CN102763655A - Granule containing chlorantraniliprole and monosultap - Google Patents
Granule containing chlorantraniliprole and monosultap Download PDFInfo
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- CN102763655A CN102763655A CN2012102754555A CN201210275455A CN102763655A CN 102763655 A CN102763655 A CN 102763655A CN 2012102754555 A CN2012102754555 A CN 2012102754555A CN 201210275455 A CN201210275455 A CN 201210275455A CN 102763655 A CN102763655 A CN 102763655A
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- rynaxypyr
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Abstract
The invention relates to a granule containing chlorantraniliprole and monosultap, which is prepared from the following components by weight: 0.01-5% of chlorantraniliprole, 0.1-15% of monosultap, 0.1-10% of chitin, 1-15% of additive, 0.5-10% of binder and the balance of carrier. The granule can be used for preventing the soil insects, the nematodes and the overground insects of crops including sugar cane, peanuts, corn, bananas and tomatoes, has an obvious synergetic effect, a good prevention effect and long duration of effect and can significantly improve the crop root knot nematode and pathogen prevention effect, promote the crop root development and plant growth and improve the crop yield and quality.
Description
Technical field
The present invention relates to a kind of granular pesticide, specifically is the granule of chloride worm benzamide and desinsection list.
Background technology
Rynaxypyr, English common name: Chlorantraniliprole; Molecular formula: C
18H
14N
5O
2BrCl
2Chemical name: 3-bromo-N-[4-chloro-2-methyl-6-[(methyl-carbamoyl) benzene]-1-(3-chloropyridine-2-yl)-1-hydrogen-pyrazoles-5-formamide; Structural formula:
Rynaxypyr belongs to the O-formammidotiazol-benzamide insecticide, and the mechanism of action is the efficient insect ryania acceptor that activates, and excessively discharges the calcium ion in the intracellular calcium store, causes the insect paralysis dead.Active high to the larva of lepidoptera pest, insecticidal spectrum is wide, and systemic action is strong, and lasting effect is good.Application number is that 201110368496.4 patent of invention discloses a kind of paddy rice insecticide fertilizer granule and preparation method thereof, and each component is Rynaxypyr 0.05%-10%, carrier fertilizer 30%-60%; Sustained release agent 0.1%-2%; Binding agent 0.1-10%, coating machine 0.1-0.5%, carrier supplies 100%.This invention is mainly used in spreads fertilizer over the fields the control snout moth's larva of rice, and control soil insect effect is relatively poor.To be that 200910035229.8 patent of invention discloses Rynaxypyr and Nitenpyram is composite can make granule to application number, and this granule is mainly used in control lepidoptera pest and homoptera pest, and control soil insect effect is relatively poor.Application number is that 200910035235 patent of invention discloses the composition that a kind of chloride worm benzamide and pyrethrin are mixed, and said composition can be made granule, and underground insect is had certain preventive effect, but relatively poor to the root-knot nematode preventive effect.
It is thus clear that the granule of disclosed chloride worm benzamide is mainly used in the control lepidoptera pest at present; And can not doublely simultaneously control soil insect and root-knot nematode; Can not satisfy the user demand of peasant household; Peasant household still needs to buy in addition the granule of control soil insect and root-knot nematode when spreading fertilizer over the fields, increased the input cost of agricultural chemicals.Behind the crop belts heavier for pest damage, that growing way is more weak, the controlling of insect pest, it is slower that crop growing state recovers, a little less than the resistance against diseases.
Summary of the invention
The granule that the purpose of this invention is to provide a kind of chloride worm benzamide and desinsection list; Solve present granule and spread fertilizer over the fields simultaneously preventing and controlling subterranean pest, overground part insect and root-knot nematode, the crop growing state that insect was caused harm recovers problem such as slow, that resistance against diseases is weak.
The present invention solves the problems of the technologies described above the technical scheme of being taked: the granule of chloride worm benzamide and desinsection list; Be made up of active ingredient, auxiliary agent, binding agent, carrier, the granule prescription is made up of following components in weight percentage: Rynaxypyr 0.01%～5%, desinsection list 0.1%～15%; Chitin 0.1%～10%; Auxiliary agent 1%～15%, binding agent 0.5%～10%, carrier complements to 100%.
