CN115196994A - Touch gold glaze ceramic and preparation method thereof - Google Patents
Touch gold glaze ceramic and preparation method thereof Download PDFInfo
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- CN115196994A CN115196994A CN202210973735.7A CN202210973735A CN115196994A CN 115196994 A CN115196994 A CN 115196994A CN 202210973735 A CN202210973735 A CN 202210973735A CN 115196994 A CN115196994 A CN 115196994A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 29
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims description 12
- 229910052737 gold Inorganic materials 0.000 title claims description 12
- 239000010931 gold Substances 0.000 title claims description 12
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 58
- 239000002184 metal Substances 0.000 claims abstract description 58
- 239000002932 luster Substances 0.000 claims abstract description 48
- 238000002679 ablation Methods 0.000 claims description 22
- 238000010304 firing Methods 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 14
- 239000003292 glue Substances 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- 239000010453 quartz Substances 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 210000000078 claw Anatomy 0.000 claims description 9
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 8
- 230000035807 sensation Effects 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- 229910021538 borax Inorganic materials 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 7
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 7
- 239000004328 sodium tetraborate Substances 0.000 claims description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 7
- 239000011787 zinc oxide Substances 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 4
- 239000005751 Copper oxide Substances 0.000 claims description 4
- 235000019738 Limestone Nutrition 0.000 claims description 4
- 239000010883 coal ash Substances 0.000 claims description 4
- 229910000431 copper oxide Inorganic materials 0.000 claims description 4
- 239000010433 feldspar Substances 0.000 claims description 4
- 239000006028 limestone Substances 0.000 claims description 4
- 239000010451 perlite Substances 0.000 claims description 4
- 235000019362 perlite Nutrition 0.000 claims description 4
- 229910052573 porcelain Inorganic materials 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- 229920001353 Dextrin Polymers 0.000 claims description 3
- 239000004375 Dextrin Substances 0.000 claims description 3
- 229910052656 albite Inorganic materials 0.000 claims description 3
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 235000019425 dextrin Nutrition 0.000 claims description 3
- 239000010459 dolomite Substances 0.000 claims description 3
- 229910000514 dolomite Inorganic materials 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 3
- 229910052628 phlogopite Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000004321 preservation Methods 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 239000000454 talc Substances 0.000 claims description 3
- 229910052623 talc Inorganic materials 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 4
- 239000010410 layer Substances 0.000 abstract description 19
- 230000000694 effects Effects 0.000 abstract description 8
- 239000003086 colorant Substances 0.000 abstract description 6
- 238000004040 coloring Methods 0.000 abstract description 3
- 239000002244 precipitate Substances 0.000 abstract description 3
- 239000011241 protective layer Substances 0.000 abstract description 3
- 229920006395 saturated elastomer Polymers 0.000 abstract description 3
- 239000002585 base Substances 0.000 description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 241000695776 Thorichthys aureus Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- MPOKJOWFCMDRKP-UHFFFAOYSA-N gold;hydrate Chemical compound O.[Au] MPOKJOWFCMDRKP-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- -1 salt ions Chemical class 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to the field of ceramic preparation processes, in particular to a gold-touch glazed ceramic which comprises a blank body, wherein a transparent ground glaze, a metallic luster glaze and a transparent overglaze are sequentially covered on the surface of the blank body. The coloring agent and the frit are matched into the metallic luster glaze, and the metallic coloring oxide is saturated and precipitated in the high-temperature sintered solution to form a precipitate with metallic luster, so that the glaze surface presents the platinum-like metallic luster and has unique color tone and luster; the transparent bottom surface provides a smooth attachment base surface for the attachment of the metallic luster glaze, so that the metal layer is smooth and flat; the transparent overglaze provides a wear-resistant oxide protective layer for the metal layer; the glaze surface is finally sintered to present the metallic luster glaze effect with local concave-convex touch and blue scattered spots.
Description
Technical Field
The invention relates to the field of ceramic preparation processes, in particular to touch gold glaze ceramic and a preparation method thereof.
