CN110304828A - A kind of preparation method and ceramic tile without overglaze ceramic tile with concave-convex discoloration metal effect - Google Patents
A kind of preparation method and ceramic tile without overglaze ceramic tile with concave-convex discoloration metal effect Download PDFInfo
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- CN110304828A CN110304828A CN201910702505.5A CN201910702505A CN110304828A CN 110304828 A CN110304828 A CN 110304828A CN 201910702505 A CN201910702505 A CN 201910702505A CN 110304828 A CN110304828 A CN 110304828A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/10—Frit compositions, i.e. in a powdered or comminuted form containing lead
- C03C8/12—Frit compositions, i.e. in a powdered or comminuted form containing lead containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a kind of preparation methods and ceramic tile without overglaze ceramic tile with concave-convex discoloration metal effect, the method in frit by adding a variety of different metal powders, and frit is first mixed with Virgin's milk glue and water with the ratio that mass ratio is 1: 4~5: 3~5, adobe surface is sprayed to again, firing, the surface of ceramic tile is set to form rough effect, and various metal powders will not settle in spraying and sintering process, under the irradiation of different light, a variety of different hair color effects are presented, promote the ornamental value of ceramic tile, simplify the production technology of ceramic tile of the surface with concave-convex effect.
Description
Technical field
The present invention relates to ceramic tile and its preparation technical field, in particular to it is a kind of with color changeable effect without overglaze ceramic tile
Preparation method and ceramic tile.
Background technique
With the development of economy, improvement of living standard, people increasingly pay close attention to while pursuing the practicability of product
The aesthetics of product, the requirement to product aesthetics increasingly improve.Currently, having the ceramic tile of concave-convex decorative effect generally to pass through mould
Flower production, then glazing etc.；But this mode is at high cost, single effect, and pattern is difficult to adjust.In addition, also by silk screen, roller
The ceramic tile with concave-convex effect is prepared in conjunction with modes such as glaze, frits；Which high production cost, pattern are single, stability is low；
Above two mode does not adapt to pursuit of the people to artistic development and innovation art now.
Ceramic tile can be made in the lower presentation of different light-illuminatings in the different metal powder of the adobe surface charity of ceramic tile
A variety of different colors have the effect of discoloration；But the specific gravity of metallic particles is larger, it is difficult to it is suspended in glaze,
It is often settled in charity or sintering process, it is difficult to realize preset hair color effect.
As it can be seen that the prior art could be improved and improve.
Summary of the invention
Place in view of above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide have concave-convex discoloration metal effect
Preparation method and ceramic tile without overglaze ceramic tile, it is intended to solve ceramic tile high production cost in the prior art with concave-convex effect, figure
The technical problem that case is single etc. and the hair color effect of metallic chromonic effect ceramic tile is undesirable.
In order to achieve the above object, this invention takes following technical schemes:
A kind of preparation method without overglaze ceramic tile with concave-convex discoloration metal effect, comprising the following steps:
Step S001. prepares ceramic adobe；
Step S002. equably sprays dry granular material in adobe；
Step S003. is fired, and obtains finished product；
Wherein, the dry granular material includes frit, Virgin's milk glue and the water that mass ratio is 1: 4~5: 3~5.
In the preparation method without overglaze ceramic tile that there is concave-convex discoloration metal effect, further include before the step S002
Frit, Virgin's milk glue and water are uniformly mixed according to a ratio, dry granular material is made.
In the preparation method without overglaze ceramic tile for having concave-convex discoloration metal effect, the frit includes following quality
The ingredient of percentage: silica 50%~60%, aluminium oxide 4%~6%, calcium oxide 3%~7%, magnesia 0.1%~2%,
Potassium oxide 3%~6%, sodium oxide molybdena 1%~2%, zinc oxide 4%~8%, barium monoxide 0.5%~2%, lead oxide 0.6%~
1%, zirconium oxide 2%~6%, talcum 0.2%~0.5%, vanadium 0.08%~0.2%, titanium 0.04%~0.08%, iron 0.1%
~0.3%, chromium 0.05%~0.09%, surplus is impurity.
It is described in the step S002 in the preparation method without overglaze ceramic tile that there is concave-convex discoloration metal effect
Dry granular material is sprayed using high pressure glaze spraying cabinet, and spray pressure is 5.2~5.5MPa.
In the preparation method without overglaze ceramic tile for having concave-convex discoloration metal effect, the cloth doses of the dry granular material is
500~518g/m2。
In the preparation method without overglaze ceramic tile for having concave-convex discoloration metal effect, the size of the frit is 150
~200 mesh.
