CN102119689A - Bactericidal composition containing fluazinam and azoxystrobin and application of same - Google Patents
Bactericidal composition containing fluazinam and azoxystrobin and application of same Download PDFInfo
- Publication number
- CN102119689A CN102119689A CN2010100176176A CN201010017617A CN102119689A CN 102119689 A CN102119689 A CN 102119689A CN 2010100176176 A CN2010100176176 A CN 2010100176176A CN 201010017617 A CN201010017617 A CN 201010017617A CN 102119689 A CN102119689 A CN 102119689A
- Authority
- CN
- China
- Prior art keywords
- fluazinam
- fluoxastrobin
- composition
- bactericidal composition
- bactericide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of farm chemicals and discloses a bactericidal composition containing fluazinam and azoxystrobin and the application of the same. The fluazinam and the azoxystrobin serve as effective components of the composition, wherein the total content of the fluazinam and the azoxystrobin in mass percentage is 1% to 80%, and the mass ratio of the fluazinam to the azoxystrobin is 50:1 to 1:30. The composition can be used for the preparation of a bactericide for preventing and treating diseases such as rice blast, pestilence, anthracnose, leaf mold, scab and the like caused by fungi and other pathogens of cereal crops, vegetable and fruit trees, and has the advantages of wide application range, low cost and good effect.
Description
Technical field
The invention belongs to the agriculture chemicals fungicide field, relate to a kind of bactericidal composition and uses thereof, be specifically related to a kind of bactericidal composition and application thereof that contains fluazinam and Fluoxastrobin.
Background technology
It is many-sided that plant disease causes economic loss.At first, concerning the producer,, cause income to reduce because disease causes crop yield minimizing and product quality reduction; Owing to spraying insecticide or otherwise expenses for prevention and control increases production cost; Sometimes have to plant disease-resistant but kind that output is not high or replant the low crop species of other economic benefits; Influence preceding owing to results to the fruits and vegetables product or the duration of storage disease has to sell off at a low price when product goes on the market in a large number, or increases fresh-keeping expense for adjusting selling period.Secondly, concerning the consumer,, they have been increased live spending or minimizing consumption figure or buy substandard products or substitute, influenced quality of life because the disease underproduction causes agricultural product constantly to appreciate; For the intermediate consumer who comes other commodity of processing with agricultural product, agricultural product price goes up can be increased production cost or influence the end product quality, tends to the expense of increase is imputed on one's body the ultimate consumer as the producer's intermediate consumer.The 3rd, to the influence of national economy: estimate that according to FAO (Food and Agriculture Organization of the United Nation) average loss was about 10%～15% of gross yield after plant suffered disease.
Fluazinam belongs to 2, and the 6-dinitroanilines is a protective fungicide, is mitochondria phosphorous oxide acidylate uncoupler.Suppress the course of infection in all stages by suppressing spore germination, mycelia breakthrough, growth and sporulation.The fungicidal spectrum of fluazinam is very wide, and its effect is better than the GPF (General Protection False bactericide.Interlink spore genus, Botrytis, Phytophthora, single shaft Pseudomonas, Sclerotinia and Venturia there are special efficacy, the Botrytis cinerea of anti-benzimidazole type and dicarboximide series bactericidal agent are belonged to good effect is also arranged.This medicine also has the effect that resistance of rainwater washing against, lasting period are long, have good control phytophagous mites concurrently in addition, and the club root of crucifer is also had remarkable preventive effect, and the microbial paddy rice damping off of friendly head mold is also had good control efficiency.
In China, because fluazinam import price height, being confined on the high part crops of economic value added of usable floor area, it is less to use area, can not use in the crop pests control widely, and this bactericide also exists the bigger defective of toxicity.
