CN105236742A - Ground-glaze-free low-temperature transmutation zirconium white glaze formula, preparation method and use method thereof - Google Patents

Ground-glaze-free low-temperature transmutation zirconium white glaze formula, preparation method and use method thereof Download PDF

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Publication number
CN105236742A
CN105236742A CN201510534544.0A CN201510534544A CN105236742A CN 105236742 A CN105236742 A CN 105236742A CN 201510534544 A CN201510534544 A CN 201510534544A CN 105236742 A CN105236742 A CN 105236742A
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glaze
parts
formula
transmutation
ground
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CN105236742B (en
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李桂贤
刁龙海
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Fujian Dehua Grangtop Ceramic Co Ltd
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Fujian Dehua Grangtop Ceramic Co Ltd
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Abstract

The invention belongs to the field of ceramic production and particularly relates to a ground-glaze-free low-temperature transmutation zirconium white glaze formula, a preparation method and a use method thereof. The ground-glaze-free low-temperature transmutation zirconium white glaze formula includes feldspar powder, boric acid, barium borate, limestone, zinc oxide, lead oxide, lead silicate and bentonite. The glaze is low in cost, is convenient to use, is low in sintering temperature and has a unique artistic feel. Glaze surface produced by sintering the ground-glaze-free low-temperature transmutation zirconium white glaze has a zirconium white dark light bottom color, wherein irregular black spots are uniformly distributed on the glaze surface. The size and distribution density of the black spots are changed according to the model of a ceramic product and glaze thickness. The glaze surface has a stone-like appearance and a slight flowing-tendency effect, thereby achieving unique artistic effects. Porcelain produced with the glaze is increased in grade and market price and is high in economic value. The glaze can be produced in large scale, can be popularized quickly and is simple in use, thereby achieving strong market competitiveness.

