CN101984817B - Bactericidal composition containing azoxystrobin and fluazinam and use thereof - Google Patents

Bactericidal composition containing azoxystrobin and fluazinam and use thereof Download PDF

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CN101984817B
CN101984817B CN 201010229488 CN201010229488A CN101984817B CN 101984817 B CN101984817 B CN 101984817B CN 201010229488 CN201010229488 CN 201010229488 CN 201010229488 A CN201010229488 A CN 201010229488A CN 101984817 B CN101984817 B CN 101984817B
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fluazinam
azoxystrobin
composition
use
present invention
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CN101984817A (en
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缪金凤
汪静莉
孙海峰
王丽霞
宋亚华
黄岳兴
孙磊
王立民
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江阴苏利化学股份有限公司
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Abstract

本发明涉及一种含有嘧菌酯和氟啶胺的杀菌组合物及其用途。 The present invention relates to a containing azoxystrobin and fluazinam fungicidal compositions and their use. 所述组合物含有嘧菌酯和氟啶胺,所述嘧菌酯和氟啶胺的重量比为2~45∶4~55。 The composition comprises azoxystrobin and fluazinam, azoxystrobin weight of fluazinam and the ratio of 2 ~ 55 ~ 45:4. 该组合物可应用于防治禾谷类作物、瓜果或蔬菜等作物病害防治。 The composition may be applied to the prevention of crop disease control cereal crops, fruits or vegetables. 该组合物适用范围广、效果好、成本低、残留低,对人、畜、环境等安全。 The composition of the wide range of applications, effective, low cost, low residual, people, animals and environment safety.

Description

一种含有嘧菌酯和氟啶胺的杀菌组合物及其用途(—)技术领域 BACKGROUND - containing composition and use germicidal azoxystrobin and fluazinam ()

[0001] 本发明涉及一种杀菌组合物及用途,尤其涉及一种含有嘧菌酯和氟啶胺的杀菌组合物及其用途。 [0001] The present invention relates to a germicidal composition and use, particularly to a fungicidal composition comprising and uses thereof azoxystrobin and fluazinam.

(二)背景技术 (B) Background Art

[0002] 近年来,由于单一用药及不科学用药,已经导致许多种作物病害对当前使用的农药产生了抗性,如白粉病、稻瘟病、灰霉病、炭疽病等,现已成为化学防治的难题之一。 [0002] In recent years, due to the single drug and scientific medicine has led to a wide variety of crop diseases pesticides currently in use have acquired resistance, such as powdery mildew, rice blast, gray mold, anthracnose, chemical control has become the one problem. 同时用药次数及用量的增加不仅加工了农民负担,又给粮食及环境安全造成了影响。 While increasing the number and amount of medication not only the processing burden on peasants, and gave food and environmental safety had an impact.

[0003] 嘧菌酯是甲氧基丙烯酸酯类杀菌剂,杀菌谱广,杀菌活性高,具有保护、铲除、内吸活性。 [0003] Azoxystrobin is a strobilurin fungicide, broad spectrum bactericidal, high fungicidal activity, protect, elimination, systemic activity. 对几乎所有的真菌界(子囊菌亚门、担子菌亚门、鞭毛菌亚门和半知菌亚门)病害如白粉病、锈病、颖枯病、网斑病、霜霉病、稻瘟病等均有良好的活性。 Almost all of the Fungi (Ascomycotina, Basidiomycotina, and flagella cotina Deuteromycotina door) diseases such as powdery mildew, rust, septoria nodorum blotch, net blotch, downy mildew, rice blast have good activity. 嘧菌酯是线粒体呼吸抑制剂,即通过抑制细胞色素b和Cl之间的电子传递而阻止细胞的ATP合成,从而抑制线粒体呼吸。 Azoxystrobin mitochondrial respiratory inhibitors, i.e., while preventing the synthesis of cellular ATP by electron transfer between cytochrome b and Cl suppression, thereby inhibiting mitochondrial respiration. 它对14-脱甲氧基化酶抑制剂、苯甲酰胺类、二羧酰胺类和苯并咪唑类无交叉抗性。 It 14- demethoxy inhibitor, benzamides, dicarboxylic amides and benzimidazoles no cross resistance. 嘧菌酯可用于茎叶喷雾、种子处理,也可进行土壤处理,主要用于谷物、水稻、花生、葡萄、马铃薯、果树、蔬菜、咖啡、草坪等,可有效防治白粉病、锈病、颖枯病、网斑病、霜霉病、稻瘟病、炭疽病、纹枯病、苹果斑点落叶病、梨黑星病等等多种作物病害。 Azoxystrobin can be used for foliage spray, seed treatment, soil treatment can be carried out, mainly for cereals, rice, peanuts, grapes, potatoes, fruit, vegetables, coffee, lawn, which can effectively control powdery mildew, rust, septoria nodorum disease, net blotch, downy mildew, rice blast, anthrax, sheath blight, apple leaf spot, scab and so a variety of crop diseases.