Background
The glaze with metal luster is a glaze material which can make the glaze surface have metal luster such as cash, silver and the like. The metallic luster glaze has good chemical stability, acid and alkali resistance, corrosion resistance and excellent usability. The early metal glaze adopts gold water to coat the glaze surface, and then the glaze surface is baked at low temperature to generate metal effect, but the metal glaze adopts precious gold or platinum as raw material, and the precious gold or the platinum is used after being made into metal, so the cost is high, and the metal glaze cannot be popularized in a large area. For this reason, a new decoration method has emerged in the year: a process for thermally spraying the surface of glazed tile to colour it includes such steps as spraying organic or inorganic metallic salt solution on the surface of hot blank, high-temp pyrolysis to form a layer of metallic oxide film on the surface of glaze, which can generate different metallic lustre according to the different colours of metallic salt ions. Although the thermal spraying process does not need to adopt precious metals such as gold and the like, the following defects still exist: the device depends on high-temperature spraying equipment, the equipment investment is large, the surface is easy to be sprayed unevenly, the local thickness is inconsistent, the glaze luster and the color of the glaze are uneven, and the like, so that the spraying is often required to be performed for five or six times.
Disclosure of Invention
An object of the present invention is to solve at least the above problems by a gold-glazed ceramic with tactile sensation and a method for preparing the same.
In order to solve the technical problems, the technical scheme adopted by the invention is as follows: touch gold glaze pottery, its characterized in that: the metal luster glaze comprises a blank body, wherein the surface of the blank body is sequentially covered with a transparent ground glaze, a metal luster glaze and a transparent overglaze, and the metal luster glaze comprises the following raw materials in parts by weight: 10-12 parts of feldspar, 8-10 parts of limestone, 12-15 parts of borax, 3-4 parts of zinc oxide, 8-10 parts of perlite, 10-12 parts of manganese dioxide, 1-1.5 parts of titanium oxide, 1-2 parts of copper oxide and 1-2 parts of nickel oxide.
Preferably, the transparent ground coat comprises the following raw materials in parts by weight: 10-12 parts of albite, 12-14 parts of calcium carbonate, 5-10 parts of talc, 15-18 parts of dolomite, 10-12 parts of kaolin, 20-25 parts of quartz and 3-4 parts of glue, wherein the transparent overglaze comprises the following raw materials in parts by weight: 30-35 parts of potassium feldspar, 10-12 parts of quartz, 5-8 parts of borax, 5-8 parts of sodium carbonate and 15-18 parts of kaolin.
Preferably, the metallic luster glaze is provided with ablation pits, the ablation pits are filled with flash glaze, and the flash glaze comprises the following components in parts by weight: 50-60 parts of flash particles, 5-8 parts of coal ash and 2-3 parts of glue.
Preferably, the flash particles comprise the following raw materials in parts by weight: 3-5 parts of nickel oxide, 5-6 parts of zinc oxide, 15-18 parts of quartz, 20-24 parts of rutile and raw materials of flash particles are mixed and melted to form blue crystals, and then the blue crystals are cooled, crushed and ground into powder and pass through a 80-mesh sieve for later use.
Preferably, a layer of metal base glaze is further arranged between the transparent base glaze and the metal luster glaze, and the metal base glaze comprises the following components in parts by weight: 90-100 parts of phlogopite, 10-15 parts of quartz and 3-4 parts of dextrin.
The preparation method of the gold glaze ceramic with the touch feeling is characterized by comprising the following steps:
step a, preparing a ceramic blank;
b, applying a layer of transparent ground coat on the surface of the blank, and firing the blank in a kiln;
c, applying metallic luster glaze, and putting into a kiln to be sintered to form a metal layer;
d, placing the porcelain on a laser seat, and applying laser to the metal layer at intervals by a laser source to form ablation pits at intervals;
e, embedding flash glaze material in the ablation concave points, and naturally drying;
and f, applying the transparent overglaze, firing in a kiln, and presenting a metal tactile glaze surface with concave-convex tactile sensation and flashing points on the ceramic.
Preferably, in the step b, glue is added into the transparent ground coat in proportion, the firing temperature is 1000-1050 ℃, and the heat preservation time is 2-3h.
Preferably, in step d, the ablation pits arranged at intervals form a pattern or are arranged in a matrix.
