CN106396740A - Black gold sand glaze porcelain, and preparation method thereof - Google Patents
Black gold sand glaze porcelain, and preparation method thereof Download PDFInfo
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- CN106396740A CN106396740A CN201610785910.4A CN201610785910A CN106396740A CN 106396740 A CN106396740 A CN 106396740A CN 201610785910 A CN201610785910 A CN 201610785910A CN 106396740 A CN106396740 A CN 106396740A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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Abstract
The invention belongs to the field of ceramic glaze material, and more specifically relates to a black gold sand glaze porcelain widely applied to the fields of art ceramic or household ceramic, and a preparation method thereof. According to the preparation method, black gold sand effects of the black gold sand glaze porcelain are realized via combination of bottom glaze and surface glaze, the black gold sand glaze porcelain obtained via firing possesses black bottom color, and the black bottom color is covered with golden gold sand particles; under a microscope, the gold sand particles are polygonal particles, light-reflecting effect of the gold sand particles is excellent, striking contrast effect and unique artistic effect are achieved via combination of the black bottom color with the gold sand particles; the bottom glaze and the surface glaze of the black gold sand glaze porcelain are combined firmly; and service life is long. The invention also provides the preparation method of the black gold sand glaze porcelain; the glaze surface effect can be achieved via adjusting the formula and thickness of bottom glaze with surface glaze; black gold sand glaze porcelain finished product ratio is high; firing temperature is low; energy is saved; the preparation method is friendly to the environment; and energy consumption is reduced.
Description
Technical field
The invention belongs to ceramic glaze field is and in particular to a kind of be widely portable to the black of the art pottery or Household ceramic
Jinsha glaze porcelain and its manufacture craft.
Background technology
Constantly can improve with people's living standard, the living standard more and more higher of people, consumer produces for pottery
The esthetic requirement of product also more and more higher, but the critical material playing modification effect for ceramic product is glaze.
Jinsha glaze porcelain, is control under to obtain countless minute metallic iron oxide crystalline substances in high temperature with burning till with the ferrous components of a large amount
Body, these crystal are not the Surface Creations in glaze, and are suspended in glaze layer, when light irradiates, can reflect radiance, with nature
The gold dust on boundary is very much like, so being referred to as " Jinsha glaze ".Existing Jinsha glaze is that appropriate iron oxide colorant is introduced ceramic tile
In glaze, high temperature separates out many fine iron oxide crystal grains when burning till later stage condensation, forms Jinsha shape, and imperceptible goldc grains suspends
Lighten sparking brilliance in glaze glass body.
There are the following problems for the effect of existing Jinsha glaze porcelain and preparation, and in effect, the background color of existing Jinsha glaze is many
It is grey or brown, Jinsha mostly yellow or brown, its background color is not strong with the contrast of Jinsha, dicoration and artistry are not
By force, and because Jinsha particle is suspended in glaze layer, its reflecting effect is also affected;In preparation, existing Jinsha glaze
In glaze, Jinsha randomly generates when burning till, and the glazing effect of therefore Jinsha layer has randomness it is not easy to control, and burns till
Rate and yields are low, additionally, in order to burn till Jinsha, the firing temperature of existing Jinsha glaze must burn till temperature more than 1280
Degree is high, high energy consumption, and therefore existing Jinsha glaze all needs further to be improved from effect or in manufacture craft.
Content of the invention
In order to solve the above problems, black it is widely portable to the black of the art pottery or Household ceramic the invention provides a kind of
Jinsha glaze porcelain.
For achieving the above object, the invention provides a dark fund sand glaze porcelain, by introversion on described ceramic body
It is sequentially provided with outward ground-coat enamel and cover-coat enamel;Ground-coat enamel composition is as follows in parts by weight:Nepheline 20-30 part, burning talcum 20-30 part, feldspar
15-20 part, iron 10-15 part, bone ash 5-10 part, kaolin 1-5 part, barium 1-5 part, manganese carbonate 1-5 part, kyanite 1-3 part;Cover-coat enamel
Composition is as follows in parts by weight:Potassium feldspar 35-45 part, albite 25-35 part, calcite 10-15 part, clear frit 10-15
Part, talcum 5-10 part, zinc 1-5 part, manganese 1-5 part, titanium 1-4 part.
Optimize, ground-coat enamel composition is as follows in parts by weight:28 parts of nepheline, burn 21 parts of talcum, 18 parts of feldspar, 13 parts of iron,
8 parts of bone ash, 3 parts of kaolin, 2 parts of barium, manganese carbonate 4,3 parts of kyanite.
