CN105358521B - 羰基化方法 - Google Patents

羰基化方法 Download PDF

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Publication number
CN105358521B
CN105358521B CN201480025855.8A CN201480025855A CN105358521B CN 105358521 B CN105358521 B CN 105358521B CN 201480025855 A CN201480025855 A CN 201480025855A CN 105358521 B CN105358521 B CN 105358521B
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CN
China
Prior art keywords
hydrogen
catalyst
zeolite
carbon monoxide
molar ratio
Prior art date
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CN201480025855.8A
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English (en)
Chinese (zh)
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CN105358521A (zh
Inventor
E.J.迪切尔
B.C.加吉亚
N.J.哈策尔
J.G.孙利
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Ineos Acetyls UK Ltd
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BP Chemicals Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7026—MFS-type, e.g. ZSM-57
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201480025855.8A 2013-03-08 2014-03-06 羰基化方法 Active CN105358521B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13158468 2013-03-08
EP13158468.2 2013-03-08
PCT/EP2014/054392 WO2014135660A1 (en) 2013-03-08 2014-03-06 Carbonylation process

Publications (2)

Publication Number Publication Date
CN105358521A CN105358521A (zh) 2016-02-24
CN105358521B true CN105358521B (zh) 2018-12-21

Family

ID=47827086

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480025855.8A Active CN105358521B (zh) 2013-03-08 2014-03-06 羰基化方法

Country Status (12)

Country Link
US (1) US9505703B2 (enExample)
EP (1) EP2964606A1 (enExample)
JP (1) JP2016513622A (enExample)
KR (1) KR20150125719A (enExample)
CN (1) CN105358521B (enExample)
BR (1) BR112015021853A2 (enExample)
CA (1) CA2903650A1 (enExample)
RU (1) RU2658005C2 (enExample)
SG (1) SG11201507107QA (enExample)
TW (1) TW201443015A (enExample)
UA (1) UA116465C2 (enExample)
WO (1) WO2014135660A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10695756B2 (en) * 2015-06-12 2020-06-30 Enerkem, Inc. Metal-loaded zeolite catalysts for the halogen-free conversion of dimethyl ether to methyl acetate
CN109476579B (zh) * 2016-04-19 2021-11-02 英力士乙酰英国有限公司 生产乙酸甲酯的羰基化工艺
WO2018004994A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Fluidized bed membrane reactor
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
KR101912840B1 (ko) * 2016-12-15 2018-10-30 국민대학교산학협력단 공유결합 트리아진 구조체 기반 비균질계 카보닐화 반응 촉매 및 이를 이용한 락톤의 제조방법
GB201705882D0 (en) 2017-04-12 2017-05-24 Bp Chem Int Ltd Process
CN111792994B (zh) * 2019-04-09 2021-09-28 中国科学院大连化学物理研究所 二甲醚羰基化生产乙酸甲酯的方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101203479A (zh) * 2005-05-05 2008-06-18 加利福尼亚大学董事会 烷基醚羰基化方法
EP1985606A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
CN101600678A (zh) * 2006-12-15 2009-12-09 加州大学评议会 脂肪醇和/或其反应性衍生物羰基化的方法
CN101687761A (zh) * 2007-04-26 2010-03-31 英国石油化学品有限公司 甲醚羰基化方法
CN102245298A (zh) * 2008-12-10 2011-11-16 英国石油化学品有限公司 使用结合的银和/或铜丝光沸石催化剂的羰基化方法
CN102421524A (zh) * 2009-05-14 2012-04-18 英国石油化学品有限公司 羰基化方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1985362A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP2189215A1 (en) * 2008-11-19 2010-05-26 BP Chemicals Limited Carbonylation process catalysed by mordenite supported on inorganic oxides
EP2199272A1 (en) * 2008-11-27 2010-06-23 BP Chemicals Limited Carbonylation process

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101203479A (zh) * 2005-05-05 2008-06-18 加利福尼亚大学董事会 烷基醚羰基化方法
CN101600678A (zh) * 2006-12-15 2009-12-09 加州大学评议会 脂肪醇和/或其反应性衍生物羰基化的方法
EP1985606A1 (en) * 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
CN101687761A (zh) * 2007-04-26 2010-03-31 英国石油化学品有限公司 甲醚羰基化方法
CN102245298A (zh) * 2008-12-10 2011-11-16 英国石油化学品有限公司 使用结合的银和/或铜丝光沸石催化剂的羰基化方法
CN102421524A (zh) * 2009-05-14 2012-04-18 英国石油化学品有限公司 羰基化方法

Also Published As

Publication number Publication date
JP2016513622A (ja) 2016-05-16
BR112015021853A2 (pt) 2017-07-18
CA2903650A1 (en) 2014-09-12
EP2964606A1 (en) 2016-01-13
US9505703B2 (en) 2016-11-29
RU2658005C2 (ru) 2018-06-19
KR20150125719A (ko) 2015-11-09
WO2014135660A1 (en) 2014-09-12
SG11201507107QA (en) 2015-10-29
US20160052857A1 (en) 2016-02-25
TW201443015A (zh) 2014-11-16
RU2015142612A (ru) 2017-04-13
CN105358521A (zh) 2016-02-24
UA116465C2 (uk) 2018-03-26

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Effective date of registration: 20210922

Address after: England Hampshire

Patentee after: Ineos acetyl UK Ltd.

Address before: The Middlesex County

Patentee before: BP Chemicals Ltd.