[0004] 但是该产品单剂使用成本太高,尚未普大面积及推广使用。 [0004] However, the use of a single dose of the product cost is too high, yet the S & P and promote the use of large area.

[0005] 氟唳胺(Fluazinam)是苯胺类保护性杀菌剂,其作用机制为线粒体氧化磷酰化解偶联剂,即通过抑制孢予萌发、菌丝突破、生长和孢子形成而抑制病原菌的侵染。 [0005] Li fluoro amine (Fluazinam) is aniline protective fungicides, its mechanism of uncoupler of mitochondrial oxidative phosphoryl, i.e. by inhibiting spore germination I, break mycelial growth and sporulation of the pathogen to inhibit invasion dye. 氟啶胺杀菌谱广,效果优于常规保护性杀菌剂。 Fluazinam broad spectrum bactericidal effects than conventional protective fungicides. 适用作物广如葡萄、苹果、梨、柑橘、小麦、大豆、马铃薯、番茄、黄瓜、水稻、茶、草坪等,对`交链孢属、葡萄孢属、疫霉属、单轴霉属、核盘菌属和黑星菌属菌非常有效。 Crops wide such as grapes, apples, pears, citrus, wheat, soybean, potato, tomato, cucumber, rice, tea, grass and so on, `Alternaria, Botrytis, Phytophthora, uniaxial Corda, nuclear Sclerotinia fungus Venturia and very effective. 对抗苯并咪唑类和二羧酰亚胺类杀茵剂的灰葡萄孢也有良好效果。 Against benzimidazoles and dicarboximide-based agents kill Yin Botrytis cinerea have good effect. 耐雨水冲刷,持效期长。 Rainfastness, long duration. 除了杀菌活性外,氟啶胺还具有一定的杀螨活性,如柑橘红蜘蛛、石竹镌螨、神泽叶螨等。 In addition to bactericidal activity, fluazinam also have some acaricidal activity, such as citrus red mite, pink mite Juan, Kanzawa mite.

[0006] 但氟啶胺无内吸活性和治疗作用,无法通过植物体表进入植物体内,虽然对很多病原菌有较好的杀菌活性,但在田间实际应用中确不太理想。 [0006] However, withdrawing the inactive fluazinam and treatment, it can not enter the plants through plant surface, although good bactericidal activity against many pathogens, but in actual field applications indeed less than ideal.

(三)发明内容 (Iii) Disclosure of the Invention

[0007] 本发明的目的之一在于克服上述不足,提供一种适用范围广、效果好、成本低、残留低的含有嘧菌酯和氟啶胺的杀菌组合物。 [0007] One object of the present invention is to overcome the above disadvantages, to provide a wide range of applications, effective, low cost, low residual fungicidal compositions containing azoxystrobin and fluazinam.

[0008] 本发明的目的之二在于提供一种含有嘧菌酯和氟啶胺的杀菌组合物的用途。 [0008] wherein two of the object of the present invention provides a use of azoxystrobin containing fluazinam and fungicidal compositions.