Optimize, cover-coat enamel composition is as follows in parts by weight:36 parts of potassium feldspar, 26 parts of albite, 12 parts of calcite, transparent
12 parts of frit, 6 parts of talcum, 3 parts of zinc, 2 parts of manganese, 3 parts of titanium.
Optimize, ground-coat enamel composition is as follows in parts by weight:23 parts of nepheline, burn 28 parts of talcum, 16 parts of feldspar, 15 parts of iron,
6 parts of bone ash, 5 parts of kaolin, 3 parts of barium, 3 parts of manganese carbonate, 1 part of kyanite.
Optimize, cover-coat enamel composition is as follows in parts by weight:40 parts of potassium feldspar, 28 parts of albite, 11 parts of calcite, transparent
10 parts of frit, 5 parts of talcum, 1 part of zinc, 2 parts of manganese, 3 parts of titanium.
The manufacture craft of dark fund sand glaze porcelain is it is characterised in that comprise the following steps:
Step one, according to dark fund sand glaze ground-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, system
Obtain ground-coat enamel glaze slip, during ball milling, material:Ball:Water=1:1.5-2:0.6-0.8, crosses 250 mesh sieves;
Step 2, according to dark fund sand glaze cover-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, system
Obtain cover-coat enamel glaze slip, during ball milling, material:Ball:Water=1:1-1.5:1, cross 200 mesh sieves;
Step 3, makes ceramic body, waits ceramic body surface natural air drying;
Step 4, ground-coat enamel glaze slip obtained by step one is uniformly imposed on ceramic body surface, waits body drying;
Step 5, cover-coat enamel glaze slip obtained by step 2 is uniformly imposed on ceramic body surface, waits body drying
Step 6, kiln-firing after ceramic blank drying, obtain dark fund sand glaze porcelain.
Further, the glazing process of the ground-coat enamel in step 4 is leaching glaze, and in step 5, the glazing process of cover-coat enamel is spray
Glaze.
Further, in step 4, the thickness of ground-coat enamel glaze slip is 0.8-1.2mm.
Further, in step 5, the thickness of cover-coat enamel glaze slip is 0.3-5mm.
Further, in step 6, when ceramic body is fired, in kiln, keep weakly reducing atmosphere, firing temperature is 1200-
1230 DEG C, after furnace heating-up to firing temperature, it is incubated 1-2 hour, rear slow cooling.
Seen from the above description, what the dark fund sand glaze porcelain that the present invention provides passed through ground-coat enamel and cover-coat enamel is implemented in combination with Galaxy Black
Effect, the dark fund sand glaze porcelain being burnt out has the background color of black, is coated with the Jinsha of Gold production on black background color
Grain, this Jinsha particle is examined under a microscope as polygon particle, and its reflecting effect is good, compared with the background color of black, has strong
Strong contrast, has the artistic effect of uniqueness;Additionally, the ground-coat enamel of this kind of dark fund sand glaze porcelain and cover-coat enamel were combined closely, using the longevity
Life length;The manufacture craft of the dark fund sand glaze porcelain that the present invention provides, the effect of glaze paint can be by the formula of ground-coat enamel and cover-coat enamel and thickness
Degree is adjusted so that the high yield rate of dark fund sand glaze, and firing temperature is low, realizes energy-conserving and environment-protective, reduces energy consumption.
Specific embodiment
In order to be better understood from technical scheme, with reference to embodiment, the present invention is discussed further.
Dark fund sand glaze porcelain, described ceramic body is sequentially provided with ground-coat enamel and cover-coat enamel from inside to outside;
Ground-coat enamel composition is as follows in parts by weight:Nepheline 20-30 part, burning talcum 20-30 part, feldspar 15-20 part, iron 10-
15 parts, bone ash 5-10 part, kaolin 1-5 part, barium 1-5 part, manganese carbonate 1-5 part, kyanite 1-3 part;
Cover-coat enamel composition is as follows in parts by weight:Potassium feldspar 35-45 part, albite 25-35 part, calcite 10-15 part, thoroughly
Bright frit 10-15 part, talcum 5-10 part, zinc 1-5 part, manganese 1-5 part, titanium 1-4 part.
