CN105961417A - Composition with sterilizing and plant growth regulating functions as well as manufacturing method thereof - Google Patents

Composition with sterilizing and plant growth regulating functions as well as manufacturing method thereof Download PDF

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Publication number
CN105961417A
CN105961417A CN201610300435.7A CN201610300435A CN105961417A CN 105961417 A CN105961417 A CN 105961417A CN 201610300435 A CN201610300435 A CN 201610300435A CN 105961417 A CN105961417 A CN 105961417A
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China
Prior art keywords
plant
compositions
sodium
polyoxin
composition
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CN201610300435.7A
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Chinese (zh)
Inventor
郑建国
张祥栋
刘俊杰
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SHANDONG DONGXIN BIOLOGICAL PESTICIDES CO Ltd
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SHANDONG DONGXIN BIOLOGICAL PESTICIDES CO Ltd
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Priority to CN201610300435.7A priority Critical patent/CN105961417A/en
Publication of CN105961417A publication Critical patent/CN105961417A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18Nitro compounds
    • A01N33/20Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/12Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof
    • A01N41/08Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N61/00Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a composition with sterilizing and plant growth regulating functions. The composition is characterized in that the composition comprises the following components: ethylicin, polyoxin, a plant growth regulator, sodium lignosulfonate, sodium dodecanesulphonate, white carbon black, and kaolin; wherein the weight ratio of the components is as follows: 150-450:10-50:1-5:50-80:20-30:20:100-450. Ethylicin, polyoxin, and the plant growth regulator are mixed for the first time, other auxiliary materials are added in order to prepare wettable powder with usage convenience. The composition has obvious cooperative synergistic effects, and has obvious killing and preventing effects for soil borne diseases, such as fusarium wilt, verticillium wilt, gummy stem blight, and root rot, as well as diseases which occur together. The composition can improve and increase crop quality, and has obvious promotion effects for plant growth. The three kinds of effective components ethylicin, polyoxin, and the plant growth regulator are compounded, so that dosage is reduced, cost is reduced, and the composition is safe for environment. The composition is effective for soil borne diseases, and is effective for rice blast, watermelon gummy stem blight, apple alternaria leaf spot and a plurality of diseases.