Described auxiliary agent is one or more combinations in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, AEO, the dioctyl sodium sulfosuccinate.
Described binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol, the carboxymethyl cellulose.
Described carrier is one or more combinations in white carbon black, diatomite, active carbon, carclazyte, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulphate, sodium sulphate, calcium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate, talcum powder, river sand, cinder, the flyash.
The preparation method of the granule of described chloride worm benzamide and desinsection list is: by formula rate Rynaxypyr, desinsection list, chitin, auxiliary agent, binding agent and carrier are mixed; Pulverize; Stir after adding water-wet; Use the screw extruder pelletizer granulation again, sieve after the drying, promptly get the granule of chloride worm benzamide of the present invention and desinsection list.
The granule of chloride worm benzamide of the present invention and desinsection list; Be used to prevent and treat soil insect, nematode and the ground insect of crops such as sugarcane, peanut, corn, banana, tomato, comprise chafer, grub, mole cricket, cutworm, root-knot nematode, snout moth's larva, aphid etc.
The present invention has following beneficial effect:
(1) active ingredient of the present invention is made up of Rynaxypyr, desinsection list, and two kinds of component synergistic functions are obvious, and prevention effect is good, and the lasting period is long, reduces spraying times and formulation rate, reduces drug cost.
(2) the present invention not only can realize the generation of prevention and control insect pest effectively, and can significantly improve the prevention effect of crop to root-knot nematode and pathogen, promotes crop root development and plant strain growth simultaneously, improves the yield and quality of crop.
(3) with urea, ammonium chloride, ammonium sulfate, potassium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate as carrier, can supply nutrient components such as the required N of crop, P, K, S, Ca, further improve output.
Embodiment
Embodiment 1
0.11% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 0.01kg, desinsection list 0.1kg, chitin 0.1kg, calcium lignosulfonate 0.6kg, lauryl sodium sulfate 0.4kg, polyvinyl alcohol 0.5kg, ammonium chloride 20kg, potassium dihydrogen phosphate 15kg, kaolin 15kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 0.11% Rynaxypyr granular insecticide.
Embodiment 2
0.6% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 0.1kg, desinsection list 0.5kg, chitin 0.4kg, AEO 2kg, lauryl sodium sulfate 0.5kg, starch 1kg, ammonium sulfate 25kg, ammonium dihydrogen phosphate (ADP) 10kg, kaolin 15kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 0.6% Rynaxypyr granular insecticide.
Embodiment 3
1.5% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 0.5kg, desinsection list 1kg, chitin 1.5kg, naphthalenesulfonate formaldehyde condensation compound 2.5kg, lauryl sodium sulfate 0.5kg, starch 5kg, ammonium sulfate 15kg, calcium sulphate 10kg, kaolin 20kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 1.5% Rynaxypyr granular insecticide.
Embodiment 4
2% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 1kg, desinsection list 1kg, chitin 1.5kg, AEO 3kg, naphthalenesulfonate formaldehyde condensation compound 2kg, sucrose 5kg, carboxymethyl cellulose 2kg, bentonite 15kg, urea 10kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 2% Rynaxypyr granular insecticide.
Embodiment 5
3% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 0.5kg, desinsection list 2.5kg, chitin 2kg, sodium butylnaphthalenesulfonate 2kg, naphthalenesulfonate formaldehyde condensation compound 2kg, sucrose 5kg, carboxymethyl cellulose 2kg, white carbon black 3kg, diatomite 15kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 3% Rynaxypyr granular insecticide.
Embodiment 6
1.2% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 0.6kg, desinsection list 0.6kg, chitin 3.8kg, dioctyl sodium sulfosuccinate 2kg, naphthalenesulfonate formaldehyde condensation compound 2kg, sucrose 5kg, carboxymethyl cellulose 1kg, calcium carbonate 10kg, ammonium chloride 20kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 1.2% Rynaxypyr granular insecticide.
Embodiment 7
2.5% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 2kg, desinsection list 0.5kg, chitin 2.5kg, sodium butylnaphthalenesulfonate 3kg, naphthalenesulfonate formaldehyde condensation compound 2kg, sucrose 5kg, carboxymethyl cellulose 2kg, bentonite 15kg, urea 15kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 2.5% Rynaxypyr granular insecticide.