Preferably, in the step d, the laser seat is a rotating platform, a vacuum chuck is arranged at the center of the rotating platform, three positioning claws for positioning the center are arranged on the turntable, and the laser source moves up and down under the driving of the lifting mechanism.
Preferably, in the step c, before the applying of the metallic luster glaze, the metallic base glaze is applied on the transparent base glaze, and after the baking at 180-220 ℃, the metallic luster glaze is applied on the metallic base glaze.
As can be seen from the above description, the touch gold glaze ceramic and the preparation method thereof provided by the invention have the following beneficial effects: the coloring agent and the frit are matched into the metallic luster glaze, and the metallic coloring oxide is saturated and precipitated in the high-temperature sintered solution to form a precipitate with metallic luster, so that the glaze surface presents the platinum-like metallic luster and has unique color tone and luster; the transparent bottom surface provides a smooth attachment base surface for the attachment of the metallic luster glaze, so that the metal layer is smooth and flat; the transparent overglaze provides a wear-resistant oxide protective layer for the metal layer; finally, the glaze surface is sintered to present the metallic luster glaze effect with local concave-convex touch and blue light scattering spots.
Detailed Description
The invention is further described below by means of specific embodiments.
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further explained by combining the specific embodiments.
The touch gold glaze ceramic comprises a blank body, wherein the surface of the blank body is sequentially covered with a transparent ground coat, a metallic luster glaze and a transparent overglaze, and the metallic luster glaze comprises the following raw materials in parts by weight: 10-12 parts of feldspar, 8-10 parts of limestone, 12-15 parts of borax, 3-4 parts of zinc oxide, 8-10 parts of perlite, 10-12 parts of manganese dioxide, 1-1.5 parts of titanium oxide, 1-2 parts of copper oxide and 1-2 parts of nickel oxide. Preparing a frit by using feldspar, limestone, borax, zinc oxide and perlite as basic glaze, preparing a colorant from manganese dioxide, titanium oxide, copper oxide and nickel oxide, and preparing a metallic luster glaze by using the colorant and the frit, wherein the metallic coloring oxide is saturated and precipitated in a high-temperature sintered solution to form a precipitate with metallic luster, so that the glaze surface presents platinum-like metallic luster and has unique color tone and luster; the transparent bottom surface provides a smooth attachment base surface for the attachment of the metallic luster glaze, so that the metal layer is smooth and flat; the transparent overglaze provides a wear-resistant oxide protective layer for the metal layer; the glaze surface is finally sintered to present the metallic luster glaze effect with local concave-convex touch and blue scattered spots.
The transparent ground glaze comprises the following raw materials in parts by weight: 10-12 parts of albite, 12-14 parts of calcium carbonate, 5-10 parts of talc, 15-18 parts of dolomite, 10-12 parts of kaolin, 20-25 parts of quartz and 3-4 parts of glue, wherein the transparent overglaze comprises the following raw materials in parts by weight: 30-35 parts of potassium feldspar, 10-12 parts of quartz, 5-8 parts of borax, 5-8 parts of sodium carbonate and 15-18 parts of kaolin.
The metal luster glaze is provided with ablation concave points, the ablation concave points are filled with flash glaze, and the flash glaze comprises the following components in parts by weight: 50-60 parts of flash particles, 5-8 parts of coal ash and 2-3 parts of glue.
The flash particles comprise the following raw materials in parts by weight: 3-5 parts of nickel oxide, 5-6 parts of zinc oxide, 15-18 parts of quartz, 20-24 parts of rutile and raw materials of flash particles are mixed and melted to form blue crystals, and then the blue crystals are cooled, crushed and ground into powder and pass through a 80-mesh sieve for later use. Because the high-temperature firing temperature of the flash particles is 1200-1220 ℃, the firing temperature of the transparent overglaze is 850-900 ℃, the firing temperature of the transparent overglaze is lower than that of the flash particles, blue crystals in the flash particles embedded in the ablation concave points are not melted in the firing process of the overglaze, the blue flash particles are formed in the ablation concave points after firing, and the coal ash burns to release gas in the firing process, therefore, slight depressions are formed at the glaze surface where the ablation concave points are located after firing, the glaze surface has depression touch, and the glue is used for helping to be fixed in the concave points.
