CN105199865A - Foam cleaning composition - Google Patents
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- CN105199865A CN105199865A CN201510673680.8A CN201510673680A CN105199865A CN 105199865 A CN105199865 A CN 105199865A CN 201510673680 A CN201510673680 A CN 201510673680A CN 105199865 A CN105199865 A CN 105199865A
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Abstract
The invention provides a foam cleaning composition which comprises an anionic surfactant, a nonionic surfactant, tea saponin, sodium alginate, sodium citrate, sodium chloride and the like, and can also comprise a sterilization deodorant, spice and a coloring agent. The foam cleaning composition provided by the invention is suitable for cleaning a bedpan, and has the characteristics of being quick in foaming, fine and rich in foam, long in duration, and the like; the sterilization deodorant is a purely natural anti-bacteria deodorant, can remove peculiar smell, has a good bactericidal effect, and is harmless to the human body and the environment.
Description
Technical field
The invention belongs to filed of daily-use chemical industry, be specifically related to a kind of foamed cleaning composition.
Background technology
Along with the development of society and improving constantly of people's living standard, the hygienic quality of people to living environment has more and more higher requirement, especially has higher requirement to the hygienic standard in lavatory.No matter be sitting wc pan or squatting wc pan at present, all adopt the design that " S " is curved, cause one " water seal ", be used for preventing the foul smell of water drain from flowing backwards.There is the water of certain volume just because of bottom, go to toilet be seated or couchant defecation time easily splash dirt, especially serious during diarrhoea.In addition, because the use location of user on sitting wc pan or squatting wc pan is different, when use location is away from " water seal ", movement can be caused to be stranded on sitting wc pan or squatting wc pan inwall, and exposed movement can discharge " stink " in atmosphere affects toilet air ambient, and, after going to toilet, movement is through the cleaning that discharges water, still have part residual, brush must be used again to clean, very inconvenient.This is all bothersome problem all the time.Having foam in water seal place can effectively prevent the ight soil fallen into from splashing spray, also there is the sitting wc pan or the squatting wc pan that rely on self material to produce foam both at home and abroad, but expensive, can not generally be used.
In recent years, there is a kind of foam toilet in public place, the high lubricity that the foam utilizing water content little has and certain stopping property, punching defecation just with sealing ight soil foul smell.The sewage draining exit of foam blocking closet is utilized during work, thus the diffusion stoping unpleasant odor interior to lavatory, and visually it is seen that the foam of white, fulsome dirt can not be seen, foam has very strong lubrication simultaneously, stool can be slipped in excrement case very smoothly, achieve the flushing to lavatory tool, except the foam in water closet pan can carry out except shutoff stool odor, the plugging device of water closet pan sewage draining exit has carried out secondary plugging to stink, solves the bad-smell problem in lavatory greatly.Reach good odor-resistant result.Although this kind of foam solution has the effect of lubrication, shutoff and covering peculiar smell, its clean descale effect is poor, only plays covering effect for peculiar smell, can not eliminate peculiar smell.Patent No. zl200810054635.4 deodorizing sterilizing foamed liquid for water closet discloses and a kind ofly integrates sterilization, deodorizing, clean, scale removal, the foam liquor that foams, but the stability of its foam is good not, easy froth breaking.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provides a kind of foamed cleaning composition, is applicable to bedpan and cleans, have foaming rapidly, fine and smooth abundant, the feature such as the time length is long of foam, have simultaneously antibacterial, eliminate the unusual smell, clean, the effect such as scale removal.
Technical solution of the present invention is as follows, a kind of foamed cleaning composition, by weight, comprises anion surfactant 13-15 part, nonionogenic tenside 4-5 part, tea saponin 3-5 part, sodium alginate 4-8 part, Trisodium Citrate 2-6 part, sodium-chlor 0.5-1 part.
Described anion surfactant is: Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, hexadecyl sulfonate, Trombovar, alpha-olefin sodium sulfonate wherein one or more; Described nonionogenic tenside is: cocoanut fatty acid diethanolamide, dimethyl dodecyl amine oxide one or both.
Cleaning compositions of the present invention can also comprise sterilizing deodoring agent 5-7 part, spices 2-3 part, one or more tinting materials 1-2 part.
