CN105385281A - 水性丙烯酸聚氨酯面漆 - Google Patents

水性丙烯酸聚氨酯面漆 Download PDF

Info

Publication number
CN105385281A
CN105385281A CN201511028973.7A CN201511028973A CN105385281A CN 105385281 A CN105385281 A CN 105385281A CN 201511028973 A CN201511028973 A CN 201511028973A CN 105385281 A CN105385281 A CN 105385281A
Authority
CN
China
Prior art keywords
parts
water
acrylic polyurethane
coat
weight proportion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201511028973.7A
Other languages
English (en)
Inventor
刘道海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianheng Paint Co Ltd
Original Assignee
Tianheng Paint Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianheng Paint Co Ltd filed Critical Tianheng Paint Co Ltd
Priority to CN201511028973.7A priority Critical patent/CN105385281A/zh
Publication of CN105385281A publication Critical patent/CN105385281A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/222—Magnesia, i.e. magnesium oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

一种水性丙烯酸聚氨酯面漆，包括如下的重量配比的原料：水性丙烯酸树脂150—200份、去离子水200-300份、消泡剂1-3份、钛白粉180—200份、中和剂1—3份、三聚磷酸铝2—6份、沉淀硫酸钡100—150份、流变助剂10—20份、闪蚀抑制剂2—4份、滑石粉25份、流平剂1—3份、催化剂0.5—2份；其特征在于：还包括抗氧化剂2-4份、纳米硫化镁1-4份、紫外线吸收剂1-4份。本发明无污染、耐水性、耐化学性、耐磨性、耐候性较好、使用寿命长，硬度高。

Description

水性丙烯酸聚氨酯面漆
技术领域：
本发明涉及一种涂料，特别涉及一种水性丙烯酸聚氨酯面漆。
背景技术：
随着社会的不断进步，各国对环保的意识不断提高。而目前广泛使用的溶剂型涂料中含有大量的可挥发有机化合物(VOC)，有机化合物(VOC)有毒、易燃，污染大气层，对环境和人体都造成危害。因此，为了减少这些有机溶剂对环境的污染，我国已将水性涂料列入今后工业涂料的发展方向。可是我国目前应用在地板涂料、金属防锈漆和船舶涂料上的水性工业涂料其耐水性、耐化学性、耐磨性和耐候性不理想。
发明内容：
本发明的目的就在于克服上述现有技术中存在的不足，而提供一种无污染、并且耐水性、耐化学性、耐磨性和耐候性较好的水性丙烯酸聚氨酯面漆。
如上构思，本发明的技术方案是：一种水性丙烯酸聚氨酯面漆，包括如下的重量配比的原料：水性丙烯酸树脂150—200份、去离子水200-300份、消泡剂1-3份、钛白粉180—200份、中和剂1—3份、三聚磷酸铝2—6份、沉淀硫酸钡100—150份、流变助剂10—20份、闪蚀抑制剂2—4份、滑石粉25份、流平剂1—3份、催化剂0.5—2份；其特征在于：还包括抗氧化剂2-4份、纳米硫化镁1-4份、紫外线吸收剂1-4份。
上述水性丙烯酸树脂由下列原料按照如下重量配比制成：丙烯酸正丁酯BA20-35份、苯乙烯ST12-30份、丙烯酸AA1—3份、甲基丙烯酸MAA1—3份、甲基丙烯酸甲酯MMA1-4份、N-羟甲基丙烯酰胺NMA5-10份、过硫酸钾K2S2O80.1-1份、OP-10及烷基硫酸钠1-4份、中和剂0.1—0.3份、丙二醇0.1—0.3份、去离子水40—60份。
上述中和剂由下列原料按照如下重量配比制成：丁醇50-80份、三乙醇胺40-70份、磷酸三丁酯40-60份。
本发明具有如下的优点和积极效果：
1、本发明降低了对环境的污染，并节约了资源。
2、本发明对各种基材均有很强的附着力，并且涂层的硬度高，具有良好的耐水性、耐候性和耐化学性和较高的耐磨性。
3、本发明用途广泛。可做为地坪、地板涂料、金属防锈漆、船舶涂料、汽车轻工业产品和饮水缸内壁防腐蚀用。
4、本发明配方中增加的紫外线吸收剂在漆膜干燥后发挥作用，它能把大部分能量高、对高分子聚合物有害的辐射光吸收，再以热量释放出来，使树脂聚合物降解速度大大减缓，以提高涂膜的保护性能，延长其使用寿命。
5、在成品储存过程中与成膜后过程中会受到氧气的侵蚀，为了提高防腐性能，本发明配方中增加了抗氧化剂，可延长成品的使用年限。
6、本发明配方中增加的纳米氧化镁可起到一定的阻燃效果，使产品的硬度大大提高。
具体实施方式：
实施例1：一种水性丙烯酸聚氨酯面漆，由下列原料按照如下的重量配比制成：水性丙烯酸树脂150Kg、去离子水200Kg、消泡剂1Kg、钛白粉180Kg、中和剂1Kg、三聚磷酸铝2Kg、沉淀硫酸钡100Kg、流变助剂10Kg、闪蚀抑制剂2Kg、滑石粉25Kg、流平剂1Kg、催化剂0.5Kg、抗氧化剂2Kg、纳米硫化镁1Kg、紫外线吸收剂1Kg。
实施例2：一种水性丙烯酸聚氨酯面漆，由下列原料按照如下的重量配比制成：水性丙烯酸树脂200Kg、去离子水300Kg、消泡剂3Kg、钛白粉200Kg、中和剂3Kg、三聚磷酸铝6Kg、沉淀硫酸钡150Kg、流变助剂20Kg、闪蚀抑制剂4Kg、滑石粉25Kg、流平剂3Kg、催化剂2Kg、抗氧化剂4Kg、纳米硫化镁4Kg、紫外线吸收剂4Kg。
实施例3：一种水性丙烯酸聚氨酯面漆，由下列原料按照如下的重量配比制成：水性丙烯酸树脂170Kg、去离子水250Kg、消泡剂2Kg、钛白粉190Kg、中和剂2Kg、三聚磷酸铝4Kg、沉淀硫酸钡125Kg、流变助剂15Kg、闪蚀抑制剂3Kg、滑石粉25Kg、流平剂2Kg、催化剂1.5Kg、抗氧化剂3Kg、纳米硫化镁3Kg、紫外线吸收剂2Kg。
上述水性丙烯酸树脂由下列原料制成：丙烯酸正丁酯(BA)、苯乙烯(ST)、丙烯酸(AA)、甲基丙烯酸(MAA)、甲基丙烯酸甲酯(MMA)、N-羟甲基丙烯酰胺(NMA)、过硫酸钾(K2S2O8)、OP-10及烷基硫酸钠、中和剂、丙二醇和去离子水。
上述中和剂由丁醇、三乙醇胺和磷酸三丁酯混合制成。
上述流变助剂可采用聚醚聚氨酯缔合型流变助剂。上述闪蚀抑制剂可采用亚硝酸钠、苯甲酸钠和四硼酸钠。
本发明施工时需要注意如下事项：
1、使用前按面漆:固化剂＝5:1配置，然后静置10min左右进行喷涂或刷涂。固化剂采用由无游离子异醋酸酯制成的水性聚氨酯固化剂。
2、喷涂或刷涂时注意物体表面无尘、无油等。
3、配好的油漆应在4小时内用完，以免胶化浪费。
4、产品符合规定条件下储存，有效贮存期一年，如超过一年经检验合格仍可继续使用。