[0009] 本发明的目的是这样实现的: [0009] The object of the present invention is implemented as follows:

[0010] 一种含有嘧菌酯和氟啶胺的杀菌组合物,所述组合物含有嘧菌酯和氟啶胺,所述嘧菌酯和氟啶胺的重量比为2〜45: 4〜55。 [0010] azoxystrobin containing fluazinam and fungicidal composition, said composition comprises azoxystrobin and fluazinam, azoxystrobin and the weight ratio of fluazinam is 2~45: 4 ~ 55.

[0011] 所述嘧菌酯和氟啶胺的重量比为5〜30: 5〜40。 [0011] The weight azoxystrobin and fluazinam ratio of 5~30: 5 ~ 40.

[0012] 所述嘧菌酯和氟啶胺的重量比为1: 1、1: 2、1: 6、1: 12、1: 18、1: 30、2: 1,6: 1、15: I 或30:1。 [0012] The weight azoxystrobin and fluazinam ratio of 1: 1,1: 2,1: 6,1: 12,1: 18,1: 30,2: 1,6: 1,15: I or 30: 1.

[0013] 所述组合物剂型为农药上允许的任意一种剂型。 [0013] The composition or dosage form of any one dosage of pesticide allowed.

[0014] 所述组合物剂型为可湿性粉剂、水分散粒剂、悬浮剂、水乳剂或乳油。 [0014] The composition or dosage form of a wettable powder, water dispersible granules, suspensions, emulsifiable concentrates or aqueous emulsion.

[0015] 所述嘧菌酯和氟啶胺在组合物中的质量百分比为2〜90%。 [0015] The mass percentage of azoxystrobin and fluazinam in the composition of 2~90%.

[0016] 一种含有嘧菌酯和氟啶胺的杀菌组合物的用途,用于作为禾谷类作物、瓜果或蔬菜作物病害的药物。 [0016] A fungicidal composition comprising the use of azoxystrobin and fluazinam, a medicament as cereals, fruit or vegetable crop diseases.

[0017] 用于作为马铃薯晚疫病的药物。 [0017] As for pharmaceutical infestans.

[0018] 与现有技术相比,本发明的有益效果是: [0018] Compared with the prior art, the beneficial effects of the present invention are:

[0019] (I)本发明组合物在一定配比范围内表现很好的增效作用,组合物的杀菌效果比单剂有了显著提高,同时降低了农药使用剂量及成本,减少了残留,也减轻了对环境的不良影响; [0019] (I) in the compositions of the present invention exhibit a certain range of the ratio of good synergistic bactericidal effect than a single dose of the composition has been significantly improved, while reducing the use of pesticides dose and cost, reducing the residual, also reduce the adverse impact on the environment;

[0020] (2)本发明中两种活性成分的作用机制不同,组合物的应用可以延缓或克服病原菌的抗性,延长产品的使用寿命; [0020] (2) according to the present invention, a different mechanism of two active ingredients, can delay the application of the composition to overcome the resistance to pathogens or extend the life of the product;

[0021] (3)本发明组合物适用范围增加,适用于防治禾谷类作物、各种瓜果、蔬菜等作物的病害,特别是水稻、小麦、番爺、香蕉、苹果、梨等作物病害,如水稻稻痕病、小麦白粉病、番茄早疫病、苹果斑点落叶病、梨树黑星病等。 [0021] (3) The composition of the present invention to increase the scope of application, suitable for controlling cereal crops, fruits of various diseases of crops, vegetables, especially rice, wheat, Fan Ye, bananas, apples, pears and other crop diseases, marks such as rice rice disease, powdery mildew, tomato early blight, apple leaf spot, pear scab and so on.

(四)具体实施方式 (IV) DETAILED DESCRIPTION

[0022] 为了是本发明的目的、技术方案及优点更加清楚明白,本发明用以下具体实例进行说明,但本发明不局限于这些例子。 [0022] For a purpose, technical scheme and advantages of the present invention will become more apparent, the present invention is illustrated by the following specific examples, but the present invention is not limited to these examples.