Description

Without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, method of preparation and use
Technical field
The invention belongs to ceramic manufacture field, be specifically related to a kind of without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, method of preparation and use.
Background technology
When furnace transmutation glaze and implements burn till in kiln, owing to containing multiple pigmentation element in kiln, through oxidation or reductive action, after kiln discharge, present beyond thought glaze chromatic effect.Traditional furnace transmutation glaze is that middle high temperature burns till, and firing temperature is more than 1200 DEG C, and firing time is mostly more than 12 hours, and its firing temperature is high, the time is long, and energy loss is large, causes cost high and not environmentally; And the glazing effect of existing lightweight white clouds pottery furnace transmutation glaze is single, kind is dull, cannot cater to the consumer demand of different individual character.
For solving the problem, the patent No. be 201110133469.9 patent of invention disclose a kind of Transmutation glaze white cloud ceramics and manufacture craft thereof, this kind of Transmutation glaze white cloud ceramics, comprise white clouds greenwave body and impose on the glaze layer on white clouds greenwave surface, this glaze layer comprises the ground-coat enamel directly executed in white clouds greenwave surface and the cover-coat enamel imposed on ground-coat enamel face; Each component of ground-coat enamel comprises low-temperature lead-free frit, coloring oxide, calcium carbonate, alkaline earth metal compound, part kaolin; Each component of described cover-coat enamel is low-temperature lead-free frit, part zinc oxide, part titanium oxide, coloring oxide, part kaolin by weight ratio.The firing temperature of this kind of furnace transmutation glaze is appointed need between 1080-1100 DEG C, and the glazed surface burnt out forms natural crystallization flower.Along with improving constantly of people's living standard, aesthetic diversified demand is also constantly changed, if it is low to develop a kind of firing temperature, there is the glaze being different from traditional transmutation effect, aesthetic diversified demand can be met there is again positive meaning.
Summary of the invention
In order to solve deficiency of the prior art, the invention provides a kind of without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, method of preparation and use.
Without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, as follows according to parts by weight: Feldspar Powder 30-45 part, boric acid 10-15 part, barium borate 1-5 part, Wingdale 5-10 part, zinc oxide 5-10 part, plumbous oxide 20-30 part, lead silicate 5-10 part, wilkinite 0-5.
Optimize, glaze formula is as follows according to parts by weight: Feldspar Powder 35 parts, boric acid 12 parts, barium borate 3 parts, 8 parts, Wingdale, 6 parts, zinc oxide, 26 parts, plumbous oxide, 10 parts, lead silicate.
Optimize, glaze formula is as follows according to parts by weight: Feldspar Powder 39 parts, boric acid 14 parts, barium borate 5 parts, 6 parts, Wingdale, 8 parts, zinc oxide, 22 parts, plumbous oxide, 6 parts, lead silicate.
Optimize, glaze formula is as follows according to parts by weight: Feldspar Powder 42 parts, boric acid 11 parts, barium borate 5 parts, 5 parts, Wingdale, 6 parts, zinc oxide, 24 parts, plumbous oxide, 7 parts, lead silicate.
Optimize, glaze formula is as follows according to parts by weight: Feldspar Powder 32 parts, boric acid 15 parts, barium borate 5 parts, 7 parts, Wingdale, 5 parts, zinc oxide, 28 parts, plumbous oxide, 8 parts, lead silicate.
The preparation method of light china low temperature transmutation covellite colour glaze, is characterized in that, comprise the following steps:
Step one, according to glaze formula weighing and proportioning, by Feldspar Powder, boric acid, barium borate, Wingdale, zinc oxide, plumbous oxide, lead silicate, and adds the water of 40-50%;
Step 2, after ball milling 12-18 hour, if having glaze slip to precipitate add wilkinite;
Step 3, sieves stand-by by the glaze that step 2 obtains, obtained transmutation covellite colour glaze.
Further, 200 mesh sieves crossed by the glaze in step 3.
The using method of light china low temperature transmutation covellite colour glaze, is characterized in that, comprise the following steps:
Step 1, prepares light ceramics base substrate;
Step 2, imposes on light ceramics base substrate by transmutation covellite colour glaze, places 5-10 hour;
Step 3, by have the ceramic body of transmutation covellite colour glaze to put into kiln oxydizing flame to fire, firing temperature is between 980 DEG C-1060 DEG C.
Further, the enameling method in step 2 is leaching glaze or glaze spraying.
Further, in step 3, after ceramic body enters kiln, kiln rapid temperature increases, to firing temperature, burns till rear naturally cooling.
Seen from the above description, provided by the invention without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, method of preparation and use, there is following beneficial effect: one is glaze cost raw material that is low, that use is all easily obtain, and manufacture craft is simple; Two is easy to use, uses this kind only need at billet surface last layer glaze without the need to ground-coat enamel without ground-coat enamel low temperature transmutation zirconium white glaze; Three is that firing temperature is low, and this kind only needs can realize transmutation effect, save energy between 980 DEG C-1060 DEG C without the firing temperature of ground-coat enamel low temperature transmutation zirconium white glaze; Four is have unique artistic feeling, this kind has the background color of zirconium white look half-light without the glazing effect that ground-coat enamel low temperature transmutation zirconium white glaze burns out, background color distributed irregular black splotch uniformly, the size of black splotch and respectively density change according to ceramic ware type and glazing thickness, glaze paint is with stone shape, slightly trickling trend effect, artistic effect is unique; The porcelain using this kind of glaze to make improves product specification and selling price, has higher economic worth; In addition this kind of glaze can bulk industrial produce, can Rapid Popularization, use simple, commercially there is stronger competitive power.