Claims (3)

1.一种水性丙烯酸聚氨酯面漆，包括如下的重量配比的原料：水性丙烯酸树脂150—200份、去离子水200-300份、消泡剂1-3份、钛白粉180—200份、中和剂1—3份、三聚磷酸铝2—6份、沉淀硫酸钡100—150份、流变助剂10—20份、闪蚀抑制剂2—4份、滑石粉25份、流平剂1—3份、催化剂0.5—2份；其特征在于：还包括抗氧化剂2-4份、纳米硫化镁1-4份、紫外线吸收剂1-4份。
2.根据权利要求1所述的水性丙烯酸聚氨酯面漆，其特征在于：上述水性丙烯酸树脂由下列原料按照如下重量配比制成：丙烯酸正丁酯BA20-35份、苯乙烯ST12-30份、丙烯酸AA1—3份、甲基丙烯酸MAA1—3份、甲基丙烯酸甲酯MMA1-4份、N-羟甲基丙烯酰胺NMA5-10份、过硫酸钾K2S2O80.1-1份、OP-10及烷基硫酸钠1-4份、中和剂0.1—0.3份、丙二醇0.1—0.3份、去离子水40—60份。
3.根据权利要求1和2所述的水性丙烯酸聚氨酯面漆，其特征在于：上述中和剂由下列原料按照如下重量配比制成：丁醇50-80份、三乙醇胺40-70份、磷酸三丁酯40-60份。
CN201511028973.7A 2015-12-30 2015-12-30 水性丙烯酸聚氨酯面漆 Pending CN105385281A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201511028973.7A CN105385281A (zh) 2015-12-30 2015-12-30 水性丙烯酸聚氨酯面漆

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201511028973.7A CN105385281A (zh) 2015-12-30 2015-12-30 水性丙烯酸聚氨酯面漆

Publications (1)

Publication Number Publication Date
CN105385281A true CN105385281A (zh) 2016-03-09

Family

ID=55418079

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201511028973.7A Pending CN105385281A (zh) 2015-12-30 2015-12-30 水性丙烯酸聚氨酯面漆

Country Status (1)