[0023] 本发明组合物以嘧菌酯和氟啶胺为有效成分,经室内生物测定试验发现,两者复配之后对抗药性病害有明显的协同增效作用,具体用以下生物测定实例加以说明。 [0023] The compositions of the invention will be described in azoxystrobin and fluazinam as an active ingredient, and the laboratory assay organisms found after both the complex significant synergistic effect on disease resistance, specific examples of the following biological assay .

[0024] 实物测定实例:嘧菌酯和氟啶胺复配对马铃薯晚疫病的毒力测定 Azoxystrobin and fluazinam Complex as potato late blight Virulence: Example [0024] Physical measurement

[0025] 1、试验对象:马铃薯晚疫病 [0025] 1, subjects: infestans

[0026] 2、试验方法:参照《农药生物测定试验准则NY/T1156.2-2006》,采用含药培养基法。 [0026] 2. Test Method: According to "Test guidelines for pesticide bioassay NY / T1156.2-2006", using medicated medium method.

[0027] 3、数据统计分析:用SAS6.12统计软件进行分析。 [0027] 3. Statistical analysis: SAS6.12 analyzed by statistical software. 根据试验数据计算菌丝生长抑制率(%),求出毒力回归方程式、相关系数(r)、EC5tl和共毒系数。 Calculation mycelial growth inhibition rate (%) according to the experimental data, the regression equation obtained virulence, the correlation coefficient (r), EC5tl and co-toxicity coefficient.

[0028] 4、评价方法:参照《农药生物测定试验准则NY/T1156.2-2006》,根据Sun&Johnson(1960)的共毒系数法(CTC)来评价药剂混用的增效作用,即CTC ( 80为拮抗作用,80 < CTC < 120为相加作用,CTC彡120为增效作用。 [0028] 4. Evaluation method: refer to "Guidelines for pesticide bioassay NY / T1156.2-2006", to evaluate the synergistic drug mix based on Sun & Johnson (1960) the co-toxicity coefficient (CTCs), i.e., CTC (80 antagonism, 80 <CTC <120 additive effect, CTC 120 San synergism.

[0029] 5、结果与分析 [0029] 5, results and analysis

[0030] 嘧菌酯、氟啶胺及其二者不同比例的混配组合对马铃薯晚疫病菌的毒力测定结果见表1,表I中“嘧:氟”为“嘧菌酯:氟啶胺”的简写。 [0030] Determination of Toxicity results Phytophthora infestans azoxystrobin, fluazinam, and compounding ratio of the two different combinations shown in Table 1, Table I "pyrimidine: fluoro" is "azoxystrobin: fluazinam amine "shorthand.

[0031] 表I嘧菌酯与氟啶胺混配对马铃薯晚疫病菌的毒力测定结果 [0031] Table I azoxystrobin fluazinam mixed with the measurement result of virulence Phytophthora infestans

[0032] [0032]

Figure CN101984817BD00051

[0033] 室内生测结果表明:嘧菌酯与氟啶胺以1: 1、1: 2、1: 6、1: 12、1: 18、 [0033] The bioassay results showed that: azoxystrobin and fluazinam to 1: 1,1: 2,1: 6,1: 12,1: 18,

I: 30,2: 1、6: 1、15: I和30: I比例进行混配,其对马铃薯晚疫病菌表现出相加或增效作用,其中以1: 6、1: 12、1: 30和2: I的增效作用较好。 I: 30,2: 1,6: 1,15: I and 30: I ratio compounded, its Phytophthora infestans exhibit additive or synergistic effects, wherein the 1: 6,1: 12,1 : 30 and 2: I better synergy. 如果仅从增效毒力比较,可以视1: 6、1: 12、1: 30和2: I的混配比例为嘧菌酯与氟啶胺对马铃薯晚疫病菌的最佳配比。 If only synergistic toxicity comparison, can optionally 1: 6,1: 12,1: 30 and 2: mixing ratio of azoxystrobin I fluazinam and the best ratio of Phytophthora infestans. 至于生产实际中以何种比例进行混配,尚需结合增效毒力、经济成本、加工工艺及毒性等进行综合考虑决定。 As for actual production were mixed in what proportion, still need to combine efficiency virulence, comprehensive consideration determine the economic cost, processing and toxicity.