Description

A kind of have sterilization, the compositions of plant regulatory function and manufacture method
Technical field
The present invention relates to composition pesticide, be exactly a kind of to there is sterilization, the compositions of plant regulatory function and system Make method.
Background technology
The agricultural antibiotic series bactericidal agent that S-Ethyl ethylthio sulfonate, polyoxin are important is the growth that can suppress various plants pathogen And breeding, and there is good systemic action and endosmosis effect, easily it is absorbed by plants, is easily decomposed by organism, to people, animal poison Property relatively low, residual hazard problem is little, free from environmental pollution, be suitable in No-harmful apple orchard application.
S-Ethyl ethylthio sulfonate mainly with preventing and treating Achlya spp, rice blast, cotton Seedling fall ill, cotton wilt, oilseed rape downy mildew, Ipomoea batatas Lam. black Pinta, purple spot of soybean, the late blight of potato etc..
Polyoxin is to wheat powdery mildew, Alternaria alternate, cucumber downy mildew, cucurbits fusarium wilt, black fleck disease of ginseng, Oryza sativa L. The multiple fungal diseases such as banded sclerotial blight, alternaria leaf spot of apple, grey mould fruit rot of strawberry, grape grey mould, forest spike top and Pear black spot There is good prevention effect.
Plant modifying agent, acts on wide, and application is many.Plant growth regulator is applicable to almost contain plant husbandry In all high and rudimentary plant, such as field crop, vegetable, fruit tree, flowers, forest, Thallus Laminariae (Thallus Eckloniae), Thallus Porphyrae, edible fungi etc., and lead to Cross regulation and control plant photosynthetic, breathe, material absorbing and operating, the physiology mistake such as signal conduction, stomatal movement, Osmoregulation, transpiration The regulation of journey and control the g and D of plant, improve the interaction of plant and environment, strengthen the anti-adversity ability of crop, carry The yield of high crop, can carry out double regulation and control, improve quality of agricultural product the External Characters of plant and internal physiological process.
In the practice of antibacterial application, by the antimicrobial combination with different model of action is used, and reasonably Collocation auxiliary agent, except improving the optimum period for applying fertilizer, expands outside the fungicidal spectrum of medicament, then can produce beyond thought effect.Kill as several Microbial inoculum compatibility uses, and is remarkably improved drug effect, even if when reducing dosage, equally reaching to prevent and treat purpose.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of has sterilization, the compositions of plant regulatory function, to Oryza sativa L. Rice blast, soil-borne disease is withered, Huang withers, blight dis-ease, root rot are effective, has growth regulation, production-increasing function simultaneously.
For solving above-mentioned technical problem, the present invention uses following technological means:
A kind of have sterilization, the compositions of plant regulatory function, it is characterised in that: including S-Ethyl ethylthio sulfonate, polyoxin, plant is adjusted Joint agent, sodium lignin sulfonate, dodecyl sodium sulfate, White Carbon black, Kaolin, the weight ratio of said components is: 150~450:10 ~50:1~5:50~80:20~30:20:100~450.
Compared with prior art, its superiority performance:
(1) present invention is for the first time S-Ethyl ethylthio sulfonate, polyoxin, plant modifying agent mixture, makes wettable by increasing other adjuvants Property powder, easy to use.
(2) this combination synergistic function is obvious, withers soil-borne disease, and Huang withers, blight dis-ease.Root rot, and mixed Sexually transmitted disease (STD) evil is killed, and preventive effect highlights.
(3) crop quality can be improved, plant growing is had obvious facilitation.
(4) S-Ethyl ethylthio sulfonate of the present invention, polyoxin, three kinds of effective ingredient of plant modifying agent compound, and dosage reduces, and reduces into This, environmentally safe.
(5) this combination is not only effective to soil-borne disease, and to multiple diseases such as rice blast, banded sclerotial blight, capsicum epidemic diseases Evil is effectively.
As preferably, the present invention further technical scheme is:
A kind of have sterilization, the compositions of plant regulatory function, also includes that sodium tripolyphosphate, solubility are formed sediment in described compositions Powder;S-Ethyl ethylthio sulfonate, polyoxin, plant modifying agent, sodium lignin sulfonate, sodium tripolyphosphate, dodecyl sodium sulfate, solubility are formed sediment Powder, White Carbon black, kaolinic weight ratio be: 150:10:4:50:15:20:100:20:450;Described plant modifying agent is amine Fresh ester.
A kind of have sterilization, the compositions of plant regulatory function, also includes sodium tripolyphosphate, dispersion in described compositions Agent NNO;S-Ethyl ethylthio sulfonate, polyoxin, plant modifying agent, sodium lignin sulfonate, sodium tripolyphosphate, dodecyl sodium sulfate, NNO, White Carbon black, kaolinic weight ratio be: 300:30:3:60:20:25:30:20:333.
A kind of have sterilization, the compositions of plant regulatory function, also includes sodium tripolyphosphate, multiple nitre in described compositions Phenol sodium, SAS, Gypsum Fibrosum;S-Ethyl ethylthio sulfonate, polyoxin, compound sodium nitrophenolate, plant modifying agent, sodium lignin sulfonate, trimerization Sodium phosphate, dodecyl sodium sulfate, SAS, White Carbon black, Gypsum Fibrosum, kaolinic weight ratio be: 450:50:4:1: 80:30:30:20:200:35:100, described plant modifying agent is naphthalene acetic acid.
A kind of have sterilization, the compositions of plant regulatory function, also includes humic acids, described corruption in described compositions Phytic acid is 5~10:1 with the weight ratio of plant modifying agent.
A kind of make the method that right to have the compositions of sterilization, plant regulatory function, comprise the steps of
(1) S-Ethyl ethylthio sulfonate and white carbon first mix, then add polyoxin, regulator, then add other auxiliary agent and filler is agitated all Even mixing;
(2) the mixture jet mill that (1) obtains is pulverized;
(3) by the powder test package obtained by (2).
Detailed description of the invention
Below in conjunction with embodiment, further illustrate the present invention.
A kind of have sterilization, the compositions of plant regulatory function, including S-Ethyl ethylthio sulfonate, polyoxin, plant modifying agent, wooden Element sodium sulfonate, dodecyl sodium sulfate, White Carbon black, Kaolin, the weight ratio of said components is: 150~450:10~50:1~ 5:50~80:20~30:20:100~450.
Embodiment 1
A kind of have sterilization, the compositions of plant regulatory function, in compositions, S-Ethyl ethylthio sulfonate, polyoxin, plant modifying agent, wood Quality sodium sulfonate, sodium tripolyphosphate, dodecyl sodium sulfate, soluble starch, White Carbon black, kaolinic weight ratio be: 150: 10:4:50:15:20:100:20:450;Described plant modifying agent is diethyl aminoethyl hexanoate.
Embodiment 2
A kind of have sterilization, the compositions of plant regulatory function, S-Ethyl ethylthio sulfonate, polyoxin, plant modifying agent, lignin sulfonic acid Sodium, sodium tripolyphosphate, dodecyl sodium sulfate, NNO, White Carbon black, kaolinic weight ratio be: 300:30:3:60:20:25: 30:20:333.
Embodiment 3
A kind of have sterilization, the compositions of plant regulatory function, S-Ethyl ethylthio sulfonate, polyoxin, compound sodium nitrophenolate, plant modifying agent, wood Quality sodium sulfonate, sodium tripolyphosphate, dodecyl sodium sulfate, SAS, White Carbon black, Gypsum Fibrosum, kaolinic weight ratio For: 450:50:4:1:80:30:30:20:200:35:100, described plant modifying agent is naphthalene acetic acid.
Embodiment 4-6 be other constituent contents identical with the constituent content of embodiment 1-3 on the basis of be separately added into corruption Phytic acid, described humic acids is 5:1 with the weight ratio of plant modifying agent, 8:1,10:1.
Above-described embodiment experiment effect is as follows:
Test 1 greenhouse pot culture test, rice blast
Temperature indoor cultivation Oryza sativa L. 2-3 leaf phase seedling, each medicament carries out spraying treatment by design concentration to blade, and chemicals treatment 24 is little Time after, inoculation test pathogen, carries out moisturizing cultivation at a temperature of 23 degree, carries out result investigation after blank is fully fallen ill, Calculate medicament EC EC50 by log concentration-preventive effect probit value method, use the abundant method of Sun Yun to calculate co-toxicity coefficient further, Result shows,
