CN105369631A - 一种合成革用无黄变高光油皮及其制备方法 - Google Patents

一种合成革用无黄变高光油皮及其制备方法 Download PDF

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CN105369631A
CN105369631A CN201510990351.6A CN201510990351A CN105369631A CN 105369631 A CN105369631 A CN 105369631A CN 201510990351 A CN201510990351 A CN 201510990351A CN 105369631 A CN105369631 A CN 105369631A
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synthetic leather
gloss oil
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陈勇刚
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Jiangsu Baoze Polymer Materials Co Ltd
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Abstract

本发明提供一种合成革用无黄变高光油皮,其用于合成革的后段工艺,包含以下组分:1000分子量BG-AA二元醇、BDO、IPDI、DMF、反应型二甲基硅油和IPDA。本发明还提供一种合成革用无黄变高光油皮的制备方法。本发明的合成革用无黄变高光油皮的各组分相互协调、共同作用,该合成革用无黄变高光油皮具有高光泽,手感滑爽,膜厚感强,有水晶透感的特点,且由于是脂肪族树脂,不会黄变,物性好。本发明的合成革用无黄变高光油皮是后段处理的一种新型材料,能够用于现有的合成革生产线,工艺简单,无需改变生产设备,不会增加生产成本。本发明的合成革用无黄变高光油皮的流平性好,抗热回粘出色,且比普通高光光油更透。

Description

一种合成革用无黄变高光油皮及其制备方法
技术领域
本发明涉及合成革用表面处理剂领域,具体涉及一种合成革用无黄变高光油皮。本发明还涉及一种合成革用无黄变高光油皮的制备方法。
背景技术
合成革目前在各种领域都可替代真皮。合成革物理性好、耐曲折、柔软、抗拉伸强度大,且也有一定的透气性。合成革表面需用一些处理剂改善其表面色泽、光泽、手感。
合成革表面处理剂可以根据产品的类别进行表面涂饰,其可以改善合成革的亮度、色泽以及手感。然而,随着消费者对皮革表面的色泽和手感要求越来越高,不但要增加合成革的触感,还要保证合成革表面的亮度及色泽度等。而现有的表面处理剂已经不能满足消费者对合成革的亮度及手感日益增加的要求,因此急需一种既能提高合成革触感,又能提高合成革的手感,亮度、光泽等综合效果的处理剂。
发明内容
为了解决上述问题及缺陷,本发明的目的在于提供一种合成革用无黄变高光油皮。本发明还提供一种合成革用无黄变高光油皮的制备方法。
本发明的合成革用无黄变高光油皮通过以下技术方案实现:
一种合成革用无黄变高光油皮,其用于合成革的后段工艺,包含以下组分:1000分子量BG-AA二元醇、BDO、IPDI、DMF、反应型二甲基硅油和IPDA。
进一步地,所述1000分子量BG-AA二元醇与BDO的重量比为1∶0.06-0.5,所述1000分子量BG-AA二元醇与IPDI的重量比为1∶0.6-2,所述1000分子量BG-AA二元醇与DMF的重量比为1∶3.5-6.5,所述1000分子量BG-AA二元醇与反应型二甲基硅油的重量比为1∶0.03-0.1,所述1000分子量BG-AA二元醇与IPDA的重量比为1∶0.2-0.5。
本发明还提供一种合成革用无黄变高光油皮的制备方法,包含以下步骤:
(1)按重量配比称取各组分物质:将1000分子量BG-AA二元醇、BDO、IPDI、DMF、和反应型二甲基硅油混合,加热搅拌进行反应;
(2)当步骤(1)所得的混合物的异氰酸酯(-NCO)的百分含量小于0.3%时,加入DMF降温至室温;
(3)在步骤(2)所得的混合物中滴加IPDA,搅拌均匀,即得所述合成革用无黄变高光油皮。
进一步地,所述1000分子量BG-AA二元醇与BDO的重量比为1∶0.06-0.5。
进一步地,所述1000分子量BG-AA二元醇与IPDI的重量比为1∶0.6-2。
进一步地,所述1000分子量BG-AA二元醇与DMF的重量比为1∶3.5-6.5。
进一步地,所述1000分子量BG-AA二元醇与反应型二甲基硅油的重量比为1∶0.03-0.1。
进一步地,所述1000分子量BG-AA二元醇与IPDA的重量比为1∶0.2-0.5
进一步地,步骤(1)的反应温度为60℃-80℃。
进一步地,步骤(1)的反应时间为3-5小时。
由于采用以上技术方案,本发明与现有技术相比具有如下有益技术效果:
(1)本发明的合成革用无黄变高光油皮的各组分相互协调、共同作用,该合成革用无黄变高光油皮具有高光泽,手感滑爽,膜厚感强,有水晶透感的特点,且由于是脂肪族树脂,不会黄变,物性好;
(2)本发明的合成革用无黄变高光油皮是后段处理的一种新型材料,能够用于现有的合成革生产线,工艺简单,无需改变生产设备,不会增加生产成本;
(3)由于本发明的合成革用无黄变高光油皮具有无黄变的特点,因此其处理一版,烘干后涂膜量相当于普通光油皮处理的2-3版;
(4)本发明的合成革用无黄变高光油皮的流平性好,抗热回粘出色,且比普通高光光油更透。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白,下面结合实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。
实施例1
合成革用无黄变高光油皮由以下配比的组分组成:1000分子量BG-AA二元醇(聚己二酸丁二醇酯)10重量份、BDO(1,4-丁二醇)1重量份、IPDI(异佛尔酮二异氰酸酯)10重量份、DMF(N,N-二甲基甲酰胺)55重量份、反应型二甲基硅油0.5重量份和IPDA(异佛尔酮二胺)3重量份。
以上合成革用无黄变高光油皮的制备方法为:
(1)将10重量份的1000分子量BG-AA二元醇、1重量份的BDO、10重量份的IPDI、55重量份的DMF、0.5重量份的反应型二甲基硅油混合,在80℃下搅拌反应3小时;
(2)当步骤(1)所得的混合物的-NCO的百分含量小于0.3%时,加入55重量份的DMF降温至室温;
(3)在步骤(2)所得的混合物中滴加3重量份的IPDA,搅拌至少30分钟至混合物混合均匀,即得所述合成革用无黄变高光油皮。所得到的合成革用无黄变高光油皮的性能指标见表1。上述制备过程中所采用的搅拌等方法均为本领域内惯用的方法。
实施例2
合成革用无黄变高光油皮由以下配比的组分组成:1000分子量BG-AA二元醇12重量份、BDO(1,4-丁二醇)2重量份、IPDI(异佛尔酮二异氰酸酯)14重量份、DMF(N,N-二甲基甲酰胺)58重量份、反应型二甲基硅油0.7重量份和IPDA(异佛尔酮二胺)4重量份。
以上合成革用无黄变高光油皮的制备方法为:
(1)将12重量份的1000分子量BG-AA二元醇、2重量份的BDO、14重量份的IPDI、58重量份的DMF、0.7重量份的反应型二甲基硅油混合,在70℃下搅拌反应4小时;
(2)当步骤(1)所得的混合物的-NCO的百分含量小于0.3%时,加入58重量份的DMF降温至室温;
(3)在步骤(2)所得的混合物中滴加4重量份的IPDA,搅拌至少30分钟至混合物混合均匀,即得所述合成革用无黄变高光油皮。所得到的合成革用无黄变高光油皮的性能指标见表1。上述制备过程中所采用的搅拌等方法均为本领域内惯用的方法。
实施例3
合成革用无黄变高光油皮由以下配比的组分组成:1000分子量BG-AA二元醇14重量份、BDO(1,4-丁二醇)4重量份、IPDI(异佛尔酮二异氰酸酯)16重量份、DMF(N,N-二甲基甲酰胺)62重量份、反应型二甲基硅油0.8重量份和IPDA(异佛尔酮二胺)4重量份。
以上合成革用无黄变高光油皮的制备方法为:
(1)将14重量份的1000分子量BG-AA二元醇、4重量份的BDO、16重量份的IPDI、62重量份的DMF、0.8重量份的反应型二甲基硅油混合,在60℃下搅拌反应3小时;
(2)当步骤(1)所得的混合物的-NCO的百分含量小于0.3%时,加入62重量份的DMF降温至室温;
(3)在步骤(2)所得的混合物中滴加4重量份的IPDA,搅拌至少30分钟至混合物混合均匀,即得所述合成革用无黄变高光油皮。所得到的合成革用无黄变高光油皮的性能指标见表1。上述制备过程中所采用的搅拌等方法均为本领域内惯用的方法。
实施例4
合成革用无黄变高光油皮由以下配比的组分组成:1000分子量BG-AA二元醇15重量份、BDO(1,4-丁二醇)5重量份、IPDI(异佛尔酮二异氰酸酯)20重量份、DMF(N,N-二甲基甲酰胺)65重量份、反应型二甲基硅油1重量份和IPDA(异佛尔酮二胺)5重量份。
以上合成革用无黄变高光油皮的制备方法为:
(1)将15重量份的1000分子量BG-AA二元醇、5重量份的BDO、20重量份的IPDI、65重量份的DMF、1重量份的反应型二甲基硅油混合,在60℃下搅拌反应3小时;
(2)当步骤(1)所得的混合物的-NCO的百分含量小于0.3%时,加入65重量份的DMF降温至室温;
(3)在步骤(2)所得的混合物中滴加5重量份的IPDA,搅拌至少30分钟至混合物混合均匀,即得所述合成革用无黄变高光油皮。所得到的合成革用无黄变高光油皮的性能指标见表1。上述制备过程中所采用的搅拌等方法均为本领域内惯用的方法。
表1
以上所述仅为本发明的较佳实施例,并非用来限定本发明的实施范围;如果不脱离本发明的精神和范围,对本发明进行修改或者等同替换,均应涵盖在本发明权利要求的保护范围当中。

Claims (10)

1.一种合成革用无黄变高光油皮,其用于合成革的后段工艺,其特征在于,包含以下组分:1000分子量BG-AA二元醇、BDO、IPDI、DMF、反应型二甲基硅油和IPDA。
2.根据权利要求1所述的合成革用无黄变高光油皮,其特征在于,所述1000分子量BG-AA二元醇与BDO的重量比为1∶0.06-0.5,所述1000分子量BG-AA二元醇与IPDI的重量比为1∶0.6-2,所述1000分子量BG-AA二元醇与DMF的重量比为1∶3.5-6.5,所述1000分子量BG-AA二元醇与反应型二甲基硅油的重量比为1∶0.03-0.1,所述1000分子量BG-AA二元醇与IPDA的重量比为1∶0.2-0.5。
3.一种合成革用无黄变高光油皮的制备方法,其特征在于,包含以下步骤:
(1)按重量配比称取各组分物质:将1000分子量BG-AA二元醇、BDO、IPDI、DMF、和反应型二甲基硅油混合,加热搅拌进行反应;
(2)当步骤(1)所得的混合物的-NCO的百分含量小于0.3%时,加入DMF降温至室温;
(3)在步骤(2)所得的混合物中滴加IPDA,搅拌均匀,即得所述合成革用无黄变高光油皮。
4.根据权利要求3所述的合成革用无黄变高光油皮,其特征在于,所述1000分子量BG-AA二元醇与BDO的重量比为1∶0.06-0.5。
5.根据权利要求3所述的合成革用无黄变高光油皮,其特征在于,所述1000分子量BG-AA二元醇与IPDI的重量比为1∶0.6-2。
6.根据权利要求3所述的合成革用无黄变高光油皮,其特征在于,所述1000分子量BG-AA二元醇与DMF的重量比为1∶3.5-6.5。
7.根据权利要求3所述的合成革用无黄变高光油皮,其特征在于,所述1000分子量BG-AA二元醇与反应型二甲基硅油的重量比为1∶0.03-0.1。
8.根据权利要求3所述的合成革用无黄变高光油皮,其特征在于,所述1000分子量BG-AA二元醇与IPDA的重量比为1∶0.2-0.5。
9.根据权利要求3所述的合成革用无黄变高光油皮,其特征在于,步骤(1)的反应温度为60℃-80℃。
10.根据权利要求3所述的合成革用无黄变高光油皮,其特征在于,步骤(1)的反应时间为3-5小时。
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