Embodiment
Technical scheme for a better understanding of the present invention, is described below in detail embodiment provided by the invention.
Without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, as follows according to parts by weight: Feldspar Powder 30-45 part, boric acid 10-15 part, barium borate 1-5 part, Wingdale 5-10 part, zinc oxide 5-10 part, plumbous oxide 20-30 part, lead silicate 5-10 part, wilkinite 0-5.
Specific embodiment one:
Glaze formula is as follows according to parts by weight: Feldspar Powder 35 parts, boric acid 12 parts, barium borate 3 parts, 8 parts, Wingdale, 6 parts, zinc oxide, 26 parts, plumbous oxide, 10 parts, lead silicate.
The preparation method of above-mentioned light china low temperature transmutation covellite colour glaze, comprises the following steps:
Step one, according to glaze formula weighing and proportioning, by Feldspar Powder, boric acid, barium borate, Wingdale, zinc oxide, plumbous oxide, lead silicate, and adds the water of 50%;
Step 2, ball milling is after 16 hours, if having glaze slip to precipitate add wilkinite;
Step 3, crosses 200 mesh sieves by the glaze that step 2 obtains stand-by, obtained transmutation covellite colour glaze.
The using method of above-mentioned light china low temperature transmutation covellite colour glaze, comprises the following steps:
Step 1, prepares light ceramics base substrate;
Step 2, imposes on light ceramics base substrate by transmutation covellite colour glaze, places 8 hours, and enameling method is leaching glaze;
Step 3, by have the ceramic body of transmutation covellite colour glaze to put into kiln oxydizing flame to fire, firing temperature is between 980 DEG C-1060 DEG C, and after ceramic body enters kiln, kiln rapid temperature increases, to firing temperature, burns till rear naturally cooling.
Specific embodiment two,
Glaze formula is as follows according to parts by weight: Feldspar Powder 39 parts, boric acid 14 parts, barium borate 5 parts, 6 parts, Wingdale, 8 parts, zinc oxide, 22 parts, plumbous oxide, 6 parts, lead silicate.
Specific embodiment three,
Glaze formula is as follows according to parts by weight: Feldspar Powder 42 parts, boric acid 11 parts, barium borate 5 parts, 5 parts, Wingdale, 6 parts, zinc oxide, 24 parts, plumbous oxide, 7 parts, lead silicate.
Specific embodiment four,
Glaze formula is as follows according to parts by weight: Feldspar Powder 32 parts, boric acid 15 parts, barium borate 5 parts, 7 parts, Wingdale, 5 parts, zinc oxide, 28 parts, plumbous oxide, 8 parts, lead silicate.
Specific embodiment two to four, the preparation method of light china low temperature transmutation covellite colour glaze, comprises the following steps:
Step one, according to glaze formula weighing and proportioning, by Feldspar Powder, boric acid, barium borate, Wingdale, zinc oxide, plumbous oxide, lead silicate, and adds the water of 40-50%;
Step 2, after ball milling 12-18 hour, if having glaze slip to precipitate add wilkinite;
Step 3, sieves stand-by by the glaze that step 2 obtains, obtained transmutation covellite colour glaze.
The using method of light china low temperature transmutation covellite colour glaze, is characterized in that, comprise the following steps:
Step 1, prepares light ceramics base substrate;
Step 2, imposes on light ceramics base substrate by transmutation covellite colour glaze, places 5-10 hour, and enameling method is leaching glaze or glaze spraying;
Step 3, by have the ceramic body of transmutation covellite colour glaze to put into kiln oxydizing flame to fire, firing temperature is between 980 DEG C-1060 DEG C, and after ceramic body enters kiln, kiln rapid temperature increases, to firing temperature, burns till rear naturally cooling.
Above-mentioned is all easily obtain without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula glaze cost raw material that is low, that use, and manufacture craft is simple; Easy to use, use this kind only need at billet surface last layer glaze without the need to ground-coat enamel without ground-coat enamel low temperature transmutation zirconium white glaze; Firing temperature is low, and this kind only needs can realize transmutation effect, save energy between 980 DEG C-1060 DEG C without the firing temperature of ground-coat enamel low temperature transmutation zirconium white glaze; There is unique artistic feeling, this kind has the background color of zirconium white look half-light without the glazing effect that ground-coat enamel low temperature transmutation zirconium white glaze burns out, background color distributed irregular black splotch uniformly, the size of black splotch and respectively density change according to ceramic ware type and glazing thickness, glaze paint is with stone shape, slightly trickling trend effect, artistic effect is unique.
The porcelain using this kind of glaze to make improves product specification and selling price, has higher economic worth; In addition this kind of glaze can bulk industrial produce, can Rapid Popularization, use simple, commercially there is stronger competitive power.
The above, be only present pre-ferred embodiments, therefore can not limit scope of the invention process with this, and the equivalence namely done according to the present patent application the scope of the claims and description changes and modifies, and all should still remain within the scope of the patent.

