CN117105698B - Flash rock glaze ceramic imitating rough surface and preparation method thereof - Google Patents
Flash rock glaze ceramic imitating rough surface and preparation method thereof Download PDFInfo
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- CN117105698B CN117105698B CN202311167140.3A CN202311167140A CN117105698B CN 117105698 B CN117105698 B CN 117105698B CN 202311167140 A CN202311167140 A CN 202311167140A CN 117105698 B CN117105698 B CN 117105698B
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- 239000011435 rock Substances 0.000 title claims abstract description 28
- 239000000919 ceramic Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 42
- 230000005284 excitation Effects 0.000 claims description 30
- 238000010304 firing Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 239000010453 quartz Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000003292 glue Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 6
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 5
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 5
- 108010059892 Cellulase Proteins 0.000 claims description 4
- 229940106157 cellulase Drugs 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 3
- 229910021532 Calcite Inorganic materials 0.000 claims description 3
- 235000019738 Limestone Nutrition 0.000 claims description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000010459 dolomite Substances 0.000 claims description 3
- 229910000514 dolomite Inorganic materials 0.000 claims description 3
- 239000010433 feldspar Substances 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 3
- 239000006028 limestone Substances 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 15
- 239000002245 particle Substances 0.000 abstract description 7
- 238000000149 argon plasma sintering Methods 0.000 abstract description 6
- 238000004088 simulation Methods 0.000 abstract description 3
- 239000002585 base Substances 0.000 description 11
- 239000010410 layer Substances 0.000 description 8
- 238000000855 fermentation Methods 0.000 description 5
- 230000004151 fermentation Effects 0.000 description 5
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
The invention relates to the technical field of ceramics and preparation thereof, in particular to a rough surface simulated flashing rock glaze ceramic and a preparation method thereof. Firstly, applying a layer of ground coat to improve the bonding degree of the blank glaze, prevent the blank from being partially exposed, and improve the bonding strength of the ground coat and the ground coat; the light scattering powder is positioned between the ground glaze and the surface glaze, can cause the surface glaze to locally warp and pit, has more natural simulation effect, presents a matte earth yellow glaze effect close to rock after the surface glaze is sintered, spreads over the pit and bulges on the surface, and is mixed with flash particles among the pits so as to have the texture of matte flash rock; the vibration of the vibration film drives the flash powder to diffuse in the airtight box body, so that the flash powder can be uniformly covered on the surface of the ground glaze.
Description
Technical Field
The invention relates to the technical field of ceramics and preparation thereof, in particular to a flash rock glazed ceramic imitating a rough surface and a preparation method thereof.
Background
The glaze is a layer of glass body covered on the surface of a ceramic blank, has similar physical and chemical properties as glass, compact texture, water resistance, air impermeability and acid and alkali corrosion resistance, and is usually prepared by adopting natural mineral raw materials and certain chemical raw materials to match, and is melted at high temperature to form a glassy layer with luster. The glaze has various weights, wherein the glaze surface has a flashing effect, namely flashing glaze, has a metal mirror-like reflection effect on incident light, when a flashing glaze finished product is observed, metal-like reflection can be seen under a certain light incident angle, the metal-like reflection is different from the reflection of a metal luster glaze, the existing flashing glaze has the characteristic of mirror reflection, components with flashing characteristics are usually directly added into the glaze, the components are mixed and then applied onto a blank body, and the flashing glaze is prepared by firing.
Disclosure of Invention
It is an object of the present invention to solve at least the above problems by a matte-like sparkling rock-glazed ceramic and a method for producing the same.
In order to solve the technical problems, the invention adopts the following technical scheme: the flash rock glaze ceramic imitating the rough surface comprises a green body, wherein the green body is covered with ground glaze and overglaze, flash powder is clamped between the ground glaze and overglaze, pits and protrusions are distributed on the surface of the overglaze after firing, and the overglaze comprises the following raw materials in parts by weight: 10-12 parts of wollastonite, 5-6 parts of zinc oxide, 8-9 parts of titanium dioxide, 5-6 parts of zirconium dioxide, 1-2 parts of ammonium tungstate, 1-2 parts of lead chromate, 1-2 parts of water glass, 20-22 parts of quartz stone, 30-35 parts of potassium feldspar, 10-12 parts of limestone and 15-18 parts of calcite.