Described sterilizing deodoring agent is the mixture of one or more in Folum Ilicis extract, Flos Caryophylli extract, Cortex Phellodendri extract, Folium Menthae extract.
Described spices can be natural or synthesis obtained, be this area usual component, can add in any usual manner, be mixed in composition or blended with other compositions for the formation of composition.
Described tinting material is known tinting material, such as pigment and dyestuff (comprising the tinting material of CI substantive dyestuff and FD & C accreditation), tinting material can add in a usual manner, that is, be mixed to composition or blended with other compositions for the formation of composition.Can improve or give outward appearance or the color of composition expectation.
Compound method of the present invention can adopt the general method of the industry to be prepared.Such as, carry out apolegamy material according to said components and parts by weight thereof and weigh, water is heated to 36-50 DEG C, adds after anion surfactant dissolves completely, then add nonionogenic tenside uniform dissolution forming surfactants solution, add tea saponin and sodium alginate again, be down to 20-37 DEG C after stirring and dissolving, by the potential of hydrogen of buffer reagent Trisodium Citrate regulator solution to pH5-6, then add sterilizing deodoring agent, spices, food dye etc. and mix, leave standstill 2-2.5 hour.Innovation of the present invention is the preferred of formula and does not lie in preparation method itself.
Though existing tensio-active agent foaming power better the stability of foam is good not, the present inventor studies discovery and adds tea saponin and can increase froth stability.Because gas, liquid is to the pressure reduction of density and both sides, interface, cause the liquid between bubble to be always constantly discharged under stress, liquid film is thinning gradually and cause bubble-break.Add the body phase viscosity that tea saponin can increase liquid between bubble, to make liquid in vacuolar membrane both not easily run off, slow down drain age velocity, the solubleness of gas in liquid film also can be made to reduce, thus increase the stability of foam.But expanding foam solution viscosity is too large, can affect again the foam performance of expanding foam solution.Therefore the amount added is too much unsuitable, and it is most suitable between 3-5 part that the present inventor studies the amount finding to add tea saponin.
Moreover, the present inventor finds that the foam that existing cleaning product or foam solution produce breaks soon under slight external force effect, and the complete dry foam of discharge opeing is also more sparse, is easily out of shape.In order to overcome this problem, improving froth stability further, improving the performance of dry foam.The present inventor studies discovery, adds sodium alginate and can significantly improve froth stability and constancy.If this is because do not form surface film, foam solution liquid phase viscosity is large again, can not form stable foam, and can form surface film after adding sodium alginate.Due to the pore forming material in solution and suds-stabilizing agent the adsorption density of face and surface film elasticity closely related, the Interaction Force being adsorbed in the surfactant molecule at surface film gas-liquid interface is large, then surface viscosity is high, film toughness is also high, as formed the hybrid films of high strength between surfactant molecule, liquid film surface viscosity then can be made to increase, thus froth stability is improved greatly.Sodium alginate has good water-soluble, can not only improve liquid phase viscosity, stops liquid film discharge opeing, can also form the film of high strength simultaneously.As can be seen from experimental result, after adding sodium alginate, foaming properties obviously improves, good film-forming property, and anti-external force improves.
Sterilizing deodoring agent used in the present invention is the mixture of one or more in Folum Ilicis extract, Flos Caryophylli extract, Cortex Phellodendri extract, Folium Menthae extract, it is the antibacterial deodovization agent of pure natural, not only can remove peculiar smell, and there is good germicidal action, to human body and environmentally friendly.Each component effect is as follows:
Leaf of Chinese Holly is Aquifoliaceae holly, cool in nature, sweet-bitter flavor, nontoxic, there is loose wind-heat, clearing heat and detoxicating, slake thirst and help produce saliva, the effects such as stomach strengthening and digestion promoting, containing the composition that triterpenes, Polyphenols, flavonoid, ursolic acid, catechin, amino acid, VITAMIN, bitter principle, lipopolysaccharides and various trace elements etc. are useful to human body, there is anti-inflammatory, the effect such as antibacterial and anti-oxidant, have certain restraining effect to bacterium such as streptococcus aureus, bacteroides fragilis, intestinal bacteria, Corynebacterium diphtheriae, beta hemolytic streptococcuss.