The manufacture craft of dark fund sand glaze porcelain, comprises the following steps:
Step one, according to dark fund sand glaze ground-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, system
Obtain ground-coat enamel glaze slip, during ball milling, material:Ball:Water=1:1.5-2:0.6-0.8, crosses 250 mesh sieves;
Step 2, according to dark fund sand glaze cover-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, system
Obtain cover-coat enamel glaze slip, during ball milling, material:Ball:Water=1:1-1.5:1, cross 200 mesh sieves;
Step 3, makes ceramic body, waits ceramic body surface natural air drying;
Step 4, ground-coat enamel glaze slip obtained by step one is uniformly imposed on ceramic body surface, waits body drying, preferably
, using leaching glaze handicraft, the thickness of ground-coat enamel glaze slip is 0.8-1.2mm;
Step 5, cover-coat enamel glaze slip obtained by step 2 is uniformly imposed on ceramic body surface, waits body drying, preferably
, using glaze spraying technique, the thickness of cover-coat enamel glaze slip is 0.3-5mm;
Step 6, kiln-firing after ceramic blank drying, obtain dark fund sand glaze porcelain, when ceramic body is fired, in kiln
Keep weakly reducing atmosphere, firing temperature is 1200-1230 DEG C, after furnace heating-up to firing temperature, be incubated 1-2 hour, afterwards slowly
Cooling.
Specific embodiment one:
Dark fund sand glaze porcelain, described ceramic body is sequentially provided with ground-coat enamel and cover-coat enamel from inside to outside;
Ground-coat enamel composition is as follows in parts by weight:28 parts of nepheline, burn 21 parts of talcum, 18 parts of feldspar, 13 parts of iron, 8 parts of bone ash,
3 parts of kaolin, 2 parts of barium, manganese carbonate 4,3 parts of kyanite.
Cover-coat enamel composition is as follows in parts by weight:36 parts of potassium feldspar, 26 parts of albite, 12 parts of calcite, clear frit 12
Part, 6 parts of talcum, 3 parts of zinc, 2 parts of manganese, 3 parts of titanium.
The manufacture craft of above-mentioned dark fund sand glaze porcelain, comprises the following steps:
Step one, according to dark fund sand glaze ground-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, system
Obtain ground-coat enamel glaze slip, during ball milling, material:Ball:Water=1:2:0.7, cross 250 mesh sieves;
Step 2, according to dark fund sand glaze cover-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, system
Obtain cover-coat enamel glaze slip, during ball milling, material:Ball:Water=1:1.2:1, cross 200 mesh sieves;
Step 3, makes ceramic body, waits ceramic body surface natural air drying;
Step 4, ground-coat enamel glaze slip obtained by step one is uniformly imposed on ceramic body surface, waits body drying, preferably
, using leaching glaze handicraft, the thickness of ground-coat enamel glaze slip is 0.9mm;
Step 5, cover-coat enamel glaze slip obtained by step 2 is uniformly imposed on ceramic body surface, waits body drying, preferably
, using glaze spraying technique, the thickness of cover-coat enamel glaze slip is 0.3mm;
Step 6, kiln-firing after ceramic blank drying, obtain dark fund sand glaze porcelain, when ceramic body is fired, in kiln
Keep weakly reducing atmosphere, firing temperature is 1210 DEG C, after furnace heating-up to firing temperature, be incubated 1 hour, rear slow cooling.
Specific embodiment two:
Dark fund sand glaze porcelain, described ceramic body is sequentially provided with ground-coat enamel and cover-coat enamel from inside to outside;
Ground-coat enamel composition is as follows in parts by weight:23 parts of nepheline, burn 28 parts of talcum, 16 parts of feldspar, 15 parts of iron, 6 parts of bone ash,
5 parts of kaolin, 3 parts of barium, 3 parts of manganese carbonate, 1 part of kyanite;
Cover-coat enamel composition is as follows in parts by weight:40 parts of potassium feldspar, 28 parts of albite, 11 parts of calcite, clear frit 10
Part, 5 parts of talcum, 1 part of zinc, 2 parts of manganese, 3 parts of titanium.