Preferably, the raw materials of the base glaze comprise the following components in parts by weight: 20-25 parts of potassium feldspar, 10-15 parts of quartz, 8-10 parts of kaolin, 7-9 parts of dolomite, 5-7 parts of zinc oxide, 10-12 parts of calcium carbonate and 6-8 parts of barium carbonate.
Preferably, the flash powder comprises the following components in parts by weight: 20-22 parts of cerium oxide, 10-12 parts of zirconium oxide, 15-16 parts of quartz stone and 10-12 parts of feldspar.
The preparation method of the simulated matte flashing rock glazed ceramic is characterized by comprising the following steps of:
Step a, preparing a blank body, and drying and forming;
b, applying a primer on the green body, and drying the primer to a semi-dry state;
Step c, placing the blank with the base glaze in an excitation box with flashing parts, and covering a layer of flashing powder on the base glaze;
step d, taking out the blank body and continuously drying;
step e, applying overglaze on the ground glaze, and drying;
And f, firing in a kiln to obtain the simulated matte flash rock glazed ceramic.
Preferably, in the step b, the primer is dried to a moisture content of 15-20%.
Preferably, in the step c, the excitation box includes box, upper cover, places seat, vibrating diaphragm and excitation source, the upper cover openable sets up in the box top, place the seat setting in the box inside, be used for placing pottery, vibrating diaphragm detachable installs in the bottom of the box, the excitation source sets up in the vibrating diaphragm below.
Preferably, the excitation source is a mechanical excitation source or an ultrasonic transducer.
Preferably, in the step c, when in use, a certain amount of flash powder is put into the laser film in advance, the upper cover is opened, the blank body with the base glaze is placed on the placing seat, after the upper cover is covered, the excitation source is started, and the excitation source drives the laser film to vibrate at high frequency, so that the flash powder is driven to diffuse into the inner space of the box body, and then the flash powder is uniformly covered on the surface of the base glaze.
Preferably, in the step f, the glaze firing temperature is 1100-1150 ℃.
Preferably, in the step b, before applying the primer on the blank, the primer is prepared, and the method specifically includes the following steps:
Adding CMC glue into 50% water, mixing, adding cellulase, fermenting in 50-60 deg.C with relative humidity of 60-80% for 1-2 days;
And mixing the fermented CMC glue with other components of the overglaze to prepare the overglaze.
As can be seen from the above description, the simulated matte flash rock glazed ceramic and the preparation method thereof provided by the invention have the following beneficial effects: firstly, applying a layer of ground coat to improve the bonding degree of the blank glaze, prevent the blank from being partially exposed, and improve the bonding strength of the ground coat and the ground coat; the light scattering powder is positioned between the ground glaze and the surface glaze, can cause the surface glaze to locally warp and pit, has more natural simulation effect, presents a matte earth yellow glaze effect close to rock after the surface glaze is sintered, spreads over the pit and bulges on the surface, and is mixed with flash particles among the pits so as to have the texture of matte flash rock; the vibration of the vibration film drives the flash powder to diffuse in the airtight box body, so that the flash powder can be uniformly covered on the surface of the ground glaze.
Detailed Description
The invention is further described below by means of specific embodiments.
The invention is further described in connection with the following detailed description, in order to make the technical means, the creation characteristics, the achievement of the purpose and the effect of the invention easy to understand.