Example 1, this compositions of the concentration of 16%, EC50 is 0.6541, and AT1 is 141.05, and TT1 is that 98.21. co-toxicity coefficient is 143.62, more than 100, represent that this mixture has potentiation.Example 2, this compositions of the concentration of 16%, EC50 is 0.6341, AT1 is 142.05, TT1 be 97.15. co-toxicity coefficient be 146.21, more than 100, represent that this mixture has potentiation.Example 3, This compositions of the concentration of 16%, EC50 is 0.5941, and AT1 is 143.05, TT1 be 96.37. co-toxicity coefficient be 148.44, be more than 100, represent that this mixture has potentiation.Example 4, this compositions of the concentration of 16%, EC50 is 0.5439, and AT1 is 142.16, TT1 be 94.37. co-toxicity coefficient be 150.64, more than 100, represent that this mixture has potentiation.
Experiment 2
BIOLOGICAL ACTIVITY EXAMPLES-cotton wilt
Use biomass growth rate method, reagent agent is diluted to design concentration, take 1 milliliter and inject in culture dish, add 9 millis Rise PSA culture medium, making ultimate density after shaking up is 5.0,2.5,1.25,0.625,0.3125(ug.ml) pastille flat board, with Add 1 milliliter of aquesterilisa and do blank.Supply examination flora outer rim to beat with 4 millimeters of card punch edges of diameter to take bacterium dish, place pastille and put down In plate, 24 degree of dark culturing 72 hours, measure each process bacterium dish extension diameter, calculate thalli growth suppression ratio, by log concentration- Suppression ratio value method calculates medicament EC EC50, uses the abundant method of Sun Yun to calculate co-toxicity coefficient further, and result shows:
Embodiment 1, this compositions of the concentration of 28%, EC50 is 0.2215, and AT1 is 214.62, and TT1 is 117.21, co-toxicity coefficient It is 183.11, more than 100, represents that this mixture has potentiation.
Embodiment 2, this compositions of the concentration of 28%, EC50 is 0.2519, and AT1 is 218.58, and TT1 is 118.39, altogether poison Coefficient is 184.63, more than 100, represents that this mixture has potentiation.
Embodiment 3, this compositions of the concentration of 28%, EC50 is 0.2157, and AT1 is 224.61, and TT1 is 120.44, altogether poison Coefficient is 186.49, more than 100, represents that this mixture has potentiation.
Embodiment 5, this compositions of the concentration of 28%, EC50 is 0.2157, and AT1 is 219.58, and TT1 is 116.49, altogether poison Coefficient is 188.49, more than 100, represents that this mixture has potentiation.
Test 3 field test examples
Reagent agent is each embodiment, and wherein contrast 1 is polyoxin, and contrast 2 is S-Ethyl ethylthio sulfonate, and embodiment 1-5 is this combination Thing;Kind and be experimental field Citrullus vulgaris (Henan), Oryza sativa L. (Hubei), Fructus Mali pumilae (Shandong) Cotton Gossypii (Shandong), in field, their early stage enters Row reagent spray processes, and experimental concentration is 750,500,250mg/l, is used in conjunction 7-10 days interval 3 times, investigation in 7 days after the 3rd time Prevention effect result of the test is as follows
Table 1: different pharmaceutical is to Oryza sativa L., the effect of cotton medicine
As shown in Table 1;The present embodiment 1-6 is superior to comparative example 1 or 2 to the effect of rice blast, cotton wilt.
Table 2: different pharmaceutical is to Citrullus vulgaris, the effect of Fructus Mali pumilae
As shown in Table 2, the present embodiment 1-6 is better than comparative example respectively to the effect of watermelon grafting, alternaria leaf spot of apple.
Experiment above be illustrative be not determinate, be several concrete instances.Protection scope of the present invention should be belonged to.
Compared with prior art, the superiority performance of the embodiment of the present invention:
(1) present invention is for the first time S-Ethyl ethylthio sulfonate, polyoxin, plant modifying agent mixture, makes wettable by increasing other adjuvants Property powder, easy to use.
(2) this combination synergistic function is obvious, remarkably productive.
(3) crop quality can be improved, plant growing is had obvious facilitation.
(4) S-Ethyl ethylthio sulfonate of the present invention, polyoxin, three kinds of effective ingredient of plant modifying agent compound, and dosage reduces, and reduces into This, environmentally safe.
(5) this combination is to rice blast, cotton wilt, spot defoliation, and the multiple diseases such as blight dis-ease is effective.
Owing to the foregoing is only the detailed description of the invention of the present invention, but the protection of the present invention is not limited to this, any skill The technical staff in art field it is contemplated that the change of equivalent of the technical program technical characteristic or replacement, all contain the present invention's Within protection domain.