The manufacture craft of dark fund sand glaze porcelain, comprises the following steps:
Step one, according to dark fund sand glaze ground-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, system
Obtain ground-coat enamel glaze slip, during ball milling, material:Ball:Water=1:2:0.8, cross 250 mesh sieves;
Step 2, according to dark fund sand glaze cover-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, system
Obtain cover-coat enamel glaze slip, during ball milling, material:Ball:Water=1:1:1, cross 200 mesh sieves;
Step 3, makes ceramic body, waits ceramic body surface natural air drying;
Step 4, ground-coat enamel glaze slip obtained by step one is uniformly imposed on ceramic body surface, waits body drying, preferably
, using leaching glaze handicraft, the thickness of ground-coat enamel glaze slip is 1.1mm;
Step 5, cover-coat enamel glaze slip obtained by step 2 is uniformly imposed on ceramic body surface, waits body drying, preferably
, using glaze spraying technique, the thickness of cover-coat enamel glaze slip is 0.5mm;
Step 6, kiln-firing after ceramic blank drying, obtain dark fund sand glaze porcelain, when ceramic body is fired, in kiln
Keep weakly reducing atmosphere, firing temperature is 1220 DEG C, after furnace heating-up to firing temperature, be incubated 2 hours, rear slow cooling.
Above-mentioned gold sand glaze porcelain passes through the effect being implemented in combination with Galaxy Black of ground-coat enamel and cover-coat enamel, the dark fund sand glaze being burnt out
Porcelain has the background color of black, is coated with the Jinsha particle of Gold production on black background color, and this Jinsha particle is seen under the microscope
Examine as polygon particle, its reflecting effect is good, compared with the background color of black, has striking contrast, there is the art effect of uniqueness
Really;Additionally, the ground-coat enamel of this kind of dark fund sand glaze porcelain and cover-coat enamel are combined closely, long service life;The dark fund sand glaze that the present invention provides
The manufacture craft of porcelain, the effect of glaze paint can be adjusted by the formula of ground-coat enamel and cover-coat enamel and thickness so that dark fund sand glaze
High yield rate, firing temperature is low, realizes energy-conserving and environment-protective, reduces energy consumption.
The above, only present pre-ferred embodiments, therefore can not with this limit the present invention enforcement scope, that is, according to
Equivalence changes and modification that scope of the present invention patent and description are made, all should still belong to the model that patent of the present invention covers
In enclosing.
Claims (10)
1. dark fund sand glaze porcelain is it is characterised in that be sequentially provided with ground-coat enamel and cover-coat enamel from inside to outside on described ceramic body;
Ground-coat enamel composition is as follows in parts by weight:Nepheline 20-30 part, burn talcum 20-30 part, feldspar 15-20 part, iron 10-15 part,
Bone ash 5-10 part, kaolin 1-5 part, barium 1-5 part, manganese carbonate 1-5 part, kyanite 1-3 part;
Cover-coat enamel composition is as follows in parts by weight:Potassium feldspar 35-45 part, albite 25-35 part, calcite 10-15 part, transparent molten
Block 10-15 part, talcum 5-10 part, zinc 1-5 part, manganese 1-5 part, titanium 1-4 part.
2. dark fund sand glaze porcelain according to claim 1 is it is characterised in that described ground-coat enamel forms in parts by weight such as
Under:28 parts of nepheline, 21 parts of talcum of burning, 18 parts of feldspar, 13 parts of iron, 8 parts of bone ash, 3 parts of kaolin, 2 parts of barium, manganese carbonate 4, kyanite
3 parts.
3. dark fund sand glaze porcelain according to claim 1 and 2 is it is characterised in that described cover-coat enamel forms in parts by weight
As follows:36 parts of potassium feldspar, 26 parts of albite, 12 parts of calcite, 12 parts of clear frit, 6 parts of talcum, 3 parts of zinc, 2 parts of manganese, 3 parts of titanium.
4. dark fund sand glaze porcelain according to claim 1 is it is characterised in that described ground-coat enamel forms in parts by weight such as
Under:23 parts of nepheline, 28 parts of talcum of burning, 16 parts of feldspar, 15 parts of iron, 6 parts of bone ash, 5 parts of kaolin, 3 parts of barium, 3 parts of manganese carbonate, aquamarine
1 part of stone.
5. dark fund sand glaze porcelain according to claim 1 is it is characterised in that described cover-coat enamel forms in parts by weight such as
Under:40 parts of potassium feldspar, 28 parts of albite, 11 parts of calcite, 10 parts of clear frit, 5 parts of talcum, 1 part of zinc, 2 parts of manganese, 3 parts of titanium.