A layer of metal base glaze is arranged between the transparent base glaze and the metal luster glaze, and the metal base glaze comprises the following components in parts by weight: 90-100 parts of phlogopite, 10-15 parts of quartz and 3-4 parts of dextrin. The metal substrate glaze can also show a golden effect, and can obviously improve the metal glossiness and the color tone when being used as the substrate of the metal luster glaze, so that the dosage of the colorant oxide in the metal luster glaze can be obviously reduced on the premise of ensuring the color development effect of the metal layer, the dosage of noble metal is reduced, and the use cost is reduced.
The preparation method of the touch gold glaze ceramic comprises the following steps:
step a, preparing a ceramic blank;
b, applying a layer of transparent ground coat on the surface of the blank, and firing the blank in a kiln;
c, applying metal luster glaze, and sintering in a kiln to form a metal layer; the sintering temperature is 1150-1200 ℃;
d, placing the porcelain on a laser seat, and applying laser to the metal layer at intervals by a laser source to form ablation pits at intervals; the aperture of the ablation concave point is controlled within 1-1.5mm, and the ablation concave point penetrates through the metal layer and reaches the ground glaze;
e, embedding flash glaze material in the ablation concave points, and naturally drying; the flash glaze can be filled into the ablation pits through a pipette;
and f, applying the transparent overglaze, firing in a kiln, and presenting a metal tactile glaze surface with concave-convex tactile sensation and flashing points on the ceramic. The firing temperature of the transparent overglaze is 850-900 ℃.
And in the step b, adding glue into the transparent ground coat in proportion, wherein the firing temperature is 1000-1050 ℃, and the heat preservation time is 2-3h. The glue is CMC glue, improves the adhesion firmness on the body, forms a smooth surface after the transparent ground coat is fired, lays a foundation for the metal mirror effect formed by the subsequent glossy glaze, and is fully fired at high temperature in a kiln, so that the glue is fully combusted, and the glaze surface is smooth after firing.
In the step d, the ablation pits arranged at intervals form a pattern or are arranged in a matrix.
In the step d, the laser seat is a rotary platform, a vacuum chuck is arranged at the center of the rotary platform, the vacuum chuck is communicated with a vacuum pump, three positioning claws for positioning the center are arranged on the turntable, the laser source is located on one side of the rotary platform, and the laser source moves up and down under the driving of the lifting mechanism. The scheme is suitable for porcelain with a ceramic body as a rotator, a rotary platform is driven by a servo motor, a lifting mechanism is a lead screw sliding table, the rotary platform and the lifting mechanism accurately control a rotary angle and the height of a laser source, ablation pits are formed at a specified position on a metal layer, positioning claws can move on the rotary platform along the radial direction, three positioning claws synchronously move centripetally and position the ceramic at the central position of the rotary platform, the positioning claws only play a role of central positioning but not play a role of fixing, the ceramic is adsorbed on the rotary platform through a vacuum chuck, a rotatable butterfly gear is arranged in the rotary platform, threads are arranged at the bottom of the positioning claws, plane threads matched with the threads of the positioning claws are arranged at the top of the butterfly gear and are meshed with the butterfly gear, and the small bevel gear is arranged in the rotary platform and is driven to rotate by rotating the small bevel gear, so that the positioning claws are driven to move to form positioning; further, by precisely controlling the rotation angle of the rotary platform and the height of the laser source, patterns can be drawn on the metal layer.
In the step c, before applying the metal luster glaze, a metal base glaze is firstly applied on the transparent base glaze, and after baking at 180-220 ℃, the metal luster glaze is applied on the metal base glaze.
The above description is only a few specific embodiments of the present invention, but the design concept of the present invention is not limited to the above, and any insubstantial modifications of the present invention using this concept should fall within the scope of the present invention.
Claims (10)
1. Touch gold glaze pottery, its characterized in that: the metal luster glaze comprises a blank body, wherein the surface of the blank body is sequentially covered with a transparent ground glaze, a metal luster glaze and a transparent overglaze, and the metal luster glaze comprises the following raw materials in parts by weight: 10-12 parts of feldspar, 8-10 parts of limestone, 12-15 parts of borax, 3-4 parts of zinc oxide, 8-10 parts of perlite, 10-12 parts of manganese dioxide, 1-1.5 parts of titanium oxide, 1-2 parts of copper oxide and 1-2 parts of nickel oxide.