Fluoxastrobin belongs to methoxy acrylic bactericide, have efficient, wide spectrum, nearly all mycota (Ascomycotina, Basidiomycotina, Mastigomycotina and Deuteromycotina) disease such as powdery mildew, rust, glume blight, net blotch, downy mildew, rice blast etc. are all had good activity.Can be used for cauline leaf spraying, seed treatment, be mainly used in crops such as cereal, paddy rice, peanut, grape, potato, fruit tree, vegetables, coffee, lawn, have good crop safety and very outstanding Environmental compatibility.Under the condition of present long-term prescription, evil bacterium pesticide resistance increases gradually, and the agent of agricultural chemicals list descends gradually to the effect of evil bacterium control.
Agriculture chemical compounding can obviously improve drug effect, and delays the generation of evil bacterium resistance.Still find no the bactericidal composition that closes fluazinam and Fluoxastrobin up to now.
Summary of the invention
The objective of the invention is at the problems referred to above, a kind of applied widely, bactericidal composition that contains fluazinam and Fluoxastrobin that cost is low, effective is provided.
Another object of the present invention provides the application of said composition in the bactericide of preparation control corps diseases.
A kind of microbicide compositions, with fluazinam and Fluoxastrobin is main active ingredient, wherein the gross mass percentage composition of fluazinam and Fluoxastrobin is 1%～80%, preferred 5%～60%, the mass ratio of fluazinam and Fluoxastrobin is 50: 1～1: 30, be preferably 30: 1～1: 20, preferred especially 20: 1～1: 10.
This bactericidal composition can become any one formulation that allows on the agricultural chemicals, the preferred suspending agent of described formulation, dry suspending agent, suspension seed-coating agent, wetting powder, pulvis, water dispersion granule, aqueous emulsion etc. with Fluoxastrobin by fluazinam with known additive compound.These known auxiliary agents are dispersant commonly used on the agricultural chemicals, diffusant, defoamer, wetting agent, disintegrant etc.
Bactericidal composition provided by the invention can be used for preparing the bactericide of preventing and treating corps diseases, be preferred for preparing the bactericide of the disease that control and cereal, vegetables or fruit tree crop cause by fungi and other pathogene, further be preferred for preparation control rice blast, banded sclerotial blight, wheat sharp eyespot, rust, powdery mildew of cucumber, downy mildew, tomato blight, grape powdery mildew, mango anthracnose, the bactericide of pear scab most preferably is used to prepare the bactericide of preventing and treating rice blast, powdery mildew of cucumber, mango anthracnose or pear scab.
Beneficial effect of the present invention:
1, the used fluazinam of the present invention is the pyridines bactericide, and Fluoxastrobin is a methoxy acrylic bactericide, and being mixed mutually can not produce conflict, can produce obvious role in synergism, can reduce dosage when using, and reduces cost.
2, the present composition has enlarged fungicidal spectrum and has widened dispenser period, has preferable antibacterial and sterilization double effects, has overcome the deficiency of a certain composition of single use, has avoided plant disease to produce the risk of resistance.
Embodiment
Embodiment 1:60% fluazinam Fluoxastrobin suspending agent
Fluazinam 45kg
Fluoxastrobin 15kg
Alkylphenol-polyethenoxy base phosphate 6kg
Organosilicon breast defoamer 0.2kg
Xanthans 0.3kg
Water complements to 100kg
The above-mentioned composition that respectively measures is mixed the back by the stirring of one-level sand mill, behind the secondary sand mill sand milling, in modulation kettle, allocate, measure packing after inspection by sampling is qualified and both got the suspending agent formulation products.
Embodiment 2:45% fluazinam Fluoxastrobin dry suspending agent
Fluazinam 35kg
Fluoxastrobin 10kg
Sodium lignin sulfonate 8kg
Sodium phosphate trimer 3kg
Ammonium sulfate 12kg
Kaolin complements to 100kg
With various compositions mix all with, pulverizing after, mix suitable water spray granulating and drying and get the dry suspending agent formulation products.
