CN101786904A - Color-changing glaze for metallic luster ceramics and preparation method thereof - Google Patents

Color-changing glaze for metallic luster ceramics and preparation method thereof Download PDF

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Publication number
CN101786904A
CN101786904A CN200910254659A CN200910254659A CN101786904A CN 101786904 A CN101786904 A CN 101786904A CN 200910254659 A CN200910254659 A CN 200910254659A CN 200910254659 A CN200910254659 A CN 200910254659A CN 101786904 A CN101786904 A CN 101786904A
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glaze
coat enamel
underlying metal
color
metal ground
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CN101786904B (en
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李缨
刘纯
成智文
王晓兰
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Xianyang Research & Design Institute Of Ceramics
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Xianyang Research & Design Institute Of Ceramics
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Abstract

The invention relates to a color-changing glaze for metallic luster ceramics and a preparation method thereof. The color-changing glaze comprises a base metal under-glaze and a color-changing over-glaze. The method comprises the following steps: respectively proportioning the base metal under-glaze and the color-changing over-glaze according to the requirements, then respectively adding 0.2-1.2% CMC, and respectively adding water to be subjected to ball milling, wherein the fineness of the base metal under-glaze is controlled to the extent that all particles can pass through a 425-meshed screen, and the fineness of the color-changing over-glaze is controlled to the extent that all particles can pass through a 325-meshed screen; spraying or pouring the base metal under-glaze on the surface of a ceramic body, and then spraying or pouring the color-changing over-glaze over the base metal under-glaze, wherein the thickness of the base metal under-glaze is controlled to range from 0.1mm to 1.2mm, and the thickness of the color-changing over-glaze is controlled to range from 0.1mm to 0.6mm; and drying the ceramic body, and carrying out the one-step firing at 1150-1210 DEG C. The obtained color-changing metal glaze has the advantages of diversified colors, good glaze quality, high mechanical property and high chemical stability, has metallic tactile sensation, and can change the colors under the irradiation of different light sources.