[0034] 本发明组合物可以用已知的方法制备称适合农业上使用的任意一种剂型,其中比较好的剂型有乳油、水分散粒剂、水乳剂、悬浮剂及可湿性粉剂,以下用具体实例进行说明。 [0034] The compositions of the invention may be prepared by known methods, said dosage form suitable for any agricultural use, wherein the dosage form has a good emulsifiable concentrates, water dispersible granules, aqueous emulsions, suspensions and wettable powders, by the following specific examples will be described.

[0035] 实施例1: [0035] Example 1:

[0036] 将卩密菌酯5g、氟唳胺30g、十二烧基磺酸钠5g、苯乙基酹聚氧乙烯醚3g、柴油加至100g,混合至均匀液相,制得本发明组合物35%乳油。 [0036] The adhesion azoxystrobin Jie 5g, fluoro Li amine 30g, twelve burning sulfonate 5g, phenethyl sprinkle polyoxyethylene 3g, was added to the diesel 100g, mix until homogeneous liquid phase composition of the present invention was prepared EC was 35%.

[0037] 实施例2: [0037] Example 2:

[0038] 将嘧菌酯3g、氟啶胺37g、扩散剂NNO(亚甲基双萘磺酸钠)4.5g、木质素磺酸钠3g、高岭土加至100g,经气流粉碎造粒,制得本发明组合物40%水分散粒剂。 [0038] The azoxystrobin 3g, 37g fluazinam, NNO diffusing agent (methylene-bis-naphthalene sulfonate) 4.5 g of, sodium lignosulfonate 3g, kaolin clay was added to 100g, granulated by jet milling, to obtain The composition of the present invention is 40% water dispersible granule.

[0039] 实施例3: [0039] Example 3:

[0040] 将嘧菌酯15g、氟啶胺25g、二十烷基磺酸钠5g、壬基酚聚氧乙烯醚3g、扩散剂NNO2g、黄原胶0.2g丙二醇5g、适量水,混合经湿法研磨,均化,制得本发明组合物40%悬浮剂。 [0040] The azoxystrobin 15g, fluazinam 25g, eicosyl sulfonate 5g, nonylphenol polyoxyethylene ether 3g, diffusing agent NNO2g, propylene glycol 0.2g xanthan gum 5g, amount of water, wet-mixed grinding, homogenization, to prepare a composition of the present invention is 40% suspension.

[0041] 实施例4:[0042] 将嘧菌酯2g、氟啶胺60g、扩散剂NNO 4.5g、木质素磺酸钠3g、白炭黑5g、高岭土加至100g,混合经气流粉碎制得本发明组合物62%可湿性粉剂。 [0041] Example 4: [0042] A azoxystrobin 2g, fluazinam 60g, diffusing agent NNO 4.5g, sodium lignosulfonate 3g, silica 5g, kaolin clay was added to 100g, jet milling prepared by mixing The composition of the present invention is 62% wettable powder.

[0043] 实施例5: [0043] Example 5:

[0044] 将嘧菌酯6g、氟啶胺12g、二甲苯7g、烷基芳基甲醛树脂聚氧乙烯醚10g、烷基酚聚氧乙烯醚磷酸酯lg、乙二醇4g、黄原胶0.lg、有机硅酮0.lg、适量水,配制油相,配制水相,在高剪切下,将油相均匀水相中或者将水相加入油相中,剪切制得本发明组合物18 %水乳剂。 [0044] The azoxystrobin 6g, fluazinam 12g, xylene 7g, alkylaryl polyoxyethylene ether formaldehyde resin 10g, polyoxyethylene alkyl phenol ether phosphate lg, ethylene glycol 4g, xanthan gum 0 . LG, organosilicone 0.lg, an appropriate amount of water to prepare an oil phase, the aqueous phase was prepared, under high shear, the oil phase homogeneous aqueous phase added to the oil phase or the aqueous phase cut to produce a composition of the present invention It was 18% water emulsion.