In the preparation method without overglaze ceramic tile that there is concave-convex discoloration metal effect, the firing in the step S003
Temperature is 1190~1220 DEG C, and firing time is 50~70min.
It is a kind of with concave-convex discoloration metal effect without overglaze ceramic tile, there is concave-convex discoloration by described in any of the above embodiments
The preparation method preparation without overglaze ceramic tile of metal effect.
It is described have concave-convex discoloration metal effect without overglaze ceramic tile, by green body and the dry granule layer group being covered on green body
At.
It is described have concave-convex discoloration metal effect without in overglaze ceramic tile, the dry granule layer with a thickness of 200~300 μm.
The utility model has the advantages that
It is described the present invention provides a kind of preparation method and ceramic tile without overglaze ceramic tile with concave-convex discoloration metal effect
Method is first mixed with Virgin's milk glue and water at a specific ratio by adding various different metal powder in frit, and by frit
It closes, then sprays to adobe surface, be burnt into, so that the surface of ceramic tile is formed rough effect, and various metal powders are spraying
It applies and will not be settled in sintering process, under the irradiation of different light, a variety of different hair color effects are presented, promote ceramic tile
Ornamental value.
Specific embodiment
The present invention provides a kind of preparation method and ceramic tile without overglaze ceramic tile with concave-convex discoloration metal effect, to make this
The purpose of invention, technical solution and effect are clearer, define, and the present invention is described in more detail by the following examples.It answers
Work as understanding, described herein specific examples are only used to explain the present invention, is not intended to limit the present invention.
The present invention provides a kind of preparation method without overglaze ceramic tile with concave-convex discoloration metal effect, including following step
It is rapid:
Ceramic adobe is prepared with the method in the prior art for preparing ceramic tile blank, removes extra moisture.
Frit, Virgin's milk glue and water are uniformly mixed at normal temperature with 1: 4~5: 3~5 ratio, dry granular material is made；So
The dry granular material is put into high pressure glaze spraying cabinet afterwards, sets the operating pressure of high pressure glaze spraying cabinet as 5.2~5.5MPa, using high pressure
The dry granular material is equably sprayed on adobe surface by glaze spraying cabinet, and cloth doses is 500~518g/m2。
Frit is first first mixed with white glue with vinyl and water, cloth is then applied by way of spraying in adobe, makes Virgin's milk glue
The frit can be sufficiently wrapped, avoids the metal powder in frit from settling, influences its hair color effect.And the treatment process
Agent bonding can will not cannot be glued because dry granular applies cloth amount excessively according to the thickness of the actual needs control dry granule layer of ceramic tile
In adobe, applicability is high.Furthermore, it is thus also avoided that the dust pollution that dry granular generates during applying cloth.
The dry granular material that frit, Virgin's milk glue and the water of aforementioned proportion form, viscosity are suitble to, and good leveling property can be equably
It is sprayed on the surface of adobe, and white glue with vinyl water energy is enough completely encapsulated in the surface of frit, the ceramic tile concave-convex effect after firing is equal
It is even, hair color effect is good.When applying 500~518g/m of cloth amount2When, adobe has excellent hair color effect and mechanical performance.Shi Buliang
Very few, the dry granule layer of formation is excessively thin, and scratch-resistant performance is low, and hardness is low, and hair color effect is undesirable；Shi Buliang is excessive, the thickness of ceramic tile
Thickness is spent, the decoration space of occupancy is more, influences its decorative performance, and waste dry granular material, is unfavorable for the raising of economic benefit.
Adobe after spraying is put into kiln, firing for 1190~1220 DEG C is 50~70min, it is cooling, obtain finished product.Firing
The phenomenon that temperature is excessively high, the firing time is too long, and ceramic tile easily deforms, glaze blistering or sagging；Firing temperature is too low, fires
Time is too short, and the porcelain effect of ceramic tile is incomplete, causes the strength reduction of finished product.