Cloves is myrtle, its dry flower contains volatile oil, main component is Eugenol, there is warming middle-JIAO to send down the adverse QI, tonify the kidney and support yang, antibacterial, anti-inflammatory, antiviral, eliminate the effects such as free radical, there is stronger restraining effect to intestinal bacteria, dysentery bacterium, Corynebacterium diphtheriae, Salmonellas, streptococcus aureus, also have inhibition in various degree to subtilis common in food, Aspergillus flavus etc.
Golden cypress is the dry bark of rutaceae wampee, and phellodendron bark has the effect such as eliminating fire and detoxication, heat-clearing and damp-drying drug.Main containing alkaloids such as Berberine (berberine), jateorhizine (jatrorrhizine), magnoflorine (magnoflorine), golden cypress (phellodedrine), n-methyl peyocactine (candicine), palmatine (palmatine), dauricines (menisperine) in its extract.In vitro tests shows that golden cypress to streptococcus aureus, streptococcus pneumoniae, diphtheria corynebacterium, Streptococcus viridans, dysentery bacterium (except Song Nei Shi), Hemolytic streptococcus, meningococcus, vibrio cholerae, anthrax bacillus all effectively or have stronger restraining effect; Also restraining effect is had to Bacillus subtilus, bordetella pertussis, tetanus bacillus; To H37Rv, mycobacterium tuberculosis without direct repression, but bacterium number can be made to reduce, but present bacteriostatic action when concentration reaches 1%.Find in test, golden cypress decoction or preserved material have bacteriostatic action in various degree to common pathogenic fungus.
Peppermint, also known as HERBA MENTHAE, water mint, Herba Menthae Rotundifoliae, jintan grass, luxuriant lotus dish etc., is Labiatae per nnial herb, is distributed widely in all parts of the country.Peppermint has antimicrobial antiphlogistic effect, in the composition of the 21 kinds of Peppermint essential oil identified, isophorone (41.22%), β-caryophyllene (10.01%), spathulenol (2.89%), beta-pinene (1.45%) and Terpane (1.13%) are main component.All anti-microbial activity is had to subtilis and Bacillus proteus, intestinal bacteria, staphylococcus epidermidis.Antimycotic and desinsection removes the effect of mite in addition.
Folum Ilicis extract of the present invention, Flos Caryophylli extract, Cortex Phellodendri extract, Folium Menthae extract etc. can be water extracts, also can be alcohol extracts, and preparation method and use, compound method are state of the art.
Foamed cleaning composition of the present invention, spray into before going to toilet or be placed in bottom bedpan, foam layer is enriched in rapid formation, this foam layer has the effect of " foam valve ", after the dirt front end of draining enters foam layer, rear end is rapidly by foam closes, on the one hand dirt the affecting its acceleration and can be subject to shock that is slow thus that alleviate sewage in bedpan due to foam layer of excretion, another aspect foam layer is capped as " cotton-wadded quilt " to the globule that may splash, and therefore " foam valve " can stop the effect that sewage spills when defecation.The effect that this foam layer has " foam envelope ", after the dirt of excretion enters foam layer, is closed by foam layer, not only euphorosia, and removing stink, prevents smelling out, improves toilet air ambient.In case of fault is cut off the water, when the dirt in bedpan can not be got rid of in time, use foam cleaner of the present invention to spray and enrich foam dirt is sealed up for safekeeping, do not make peculiar smell excessive, again can cleaning sterilization, effect is better.This foam layer has the effect of " foam pad ", due to the existence of foam layer, the dirt of excretion can not directly and bedpan contact internal walls, as bottom rapid landing to bedpan one deck " foam pad ", prevent dirt and the adhesion of bedpan inwall of excretion, avoid movement after going to toilet and still have the residual drawback that brush must be used again to clean of part through the cleaning that discharges water.
Foamed cleaning composition of the present invention has following beneficial effect:
1, remarkable foaming and surely steep ability: the ionic surface active agent of employing has detergency and foaming power is strong, can form a lot of foam in the short period of time; The tea saponin added and sodium alginate extend the broken bubble time of resistance aqueous foam significantly.
2, clean strong detergency: the present invention can produce careful bubble, can powerful attached work on dirty, allow stupid dirt decompose landing.The yellow dirt of effective removing, urine dirt, incrustation scale.