The invention discloses a rough-surface-imitated flash rock glaze ceramic, which comprises a green body, wherein the green body is covered with a ground glaze and a cover glaze, flash powder is clamped between the ground glaze and the cover glaze, pits and protrusions are distributed on the surface of the cover glaze after firing, and the cover glaze comprises the following raw materials in parts by weight: 10-12 parts of wollastonite, 5-6 parts of zinc oxide, 8-9 parts of titanium dioxide, 5-6 parts of zirconium dioxide, 1-2 parts of ammonium tungstate, 1-2 parts of lead chromate, 1-2 parts of water glass, 20-22 parts of quartz stone, 30-35 parts of potassium feldspar, 10-12 parts of limestone and 15-18 parts of calcite. If only one layer of overglaze is applied, the overglaze is easy to fall off after skinning and pit forming, so that local blank body is exposed, therefore, a layer of base glaze is firstly applied to improve the combination degree of the blank glaze, prevent the blank body from being exposed locally and improve the bonding strength of the overglaze and the base glaze; the light scattering powder is positioned between the ground glaze and the surface glaze, so that local warping and pit of the surface glaze can be caused, the simulation effect is more natural, the light scattering powder is not directly mixed in the surface glaze, the proportion of the light scattering powder is not well controlled, the surface glaze with too high proportion can fall off in a large amount, the rough surface effect is not obvious when the proportion is too low, and the concave glaze and the peeling are not well caused when the light scattering powder is positioned on the surface layer of the surface glaze; the surface glaze has a matte earth yellow glaze effect similar to that of rock after firing, the surface of the surface glaze is spread over pits and bulges, and flash particles are mixed among the pits, so that the surface glaze has the texture of rough surface flash rock.
The raw materials of the base glaze comprise the following components in parts by weight: 20-25 parts of potassium feldspar, 10-15 parts of quartz, 8-10 parts of kaolin, 7-9 parts of dolomite, 5-7 parts of zinc oxide, 10-12 parts of calcium carbonate and 6-8 parts of barium carbonate. The ground glaze is transparent glaze, is positioned between the green body and the overglaze, is used as a bonding layer of the overglaze and the green body, improves the bonding degree of the overglaze, and prevents the green body from being exposed locally when the overglaze locally generates concave glaze or skin.
The flash powder comprises the following components in parts by weight: 20-22 parts of cerium oxide, 10-12 parts of zirconium oxide, 15-16 parts of quartz stone and 10-12 parts of feldspar. The preparation method of the flash powder comprises the following steps: the components are mixed and then calcined at a high temperature of 1400 ℃, then crushed and ground into sparkling particles with the required particle size, the particle size is controlled to be 0.2-0.3mm, the crystal growth of the cerium oxide after glaze firing is grown, and the cerium oxide is directionally separated out, so that the prepared sparkling powder has good radioactivity, the sparkling powder has a sparkling effect, and finally the prepared glaze can observe the sparkling particles in illumination.
The preparation method of the flash rock glaze ceramic with the simulated rough surface comprises the following steps:
Step a, preparing a blank body, and drying and forming;
b, applying a primer on the green body, and drying the primer to a semi-dry state;
Step c, placing the blank with the base glaze in an excitation box with flashing parts, and covering a layer of flashing powder on the base glaze;
step d, taking out the blank body and continuously drying;
step e, applying overglaze on the ground glaze, and drying;
And f, firing in a kiln to obtain the simulated matte flash rock glazed ceramic. The melting point of the flash powder is higher than that of the ground glaze and the overglaze, so that the stability of the flash powder is higher in the glaze firing process, and the flash powder and the overglaze are in great difference in terms of dryness, humidity, fluidity and combination property, so that the overglaze is partially broken to generate concave glaze or skin, the overglaze presents an uneven simulated flash rock glaze effect, meanwhile, CMC glue in the overglaze is subjected to fermentation treatment in advance, and the phenomenon of partial blackening and graying is formed after firing, which is similar to the partial dark gray rock effect on flash rock, and has a good artistic effect.
In the step b, the ground coat is dried until the water content is 15-20%. The ground glaze is dried to a semi-dry state, the fluidity of the glaze is reduced, the ground glaze structure is relatively stable, and meanwhile, a certain water content is reserved, so that the astigmatic powder can be effectively adsorbed.
In step c, the excitation case includes box, upper cover, place the seat, vibrating diaphragm and excitation source, the upper cover openable sets up in the box top, place the seat set up in the box inside, be used for placing pottery, vibrating diaphragm detachable installs in the bottom half, the excitation membrane is installed on the frame, frame detachable installs in the bottom half, the vibrating diaphragm is the polymer film that has elasticity, the excitation source sets up in the vibrating diaphragm below, under the drive of excitation source, the excitation membrane can take place high-frequency vibration, and then drive the flash powder vibration on it and spread to whole box in, the air current flow that its produced is very little, the destruction to the overglaze is little. The excitation source is a mechanical excitation source or an ultrasonic transducer.