Specifically, the frit includes the ingredient of following mass percent: silica 50%~60%, aluminium oxide 4%~
6%, calcium oxide 3%~7%, magnesia 0.1%~2%, potassium oxide 3%~6%, sodium oxide molybdena 1%~2%, zinc oxide 4%~
8%, barium monoxide 0.5%~2%, lead oxide 0.6%~1%, zirconium oxide 2%~6%, talcum 0.2%~0.5%, vanadium
0.08%~0.2%, titanium 0.04%~0.08%, iron 0.1%~0.3%, chromium 0.05%~0.09%, surplus is impurity.Institute
It states frit and uses oxide and metal powder with different initial melting temperatures, melt it gradually in sintering process, in adobe
Surface form concave-convex effect, and the metal powder cannot settle under the action of white glue with vinyl, with the fusing of frit
Natural texture, and the color different because of metal itself are formed, the effect of discoloration is generated under the irradiation of light different angle,
It creates an aesthetic feeling, it is decorative strong.
More specifically, the size of the frit is 150~200 mesh；Conducive to forming difference in thickness after being uniformly distributed and being burnt into
Few dry granule layer.Frit granules are too small, dust pollution are easy to produce when increasing broken difficulty, and preparing dry granular material, no
It only wastes raw material, also not environmentally, improves production cost；Frit granules are excessive, are unfavorable for being uniformly distributed in adobe, when firing
The time melted completely is long, be easy to cause burn-off phenomenon.
It is a kind of with concave-convex discoloration metal effect without overglaze ceramic tile, pass through the above-mentioned nothing with concave-convex discoloration metal effect
It is prepared by the preparation method of overglaze ceramic tile；There is the concave-convex texture of self-assembling formation on the surface of the ceramic tile, different under the irradiation of light
Angle observes the effect that can generate discoloration, and ornamental value is high.
It is described have concave-convex discoloration metal effect without overglaze ceramic tile, by green body and the dry granule layer group being covered on green body
At；Wherein, the dry granule layer with a thickness of 200~300 μm.The ceramic tile is not directly by dry granule layer charity on ceramic tile, and not
With overglaze, manufacture craft is simplified, reduces the thickness of ceramic tile, improves its decorative performance to a certain extent.
Embodiment 1
A kind of preparation method without overglaze ceramic tile with concave-convex discoloration metal effect, comprising the following steps:
Ceramic adobe is prepared with the method in the prior art for preparing ceramic tile blank, removes extra moisture；
Frit, Virgin's milk glue and water are uniformly mixed at normal temperature with 1: 4: 3 ratio, dry granular material is made；Then by institute
It states dry granular material to be put into high pressure glaze spraying cabinet, sets the operating pressure of high pressure glaze spraying cabinet as 5.5MPa, using high pressure glaze spraying cabinet by institute
It states dry granular material and is equably sprayed on adobe surface, cloth doses is 500~518g/m2；
Adobe after spraying is put into kiln, firing for 1200 DEG C is 60min, it is cooling, obtain finished product.
Wherein, the frit includes the ingredient of following mass percent: silica 50%, aluminium oxide 5%, calcium oxide 6%,
Magnesia 0.8%, potassium oxide 5%, sodium oxide molybdena 2%, zinc oxide 6%, barium monoxide 2%, lead oxide 1%, zirconium oxide 4%, talcum
0.4%, vanadium 0.1%, titanium 0.08%, iron 0.2%, chromium 0.09%, surplus is impurity；The size of the frit is 150~200
Mesh.
Above method preparation have concave-convex discoloration metal effect without overglaze ceramic tile, by green body and be covered on green body
Dry granule layer composition；Wherein, the dry granule layer with a thickness of 220~250 μm；There is uniform concave-convex effect on the surface of ceramic tile, and
Texture with natural discoloration metal effect, good decorating effect.
Embodiment 2
A kind of preparation method without overglaze ceramic tile with concave-convex discoloration metal effect, comprising the following steps:
Ceramic adobe is prepared with the method in the prior art for preparing ceramic tile blank, removes extra moisture；
Frit, Virgin's milk glue and water are uniformly mixed at normal temperature with 1: 4: 4 ratio, dry granular material is made；Then by institute
It states dry granular material to be put into high pressure glaze spraying cabinet, sets the operating pressure of high pressure glaze spraying cabinet as 5.2MPa, using high pressure glaze spraying cabinet by institute
It states dry granular material and is equably sprayed on adobe surface, cloth doses is 500~518g/m2；
Adobe after spraying is put into kiln, firing for 1190 DEG C is 65min, it is cooling, obtain finished product.
Wherein, the frit includes the ingredient of following mass percent: silica 55%, aluminium oxide 6%, calcium oxide 5%,
Magnesia 0.1%, potassium oxide 3%, sodium oxide molybdena 1%, zinc oxide 7%, barium monoxide 1.5%, lead oxide 0.6%, zirconium oxide 2%,
Talcum 0.5%, vanadium 0.08%, titanium 0.04%, iron 0.1%, chromium 0.07%, surplus are impurity；The size of the frit be 150~
200 mesh.
