CN105112182A - Normal-pressure foam-type toilet cleaning agent and preparation method thereof - Google Patents
Normal-pressure foam-type toilet cleaning agent and preparation method thereof Download PDFInfo
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- CN105112182A CN105112182A CN201510519812.1A CN201510519812A CN105112182A CN 105112182 A CN105112182 A CN 105112182A CN 201510519812 A CN201510519812 A CN 201510519812A CN 105112182 A CN105112182 A CN 105112182A
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Abstract
The invention discloses a normal-pressure foam-type toilet cleaning agent. The foam-type toilet cleaning agent comprises, by weight, 0.01-2% of foam stabilizer, 1-15% of foamer, 0.5-15% of organic acid, 0.1-5% of bactericide, 0.1-5% of other constituents and the balance deionized water. The foam stabilizer is non-ionic cellulose ether, wherein the substitution degree of the non-ionic cellulose ether is 0.4-2.0, and the molecular weight of the non-ionic cellulose ether is larger than 10000. The foam-type toilet cleaning agent achieves foaming of toilet cleaning agent products, has rich and fine foam and can be attached to a wall for a longer time to clear away stubborn stains and dirt adhering to the wall of a toilet. The use range of toilet cleaning products is expanded, and the foam-type toilet cleaning agent can be used for cleaning toilet seats, toilet covers and the like, can be used more conveniently in a spraying-smearing mode, has the bactericidal effect and the peculiar smell removing effect and brings fragrance experience to people.
Description
Technical field
The present invention relates to a kind of cleanser compositions, belong to daily chemical product technical field, specifically relate to a kind of normal pressure foam type cleaning toilet sanitising agent.
Background technology
Along with the development of raising and the social environment day by day of the standard of living of people, also more and more higher to the sanitary requirement in lavatory.Huge numbers of families come into by water closet, and long use can make toilet glaze paint ties one deck dirt, the settling etc. of mainly greasy dirt, rusty stain, urine alkali and hard water generation, and general being difficult to is cleaned, and easily produces peculiar smell.
At present, lavatory cleaning product common on market has two kinds: a kind of cleaning agent for liquid type, and a kind of is the toilet cleaning block of solid kind.Toilet cleaning block mainly adopts slow release method, and the effective constituents such as sanitising agent, binding agent, sterilant and pigment are made solid substance, puts in cistern and slowly dissolves, and release effective constituent, plays cleaning action.This series products is easy to use, can effectively protect toilet for a long time, but its detersive power limited use.The cleaning agent of liquid type mainly relies on inorganic acid as functional component, thickening technology is adopted to realize the wall built-up effect in its use procedure, effectively can remove the rusty stain of bowl rim, urinate the stains such as the settling of alkali and hard water generation, while scale removal, also have degerming antibacterial effect.This series products generally adopts strong acid as functional component, is effective to the clean of water closet pan, but use procedure pungency is comparatively large, has certain use safety hidden danger.Foam type Closestool cleanser overcomes above-mentioned shortcoming, and safety is gentle, and the wall built-up time is more permanent, both can effectively clean the stain such as settling of the rusty stain of water closet pan, urine alkali and hard water generation, again can cleaning closestool seat cushion, bung etc., easy to use, does not hinder crust.
Chinese patent CN104312773A discloses a kind of foam toilet Bactericidal cleaner and preparation method thereof, and it adopts propelling agent, whipping agent, stablizer, tensio-active agent to be main component, adopts moss tank to store, utilizes propelling agent to foam.This patent only achieves foam, and the shortcoming of existence is apparent, only relies on tensio-active agent to remove toilet grime and is difficult to.And adopt propelling agent to foam, without aseptic technic, also there is very large leakage tank potential safety hazard.Chinese patent CN101239194A discloses a kind of deodorizing sterilizing foamed liquid for water closet, and it adopts base formulation system, uses tensio-active agent to realize foaming decontamination.The dirt of WC pans is rusty stain, stupid stain dirt such as urine alkali, incrustation scale etc., and be difficult to remove by tensio-active agent, can predict, the detersive power effect of product to WC pans dirt of this patent is poor.
Summary of the invention
In order to overcome the above-mentioned deficiency of existing lavatory foam cleaner, the object of the present invention is to provide a kind of normal pressure foam type cleaning toilet sanitising agent, by normal pressure foam lance ejection cleaning toilet foam, can wall built-up lastingly, disintegrate the rusty stain of the attachment on the wall of lavatory, urinate the stupid stain dirt such as alkali, incrustation scale, use simple, safety non-toxic, has again effect of sterilization, taste removal, does not hinder toilet crust, there is provided fragrant atmosphere to experience, pleasant mental and body simultaneously.