Claims (6)

1. one kind has sterilization, the compositions of plant regulatory function, it is characterised in that: include S-Ethyl ethylthio sulfonate, polyoxin, plant Regulator, sodium lignin sulfonate, dodecyl sodium sulfate, White Carbon black, Kaolin, the weight ratio of said components is: 150~450: 10~50:1~5:50~80:20~30:20:100~450.
The most according to claim 1 have sterilization, the compositions of plant regulatory function, it is characterised in that described combination Thing also includes sodium tripolyphosphate, soluble starch;S-Ethyl ethylthio sulfonate, polyoxin, plant modifying agent, sodium lignin sulfonate, trimerization Sodium phosphate, dodecyl sodium sulfate, soluble starch, White Carbon black, kaolinic weight ratio be: 150:10:4:50:15:20: 100:20:450;Described plant modifying agent is diethyl aminoethyl hexanoate.
The most according to claim 1 have sterilization, the compositions of plant regulatory function, it is characterised in that described combination Thing also includes sodium tripolyphosphate, dispersant NNO;S-Ethyl ethylthio sulfonate, polyoxin, plant modifying agent, sodium lignin sulfonate, trimerization phosphorus Acid sodium, dodecyl sodium sulfate, NNO, White Carbon black, kaolinic weight ratio be: 300:30:3:60:20:25:30:20:333.
The most according to claim 1, described have sterilization, the compositions of plant regulatory function, it is characterised in that described Compositions also includes sodium tripolyphosphate, compound sodium nitrophenolate, SAS, Gypsum Fibrosum;S-Ethyl ethylthio sulfonate, polyoxin, compound sodium nitrophenolate, Plant modifying agent, sodium lignin sulfonate, sodium tripolyphosphate, dodecyl sodium sulfate, SAS, White Carbon black, Gypsum Fibrosum, height The weight ratio of ridge soil is: 450:50:4:1:80:30:30:20:200:35:100, described plant modifying agent is naphthalene acetic acid.
5. according to described in claim 1-4 any claim, there is sterilization, the compositions of plant regulatory function, its feature It is, described compositions also including, humic acids, described humic acids are 5~10:1 with the weight ratio of plant modifying agent.
6. one kind makes right and wants the side of the compositions with sterilization, plant regulatory function described in 1-4 any claim Method, it is characterised in that comprise the steps of
(1) S-Ethyl ethylthio sulfonate and white carbon first mix, then add polyoxin, regulator, then add other auxiliary agent and filler is agitated all Even mixing;
(2) the mixture jet mill that (1) obtains is pulverized;
(3) by the powder test package obtained by (2).
CN201610300435.7A 2016-05-06 2016-05-06 Composition with sterilizing and plant growth regulating functions as well as manufacturing method thereof Pending CN105961417A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110896952A (en) * 2019-12-10 2020-03-24 广西大学 Medicament composition for breaking cherry dormancy
CN115024332A (en) * 2022-05-20 2022-09-09 衡阳市蔬菜研究所 Pesticide composition for preventing and treating pepper anthracnose

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1174658A (en) * 1996-08-27 1998-03-04 张长兴 Compound broad spectrum pesticide
CN1461589A (en) * 2002-05-26 2003-12-17 汪建利 Composition of ethylicin and plant growth regulator
CN101015296A (en) * 2006-12-12 2007-08-15 辽宁师范大学 Garden plant growth regulator and preparing method thereof
CN101796955A (en) * 2009-12-31 2010-08-11 青岛星牌作物科学有限公司 Composite bactericidal composite and applications thereof
CN102113504A (en) * 2010-01-05 2011-07-06 海南正业中农高科股份有限公司 Sterilization composite containing polyoxin and prochloraz

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1174658A (en) * 1996-08-27 1998-03-04 张长兴 Compound broad spectrum pesticide
CN1461589A (en) * 2002-05-26 2003-12-17 汪建利 Composition of ethylicin and plant growth regulator
CN101015296A (en) * 2006-12-12 2007-08-15 辽宁师范大学 Garden plant growth regulator and preparing method thereof
CN101796955A (en) * 2009-12-31 2010-08-11 青岛星牌作物科学有限公司 Composite bactericidal composite and applications thereof
CN102113504A (en) * 2010-01-05 2011-07-06 海南正业中农高科股份有限公司 Sterilization composite containing polyoxin and prochloraz

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110896952A (en) * 2019-12-10 2020-03-24 广西大学 Medicament composition for breaking cherry dormancy
CN115024332A (en) * 2022-05-20 2022-09-09 衡阳市蔬菜研究所 Pesticide composition for preventing and treating pepper anthracnose

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