Description

A kind of metalluster ceramic glaze and preparation method thereof with color changeable effect
One, technical field
The present invention relates to a kind of metalluster ceramic glaze with color changeable effect, is the glaze that a kind of pottery is used, and specifically relates to have the glaze of the metalluster effect of changeable colour under the Different Light irradiation.
Two, background technology
Under the modern civilization tide promoted, people were to the expectation of the aesthstic level of ceramic and pursue strong day by day, and metal-lustrous glaze is developed for this aesthetic psychology that satisfies people and go back to nature.And metal glaze belongs to more special product, except that presenting at surface energy the different metal gloss, can arrange in pairs or groups performances such as spraying, printing other plant the style product, as series modelled after an antique, effects such as imitative stone material.Make ceramic tile effect field more colourful.
The making method that realizes metal lustre decorative glaze at present has three kinds: (1) is direct splash melting metal layer on ceramic body; (2) on the ceramic glaze, be coated with to contain the coating of metal or metal compound powders, handle, form the metallization ornament layer through reduction heat; When (3) glaze of definite composition burnt till in company with goods, outer appearnces such as generation color harmony gloss were like the metal-imitation glaze of certain metalloid.
Chinese patent CN1432483A discloses a kind of preparation method of artistic porcelain glaze with metal rust spots, and its technical essential is that glazing process is: execute ground-coat enamel earlier, execute coloured glaze again, with acid solution the coloured glaze surface is handled at last.The present invention can produce rust staining goods true to nature.
Chinese patent CN1521145A discloses a kind of construction sanitary ceramic metalluster crystalline glaze, it is with zinc oxide, silicon oxide or titanium oxide are the one-tenth eutectic substance of glaze, with low temperature frit, boric acid is for forming the Vitrea flux raw material of glaze, with cupric oxide, ferric oxide, manganese oxide, metal oxides such as titanium oxide are tinting material, be prepared by common ceramic glaze production technique, impose on the surface of construction sanitary ceramic, by burning till continuously fast of being fit to, adopt short insulation to educate the distinct temperature curve in brilliant cycle, glaze is formed have the glass-ceramic layer of metalluster, the decorative effect of its existing metalluster has the physical strength of devitrified glass again like this.
Chinese patent CN101148369A discloses a kind of ceramic glaze with metal-like, it comprises the underlying metal cover-coat enamel that is mixed and made into by multiple metal oxide and covers screen printing glaze two portions, this glaze is sprayed on pottery, make ceramic product not only present various metallic luster, the surface has certain metal-like.
Chinese patent CN101531540A discloses a kind of preparation method of low-temperature metal lustre decorative glaze, with albite powder, kaolin powder, tricalcium phosphate powder, quartzy powder, Zinc oxide powder, ferric oxide powder, sodium polyphosphate powder and nickel oxide powder mix compound; Compound at 700～900 ℃ of sintering, is smashed to pieces the compound behind the sintering and crossed 120 mesh sieves behind the ball milling; At last, the compound after sieving and water are mixed and made into the glaze slip of suspension, with this glaze slip after firing temperature is 1100～1200 ℃ of coolings after the ceramic body surface glazing metal lustre decorative glaze.
Three, summary of the invention
The objective of the invention is at the deficiencies in the prior art, the decorative effect of abundant pottery, a kind of metalluster ceramic glaze with color changeable effect is proposed, it is ornamental to increase existing ceramic product, and usability provides a kind of market frontier that has, the color variation, glaze quality is good, and mechanical property is strong, and chemical stability is high has metal-like, the ceramic glaze of colour-change can take place under the Different Light irradiation.Another object of the present invention relates to preparation method of the present invention.
It is to be made of underlying metal ground-coat enamel and variable color cover-coat enamel two portions for the present invention, and the component of underlying metal ground-coat enamel and variable color cover-coat enamel is respectively as follows:
Underlying metal ground-coat enamel of the present invention is made of by weight ratio following composition:
SiO 2?20～55％、Al 2O 3?10～40％、P 2O 5?2～20％、CaO?2～20％、B 2O 31～15％、Na 2O?1～20％、BaO?0～15％、PbO?0～12％、ZnO?1～15％、MnO 2?0～10％、V 2O 5?0～8％、CuO?0～10％、TiO 2?0～15％、NiO?0～10％、Fe 2O 3?0～15％；
Variable color cover-coat enamel of the present invention is made of by weight ratio following composition:
SiO 2?22～60％、Al 2O 3?11～50％、CaO?1～20％、B 2O 3?1～15％、Na 2O?2～15％、ZnO?1～15％、Nd 2O 3?5～13％、Pr 2O 3?1～5％；
Preparation method of the present invention:
(1), the underlying metal ground-coat enamel prepares by above-mentioned component, carries out ball milling after adding 0.2～1.2% CMC, reduce the water ratio of glaze and promote the flowability of glaze.Underlying metal ground-coat enamel fineness is controlled at 425mesh sieve all-pass mistake, and underlying metal ground-coat enamel glazing gauge control is between 0.1～1.2 millimeter;
(2), the variable color cover-coat enamel is prepared by above-mentioned component, carry out ball milling behind the CMC of adding 0.2～1.2%, reduce the flowability of the water ratio and the promotion glaze of glaze, variable color cover-coat enamel fineness is controlled at 325mesh sieve all-pass mistake, and variable color cover-coat enamel glazing gauge control is between 0.1～0.6 millimeter.
(3), the underlying metal ground-coat enamel is sprayed or water pouring behind the ceramic body surface, again the variable color cover-coat enamel is covered on the underlying metal ground-coat enamel with spraying or water the pouring method, behind the oven dry ceramic body, get final product at 1150～1210 ℃ of once-firings.