3, antibacterially to eliminate the unusual smell: adopt pure plant extracts, peculiar smell can be removed and do not rely on fragrance and cover, can efficient-decomposition peculiar smell, can not rebound with rear smell.And plant milk extract used to have sterilizing and deodorizing function remarkable, to human body and environmentally friendly.Taste removal can distribute the pure and fresh plant scent of nature simultaneously.
Embodiment
Embodiment 1, a kind of foamed cleaning composition, comprise sodium lauryl sulphate 15 grams, cocoanut fatty acid diethanolamide 4 grams, tea saponin 4 grams, sodium alginate 6 grams, Trisodium Citrate 3 grams, 0.8 gram, sodium-chlor, lemon flavouring 2 grams.
Compound method: carry out apolegamy material according to said components and weight thereof and weigh, 100 grams of water (being preferably pure water) are heated to 36-50 DEG C, add after anionic dissolves completely, add nonionogenic tenside cocoanut fatty acid diethanolamide uniform dissolution forming surfactants solution again, add tea saponin and sodium alginate again, 20-37 DEG C is down to after stirring and dissolving, by the potential of hydrogen of buffer reagent Trisodium Citrate regulator solution to pH5.6, add spices etc. again to mix, leave standstill 2-2.5 hour.
Embodiment 2, a kind of foamed cleaning composition, comprise sodium lauryl sulphate 8 grams, alpha-olefin sodium sulfonate 5 grams, dimethyl dodecyl amine oxide 5 grams, tea saponin 4 grams, sodium alginate 5 grams, Trisodium Citrate 3 grams, sterilizing deodoring agent 7 grams, 0.7 gram, sodium-chlor, tinting material 1 gram.
Sterilizing deodoring agent is Flos Caryophylli extract 2 grams, Cortex Phellodendri extract 1 gram, Folium Menthae extract 2 grams.
Compound method is identical with embodiment 1.
Embodiment 3, a kind of foamed cleaning composition, comprise Sodium dodecylbenzene sulfonate 5 grams, Trombovar 5 grams, alpha-olefin sodium sulfonate 5 grams, dimethyl dodecyl amine oxide 4 grams, tea saponin 5 grams, sodium alginate 8 grams, Trisodium Citrate 5 grams, sterilizing deodoring agent 7 grams, 1 gram, sodium-chlor, tinting material 1.5 grams.
Sterilizing deodoring agent is Folum Ilicis extract 1 gram, Flos Caryophylli extract 4 grams, Folium Menthae extract 2 grams.
Compound method is identical with embodiment 1.
Embodiment 4, a kind of foamed cleaning composition, comprise 5 grams, hexadecyl sulfonate, sodium lauryl sulphate 8 grams, cocoanut fatty acid diethanolamide 4.5 grams, tea saponin 4.5 grams, sodium alginate 6 grams, Trisodium Citrate 3 grams, sterilizing deodoring agent 5 grams, 1 gram, sodium-chlor, mint flavouring 2 grams.
Sterilizing deodoring agent is Cortex Phellodendri extract 3 grams, Folium Menthae extract 2 grams.
Compound method is identical with embodiment 1.
Embodiment 5, a kind of foamed cleaning composition, comprise Trombovar 6 grams, alpha-olefin sodium sulfonate 8 grams, cocoanut fatty acid diethanolamide 2 grams, dimethyl dodecyl amine oxide 3 grams, tea saponin 4 grams, sodium alginate 7 grams, Trisodium Citrate 5 grams, sterilizing deodoring agent 6 grams, 0.5 gram, sodium-chlor.
Sterilizing deodoring agent is Cortex Phellodendri extract 3 grams, Folium Menthae extract 2 grams, Flos Caryophylli extract 1 gram.
Compound method is identical with embodiment 1.
Embodiment 6, a kind of foamed cleaning composition, comprise 5 grams, hexadecyl sulfonate, sodium lauryl sulphate 8 grams, cocoanut fatty acid diethanolamide 4 grams, tea saponin 4 grams, sodium alginate 6 grams, Trisodium Citrate 3 grams, sterilizing deodoring agent 5 grams, 1 gram, sodium-chlor, mint flavouring 2 grams.