6. the manufacture craft of dark fund sand glaze porcelain is it is characterised in that comprise the following steps:
Step one, according to dark fund sand glaze ground-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, prepared bottom
Glaze glaze slip, during ball milling, material:Ball:Water=1:1.5-2:0.6-0.8, crosses 250 mesh sieves;
Step 2, according to dark fund sand glaze cover-coat enamel composition of raw materials weighing and proportioning, raw material will be uniformly mixed into row wet ball mill, prepared face
Glaze glaze slip, during ball milling, material:Ball:Water=1:1-1.5:1, cross 200 mesh sieves;
Step 3, makes ceramic body, waits ceramic body surface natural air drying;
Step 4, ground-coat enamel glaze slip obtained by step one is uniformly imposed on ceramic body surface, waits body drying;
Step 5, cover-coat enamel glaze slip obtained by step 2 is uniformly imposed on ceramic body surface, waits body drying
Step 6, kiln-firing after ceramic blank drying, obtain dark fund sand glaze porcelain.
7. according to claim 6 dark fund sand glaze porcelain manufacture craft it is characterised in that:Ground-coat enamel in described step 4
Glazing process is leaching glaze, and in step 5, the glazing process of cover-coat enamel is glaze spraying.
8. according to claim 6 or 7 dark fund sand glaze porcelain manufacture craft it is characterised in that:Ground-coat enamel in described step 4
The thickness of glaze slip is 0.8-1.2mm.
9. according to claim 6 or 7 dark fund sand glaze porcelain manufacture craft it is characterised in that:Cover-coat enamel in described step 5
The thickness of glaze slip is 0.3-5mm.
10. according to claim 6 dark fund sand glaze porcelain manufacture craft it is characterised in that:In described step 6, ceramic blank
When body is fired, keep weakly reducing atmosphere in kiln, firing temperature is 1200-1230 DEG C, after furnace heating-up to firing temperature, insulation
1-2 hour, rear slow cooling.
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Cited By (7)
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CN107759090A (en) * | 2017-11-21 | 2018-03-06 | 广东道氏技术股份有限公司 | A kind of glaze of imitative dark fund sand marbling effect and its application |
CN109574710A (en) * | 2018-12-28 | 2019-04-05 | 福建泉州顺美集团有限责任公司 | A kind of point reduction skin texture glaze ceramics and its manufacture craft |
CN113666727A (en) * | 2021-08-17 | 2021-11-19 | 德化县如瓷生活文化有限公司 | Black matt glaze ceramic and preparation method thereof |
CN115124320A (en) * | 2022-07-15 | 2022-09-30 | 佛山市陶莹新型材料有限公司 | Preparation process of black gold sand glaze ceramic product |
CN115611516A (en) * | 2022-12-09 | 2023-01-17 | 佛山市道氏科技有限公司 | Colored gold sand glaze and ceramic tile thereof |
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Cited By (10)
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CN107759090A (en) * | 2017-11-21 | 2018-03-06 | 广东道氏技术股份有限公司 | A kind of glaze of imitative dark fund sand marbling effect and its application |
CN109574710A (en) * | 2018-12-28 | 2019-04-05 | 福建泉州顺美集团有限责任公司 | A kind of point reduction skin texture glaze ceramics and its manufacture craft |
CN109574710B (en) * | 2018-12-28 | 2023-09-26 | 福建泉州顺美集团有限责任公司 | Pinch-point texture glaze ceramic and manufacturing process thereof |
CN113666727A (en) * | 2021-08-17 | 2021-11-19 | 德化县如瓷生活文化有限公司 | Black matt glaze ceramic and preparation method thereof |
CN115124320A (en) * | 2022-07-15 | 2022-09-30 | 佛山市陶莹新型材料有限公司 | Preparation process of black gold sand glaze ceramic product |
CN115611516A (en) * | 2022-12-09 | 2023-01-17 | 佛山市道氏科技有限公司 | Colored gold sand glaze and ceramic tile thereof |
CN115611516B (en) * | 2022-12-09 | 2023-10-31 | 佛山市道氏科技有限公司 | Colored gold sand glaze and ceramic tile thereof |
CN115849712A (en) * | 2022-12-14 | 2023-03-28 | 贵州亚泰陶瓷有限公司 | Black golden flower ceramic tile surface treatment glaze and method |
CN116444252A (en) * | 2023-04-04 | 2023-07-18 | 天欣科技股份有限公司 | Manufacturing method of whole-body black gold-flash ceramic tile manufactured by slag |
CN116444252B (en) * | 2023-04-04 | 2024-06-04 | 天欣科技股份有限公司 | Manufacturing method of whole-body black gold-flash ceramic tile manufactured by slag |
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Application publication date: 20170215 |