2. A tactile gold-glazed ceramic according to claim 1, wherein: the transparent ground glaze comprises the following raw materials in parts by weight: 10-12 parts of albite, 12-14 parts of calcium carbonate, 5-10 parts of talc, 15-18 parts of dolomite, 10-12 parts of kaolin, 20-25 parts of quartz and 3-4 parts of glue, wherein the transparent overglaze comprises the following raw materials in parts by weight: 30-35 parts of potassium feldspar, 10-12 parts of quartz, 5-8 parts of borax, 5-8 parts of sodium carbonate and 15-18 parts of kaolin.
3. A tactile gold-glazed ceramic according to claim 1, wherein: the metal luster glaze is provided with ablation concave points, flash glaze is filled in the ablation concave points, and the flash glaze comprises the following components in parts by weight: 50-60 parts of flash particles, 5-8 parts of coal ash and 2-3 parts of glue.
4. A tactile gold-glazed ceramic according to claim 1, wherein: the flash particles comprise the following raw materials in parts by weight: 3-5 parts of nickel oxide, 5-6 parts of zinc oxide, 15-18 parts of quartz, 20-24 parts of rutile and raw materials of flash particles are mixed and melted to form blue crystals, and then the blue crystals are cooled, crushed, ground into powder and sieved for later use.
5. A tactile gold-glazed ceramic according to claim 1, wherein: a layer of metal base glaze is arranged between the transparent base glaze and the metal luster glaze, and the metal base glaze comprises the following components in parts by weight: 90-100 parts of phlogopite, 10-15 parts of quartz and 3-4 parts of dextrin.
6. A method of making a gold-glazed ceramic touch screen as claimed in claims 1 to 5, comprising the steps of:
step a, preparing a ceramic blank;
b, applying a layer of transparent ground coat on the surface of the blank, and firing the blank in a kiln;
c, applying metallic luster glaze, and putting into a kiln to be sintered to form a metal layer;
d, placing the porcelain on a laser seat, and applying laser to the metal layer at intervals by a laser source to form ablation pits at intervals;
e, embedding flash glaze in the ablation pits, and naturally drying;
and f, applying the transparent overglaze, firing in a kiln, and presenting a metal tactile glaze surface with concave-convex tactile sensation and flashing points on the ceramic.
7. The method for producing a gold-glazed ceramic touch sensation according to claim 6, wherein: and in the step b, adding glue into the transparent ground coat according to a proportion, wherein the firing temperature is 1000-1050 ℃, and the heat preservation time is 2-3h.
8. The method for producing a gold-glazed ceramic touch sensation according to claim 6, wherein: in the step d, the ablation pits arranged at intervals form a pattern or are arranged in a matrix.
9. The method for preparing a gold-glazed ceramic touch sensation according to claim 6, wherein: in the step d, the laser seat is a rotating platform, a vacuum chuck is arranged at the center of the rotating platform, three positioning claws for positioning the center are arranged on the turntable, and the laser source moves up and down under the driving of the lifting mechanism.
10. The method for producing a gold-glazed ceramic touch sensation according to claim 6, wherein: in the step c, before the metal luster glaze is applied, the metal base glaze is applied on the transparent base glaze, and after the metal base glaze is baked at 180-220 ℃, the metal luster glaze is applied on the metal base glaze.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210973735.7A CN115196994B (en) | 2022-08-15 | 2022-08-15 | Gold glazed ceramic with touch feeling and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210973735.7A CN115196994B (en) | 2022-08-15 | 2022-08-15 | Gold glazed ceramic with touch feeling and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115196994A true CN115196994A (en) | 2022-10-18 |
| CN115196994B CN115196994B (en) | 2023-09-19 |
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| CN202210973735.7A Active CN115196994B (en) | 2022-08-15 | 2022-08-15 | Gold glazed ceramic with touch feeling and preparation method thereof |
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| CN117105698B (en) * | 2023-09-12 | 2024-07-09 | 福建省德化县鹏立达陶瓷工艺有限公司 | Flash rock glaze ceramic imitating rough surface and preparation method thereof |
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