Claims (10)

1., without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, it is characterized in that,
Described glaze formula is as follows according to parts by weight: Feldspar Powder 30-45 part, boric acid 10-15 part, barium borate 1-5 part, Wingdale 5-10 part, zinc oxide 5-10 part, plumbous oxide 20-30 part, lead silicate 5-10 part, wilkinite 0-5.
2. according to claim 1 without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, it is characterized in that, described glaze formula is as follows according to parts by weight: Feldspar Powder 35 parts, boric acid 12 parts, barium borate 3 parts, 8 parts, Wingdale, 6 parts, zinc oxide, 26 parts, plumbous oxide, 10 parts, lead silicate.
3. according to claim 1 without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, it is characterized in that, described glaze formula is as follows according to parts by weight: Feldspar Powder 39 parts, boric acid 14 parts, barium borate 5 parts, 6 parts, Wingdale, 8 parts, zinc oxide, 22 parts, plumbous oxide, 6 parts, lead silicate.
4. according to claim 1 without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, it is characterized in that, described glaze formula is as follows according to parts by weight: Feldspar Powder 42 parts, boric acid 11 parts, barium borate 5 parts, 5 parts, Wingdale, 6 parts, zinc oxide, 24 parts, plumbous oxide, 7 parts, lead silicate.
5. according to claim 1 without ground-coat enamel low temperature transmutation zircon-opacified glaze material formula, it is characterized in that, described glaze formula is as follows according to parts by weight: Feldspar Powder 32 parts, boric acid 15 parts, barium borate 5 parts, 7 parts, Wingdale, 5 parts, zinc oxide, 28 parts, plumbous oxide, 8 parts, lead silicate.
6. the preparation method of light china low temperature transmutation covellite colour glaze, is characterized in that, comprise the following steps:
Step one, according to glaze formula weighing and proportioning, by Feldspar Powder, boric acid, barium borate, Wingdale, zinc oxide, plumbous oxide, lead silicate, and adds the water of 40-50%;
Step 2, after ball milling 12-18 hour, if having glaze slip to precipitate add wilkinite;
Step 3, sieves stand-by by the glaze that step 2 obtains, obtained transmutation covellite colour glaze.
7. the preparation method of light china low temperature transmutation covellite colour glaze according to claim 6, is characterized in that: 200 mesh sieves crossed by the glaze in step 3.
8. the using method of the light china low temperature transmutation covellite colour glaze according to claim 1 to 5 any one, is characterized in that, comprise the following steps:
Step 1, prepares light ceramics base substrate;
Step 2, imposes on light ceramics base substrate by transmutation covellite colour glaze, places 5-10 hour;
Step 3, by have the ceramic body of transmutation covellite colour glaze to put into kiln oxydizing flame to fire, firing temperature is between 980 DEG C-1060 DEG C.
9. the using method of institute's light china low temperature transmutation covellite colour glaze according to Claim 8, is characterized in that: the enameling method in described step 2 is leaching glaze or glaze spraying.
10. the using method of light china low temperature transmutation covellite colour glaze according to claim 8, it is characterized in that: in described step 3, after ceramic body enters kiln, kiln rapid temperature increases, to firing temperature, burns till rear naturally cooling.
CN201510534544.0A 2015-08-27 2015-08-27 Without ground-coat enamel low temperature transmutation zirconium white glaze, method of preparation and use Active CN105236742B (en)

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CN201510534544.0A CN105236742B (en) 2015-08-27 2015-08-27 Without ground-coat enamel low temperature transmutation zirconium white glaze, method of preparation and use
CN201810317063.8A CN108358448A (en) 2015-08-27 2015-08-27 A kind of application method of no ground-coat enamel low temperature furnace transmutation glaze
CN201810317510.XA CN108383383B (en) 2015-08-27 2015-08-27 Preparation process of bottom glaze-free low-temperature transmutation zirconium white glaze

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CN106830881A (en) * 2017-04-06 2017-06-13 潮州市潮安区皓强瓷业有限公司 The production method of domestic ceramics transmutation color glaze product

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CN108358448A (en) * 2015-08-27 2018-08-03 福建省德化县冠鸿陶瓷有限公司 A kind of application method of no ground-coat enamel low temperature furnace transmutation glaze

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CN108358448A (en) * 2015-08-27 2018-08-03 福建省德化县冠鸿陶瓷有限公司 A kind of application method of no ground-coat enamel low temperature furnace transmutation glaze

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CN102718562A (en) * 2012-06-11 2012-10-10 卡罗比亚釉料(昆山)有限公司 Leaded milky-white frit for ceramic preparation
CN102924126A (en) * 2012-11-30 2013-02-13 山东炳坤腾泰陶瓷科技有限公司 Milky-white frit for zirconium-free glaze and method for producing milky-white frit for zirconium-free glaze
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Publication number Priority date Publication date Assignee Title
CN106830881A (en) * 2017-04-06 2017-06-13 潮州市潮安区皓强瓷业有限公司 The production method of domestic ceramics transmutation color glaze product

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CN108358448A (en) 2018-08-03

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