Embodiment 3:5% fluazinam Fluoxastrobin suspension seed-coating agent
Fluazinam 4kg
Fluoxastrobin 1kg
Aliphatic alcohol polyoxyvinethene phosphate class 5kg
Bentonite 2kg
Xanthans 0.3kg
Ethylene glycol 5kg
Polyvinyl alcohol blending modification film forming agent 0.2kg
Pigment 0.2kg
Water complements to 100kg
Active component in above-mentioned, bentonite, emulsifier and part water fully mixed stirs the back sand milling, in modulation kettle, add successively then film forming agent, thickener, antifreezing agent and excess water fully mix after both the suspension seed-coating agent formulation products.
Embodiment 4:10% fluazinam Fluoxastrobin wetting powder
Fluazinam 4kg
Fluoxastrobin 6kg
Draw back powder 3kg
Naphthalene sulfonate 2kg
White carbon 5kg
Kaolin complements to 100kg
Above metering composition is mixed laggard promoting the circulation of qi stream pulverize, both got the wetting powder formulation products.
Embodiment 5:45% fluazinam azoxystrobin water emulsion
Fluazinam 30kg
Fluoxastrobin 15kg
Phosphoric acid esters wedding agents 3kg
Block polymerization ethers 2kg
Ethylene glycol 5kg
Water complements to 100kg
After dividing oil phase and water two parts to mix the above-mentioned metering composition, utilize high-shear homogenizer to stir, both the aqueous emulsion formulation products.
Embodiment 6:80% fluazinam Fluoxastrobin water dispersion granule
Fluazinam 40kg
Fluoxastrobin 40kg
Naphthalene sulfonate 6kg
Ammonium sulfate 4kg
Kaolin complements to 100kg
To add wetting dispersing agent after the active ingredient dissolving, filler is added in the back that stirs, and grinds the pressure granulation after the mixing, and oven dry had both got the water dispersion granule formulation products.
Embodiment 7:40% fluazinam Fluoxastrobin water dispersion granule
Fluazinam 10kg
Fluoxastrobin 30kg
Naphthalene sulfonate 6kg
Ammonium sulfate 4kg
Kaolin complements to 100kg
To add wetting dispersing agent after the active ingredient dissolving, filler is added in the back that stirs, and grinds the pressure granulation after the mixing, and oven dry had both got the water dispersion granule formulation products.
Embodiment 8:40% fluazinam Fluoxastrobin suspending agent
Fluazinam 25kg
Fluoxastrobin 15kg
Alkylphenol-polyethenoxy base phosphate 6kg
Organosilicon breast defoamer 0.2kg
Xanthans 0.3kg
Water complements to 100kg
The above-mentioned composition that respectively measures is mixed the back by the stirring of one-level sand mill, behind the secondary sand mill, in modulation kettle, allocate, measure packing after inspection by sampling is qualified and both got the suspending agent formulation products.
Embodiment 9:10% fluazinam Fluoxastrobin wetting powder
Fluazinam 1kg
Fluoxastrobin 9kg
Draw back powder 3kg
Naphthalene sulfonate 2kg
White carbon 5kg
Kaolin complements to 100kg
Above metering composition is mixed laggard promoting the circulation of qi stream pulverize, both got the wetting powder formulation products.
Embodiment 10:30% fluazinam Fluoxastrobin water dispersion granule
Fluazinam 5kg
Fluoxastrobin 25kg
Naphthalene sulfonate 5kg
Ammonium sulfate 3kg
Kaolin complements to 100kg
To add wetting dispersing agent after the active ingredient dissolving, filler is added in the back that stirs, and grinds the pressure granulation after the mixing, and oven dry had both got the water dispersion granule formulation products.
Embodiment 11:33% fluazinam Fluoxastrobin dry suspending agent
Fluazinam 30kg
Fluoxastrobin 3kg
Sodium lignin sulfonate 6kg
Sodium phosphate trimer 2kg
Ammonium sulfate 10kg
Kaolin complements to 100kg
With various compositions mix all with, pulverizing after, mix suitable water spray granulating and drying and get the dry suspending agent formulation products.
Embodiment 12:64% fluazinam azoxystrobin water emulsion
Fluazinam 60kg
Fluoxastrobin 4kg
Phosphoric acid esters wedding agents 5kg
Block polymerization ethers 3kg
Ethylene glycol 7kg
Water complements to 100kg
After dividing oil phase and water two parts to mix the above-mentioned metering composition, utilize high-shear homogenizer to stir, both the aqueous emulsion formulation products.