Above method preparation have concave-convex discoloration metal effect without overglaze ceramic tile, by green body and be covered on green body
Dry granule layer composition；Wherein, the dry granule layer with a thickness of 220~240 μm；There is uniform concave-convex effect on the surface of ceramic tile, and
Texture with natural discoloration metal effect, good decorating effect.
Embodiment 3
A kind of preparation method without overglaze ceramic tile with concave-convex discoloration metal effect, comprising the following steps:
Ceramic adobe is prepared with the method in the prior art for preparing ceramic tile blank, removes extra moisture；
Frit, Virgin's milk glue and water are uniformly mixed at normal temperature with 1: 5: 5 ratio, dry granular material is made；Then by institute
It states dry granular material to be put into high pressure glaze spraying cabinet, sets the operating pressure of high pressure glaze spraying cabinet as 5.3MPa, using high pressure glaze spraying cabinet by institute
It states dry granular material and is equably sprayed on adobe surface, cloth doses is 500~518g/m2；
Adobe after spraying is put into kiln, firing for 1220 DEG C is 70min, it is cooling, obtain finished product.
Wherein, the frit includes the ingredient of following mass percent: silica 58%, aluminium oxide 5.5%, calcium oxide
3%, magnesia 2%, potassium oxide 6%, sodium oxide molybdena 1.2%, zinc oxide 8%, barium monoxide 1.6%, lead oxide 0.8%, zirconium oxide
6%, talcum 0.2%, vanadium 0.15%, titanium 0.06%, iron 0.3%, chromium 0.05%, surplus is impurity；The size of the frit is
150~200 mesh.
Above method preparation have concave-convex discoloration metal effect without overglaze ceramic tile, by green body and be covered on green body
Dry granule layer composition；Wherein, the dry granule layer with a thickness of 280~300 μm；There is uniform concave-convex effect on the surface of ceramic tile, and
Texture with natural discoloration metal effect, good decorating effect.
Embodiment 4
A kind of preparation method without overglaze ceramic tile with concave-convex discoloration metal effect, comprising the following steps:
Ceramic adobe is prepared with the method in the prior art for preparing ceramic tile blank, removes extra moisture；
Frit, Virgin's milk glue and water are uniformly mixed at normal temperature with 1: 5: 3 ratio, dry granular material is made；Then by institute
It states dry granular material to be put into high pressure glaze spraying cabinet, sets the operating pressure of high pressure glaze spraying cabinet as 5.4MPa, using high pressure glaze spraying cabinet by institute
It states dry granular material and is equably sprayed on adobe surface, cloth doses is 500~518g/m2；
Adobe after spraying is put into kiln, firing for 1200 DEG C is 60min, it is cooling, obtain finished product.
Wherein, the frit includes the ingredient of following mass percent: silica 52%, aluminium oxide 4.5%, calcium oxide
4%, magnesia 1.2%, potassium oxide 4%, sodium oxide molybdena 1.6%, zinc oxide 4%, barium monoxide 1.7%, lead oxide 0.7%, oxidation
Zirconium 5%, talcum 0.3%, vanadium 0.2%, titanium 0.05%, iron 0.15%, chromium 0.06%, surplus are impurity；The size of the frit
For 150~200 mesh.
Above method preparation have concave-convex discoloration metal effect without overglaze ceramic tile, by green body and be covered on green body
Dry granule layer composition；Wherein, the dry granule layer with a thickness of 200~220 μm；There is uniform concave-convex effect on the surface of ceramic tile, and
Texture with natural discoloration metal effect, good decorating effect.
Embodiment 5
A kind of preparation method without overglaze ceramic tile with concave-convex discoloration metal effect, comprising the following steps:
Ceramic adobe is prepared with the method in the prior art for preparing ceramic tile blank, removes extra moisture；
Frit, Virgin's milk glue and water are uniformly mixed at normal temperature with 1: 4: 5 ratio, dry granular material is made；Then by institute
It states dry granular material to be put into high pressure glaze spraying cabinet, sets the operating pressure of high pressure glaze spraying cabinet as 5.5MPa, using high pressure glaze spraying cabinet by institute
It states dry granular material and is equably sprayed on adobe surface, cloth doses is 500~518g/m2；
Adobe after spraying is put into kiln, firing for 1190 DEG C is 60min, it is cooling, obtain finished product.