Another object of the present invention is to the preparation method that a kind of above-mentioned normal pressure foam type cleaning toilet sanitising agent is provided.
The present invention is achieved by the following technical solutions.
A kind of normal pressure foam type cleaning toilet sanitising agent that the present invention proposes, comprises each feed composition of following weight percent: suds-stabilizing agent 0.01-2%, whipping agent 1-15%, organic acid 0.5-15%, sterilant 0.1-5%, other component 0.1-5%.Surplus is deionized water; This suds-stabilizing agent is a kind of nonionic cellulose ether, and the general structure of this nonionic cellulose ether is:
Wherein, R is-H ,-CH
3,-CH
2-CH
2-OH ,-CH
2-CH
2-CH
2-OH or be
the substitution value of this nonionic cellulose ether is 0.4 ~ 2.0, molecular weight ﹥ 10000.
Nonionic cellulose ether of the present invention is one or more in Natvosol, hydroxypropylcellulose, methylcellulose gum, Vltra tears.Wherein more preferred Natvosol or hydroxypropylcellulose.Preferred addition is 0.01-2.0%, and particularly preferred content is 0.01-0.6%.
Whipping agent of the present invention is nonionogenic tenside or amphoterics, is specially fatty alcohol-polyoxyethylene ether-9, AMONYL 380LC, coconut oleoyl amine hydroxy sulfo lycine, any one of lauroylamidopropyl betaine or two or more mixture.Wherein more preferred fat polyoxyethylenated alcohol-9 and AMONYL 380LC, preferred addition is 3-12.0%.
Organic acid of the present invention is any one in oxalic acid, citric acid, thionamic acid, acetic acid, tartrate or two or more mixture.Wherein more preferred thionamic acid and citric acid, preferred addition is 0.5-15.0%.Particularly preferred content is 2.0-8.0%.
Sterilant of the present invention is one or more mixture of dodecyl benzyl dimethyl ammonium chloride, cetalkonium chloride, dodecyl dimethyl benzyl ammonium bromide, wherein more preferred dodecyl benzyl dimethyl ammonium chloride.Preferred addition is 0.5-1.0%.
Other compositions of the present invention are essence and flavoring agent and pigment, and these components are the general component of Betengent product, and kind does not do specific restriction, and the preferred addition of other components is 0.1-5.0%.
The preparation method of above-described normal pressure foam type cleaning toilet sanitising agent, comprises the following steps:
1) first the pH value of deionized water is adjusted to 8-10 scope, then suds-stabilizing agent is added to the water dispersed with stirring to clear transparent solutions.
2) organic acid is joined in solution be stirred to abundant dissolving.
3) whipping agent and sterilant are joined in solution be stirred to uniform solution.
4) essence and flavoring agent and pigment are added solution, stir to abundant dissolving.Sampling detects, and carries out filling, packaging through after the assay was approved, i.e. obtained described normal pressure foam type cleaning toilet sanitising agent.
Above-mentioned steps is the scheme that preferably feeds intake of the present invention, and certain batching of the present invention is not limited to above-mentioned feeding sequence.Step 3) component also can prior to step 2) prepare.
As preferably, above-mentioned step 4) in, above-mentioned normal pressure foam type cleaning toilet cleaner packing form is the packing bottle of band spray gun structure, and the subsidiary reticular membrane of gun slot, reticular membrane pore size is 50 ~ 200 orders.
Compared to prior art, the present invention has following advantage and beneficial effect:
1) by the foam film intensity of high molecular cellulose ether enhanced foaming agent, foam under realizing cleaning toilet product normal pressure, foam can wall built-up lastingly.Effective constituent durable attachment, on the wall of lavatory, can be disintegrated the rusty stain of the attachment on the wall of lavatory, stupid stain dirt such as urine alkali, incrustation scale etc., use simple, water-saving efficient.
2) normal pressure foam type cleaning toilet sanitising agent of the present invention uses more convenient, can the place that can not clean of the general Closestool cleanser such as cleaning closestool seat cushion, bung, safety non-toxic, there is again effect of sterilization, taste removal, do not hinder toilet crust, provide the experience of fragrant atmosphere, pleasant mental and body simultaneously.