Characteristic of the present invention is:
1, product presents distinct colors under different light source irradiation.The said rare earth neodymium changing colour enamal of the present invention pigment is that 17～29% variable color neodymium pigment and 83～71% feldspar glaze are formed by weight percent; Rare earth neodymium changing colour enamal of the present invention is combined into the changing colour enamal product with camouflage paint in ceramic glaze and porcelain, and it shows distinct colors under the Different Light irradiation.As showing light blue under fluorescent light, apparent lilac under the natural light, the next apparent light green of electricity-saving lamp.
2, product surface has metalluster texture, has decorative effect preferably;
The allotment of underlying metal ground-coat enamel different ingredients that 3, can be by above-mentioned prescription and the collocation of firing temperature can constitute multiple different metallic luster such as cuprous look, highlighted iron look, orichalceous, gold look, inferior light platinum look etc.;
4, adopt its glaze quality of product of above-mentioned prescription and technology good, mechanical property is strong, the chemical stability height;
Four, embodiment
A kind of metalluster ceramic glaze of the present invention with color changeable effect, can be according to the difference collocation of the underlying metal ground-coat enamel and the different and firing temperature of variable color cover-coat enamel different ingredients, glazing thickness, can constitute multiple different metallic luster such as cuprous look, highlighted iron look, orichalceous, gold look, inferior light platinum look etc., with under Different Light irradiation, present different light blue of the depth, lilac, absinthe-green masonry effect.
Embodiment of the present invention 1:
(1), underlying metal ground-coat enamel prescription is: SiO 254%, Al 2O 313%, P 2O 55%, CaO 2%, B 2O 33%, Na 2O 2%, BaO 1%, PbO 2%, ZnO 6%, V 2O 54.5%, Fe 2O 37.5%.
(2), variable color cover-coat enamel prescription is: SiO 259%, Al 2O 316.5%, CaO 4%, B 2O 33%, K 2O 4.2%, Na 2O 3.3%, ZnO 3%, Nd 2O 36%, Pr 2O 31%.
The preparation method: (1), underlying metal ground-coat enamel are prepared by above-mentioned component, carry out ball milling behind the CMC of adding 0.5%, reduce the flowability of the water ratio and the promotion glaze of glaze.Underlying metal ground-coat enamel fineness is controlled at 425mesh sieve all-pass mistake, and underlying metal ground-coat enamel glazing gauge control is between 0.3～0.4 millimeter;
(2), the variable color cover-coat enamel is prepared by above-mentioned component, carry out ball milling behind the CMC of adding 0.5%, reduce the flowability of the water ratio and the promotion glaze of glaze, variable color cover-coat enamel fineness is controlled at 325mesh sieve all-pass mistake, and variable color cover-coat enamel glazing gauge control is between 0.5～0.6 millimeter;
(3), the underlying metal ground-coat enamel is sprayed or water pouring behind the ceramic body surface, again the variable color cover-coat enamel is covered on the underlying metal ground-coat enamel with spraying or water the pouring method, behind the oven dry ceramic body, get final product at 1150 ℃ of once-firings.Product presents golden metalluster, and presents the more shallow different colours of band under the Different Light irradiation.
Embodiment of the present invention 2:
(1), underlying metal ground-coat enamel prescription is: SiO 258%, Al 2O 316%, P 2O 53%, CaO 2%, B 2O 31%, Na 2O 1%, BaO 1%, ZnO 2%, V 2O 54%, Fe 2O 34%, TiO 25%, NiO 3%
(2), variable color cover-coat enamel prescription is: SiO 261%, Al 2O 317%, CaO 3%, B 2O 31%, K 2O 4%, Na 2O 2%, ZnO 2%, Nd 2O 38%, Pr 2O 32%.
The preparation method: (1), underlying metal ground-coat enamel are prepared by above-mentioned component, carry out ball milling behind the CMC of adding 0.8%, reduce the flowability of the water ratio and the promotion glaze of glaze.Underlying metal ground-coat enamel fineness is controlled at 425mesh sieve all-pass mistake, and underlying metal ground-coat enamel glazing gauge control is between 0.2～0.3 millimeter;
(2), the variable color cover-coat enamel is prepared by above-mentioned component, carry out ball milling behind the CMC of adding 0.8%, reduce the flowability of the water ratio and the promotion glaze of glaze, variable color cover-coat enamel fineness is controlled at 325mesh sieve all-pass mistake, and variable color cover-coat enamel glazing gauge control is between 0.3～0.4 millimeter;
(3), on ceramic body, adopt the glazing of glaze spraying mode, behind the oven dry ceramic body, get final product at 1180 ℃ of once-firings.Product presents the metalluster of silver color, and presents the darker different colours of band under the Different Light irradiation.
Embodiments of the invention 3
With underlying metal ground-coat enamel prescription be: SiO 258%, Al 2O 316%, P 2O 53%, CaO 2%, B 2O 31%, Na 2O 1%, BaO 1%, ZnO 2%, V 2O 54%, Fe 2O 34%, TiO 25%, NiO 3% variable color cover-coat enamel prescription is: SiO 261%, Al 2O 317%, CaO 3%, B 2O 31%, K 2O 4%, Na 2O 2%, ZnO2%, Nd 2O 38%, Pr 2O 32%.
The preparation method: (1), underlying metal ground-coat enamel are prepared by above-mentioned component, carry out ball milling behind the CMC of adding 0.8%, reduce the flowability of the water ratio and the promotion glaze of glaze.Underlying metal ground-coat enamel fineness is controlled at 425mesh sieve all-pass mistake, and underlying metal ground-coat enamel glazing gauge control is between 0.2～0.3 millimeter;
(2), the variable color cover-coat enamel is prepared by above-mentioned component, carry out ball milling behind the CMC of adding 0.8%, reduce the flowability of the water ratio and the promotion glaze of glaze, variable color cover-coat enamel fineness is controlled at 325mesh sieve all-pass mistake, and variable color cover-coat enamel glazing gauge control is between 0.3～0.4 millimeter;
(3), on ceramic body, adopt the glazing of glaze spraying mode, behind the oven dry ceramic body, get final product at 1180 ℃ of once-firings.Product presents the metalluster of silver color, and presents the darker different colours of band under the Different Light irradiation.