Sterilizing deodoring agent is Cortex Phellodendri extract 3 grams, Folium Menthae extract 2 grams.
Compound method is identical with embodiment 1.
Test example 1, foaming and foam stability can be tested
By 100 milliliters of cleaning compositions of the present invention (expanding foam solution), join in jar, high-speed stirring stopped after 5 minutes, foam is poured in 2L graduated cylinder, and reads lather volume, investigated foaming power and stability.
Foaming power: the foam that cleaning compositions of the present invention for 100ml sends is poured in graduated cylinder and measures lather volume V, as the foaming power of foam solution.
Stability: record the time of above-mentioned lather volume decay needed for half, be called the transformation period (t of foam
1/2v), to weigh the stability of foam, t
1/2vlonger, surfactant foam liquid more stability is better.
Table 1 cleaning compositions foaming power of the present invention and stability result
| Test number | Lather volume V (mL) | t 1/2v(hour) |
| Embodiment 1 | 2400 | 86.6 |
| Embodiment 2 | 2390 | 85.9 |
| Embodiment 3 | 2410 | 88.7 |
| Embodiment 4 | 2395 | 83.1 |
| Embodiment 5 | 2405 | 86.0 |
| Embodiment 6 | 2400 | 87.4 |
Test example 2, add the impact of tea saponin on froth stability
Because gas, liquid is to the pressure reduction of density and both sides, interface, cause the liquid between bubble to be always constantly discharged under stress, liquid film is thinning gradually and cause bubble-break.For increasing the stability of foam, suitably should increase the body phase viscosity of liquid between bubble, to make liquid in vacuolar membrane both not easily run off, slow down drain age velocity, makes again the solubleness of gas in liquid film reduce.Can suitably add the material that can increase viscosity in expanding foam solution, but expanding foam solution viscosity is too large, can affect again the foam performance of expanding foam solution.Therefore, suitable viscosity increaser and add-on need make further experiment screening.The present inventor finds there is the ability forming hydrogen bond between the intermolecular carboxyl of saponin and carbonyl, thus has very high surface viscosity, can form very stable foam.Therefore investigated tea saponin as after viscosity increaser and surfactant compound on the impact of froth stability, found that adding of tea saponin improves a lot to the stability of system.For determining the consumption of tea saponin in compound system further, fixing anionic 15 parts, the massfraction changing tea saponin under the prerequisite that nonionogenic tenside cocoanut fatty acid diethanolamide is 4 parts is tested at 30 DEG C, the results are shown in Table 2.
The dosage of table 2 tea saponin is on the impact of froth stability
| Test number | Tea saponin parts by weight | V/mL | t 1/2v/h |
| 1 | 0 | 1300 | 11.2 |
| 2 | 1 | 2100 | 20.3 |
| 3 | 2 | 2200 | 26.8 |
| 4 | 3 | 2300 | 35.1 |
| 5 | 4 | 2300 | 55.7 |
| 6 | 5 | 2350 | 65.4 |
| 7 | 6 | 2300 | 42.9 |
| 8 | 7 | 2100 | 30.2 |
| 9 | 8 | 2000 | 30.7 |
As can be seen here, add the body phase viscosity that tea saponin can increase liquid between bubble, to make liquid in vacuolar membrane both not easily run off, slow down drain age velocity, the solubleness of gas in liquid film also can be made to reduce, thus increase the stability of foam.But add-on is too much, and the stability of foam reduces on the contrary.Research finds that the amount adding tea saponin is most suitable between 3-5 part.
Test example 3, add the impact of sodium alginate on froth stability
Contriver finds that the foam of existing expanding foam solution breaks soon under slight external force effect, and the complete dry foam of discharge opeing is also more sparse, is easily out of shape.In order to improve froth stability further, improve the performance of dry foam, contriver considers to add auxiliary film forming matter in expanding foam solution.Because liquid phase viscosity is only cofactor, if do not form surface film, liquid phase viscosity is large again, can not form stable foam.Pore forming material and suds-stabilizing agent the adsorption density of face and surface film elasticity closely related, the Interaction Force being adsorbed in the surfactant molecule at surface film gas-liquid interface is large, then surface viscosity is high, film toughness is also high, as formed the hybrid films of high strength between surfactant molecule, liquid film surface viscosity then can be made to increase, thus froth stability is improved greatly.On the basis of the present inventor's component proportion of test number 6 in test example 2, add sodium alginate, the experimental result at 30 DEG C is in table 3.