Embodiment 8
4.5% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 0.2kg, desinsection list 4.3kg, chitin 1.5kg, AEO 3kg, AEO 5kg, sucrose 5kg, carboxymethyl cellulose 2kg, ammonium sulfate 15kg, flyash 12kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 4.5% Rynaxypyr granular insecticide.
Embodiment 9
6.5% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 0.5kg, desinsection list 6kg, chitin 1.5kg, dioctyl sodium sulfosuccinate 3kg; Sodium lignin sulfonate 7kg, AEO 5kg, polyvinyl alcohol 5kg, starch 5kg; Carclazyte 3kg, calcium dihydrogen phosphate 10kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 6.5% Rynaxypyr granular insecticide.
Embodiment 10
5% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 2kg, desinsection list 3kg, chitin 5kg, sodium lignin sulfonate 6kg; AEO 4kg, sodium butylnaphthalenesulfonate 5kg, carboxymethyl cellulose 3kg, starch 5kg; Potassium sulphate 15kg, calcium dihydrogen phosphate 10kg, diatomite complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 5% Rynaxypyr granular insecticide.
Embodiment 11
11% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 1kg, desinsection list 10kg, chitin 4kg, calcium lignosulfonate 5kg, AEO 3kg, polyvinyl alcohol 5kg, starch 5kg, kaolin 15kg, talcum powder 5kg, cinder complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 11% Rynaxypyr granular insecticide.
Embodiment 12
7.5% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 1.5kg, desinsection list 6kg, chitin 10kg, calcium lignosulfonate 3kg, AEO 4kg, polyvinyl alcohol 2kg, starch 6kg, potassium sulphate 10kg, active carbon 10kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 7.5% Rynaxypyr granular insecticide.
Embodiment 13
20% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 5kg, desinsection list 15kg, chitin 5kg, calcium lignosulfonate 4kg, AEO 5kg, polyvinyl alcohol 6kg, sucrose 3kg, kaolin 15kg, calcium carbonate 8kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 20% Rynaxypyr granular insecticide.
Embodiment 14
5.1% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 5kg, desinsection list 0.1kg, chitin 10kg, calcium lignosulfonate 3kg, sodium butylnaphthalenesulfonate 4kg, carboxymethyl cellulose 3kg, sucrose 6kg, kaolin 10kg, urea 15kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 5.1% Rynaxypyr granular insecticide.
Embodiment 15
13% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 3kg, desinsection list 10kg, chitin 0.1kg, calcium lignosulfonate 5kg, AEO 3kg, polyvinyl alcohol 3kg, sucrose 5kg, kaolin 10kg, potassium dihydrogen phosphate 15kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 13% Rynaxypyr granular insecticide.
Embodiment 16
15.01% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 0.01kg, desinsection list 15kg, chitin 10kg, calcium lignosulfonate 5kg, sodium butylnaphthalenesulfonate 5kg, polyvinyl alcohol 6kg, starch 4kg, bentonite 10kg, calcium carbonate 10kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 15.01% Rynaxypyr granular insecticide.
Embodiment 17
16% Rynaxypyr granular insecticide
Prescription: Rynaxypyr 1kg, desinsection list 15kg, chitin 10kg, sodium butylnaphthalenesulfonate 5kg, dioctyl sodium sulfosuccinate 2kg, carboxymethyl cellulose 3kg, sucrose 6kg, kaolin 15kg, sodium sulphate 5kg, river sand complements to 100kg.
Above-mentioned recipe ingredient is mixed, pulverize, stir after adding water-wet, use the screw extruder pelletizer granulation again, sieve after the drying and promptly get 16% Rynaxypyr granular insecticide.
Invention application implementation example 1
Carry out the control of peanut grub and peanut aphid with embodiment 1-9 products obtained therefrom,, will test to handle being provided with as follows according to the product estimated cost:
Handle 1:0.11% Rynaxypyr desinsection list (0.01:0.1) granule 75kg/ mu.
Handle 2:0.6% Rynaxypyr desinsection list (0.1:0.5) granule 10kg/ mu.
Handle 3:1.5% Rynaxypyr desinsection list (0.5:1) granule 2kg/ mu.
Handle 4:2% Rynaxypyr desinsection list (1:1) granule 1kg/ mu.
Handle 5:3% Rynaxypyr desinsection list (0.5:2.5) granule 2kg/ mu.