In the step c, when the device is used, a certain amount of flash powder is put into the laser film in advance, the upper cover is opened, a blank body with the ground coat is put on the placing seat, after the upper cover is covered, the excitation source is started, and the excitation source drives the laser film to vibrate at high frequency, so that the flash powder is driven to diffuse into the inner space of the box body, and the flash powder is further uniformly covered on the surface of the ground coat. The flash powder is driven to diffuse in the airtight box body by vibration of the vibrating diaphragm, so that the flash powder can be uniformly covered on the surface of the base glaze, if the flash powder is driven in a blowing mode, more flash powder on the windward side can be possibly caused under the action of the blowing, less flash powder on the leeward side is possibly caused, the distribution is uneven, and the local structure of the incompletely dried base glaze can be damaged by excessive airflow, so that the base body is exposed.
In the step f, the glaze firing temperature is 1100-1150 ℃. And preserving the heat for 3-4 hours after reaching the glaze firing temperature.
In the step b, before the ground coat is applied on the green body, the ground coat is prepared, and the method specifically comprises the following steps:
Adding CMC glue into 50% water, mixing, adding cellulase, fermenting in 50-60 deg.C with relative humidity of 60-80% for 1-2 days; after fermentation, the CMC glue is partially decomposed into glucose and xylose, so that the formation of pits on the glaze surface is aggravated, and partial organic matters are carbonized after glaze firing, so that the glaze surface has the effects of partial blackening and graying; the fermentation speed is low, and the fermentation speed can be improved through the fermentation of cellulase and a high-temperature and high-humidity environment.
And mixing the fermented CMC glue with other components of the overglaze to prepare the overglaze.
The foregoing is merely a few specific embodiments of the present invention, but the design concept of the present invention is not limited thereto, and any insubstantial modification of the present invention by using the concept should be construed as infringement of the protection scope of the present invention.
Claims (6)
1. The preparation method of the flash rock glaze ceramic with the simulated rough surface is characterized by comprising the following steps:
Step a, preparing a blank body, and drying and forming;
b, applying a primer on the green body, and drying the primer to a semi-dry state;
C, placing the blank with the base glaze in an excitation box with flashing powder, and covering a layer of flashing powder on the base glaze;
step d, taking out the blank body and continuously drying;
step e, applying overglaze on the ground glaze, and drying;
f, firing in a kiln to obtain the simulated rough surface flash rock glazed ceramic;
In the step c, the excitation box comprises a box body, an upper cover, a placing seat, a vibration excitation film and an excitation source, wherein the upper cover is arranged at the top of the box body in an openable manner, the placing seat is arranged in the box body and is used for placing ceramics, the vibration excitation film is detachably arranged at the bottom of the box body, and the excitation source is arranged below the vibration excitation film;
The excitation source is a mechanical excitation source or an ultrasonic transducer;
In the step c, when the device is used, a certain amount of flash powder is put on the laser film in advance, the upper cover is opened, a blank body with ground glaze is put on the placing seat, after the upper cover is covered, the excitation source is started, and the excitation source drives the laser film to vibrate at high frequency, so that the flash powder is driven to diffuse into the inner space of the box body, and the flash powder is further uniformly covered on the surface of the ground glaze;
The rough surface-imitating flash rock glaze ceramic comprises a green body, wherein the green body is covered with ground glaze and overglaze, flash powder is clamped between the ground glaze and overglaze, pits and protrusions are distributed on the surface of the overglaze after firing, and the overglaze comprises the following raw materials in parts by weight: 10-12 parts of wollastonite, 5-6 parts of zinc oxide, 8-9 parts of titanium dioxide, 5-6 parts of zirconium dioxide, 1-2 parts of ammonium tungstate, 1-2 parts of lead chromate, 1-2 parts of water glass, 20-22 parts of quartz stone, 30-35 parts of potassium feldspar, 10-12 parts of limestone and 15-18 parts of calcite.