Table 3 adds the impact of sodium alginate on froth stability and film-forming properties
As can be seen from above test-results, in expanding foam solution, add sodium alginate can not only improve liquid phase viscosity, stop liquid film discharge opeing, the film of high strength can also be formed simultaneously.After adding sodium alginate, foaming properties obviously improves, good film-forming property, and anti-external force improves.Sodium alginate add-on is most suitable 4-8 part.
Test example 4, degerming test
In daily life, common microbiological has: enterobacteria, staphylococcus, alpha streptococcus, streptococcus faecium, subtilis, diphtheroid, acid-fast bacilli, the how bacterium such as Bordetella, lactobacillus, Bacillus proteus, clostridium perfringens, Pseudomonas aeruginosa and minority actinomycetes and fungi.This research is chosen representative bacterium and is carried out bacteriostatic test, with the scientific experimental data providing the present invention to have bactericidal effect.
From toilet inwall collecting sample, be divided into three parts, use detergent treatment of the present invention for two parts, another part is with common commercially available cleaning agent process, and before and after processing aftertreatment in 3 minutes, comparative result is in table 4.
Effectiveness comparison (the cfu/cm of table 4 sanitising agent of the present invention and common cleaning agent treatment process
2)
Claims (5)
1. a foamed cleaning composition, is characterized in that, by weight, comprises anion surfactant 13-15 part, nonionogenic tenside 4-5 part, tea saponin 3-5 part, sodium alginate 4-8 part, Trisodium Citrate 2-6 part, sodium-chlor 0.5-1 part;
Described anion surfactant is: Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, hexadecyl sulfonate, Trombovar, alpha-olefin sodium sulfonate wherein one or more;
Described nonionogenic tenside is: cocoanut fatty acid diethanolamide, dimethyl dodecyl amine oxide one or both.
2. foamed cleaning composition as claimed in claim 1, is characterized in that, also comprise sterilizing deodoring agent 5-7 part.
3. foamed cleaning composition as claimed in claim 2, it is characterized in that, described sterilizing deodoring agent is the mixture of one or more in Folum Ilicis extract, Flos Caryophylli extract, Cortex Phellodendri extract, Folium Menthae extract.
4. foamed cleaning composition as claimed in claim 1 or 2, is characterized in that, also comprise spices 2-3 part.
5. foamed cleaning composition as claimed in claim 1 or 2, is characterized in that, also comprise one or more tinting materials 1-2 part.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384625A (en) * | 2017-07-05 | 2017-11-24 | 芜湖慧宇商贸有限公司 | A kind of preparation method of the Traditional Chinese medicine laundry detergent containing phellodendron extract |
| CN107841393A (en) * | 2017-11-29 | 2018-03-27 | 鹿寨卡森洗涤服务有限公司 | Cleaning compositions |
| CN109666545A (en) * | 2018-12-28 | 2019-04-23 | 中山市天图精细化工有限公司 | A kind of efficient cleaning toilet foam aerosol and preparation method thereof |
| CN114686315A (en) * | 2021-12-31 | 2022-07-01 | 北京绿伞科技股份有限公司 | Foam cleaning agent for toilet bowl and preparation method thereof |
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| CN101239194A (en) * | 2008-03-17 | 2008-08-13 | 张博 | Deodorizing sterilizing foamed liquid for water closet |
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| CN109666545A (en) * | 2018-12-28 | 2019-04-23 | 中山市天图精细化工有限公司 | A kind of efficient cleaning toilet foam aerosol and preparation method thereof |
| CN109666545B (en) * | 2018-12-28 | 2020-10-02 | 中山市天图精细化工有限公司 | Efficient toilet cleaning foam aerosol and preparation method thereof |
| CN114686315A (en) * | 2021-12-31 | 2022-07-01 | 北京绿伞科技股份有限公司 | Foam cleaning agent for toilet bowl and preparation method thereof |
| CN114686315B (en) * | 2021-12-31 | 2024-04-12 | 北京绿伞科技股份有限公司 | Foam cleaning agent for closestool and preparation method thereof |
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