Handle 6:1.2% Rynaxypyr desinsection list (0.6:0.6) granule 1.6kg/ mu.
Handle 7:2.5% Rynaxypyr desinsection list (2:0.5) granule 0.6kg/ mu.
Handle 8:4.5% Rynaxypyr desinsection list (0.2:4.3) granule 3.3kg/ mu.
Handle 9:6.5% Rynaxypyr desinsection list (0.5:6) granule 1.8kg/ mu.
Handle 10:0.25% Rynaxypyr granule 5kg/ mu.
Handle 11:10% granular insecticide 5kg/ mu.
Handle 12: blank.
Above-mentioned processing is used when peanut seeding; Wherein, Handle 3-handle 9 sneak into sandy soil 3kg, 4kg, 3kg, 3.4kg, 4.4kg, 1.7kg, 3.2kg respectively and stir after use again; 30 days " Invest, Then Investigate " peanut aphids situation that causes harm is gathered in the crops after 100 days and is carried out the investigation of peanut grub insect population number and peanut yield is measured, and final statistics is as shown in the table:
It is thus clear that under the approaching prerequisite of use cost, embodiment 1-9 products obtained therefrom is aspect control peanut aphid and peanut grub, all obviously only the preventive effect of time spent is high than Rynaxypyr, desinsection for preventive effect, and the lasting period is long, and can make the peanut yield growth more than 20%.
Invention application implementation example 2
Carry out the control of sugarcane moth borer with embodiment 10-17 products obtained therefrom,, will test to handle being provided with as follows according to the product estimated cost:
Handle 1:5% Rynaxypyr desinsection list (2:3) granule 0.5kg/ mu.
Handle 2:11% Rynaxypyr desinsection list (1:10) granule 0.8kg/ mu.
Handle 3:7.5% Rynaxypyr desinsection list (1.5:6) granule 0.6kg/ mu.
Handle 4:20% Rynaxypyr desinsection list (5:15) granule 0.2kg/ mu.
Handle 5:5.1% Rynaxypyr desinsection list (5:0.1) granule 0.2kg/ mu.
Handle 6:13% Rynaxypyr desinsection list (3:10) granule 0.4kg/ mu.
Handle 7:15.01% Rynaxypyr desinsection list (0.01: 15) granule 1.5kg/ mu.
Handle 8:16% Rynaxypyr desinsection list (1:15) granule 0.7kg/ mu.
Handle 9:0.25% Rynaxypyr granule 5kg/ mu.
Handle 10:10% granular insecticide 5kg/ mu.
Handle 11: blank.
Above-mentioned processing is used when sugarcane is sowed; Wherein, Handle 1-handle 8 sneak into sandy soil 4.5kg, 4.2kg, 4.4kg, 4.8kg, 4.8kg, 4.6kg, 3.5kg, 4.3kg respectively and stir after use again; Carried out the sugarcane moth borer condition survey of causing harm behind the medicine in 60 days, 90 days respectively, carry out determination of yield during the sugarcane harvesting, final statistics is as shown in the table:
It is thus clear that under the approaching prerequisite of use cost, obviously only the preventive effect of time spent is high than Rynaxypyr, desinsection to the preventive effect of sugarcane moth borer for embodiment 10-18 products obtained therefrom, the lasting period is long, and can make the sugarcane yield growth more than 30%.
Rynaxypyr and desinsection list and be mixed to the test of the Toxicity Determination of corn borer:
Test with Rynaxypyr, two kinds of single agent of desinsection list as the contrast medicament, and according to No. 5, No. 1-mixture of following ratio preparation mixture:
No. 1, mixture: Rynaxypyr: desinsection list=1:1500
No. 2, mixture: Rynaxypyr: desinsection list=1:20
No. 3, mixture: Rynaxypyr: desinsection list=1:1
No. 4, mixture: Rynaxypyr: desinsection list=4:1
No. 5, mixture: Rynaxypyr: desinsection list=50:1
Test is the examination worm with the corn borer, and blank is set, and adopts dip method to carry out toxicity test and do statistical analysis Rynaxypyr, desinsection list and above-mentioned 5 mixtures, and final statistics is as shown in the table:
Toxicity Determination result shows, Rynaxypyr and desinsection individual palpation are mixed co-toxicity coefficient to corn borer all greater than 120 according to above-mentioned 5 different ratios, explains that this Rynaxypyr and desinsection list are mixed and have synergistic function.