[0045] 应用实施例: [0045] Application Example:

[0046] 利用上述实施例制得的制剂防治马铃薯晚疫病试验。 [0046] Potato Late Blight Control tests using the formulation obtained in the above-described embodiments.

[0047] 1、试验处理:本试验药剂用量根据各个成分的不同分别设三个处理浓度,对照药剂分别是市售农药25 %嘧菌酯悬浮剂、50 %氟啶胺可湿性粉剂及清水空白对照。 [0047] 1, processing test: This test pharmaceutical dosage depending on the individual components are arranged three treatment concentration, control agents are commercially available pesticide azoxystrobin SC 25%, 50% WP fluazinam and water blank control.

[0048] 2、试验方式:试验选择在历年马铃薯晚疫病比较严重的田块进行,试验每个小区为30m2,重复4次。 [0048] 2. Test Method: Test selection in the calendar year infestans serious plots, each test cell is 30m2, repeated four times. 调查方法及药效评价按GB/T 17980.34-2000进行。 The survey methodology and efficacy evaluation according to GB / T 17980.34-2000.

[0049] 3、试验结果如下表: [0049] 3, results in the following table:

[0050] [0050]

Figure CN101984817BD00061

[0051] 注:a表示在α = 0.05水平上显著,b表示在α = 0.05水平上有差异,c表示在α = 0.05水平上有不显著。 [0051] Note: a represents the α = 0.05 level significantly, b represents the difference in the α = 0.05 level, c denotes the α = 0.05 has the insignificant level.

[0052] 田间药效试验表明,嘧菌酯与氟啶胺杀菌组合物对马铃薯晚疫病具有良好的防效,防治效果优于单剂品种。 [0052] The field efficacy trials show that azoxystrobin and fluazinam fungicidal composition having excellent control effect on potato late blight control effect than single agent species.

Claims (5)

1.一种含有嘧菌酯和氟啶胺的杀菌组合物,其特征在于:所述组合物的活性成分为嘧菌酯和氟啶胺,二者的重量比为1: 6、1: 12、1: 18、2: 1、6:1或15:1。 A azoxystrobin containing fluazinam and fungicidal compositions, characterized in that: the active ingredient of the composition is azoxystrobin and fluazinam, both the weight ratio of 1: 6,1: 12 , 1: 18,2: 1, 6: 1 or 15: 1.
2.根据权利要求1所述的一种含有嘧菌酯和氟啶胺的杀菌组合物,其特征在于:所述组合物剂型为可湿性粉剂、水分散粒剂、悬浮剂、水乳剂或乳油。 According to one of the claim 1 comprising azoxystrobin and fluazinam fungicidal composition, characterized in that: said composition is a dosage form of a wettable powder, water dispersible granules, suspensions, emulsifiable concentrates or aqueous emulsion .
3.根据权利要求1所述的一种含有嘧菌酯和氟啶胺的杀菌组合物,其特征在于:所述嘧菌酯和氟啶胺在组合物中的质量百分比为2〜90%。 According to one of the claims 1 fungicidal composition comprising azoxystrobin and fluazinam, wherein: the mass percentage of azoxystrobin and fluazinam ester in the composition is 2~90%.
4.一种权利要求1所述的含有嘧菌酯和氟啶胺的杀菌组合物的用途,其特征在于:用于作为禾谷类作物、瓜果或蔬菜作物病害的药物。 As cereals, fruits and crop diseases or medicament for vegetables: the use of germicidal composition containing azoxystrobin and fluazinam, wherein A of claim 1.
5.根据权利要求4所述的含有嘧菌酯和氟啶胺的杀菌组合物的用途,其特征在于:用于作为马铃薯晚疫病的药物。 5. Use germicidal composition containing azoxystrobin and fluazinam of claim 4, wherein: for a pharmaceutical infestans.
CN 201010229488 2010-07-15 2010-07-15 Bactericidal composition containing azoxystrobin and fluazinam and use thereof CN101984817B (en)

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