Embodiment 13:62% fluazinam Fluoxastrobin wetting powder
Fluazinam 60kg
Fluoxastrobin 2kg
Draw back powder 4kg
Naphthalene sulfonate 3kg
White carbon 6kg
Kaolin complements to 100kg
Above metering composition is mixed laggard promoting the circulation of qi stream pulverize, both got the wetting powder formulation products.
Application Example 1: prevent and treat the powdery mildew of cucumber experiment
1, be that indoor conventional screening is felt the powdery mildew kind with cucumber for studying thing.
2, test is handled: this test medicine consumption is provided with 5 concentration gradients according to the difference of composition, and the contrast medicament is fluazinam and Fluoxastrobin and the contrast of blank clear water.
3, test method: from the cucumber cotyledons phase, on the cucumber leaves that 2 true leaves are arranged, the spray medicine is handled after 24 hours with cucurbits powdery mildew bacterium spore suspension spray inoculation.Inspection method is calculated co-toxicity coefficient for statistics blade disease index.
4, result of the test sees Table 1:
Table 1
Laboratory test fluazinam and Fluoxastrobin are by the EC of 50: 1,30: 1,20: 1,1: 10,1: 20,1: 30 back each proportioning of mensuration that is mixed
50, calculate the co-toxicity coefficient of each proportioning mixture at last.The result shows that both are composite and has an obvious synergistic effect.
Application Example 2: the field trial of control rice blast
Test with the pesticidal preparations control rice blast that the foregoing description makes.
1, test is handled: this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, and the contrast medicament is respectively commercially available agricultural chemicals 25% Fluoxastrobin suspending agent (SC) and 50% fluazinam aqueous suspension agent SC and the test of blank clear water.
2, each sub-district area of test method is 66.7m
2, repeat 3 times; Inspection drug effect method before the dispenser after investigation and the control is: random sampling 5 points in the test treatment region, every 50 fringe is checked the rice blast occurrence degree.
3, result of the test sees Table:
Table 2
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable.
Consumption in the table 2 refers to the consumption of active ingredient in each preparation.Field efficacy is the result show, fluazinam and azoxystrobin composite have good control efficiency to rice blast, and control efficiency all is better than single agent kind.
Application example 3: prevent and treat the pear scab test.
1. test is handled: this test medicine consumption is the consumption of active ingredient, and different preparations are established three concentration of treatment respectively, and the contrast medicament is respectively commercially available agricultural chemicals 50% fluazinam suspending agent (SC) and 25% Fluoxastrobin suspending agent (SC) and the test of blank clear water.
2. test method: each sub-district 2 row, repeat 3 times; Inspection drug effect method before the dispenser after investigation and the control is: random sampling 5 points in the test treatment region, check the scab occurrence degree.
3. result of the test sees Table 3:
Table 3
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable.
Consumption in the table 3 refers to the consumption of active ingredient in each preparation.Field efficacy is the result show, fluazinam and azoxystrobin composite have good control efficiency to pear scab, and control efficiency all is better than single agent kind.
Application Example 4: biocontrol of mango anthracnose test
1. test is handled: this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, and the contrast medicament is respectively 25% Fluoxastrobin suspending agent SC, the fluazinam suspending agent SC of 500g/L and the test of blank clear water.
2. the inspection drug effect method after investigation and the control is before the test method dispenser: random sampling 5 points in the test treatment region, every 10 mango are checked mango anthracnose generation disease index, calculate preventive effect.