Claims (2)

1. metalluster ceramic glaze with color changeable effect, it is characterized in that: it is to be made of underlying metal ground-coat enamel and variable color cover-coat enamel two portions, and the component of underlying metal ground-coat enamel and variable color cover-coat enamel is respectively as follows:
The underlying metal ground-coat enamel is made of by weight ratio following composition:
SiO 2?20～55％、 Al 2O 3?10～40％、 P 2O 5 2～20％、 CaO?2～20％、
B 2O 3?1～15％、 Na 2O 1～20％、 BaO 0～15％、 PbO?0～12％、
ZnO 1～15％、 MnO 2 0～10％、 V 2O 5 0～8％、 CuO?0～10％、
TiO 2?0～15％、 NiO 0～10％、 Fe 2O 3?0～15％；
The variable color cover-coat enamel is made of by weight ratio following composition:
SiO 2?22～60％、 Al 2O 3?11～50％、 CaO 1～20％、 B 2O 3 1～15％、
Na 2O?2～15％、 ZnO 1～15％、 Nd 2O 3?5～13％、 Pr 2O 3?1～5％；
2. as claims 1 described a kind of preparation method with metalluster ceramic glaze of color changeable effect:
(1), the underlying metal ground-coat enamel is prepared by above-mentioned component, carry out ball milling behind the CMC of adding 0.2～1.2%, reduce the flowability of the water ratio and the promotion glaze of glaze, underlying metal ground-coat enamel fineness is controlled at 425mesh sieve all-pass mistake, and underlying metal ground-coat enamel glazing gauge control is between 0.1～1.2 millimeter;
(2), the variable color cover-coat enamel is prepared by above-mentioned component, carry out ball milling behind the CMC of adding 0.2～1.2%, reduce the flowability of the water ratio and the promotion glaze of glaze, variable color cover-coat enamel fineness is controlled at 325mesh sieve all-pass mistake, and variable color cover-coat enamel glazing gauge control is between 0.1～0.6 millimeter.
(3), the underlying metal ground-coat enamel is sprayed or water pouring behind the ceramic body surface, again the variable color cover-coat enamel is covered on the underlying metal ground-coat enamel with spraying or water the pouring method, behind the oven dry ceramic body, get final product at 1150～1210 ℃ of once-firings.
CN2009102546599A 2009-12-22 2009-12-22 Color-changing glaze for metallic luster ceramics and preparation method thereof Expired - Fee Related CN101786904B (en)

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