worm amine percentage by weight is 0.2%～5%.
3. the granule that contains ivermectin and thiophene worm amine according to claim 1 and 2; It is characterized in that described auxiliary agent is calcium lignosulfonate, sodium lignin sulfonate, magnesium lignosulfonate, naphthalenesulfonate formaldehyde condensation compound, alkylnaphthalene sulfonate formaldehyde condensation products, polycarboxylate, draw back one or more the combination in powder, lauryl sodium sulfate, AEO, APES, calcium dodecyl benzene sulfonate, azone, thiophene ketone, the maleic acid di-sec-octyl sodium sulfonate.
4. the granule that contains ivermectin and thiophene worm amine according to claim 1 and 2 is characterized in that, described binding agent is one or more the combination in starch, sucrose, polyvinyl alcohol, the carboxymethyl cellulose.
5. the granule that contains ivermectin and thiophene worm amine according to claim 1 and 2; It is characterized in that described carrier is one or more the combination in river sand, kaolin, diatomite, bentonite, white carbon, gypsum, sodium sulphate, ammonium sulfate, calcium carbonate, ammonium dihydrogen phosphate (ADP), potassium dihydrogen phosphate, ammonium chloride, potassium chloride, the urea.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210286739.4A CN102763672B (en) | 2012-08-13 | 2012-08-13 | Granula containing ivermectin and clothianidin |
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| CN201210286739.4A CN102763672B (en) | 2012-08-13 | 2012-08-13 | Granula containing ivermectin and clothianidin |
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| CN102763672B CN102763672B (en) | 2014-01-08 |
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| CN104920407A (en) * | 2015-06-17 | 2015-09-23 | 湖南海利化工股份有限公司 | Composition for preventing and treating underground insects |
| CN105145616A (en) * | 2015-10-14 | 2015-12-16 | 南通功成精细化工有限公司 | Termite killing composition, preparation containing composition and application of preparation |
| CN107668054A (en) * | 2016-08-01 | 2018-02-09 | 江苏龙灯化学有限公司 | A kind of nematicidal agent composition and its application method |
| CN115227645A (en) * | 2022-08-03 | 2022-10-25 | 上虞颖泰精细化工有限公司 | Antiparasitic solution preparation containing ivermectin and neonicotinoid insecticides and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104920407A (en) * | 2015-06-17 | 2015-09-23 | 湖南海利化工股份有限公司 | Composition for preventing and treating underground insects |
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| CN107668054A (en) * | 2016-08-01 | 2018-02-09 | 江苏龙灯化学有限公司 | A kind of nematicidal agent composition and its application method |
| CN115227645A (en) * | 2022-08-03 | 2022-10-25 | 上虞颖泰精细化工有限公司 | Antiparasitic solution preparation containing ivermectin and neonicotinoid insecticides and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN102763672B (en) | 2014-01-08 |
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