Wherein, the frit includes the ingredient of following mass percent: silica 60%, aluminium oxide 4%, calcium oxide 7%,
Magnesia 1.6%, potassium oxide 4%, sodium oxide molybdena 1.5%, zinc oxide 5%, barium monoxide 1.8%, lead oxide 0.9%, zirconium oxide
3%, talcum 0.4%, vanadium 0.12%, titanium 0.07%, iron 0.25%, chromium 0.08%, surplus is impurity；The size of the frit is
150~200 mesh.
Above method preparation have concave-convex discoloration metal effect without overglaze ceramic tile, by green body and be covered on green body
Dry granule layer composition；Wherein, the dry granule layer with a thickness of 260~280 μm；There is uniform concave-convex effect on the surface of ceramic tile, and
Texture with natural discoloration metal effect, good decorating effect.
It, can according to the technique and scheme of the present invention and its hair it is understood that for those of ordinary skills
Bright design is subject to equivalent substitution or change, and all these changes or replacement all should belong to the guarantor of appended claims of the invention
Protect range.
Claims (10)
1. a kind of preparation method without overglaze ceramic tile with concave-convex discoloration metal effect, which comprises the following steps:
Step S001. prepares ceramic adobe；
Step S002. equably sprays dry granular material in adobe；
Step S003. is fired, and obtains finished product；
Wherein, the dry granular material includes frit, Virgin's milk glue and the water that mass ratio is 1: 4~5: 3~5.
2. the preparation method without overglaze ceramic tile with concave-convex discoloration metal effect according to claim 1, feature exist
In further including being uniformly mixed according to a ratio frit, Virgin's milk glue and water before the step S002, dry granular material be made.
3. the preparation method without overglaze ceramic tile with concave-convex discoloration metal effect according to claim 1, feature exist
In the frit includes the ingredient of following mass percent: silica 50%~60%, aluminium oxide 4%~6%, calcium oxide 3%
~7%, magnesia 0.1%~2%, potassium oxide 3%~6%, sodium oxide molybdena 1%~2%, zinc oxide 4%~8%, barium monoxide
0.5%~2%, lead oxide 0.6%~1%, zirconium oxide 2%~6%, talcum 0.2%~0.5%, vanadium 0.08%~0.2%,
Titanium 0.04%~0.08%, iron 0.1%~0.3%, chromium 0.05%~0.09%, surplus are impurity.
4. the preparation method without overglaze ceramic tile with concave-convex discoloration metal effect according to claim 1, feature exist
In in the step S002, the dry granular material is sprayed using high pressure glaze spraying cabinet, and spray pressure is 5.2~5.5MPa.
5. the preparation method without overglaze ceramic tile with concave-convex discoloration metal effect according to claim 1, feature exist
In the cloth doses of the dry granular material is 500~518g/m2。
6. the preparation method without overglaze ceramic tile with concave-convex discoloration metal effect according to claim 1, feature exist
In the size of the frit is 150~200 mesh.
7. the preparation method without overglaze ceramic tile with concave-convex discoloration metal effect according to claim 1, feature exist
In the firing temperature in the step S003 is 1190~1220 DEG C, and firing time is 50~70min.
8. it is a kind of with concave-convex discoloration metal effect without overglaze ceramic tile, which is characterized in that by any in claim 1~7
The preparation method preparation without overglaze ceramic tile with concave-convex discoloration metal effect described in.
9. it is according to claim 8 have concave-convex discoloration metal effect without overglaze ceramic tile, which is characterized in that the ceramic tile
It is made of green body and the dry granule layer being covered on green body.
10. it is according to claim 9 have concave-convex discoloration metal effect without overglaze ceramic tile, which is characterized in that it is described dry
Granulosa with a thickness of 200~300 μm.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111452197A (en) * | 2020-04-08 | 2020-07-28 | 郭五连 | Surface glazing treatment process for preparing decorative wall brick |
| CN114890777A (en) * | 2022-06-15 | 2022-08-12 | 佛山市三水天宇陶瓷颜料有限公司 | Dry granules with metal luster for blank, preparation process and preparation process of ceramic tile |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111452197A (en) * | 2020-04-08 | 2020-07-28 | 郭五连 | Surface glazing treatment process for preparing decorative wall brick |
| CN114890777A (en) * | 2022-06-15 | 2022-08-12 | 佛山市三水天宇陶瓷颜料有限公司 | Dry granules with metal luster for blank, preparation process and preparation process of ceramic tile |
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