3. result of the test sees Table 4:
Table 4
| Handle medicament | Consumption (g a.i/L) | 3 days control rates | 7 days control rates | 14 days control rates |
| Example 1 | 0.3 | 67.4％～68.5％ | 76.4％～82.6％ | 72.4％～80.5％ |
| Example 3 | 0.3 | 69.6％～72.6％ | 76.4％～84.5％ | 78.4％～86.7％ |
| Example 4 | 0.3 | 68.3％～69.2％ | 77.6％～84..3％ | 80.4％～85.6％ |
| Example 5 | 0.3 | 64.3％～67.8％ | 74.2％～83.6％ | 81.4％～89.5％ |
| Example 8 | 0.3 | 66.3％～70.2％ | 75.8％～87.5％ | 81.6％～86.4％ |
| 25% Fluoxastrobin SC | 0.3 | 50.6％～58.9％ | 60.7％～64.3％ | 65.8％～69.9％ |
| 50% fluazinam SC | 0.3 | 42.7％～48.6％ | 49.7％～53.8％ | 55.4％～58.9％ |
Learn by above form, the composite bactericide that makes of Fluoxastrobin and fluazinam, its control efficiency will good far away and Fluoxastrobin and the agent of fluazinam list.
Claims (10)
1. a microbicide compositions is characterized in that said composition is an active ingredient with fluazinam and Fluoxastrobin, and wherein the mass ratio of fluazinam and Fluoxastrobin is 50: 1～1: 30.
2. bactericidal composition according to claim 1 is characterized in that the mass ratio of fluazinam and Fluoxastrobin is 35: 1～1: 20 in the described composition.
3. bactericidal composition according to claim 2 is characterized in that the mass ratio of fluazinam and Fluoxastrobin is 20: 1～1: 10 in the described composition.
4. according to claim 1,2 or 3 described bactericidal compositions, it is characterized in that the gross mass percentage composition of fluazinam and Fluoxastrobin is 1%～80% in the described composition.
5. bactericidal composition according to claim 1 is characterized in that the gross mass percentage composition of fluazinam and Fluoxastrobin is 5%～60% in the described composition.
6. bactericidal composition according to claim 1 is characterized in that described bactericidal composition becomes any one formulation that allows on the agricultural chemicals by fluazinam with Fluoxastrobin with known additive compound.
7. according to the described bactericidal composition of claim 6, it is characterized in that described formulation is suspending agent, dry suspending agent, suspension seed-coating agent, wetting powder, pulvis, aqueous emulsion, water dispersion granule.
8. the application of the described bactericidal composition of claim 1 in the bactericide of preparation control corps diseases.
9. the application of the described bactericidal composition of claim 1 in the bactericide of preparation control and cereal, vegetables or fruit tree crop disease.
10. the described bactericidal composition of claim 1 is in preparation control rice blast, banded sclerotial blight, wheat sharp eyespot, rust, powdery mildew of cucumber, downy mildew, tomato blight, grape powdery mildew, application in the bactericide of mango anthracnose or pear scab, the preferably application in the bactericide of preparation control rice blast, powdery mildew of cucumber, mango anthracnose or pear scab.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010017617 CN102119689B (en) | 2010-01-08 | 2010-01-08 | Bactericidal composition containing fluazinam and azoxystrobin and application of same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010017617 CN102119689B (en) | 2010-01-08 | 2010-01-08 | Bactericidal composition containing fluazinam and azoxystrobin and application of same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102119689A true CN102119689A (en) | 2011-07-13 |
| CN102119689B CN102119689B (en) | 2013-06-19 |
Family
ID=44248435
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010017617 Active CN102119689B (en) | 2010-01-08 | 2010-01-08 | Bactericidal composition containing fluazinam and azoxystrobin and application of same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102119689B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101984817A (en) * | 2010-07-15 | 2011-03-16 | 江阴苏利科技有限公司 | Bactericidal composition containing azoxystrobin and fluazinam and use thereof |
| WO2014029697A1 (en) * | 2012-08-22 | 2014-02-27 | Basf Se | Fungicidal ternary mixtures comprising fluazinam |