Country Link
CN (1) CN105385281A (zh)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106380918A (zh) * 2016-09-21 2017-02-08 苏州瑞斯格电子科技有限公司 一种环保彩色纳米丙烯酸地坪漆
CN106928812A (zh) * 2017-04-17 2017-07-07 浩力森化学科技（江苏）有限公司 轨道交通内饰件用水性阻燃涂料及其制备方法和使用方法
CN108948901A (zh) * 2018-07-25 2018-12-07 江西恒毅科技有限公司 一种防腐防锈水性丙烯酸漆及其制备方法
CN110183951A (zh) * 2019-05-29 2019-08-30 张家港市天源制漆涂装有限公司 一种水性丙烯酸聚氨酯面漆及其制备方法
CN114958110A (zh) * 2022-06-15 2022-08-30 哈尔滨正罡科技开发有限公司 一种具有抗凝冰功能的建筑外墙涂层及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102234476A (zh) * 2010-05-06 2011-11-09 天津五一天立油漆有限公司 水性丙烯酸聚氨酯面漆
WO2011162740A1 (en) * 2010-06-21 2011-12-29 Basf Se Sound damping compositions and methods for application and use
CN103555178A (zh) * 2013-11-07 2014-02-05 天津五一天立油漆有限公司 高固体无铬丙烯酸聚氨酯面漆

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102234476A (zh) * 2010-05-06 2011-11-09 天津五一天立油漆有限公司 水性丙烯酸聚氨酯面漆
WO2011162740A1 (en) * 2010-06-21 2011-12-29 Basf Se Sound damping compositions and methods for application and use
CN103555178A (zh) * 2013-11-07 2014-02-05 天津五一天立油漆有限公司 高固体无铬丙烯酸聚氨酯面漆

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106380918A (zh) * 2016-09-21 2017-02-08 苏州瑞斯格电子科技有限公司 一种环保彩色纳米丙烯酸地坪漆
CN106928812A (zh) * 2017-04-17 2017-07-07 浩力森化学科技（江苏）有限公司 轨道交通内饰件用水性阻燃涂料及其制备方法和使用方法
CN108948901A (zh) * 2018-07-25 2018-12-07 江西恒毅科技有限公司 一种防腐防锈水性丙烯酸漆及其制备方法
CN108948901B (zh) * 2018-07-25 2020-10-23 江西恒毅科技有限公司 一种防腐防锈水性丙烯酸漆及其制备方法
CN110183951A (zh) * 2019-05-29 2019-08-30 张家港市天源制漆涂装有限公司 一种水性丙烯酸聚氨酯面漆及其制备方法
CN114958110A (zh) * 2022-06-15 2022-08-30 哈尔滨正罡科技开发有限公司 一种具有抗凝冰功能的建筑外墙涂层及其制备方法
CN114958110B (zh) * 2022-06-15 2022-11-22 哈尔滨正罡科技开发有限公司 一种具有抗凝冰功能的建筑外墙涂层及其制备方法

Similar Documents

Publication Publication Date Title
CN102234476A (zh) 水性丙烯酸聚氨酯面漆
CN105385281A (zh) 水性丙烯酸聚氨酯面漆
CN102796427B (zh) 一种水性高性能单组分底面合一防腐涂料
CN102993810A (zh) 一种通用型水性快干防锈漆及制备方法
CN109266156B (zh) 一种水性底面合一漆及其制备方法
CN105295623A (zh) 一种室外防水涂料及其制备方法
CN106147527A (zh) 一种建筑外墙用水性环氧涂料
CN106634382A (zh) 一种环保防腐快干型的底面合一自干漆及其制备方法
CN103571293A (zh) 防火防腐蚀油漆
KR100764081B1 (ko) 친환경 초 중방식, 초 내후성방식공법용 수성도료 조성물및 바인더 수지 조성물
CN104762000A (zh) 一种耐盐雾水性集装箱及其环保金属漆
CN104403470A (zh) 含砂反射隔热多彩涂料
CN102757724A (zh) 一种石油钢管用黑色防锈uv漆
CN103666185A (zh) 一种表面防火阻燃涂料
CN105505160A (zh) 一种丙烯酸油漆
CN104371386A (zh) 一种干燥速度快的油漆
CN105295462A (zh) 一种耐高温防腐涂料及制备方法
CN102977763A (zh) 一种防止油漆铁桶、铁罐焊接处生锈的uv罩光面漆
CN105238108A (zh) 一种船舶专用抗腐蚀涂料
CN101701121A (zh) 水性烤漆及其制备方法
CN102372999A (zh) 聚氨酯树脂-丙烯酸树脂防锈涂料
CN104927633A (zh) 建筑外墙板用uv涂料及其制备方法
CN105969040A (zh) 一种金属用水性防锈漆
CN104479525A (zh) 一种多种设备壳体用水性防锈漆及其制备方法
CN105400397A (zh) 一种改性醇酸涂料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160309