Claims (4)
1. the granule of chloride worm benzamide and desinsection list is made up of active ingredient, auxiliary agent, binding agent, carrier, it is characterized in that; The granule prescription is made up of following components in weight percentage: Rynaxypyr 0.01%～5%; Desinsection list 0.1%～15%, chitin 0.1%～10%, auxiliary agent 1%～15%; Binding agent 0.5%～10%, carrier complements to 100%.
2. the granule of chloride worm benzamide according to claim 1 and desinsection list; It is characterized in that described auxiliary agent is one or more combinations in lauryl sodium sulfate, calcium lignosulfonate, sodium lignin sulfonate, naphthalenesulfonate formaldehyde condensation compound, sodium butylnaphthalenesulfonate, AEO, the dioctyl sodium sulfosuccinate.
3. the granule of chloride worm benzamide according to claim 1 and 2 and desinsection list is characterized in that, described binding agent is one or more combinations in starch, sucrose, polyvinyl alcohol, the carboxymethyl cellulose.
4. the granule of chloride worm benzamide according to claim 1 and 2 and desinsection list; It is characterized in that described carrier is one or more combinations in white carbon black, diatomite, active carbon, carclazyte, kaolin, bentonite, calcium carbonate, urea, ammonium chloride, ammonium sulfate, potassium sulphate, sodium sulphate, calcium sulphate, potassium dihydrogen phosphate, ammonium dihydrogen phosphate (ADP), calcium dihydrogen phosphate, talcum powder, river sand, cinder, the flyash.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012102754555A CN102763655A (en) | 2012-08-03 | 2012-08-03 | Granule containing chlorantraniliprole and monosultap |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2012102754555A CN102763655A (en) | 2012-08-03 | 2012-08-03 | Granule containing chlorantraniliprole and monosultap |
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Cited By (8)
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| CN103766332A (en) * | 2014-01-26 | 2014-05-07 | 江苏艾津农化有限责任公司 | Novel environment-friendly oncomelania killing granule capable of being sprayed and preparation method thereof |
| CN105494325A (en) * | 2015-12-11 | 2016-04-20 | 江苏仁信作物保护技术有限公司 | Application of coal ash serving as pesticide granule filler |
| CN106489949A (en) * | 2016-08-31 | 2017-03-15 | 江苏天容集团股份有限公司 | Containing chlorantraniliprole Pesticidal combination |
| CN107540447A (en) * | 2017-09-13 | 2018-01-05 | 福建农林大学 | A kind of medicine fertilizer of containing chlorantraniliprole and dimehypo and preparation method thereof |
| CN107827624A (en) * | 2017-12-20 | 2018-03-23 | 青岛住商中农肥料有限公司 | A kind of Synergistic slow release urea and its preparation technology |
| CN110250172A (en) * | 2019-08-05 | 2019-09-20 | 四川百事东旺生物科技有限公司 | A kind of bactericidal composition comprising kasugarnycin and polyoxin and its application |
| CN112500225A (en) * | 2020-12-14 | 2021-03-16 | 广西首控生物科技股份有限公司 | Pesticide fertilizer granules containing chlorantraniliprole and dinotefuran |
| CN113973829A (en) * | 2021-10-28 | 2022-01-28 | 河南好年景生物发展有限公司 | Sustained-release granule applied to corn leaves for preventing and treating spodoptera frugiperda |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103766332A (en) * | 2014-01-26 | 2014-05-07 | 江苏艾津农化有限责任公司 | Novel environment-friendly oncomelania killing granule capable of being sprayed and preparation method thereof |
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| CN107827624A (en) * | 2017-12-20 | 2018-03-23 | 青岛住商中农肥料有限公司 | A kind of Synergistic slow release urea and its preparation technology |
| CN110250172A (en) * | 2019-08-05 | 2019-09-20 | 四川百事东旺生物科技有限公司 | A kind of bactericidal composition comprising kasugarnycin and polyoxin and its application |
| CN112500225A (en) * | 2020-12-14 | 2021-03-16 | 广西首控生物科技股份有限公司 | Pesticide fertilizer granules containing chlorantraniliprole and dinotefuran |
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Application publication date: 20121107 |