2. The method for preparing the simulated matte flashing rock glazed ceramic according to claim 1, wherein the method comprises the following steps: the base glaze comprises the following raw materials in parts by weight: 20-25 parts of potassium feldspar, 10-15 parts of quartz, 8-10 parts of kaolin, 7-9 parts of dolomite, 5-7 parts of zinc oxide, 10-12 parts of calcium carbonate and 6-8 parts of barium carbonate.
3. The method for preparing the simulated matte flashing rock glazed ceramic according to claim 1, wherein the method comprises the following steps: the flashing powder comprises the following components in parts by weight: 20-22 parts of cerium oxide, 10-12 parts of zirconium oxide, 15-16 parts of quartz stone and 10-12 parts of feldspar.
4. The method for preparing the simulated matte flashing rock glazed ceramic according to claim 1, wherein the method comprises the following steps: in the step b, the ground coat is dried until the water content is 15-20%.
5. The method for preparing the simulated matte flashing rock glazed ceramic according to claim 1, wherein the method comprises the following steps: in the step f, the glaze firing temperature is 1100-1150 ℃.
6. The method for preparing the simulated matte flashing rock glazed ceramic according to claim 1, wherein the method comprises the following steps: in the step b, before the ground coat is applied on the green body, the ground coat is prepared, and the method specifically comprises the following steps:
Adding CMC glue into 50% water, mixing, adding cellulase, fermenting in 50-60 deg.C with relative humidity of 60-80% for 1-2 days;
And mixing the fermented CMC glue with other components of the ground coat to prepare the ground coat.
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| CN115196994A (en) * | 2022-08-15 | 2022-10-18 | 福建省德化环宇陶瓷有限公司 | Touch gold glaze ceramic and preparation method thereof |
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| WO2008137129A1 (en) * | 2007-05-04 | 2008-11-13 | E. I. Du Pont De Nemours And Company | Coated particle with shimmering appearance and engineered stone containing coated particles |
| KR101851396B1 (en) * | 2009-11-10 | 2018-04-23 | 롯데첨단소재(주) | Colored Material Coated Transparent Chip and Native Rock Combined With Resin Composition Including The Same |
| CN102491787B (en) * | 2011-11-14 | 2013-05-01 | 星谊精密陶瓷科技（昆山）有限公司 | High-temperature mirror surface flashy fritted glaze and preparation method thereof |
| CN103102181B (en) * | 2012-12-19 | 2015-01-21 | 广东东鹏陶瓷股份有限公司 | Method for preparing flash glazed wall tile |
| CN105924134B (en) * | 2016-04-25 | 2018-05-25 | 广东宏宇新型材料有限公司 | There is resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof on surface |
| CN107352968A (en) * | 2017-08-24 | 2017-11-17 | 四川汇丰陶瓷有限公司 | A kind of preparation method of ceramic body and bright convex glaze ceramics |
| CN110357668A (en) * | 2019-08-09 | 2019-10-22 | 东莞市唯美陶瓷工业园有限公司 | A kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments |
| CN111574245B (en) * | 2020-04-30 | 2021-05-04 | 佛山市陶莹新型材料有限公司 | 3D (three-dimensional) dazzling ceramic tile and preparation method thereof |
| CN112811939A (en) * | 2021-02-07 | 2021-05-18 | 广东萨米特陶瓷有限公司 | Ceramic plate with glittering grain effect and manufacturing method thereof |
| CN112794736B (en) * | 2021-04-09 | 2021-08-10 | 蒙娜丽莎集团股份有限公司 | Ceramic plate with colorful cloud surface decoration effect and preparation method thereof |
| CN114620936A (en) * | 2022-03-31 | 2022-06-14 | 杭州天尼文化艺术有限公司 | Celadon product with surface flashing and in-glaze color effects and decoration method |
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| CN109968505A (en) * | 2019-04-24 | 2019-07-05 | 江西斯米克陶瓷有限公司 | A kind of Glazing device for ceramic process |
| CN115196994A (en) * | 2022-08-15 | 2022-10-18 | 福建省德化环宇陶瓷有限公司 | Touch gold glaze ceramic and preparation method thereof |
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