| CN111685120A (en) * | 2020-06-29 | 2020-09-22 | 广西南亚热带农业科学研究所 | Method for preventing and controlling seedling stage diseases of elaeagnus pungens |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101087523A (en) * | 2004-12-23 | 2007-12-12 | 巴斯福股份公司 | Fungicidal mixtures |
| WO2009068195A2 (en) * | 2007-11-29 | 2009-06-04 | Bayer Cropscience Ag | Method for reducing mycotoxin contamination in maize |
-
2010
- 2010-01-08 CN CN 201010017617 patent/CN102119689B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101087523A (en) * | 2004-12-23 | 2007-12-12 | 巴斯福股份公司 | Fungicidal mixtures |
| WO2009068195A2 (en) * | 2007-11-29 | 2009-06-04 | Bayer Cropscience Ag | Method for reducing mycotoxin contamination in maize |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101984817A (en) * | 2010-07-15 | 2011-03-16 | 江阴苏利科技有限公司 | Bactericidal composition containing azoxystrobin and fluazinam and use thereof |
| CN101984817B (en) * | 2010-07-15 | 2013-06-05 | 江阴苏利化学股份有限公司 | Bactericidal composition containing azoxystrobin and fluazinam and use thereof |
| WO2014029697A1 (en) * | 2012-08-22 | 2014-02-27 | Basf Se | Fungicidal ternary mixtures comprising fluazinam |
| CN111685120A (en) * | 2020-06-29 | 2020-09-22 | 广西南亚热带农业科学研究所 | Method for preventing and controlling seedling stage diseases of elaeagnus pungens |
| CN111685120B (en) * | 2020-06-29 | 2021-10-26 | 广西南亚热带农业科学研究所 | Method for preventing and controlling seedling stage diseases of elaeagnus pungens |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102119689B (en) | 2013-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104839190B (en) | It is a kind of containing topramezone and the grand maize post-emergence compound herbicide of thiophene ketone sulphur | |
| CN104412981B (en) | A kind of bactericidal composition of fluorine-containing ether bacterium amide and methoxy acrylic | |
| CN102119689B (en) | Bactericidal composition containing fluazinam and azoxystrobin and application of same | |
| CN102119693B (en) | Synergetic antibacterial composition containing fluazinam and tebuconazole and use thereof | |
| CN104938491B (en) | A kind of composition pesticide for preventing and treating corn top-rotten disease | |
| CN102119691B (en) | Bactericidal composition containing fluazinam and difenoconazole and application of same | |
| CN101194620B (en) | Bactericide agent composition containing tebuconazole | |
| CN102119685B (en) | Bactericidal composition containing fluazinam and validamycin and application of same | |
| CN102119690B (en) | Bactericidal composition containing fluazinam and epoxiconazole and application of same | |
| CN103329905B (en) | Sterilization composition containing penflufen and validamycin | |
| CN102119683B (en) | Bactericidal composition containing fluazinam and kasugamycin and application thereof | |
| CN102119697B (en) | Synergistic bactericidal composition containing fluazinam and carbendazim and application thereof | |
| CN102119698A (en) | Bactericidal composition containing fluazinam and thiophanate methyl and application of same | |
| CN102119699B (en) | Bactericidal composition containing fluazinam and prochloraz and application thereof | |
| CN106135252A (en) | A kind of containing Boscalid and the bactericidal composition of prochloraz-manganese chloride complex and application | |
| CN102119688A (en) | Bactericidal composition containing fluazinam and cyprodinil and application of same | |
| CN105340944A (en) | Pesticide granule containing imidacloprid and azoxystrobin | |
| CN104488891A (en) | Powdery mildew control sterilization composition | |
| CN102119684B (en) | Bactericidal composition containing fluazinam and dimethachlon and application of same | |
| CN109400382A (en) | A kind of medicine fertilizer composition, preparation and its application | |
| CN102119700B (en) | Synergetic antibacterial composition containing fluazinam and iprobenfos and use thereof | |
| CN106431621A (en) | Rice seedling raising medical fertilizer | |
| CN106538604A (en) | A kind of bactericide containing isopyrazam | |
| CN105948896A (en) | Foliar fertilizer for wheat growth | |
| CN105475356A (en) | Pesticide composition containing propineb and prochloraz manganese |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |