CN105256313A - Enamelling sheet steel fireplace and manufacturing method thereof - Google Patents

Enamelling sheet steel fireplace and manufacturing method thereof Download PDF

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Publication number
CN105256313A
CN105256313A CN201510769219.2A CN201510769219A CN105256313A CN 105256313 A CN105256313 A CN 105256313A CN 201510769219 A CN201510769219 A CN 201510769219A CN 105256313 A CN105256313 A CN 105256313A
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Prior art keywords
fireplace
heater
enamel
sheet steel
enamelling
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CN201510769219.2A
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CN105256313B (en
Inventor
付荣利
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HENAN HI-FLAME METAL Co Ltd
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HENAN HI-FLAME METAL Co Ltd
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Abstract

The invention belongs to the technical field of fireplace production, and particularly relates to an enamelling sheet steel fireplace and a manufacturing method thereof. A steel plate which is 4-6 mm thick is integrally machined into a fireplace body; the fireplace body is integrally annealed under 820-860 DEG C for 15-20 min; the annealed fireplace body is subjected to integral grinding and abrasive blasting; firstly, ground glaze slip is sprayed to the fireplace body obtained after grinding and abrasive blasting at the room temperature to 150 DEG C and then is dried, secondly, the fireplace body is sintered under 820-860 DEG C for 10-25 min and then cooled to 250-350 DEG C, thirdly, surface glaze slip is sprayed and then dried, and finally a finished product is obtained after the fireplace body is sintered under 760-860 DEG C for 10-25 min. The enamelling sheet steel fireplace integrates the features of the steel plate and the features of enamel glaze, and is a novel product in the original fireplace market; the defects that an original cast-iron enamelling fireplace is thick in wall and overlarge in wall thickness difference and consequently the overall weight is high and the appearance is bulky, and the like are overcome.

Description

Enamelling Sheet Steel fireplace and preparation method thereof
Technical field
The invention belongs to fireplace production technical field, be specifically related to a kind of Enamelling Sheet Steel fireplace and preparation method thereof.
Background technology
The shell of the true fire burning type fireplace used both at home and abroad is at present except in order to also have except overall pitch-dark steel plate fireplace, cast iron is pitch-dark, cast iron enamel fireplace, and latter two is all adopt the split three after producing to assemble.The technical process that cast iron enamel fireplace is produced owing to adopting split, assembled later, often cause the product after assembling intuitively can feel each of fireplace each gap inequality after be combineding with each other, and former cast iron enamel fireplace wall thickness and difference is excessive easily causes the deficiencies such as overall weight is large, outward appearance is heavy.
Summary of the invention
For solving former cast iron enamel fireplace wall thickness and difference crosses the deficiencies such as roughly overall weight is large, outward appearance is heavy, the object of the present invention is to provide a kind of Enamelling Sheet Steel fireplace and preparation method thereof.
For achieving the above object, the technical scheme taked of the present invention is as follows:
The preparation method of Enamelling Sheet Steel fireplace, preparation process is:
(1), overall processing: 4-6mm Plate Steel is integrally processed into body of heater;
(2), integrally annealed: by body of heater at 820-860 DEG C of integrally annealed 15-20min;
(3), overall sandblasting: to the body of heater entirety polishing sandblasting after annealing;
(4), wet method heat spray: to the body of heater after polishing sandblasting, first spray ground-coat enamel slurry, with post-drying room temperature-150 DEG C, then, at 820-860 DEG C of sintering 10-25min, after being cooled to 250-350 DEG C, cover-coat enamel slurry is sprayed, dry again, then at 760-860 DEG C of sintering 10-25min, get product;
Wherein, the preparation process of described ground-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 48.0 ~ 58.0%, B 2o 3: 11.0 ~ 18.0%, Fe 2o 3: 0.9 ~ 1.9%, R 2o:15.0 ~ 21.0%, CaF 2: 8.0 ~ 10.0%, Al 2o 3: 1.8 ~ 3.5%, CoO:0.5 ~ 1.1%, MnO 2: 0 ~ 1.8%, PbO:0 ~ 5.0%, NiO:1.0 ~ 2.5%; (ii) after being melting into enamel at 1150-1250 DEG C, ball milling pulping; Wherein R 2r in O is Li, Na, K or its combination;
The preparation process of described cover-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 42.0 ~ 55.0%, Al 2o 3: 4.0 ~ 10.0%, R 2o:15.0 ~ 25.0%, CaF 2: 1.2 ~ 2.8%, B 2o 3: 8.0 ~ 15.0%, Na 2siF 6: 1.9 ~ 7.6%, TiO 2: 0 ~ 3.0%, BaO:1.5 ~ 5.0%, CeO 2: 0 ~ 10.0%, MnO 2: 0 ~ 4.5%, Fe 2o 3: 0 ~ 8.5%; (ii) after being melting into enamel at 1150-1250 DEG C, ball milling pulping; Wherein R 2r in O is Li, Na, K or its combination.
According to Enamelling Sheet Steel fireplace prepared by aforementioned preparation process.
Innovation of the present invention is:
1, differ for making steel plate fireplace and metallic object in preparation process because its moulding is impetuous, built-in, asymmetric and stress that is that produces obtains evenly reasonably discharging, fireplace of the present invention just adopts the integrally annealed of metal body of heater, it not only can get rid of its some stress completed in treating processes like this, metal surface is obtained fully oxidized, the impurity of the harmful enamel of part in steel plate can be got rid of again, later the overall sandblasting to body of heater is adopted, make steel plate spill brand-new metal surface, be convenient to the mortise of itself and enamel.
2, warding off some special cobalt nickel enamels by executing its top layer, making it in sintering process, produce enough physics and chemistry adherences with steel plate, both are combined as a whole securely.
3, adopt this novel method of wet method heat spray, the layer glaze that enamel coating top layer can be made to spray is controlled, and porcelain thickness is reasonably adjusted, can adjust the color and luster of layer glaze again (mainly through adjustment cover-coat enamel component proportions, such as MnO. simultaneously 2adjust intense violet color, Fe 2o 3adjust yellow), thus obtain the different porcelain thicknesses needed for design requirements, color and luster can adjust on request at any time.By wet method heat spray this method can by moisture content because the salt impurity in some pigments and other mill addition is reasonably disperseed, it can be obtained fully enough volatilizations in burning till again, avoid and burn till rear enamel coating and occur that salt mist film (spot) and strain line are not enough, thus make the outward appearance that the top layer of body of heater obtains.
Beneficial effect of the present invention:
1, be expert at the enamel fireplace that the overall application of slip of steel plate is produced in still belong to first batch of, it integrates the speciality of steel plate and frit for porcelain enamel, and the product of production is the another new variety on former fireplace market.
2, wet method hot spray method is adopted to carry out artificial glazing to body of heater top layer, the quality of product is made to obtain conservative control, the enamel coating quality at the particularly R angle place that some radius-of-curvature are less, the corner of metal body of heater can be made to be controlled, avoid enamel coating became uneven, uncontrollable adjustment, enamel gathering or the undesirable element such as deficiency at some specific positions, simultaneously by porcelain thickness and glaze adjusting performance, some performances such as enamel coating is heat-resisting, shock-resistant can be made to be improved.
3, adopt artificial method for making body of heater top layer can be made by the requirement of client the product (being realized by porcelain thickness and glaze adjusting performance) that different performance requires, make its top layer smoothly fine and smooth, glossiness is good, multiple color and luster, and color and luster is homogeneous, harmonious.
4, by the long burning method of low temperature after spraying, the stress deformation that whole body of heater causes because metal component structure is uneven can be avoided, can ensure that again enamel coating in use can bear local temperature difference and the deficiency such as crackle, burst porcelain caused.
5, the market of this product is expanded again by the adjustability of color, gloss further, and it can be the goods that each human consumer provides to achieve one's goal.
Embodiment
Embodiment 1
Enamelling Sheet Steel fireplace, preparation process is:
(1), overall processing: 5mm Plate Steel is integrally processed into body of heater;
(2), integrally annealed: by body of heater at 840 DEG C of integrally annealed 20min;
(3), overall sandblasting: to the body of heater entirety polishing sandblasting after annealing;
(4), wet method heat spray: to the body of heater after polishing sandblasting, first spray ground-coat enamel slurry at 100 DEG C, with post-drying, then at 860 DEG C of sintering 20min, after being cooled to 350 DEG C, spraying cover-coat enamel slurry, then dry, then at 860 DEG C of sintering 20min, get product;
Wherein, the preparation process of described ground-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 50.18%, B 2o 3: 12.84%, Fe 2o 3: 1.81%, Na 2o:16%, K 2o:4.61%, CaF 2: 8.52%, Al 2o 3: 1.88%, CoO:0.8%, MnO 2: 1.6%, PbO:0%, NiO:1.76%; (ii) after being melting into enamel at 1200 DEG C, ball milling pulping;
The preparation process of described cover-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 47.19%, Al 2o 3: 9.21%, Na 2o:12.29%, K 2o:2.5%, CaF 2: 4.45%, B 2o 3: 10.12%, Na 2siF 6: 7.53%, TiO 2: 1.45%, BaO:4.84%, CeO 2: 0%, MnO 2: 0%, Fe 2o 3: 0.42%; (ii) after being melting into enamel at 1200 DEG C, ball milling pulping.
Embodiment 2
Enamelling Sheet Steel fireplace, preparation process is:
(1), overall processing: 5mm Plate Steel is integrally processed into body of heater;
(2), integrally annealed: by body of heater at 840 DEG C of integrally annealed 18min;
(3), overall sandblasting: to the body of heater entirety polishing sandblasting after annealing;
(4), wet method heat spray: to the body of heater after polishing sandblasting, first spray ground-coat enamel slurry at 100 DEG C, with post-drying, then at 840 DEG C of sintering 20min, after being cooled to 300 DEG C, spraying cover-coat enamel slurry, then dry, then at 800 DEG C of sintering 20min, get product;
Wherein, the preparation process of described ground-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 55%, B 2o 3: 11%, Fe 2o 3: 1.2%, Li 2o:17%, CaF 2: 9%, Al 2o 3: 3%, CoO:0.8%, MnO 2: 1.8%, PbO:0.2%, NiO:1%; (ii) after being melting into enamel at 1200 DEG C, ball milling pulping;
The preparation process of described cover-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 42%, Al 2o 3: 4%, Li 2o:20%, CaF 2: 1.2%, B 2o 3: 8%, Na 2siF 6: 2.8%, TiO 2: 1%, BaO:2%, CeO 2: 10%, MnO 2: 3%, Fe 2o 3: 6%; (ii) after being melting into enamel at 1200 DEG C, ball milling pulping.
Embodiment 3
Enamelling Sheet Steel fireplace, preparation process is:
(1), overall processing: 4mm Plate Steel is integrally processed into body of heater;
(2), integrally annealed: by body of heater at 820 DEG C of integrally annealed 15min;
(3), overall sandblasting: to the body of heater entirety polishing sandblasting after annealing;
(4), wet method heat spray: to the body of heater after polishing sandblasting, first spray ground-coat enamel slurry in room temperature, with post-drying, then at 820 DEG C of sintering 10min, after being cooled to 250 DEG C, spraying cover-coat enamel slurry, then dry, then at 760 DEG C of sintering 10min, get product;
Wherein, the preparation process of described ground-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 50%, B 2o 3: 17.1%, Fe 2o 3: 0.9%, K 2o:15%, CaF 2: 8%, Al 2o 3: 2.5%, CoO:0.5%, MnO 2: 0%, PbO:5%, NiO:1%; (ii) after being melting into enamel at 1150 DEG C, ball milling pulping;
The preparation process of described cover-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 55%, Al 2o 3: 10%, K 2o:15%, CaF 2: 2.8%, B 2o 3: 8%, Na 2siF 6: 1.9%, TiO 2: 0%, BaO:3%, CeO 2: 4.3%, MnO 2: 0%, Fe 2o 3: 0%; (ii) after being melting into enamel at 1150 DEG C, ball milling pulping.
Embodiment 4
Enamelling Sheet Steel fireplace, preparation process is:
(1), overall processing: 6mm Plate Steel is integrally processed into body of heater;
(2), integrally annealed: by body of heater at 860 DEG C of integrally annealed 20min;
(3), overall sandblasting: to the body of heater entirety polishing sandblasting after annealing;
(4), wet method heat spray: to the body of heater after polishing sandblasting, first spray ground-coat enamel slurry at 150 DEG C, with post-drying, then at 860 DEG C of sintering 25min, after being cooled to 350 DEG C, spraying cover-coat enamel slurry, then dry, then at 860 DEG C of sintering 25min, get product;
Wherein, the preparation process of described ground-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 48%, B 2o 3: 13.5%, Fe 2o 3: 1.5%, Na 2o:20%, CaF 2: 10%, Al 2o 3: 3.5%, CoO:1%, MnO 2: 0%, PbO:0%, NiO:2.5%; (ii) after being melting into enamel at 1250 DEG C, ball milling pulping;
The preparation process of described cover-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 42%, Al 2o 3: 5%, Na 2o:15%, CaF 2: 1.2%, B 2o 3: 15%, Na 2siF 6: 4.3%, TiO 2: 3%, BaO:1.5%, CeO 2: 0%, MnO 2: 4.5%, Fe 2o 3: 8.5%; (ii) after being melting into enamel at 1250 DEG C, ball milling pulping.

Claims (2)

1. the preparation method of Enamelling Sheet Steel fireplace, is characterized in that preparation process is:
(1), overall processing: 4-6mm Plate Steel is integrally processed into body of heater;
(2), integrally annealed: by body of heater at 820-860 DEG C of integrally annealed 15-20min;
(3), overall sandblasting: to the body of heater entirety polishing sandblasting after annealing;
(4), wet method heat spray: to the body of heater after polishing sandblasting, first spray ground-coat enamel slurry, with post-drying room temperature-150 DEG C, then, at 820-860 DEG C of sintering 10-25min, after being cooled to 250-350 DEG C, cover-coat enamel slurry is sprayed, dry again, then at 760-860 DEG C of sintering 10-25min, get product;
Wherein, the preparation process of described ground-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 48.0 ~ 58.0%, B 2o 3: 11.0 ~ 18.0%, Fe 2o 3: 0.9 ~ 1.9%, R 2o:15.0 ~ 21.0%, CaF 2: 8.0 ~ 10.0%, Al 2o 3: 1.8 ~ 3.5%, CoO:0.5 ~ 1.1%, MnO 2: 0 ~ 1.8%, PbO:0 ~ 5.0%, NiO:1.0 ~ 2.5%; (ii) after being melting into enamel at 1150-1250 DEG C, ball milling pulping; Wherein R 2r in O is Li, Na, K or its combination;
The preparation process of described cover-coat enamel slurry is: (i) in weight percent summation 100%, batching: SiO 2: 42.0 ~ 55.0%, Al 2o 3: 4.0 ~ 10.0%, R 2o:15.0 ~ 25.0%, CaF 2: 1.2 ~ 2.8%, B 2o 3: 8.0 ~ 15.0%, Na 2siF 6: 1.9 ~ 7.6%, TiO 2: 0 ~ 3.0%, BaO:1.5 ~ 5.0%, CeO 2: 0 ~ 10.0%, MnO 2: 0 ~ 4.5%, Fe 2o 3: 0 ~ 8.5%; (ii) after being melting into enamel at 1150-1250 DEG C, ball milling pulping; Wherein R 2r in O is Li, Na, K or its combination.
2. the Enamelling Sheet Steel fireplace prepared of preparation method according to claim 1.
CN201510769219.2A 2015-09-25 2015-11-12 Enamelling sheet steel fireplace and preparation method thereof Expired - Fee Related CN105256313B (en)

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CN2015106194289 2015-09-25
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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN108385106A (en) * 2018-05-30 2018-08-10 深圳市金合联供应链技术有限公司 A kind of heat safe method of improvement enamel grate
CN108516685A (en) * 2018-04-20 2018-09-11 攀枝花学院 Heat and corrosion resistant enamel coating and preparation method thereof
CN112342544A (en) * 2020-10-19 2021-02-09 青岛裕晋精搪涂层有限公司 Low-temperature acid and alkali resistant cast iron enamel processing technology and coating formula

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108516685A (en) * 2018-04-20 2018-09-11 攀枝花学院 Heat and corrosion resistant enamel coating and preparation method thereof
CN108385106A (en) * 2018-05-30 2018-08-10 深圳市金合联供应链技术有限公司 A kind of heat safe method of improvement enamel grate
CN112342544A (en) * 2020-10-19 2021-02-09 青岛裕晋精搪涂层有限公司 Low-temperature acid and alkali resistant cast iron enamel processing technology and coating formula

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