Embodiment
A kind of normal pressure foam type cleaning toilet sanitising agent of the present invention, comprise each feed composition of following weight percent: suds-stabilizing agent 0.01-2% (preferred addition is 0.1-0.6%), whipping agent 1-15% (preferred addition is 3-12%), organic acid 0.5-15% (preferred addition is 2.0-8.0%), sterilant 0.1-5% (preferred addition is 0.5-1.0%), other component 0.1-5%.Surplus is deionized water; This suds-stabilizing agent is a kind of nonionic cellulose ether, and the general structure of this nonionic cellulose ether is:
Wherein, R is-H ,-CH
3,-CH
2-CH
2-OH ,-CH
2-CH
2-CH
2-OH or be
the substitution value of this nonionic cellulose ether is 0.4 ~ 2.0, molecular weight ﹥ 10000.
Below by way of concrete preferred embodiment in conjunction with effect test example, normal pressure foam type cleaning toilet sanitising agent of the present invention is described in further detail, but the present invention is not limited in following embodiment.
embodiment 1 ~ 3
According to table 1 formulation content, prepare embodiment 1 ~ 3 normal pressure foam type cleaning toilet sanitising agent respectively, its preparation method is:
First deionized water pH value is adjusted to 8-10, then Natvosol is added in deionized water, stir, Natvosol is fully dissolved.Add citric acid and thionamic acid again, stir and make it to dissolve.Add AEO9, AMONYL 380LC and dodecyl benzyl dimethyl ammonium chloride again, stir, make abundant dissolving.Finally add essence, stir and fully become transparent and homogeneous liquid.Draw samples is also tested by quality standard, and being up to the standards can be filling, packaging final prod.
The formula composition of the normal pressure foam type cleaning toilet sanitising agent of table 1 embodiment 1 ~ 3
embodiment 4 ~ 6
According to table 2 formulation content, prepare embodiment 4 ~ 6 normal pressure foam type cleaning toilet sanitising agent respectively, its preparation method is:
First methylcellulose gum is added in deionized water, stir, methylcellulose gum is fully dissolved.Add citric acid and oxalic acid again, stir and make it to dissolve.Add AEO9, coconut oleoyl amine hydroxyl sulfo group dish alkali and cetalkonium chloride again, stir, make abundant dissolving.Finally add essence and pigment, stir and fully become transparent and homogeneous liquid.Draw samples is also tested by quality standard, and being up to the standards can be filling, packaging final prod.
The formula composition of the normal pressure foam type cleaning toilet sanitising agent of table 2 embodiment 4 ~ 6
embodiment 7 ~ 9
According to table 3 formulation content, prepare embodiment 7 ~ 9 normal pressure foam type cleaning toilet sanitising agent respectively, its preparation method is:
First hydroxypropylcellulose is added in deionized water, stir, hydroxypropylcellulose is fully dissolved.Add citric acid, oxalic acid and acetic acid again, stir and make it to dissolve.Add AEO9, coconut oleoyl amine hydroxy sulfo lycine and dodecyl benzyl dimethyl ammonium chloride again, stir, make abundant dissolving.Finally add essence, stir and fully become transparent and homogeneous liquid.Draw samples is also tested by quality standard, and being up to the standards can be filling, packaging final prod.
The formula composition of the normal pressure foam type cleaning toilet sanitising agent of table 3 embodiment 7 ~ 9
embodiment 10 ~ 12
According to table 4 formulation content, prepare embodiment 10 ~ 12 normal pressure foam type cleaning toilet sanitising agent respectively, its preparation method is:
First deionized water pH value is adjusted to 8-10, then Natvosol is added in deionized water, stir, Natvosol is fully dissolved.Add citric acid, oxalic acid and thionamic acid again, stir and make it to dissolve.Add AEO9, coconut oleoyl amine hydroxy sulfo lycine and dodecyl benzyl dimethyl ammonium chloride again, stir, make abundant dissolving.Finally add essence, stir and fully become transparent and homogeneous liquid.Draw samples is also tested by quality standard, and being up to the standards can be filling, packaging final prod.
The formula composition of the normal pressure foam type cleaning toilet sanitising agent of table 4 embodiment 10 ~ 12
embodiment 13 ~ 15
According to table 5 formulation content, prepare embodiment 13 ~ 15 normal pressure foam type cleaning toilet sanitising agent respectively, its preparation method is:
First Vltra tears is added in deionized water, stir, Vltra tears is fully dissolved.Add citric acid, oxalic acid, thionamic acid and acetic acid again, stir and make it to dissolve.Add AEO9, lauroylamidopropyl betaine and cetalkonium chloride again, stir, make abundant dissolving.Finally add essence, stir and fully become transparent and homogeneous liquid.Draw samples is also tested by quality standard, and being up to the standards can be filling, packaging final prod.
The formula composition of the normal pressure foam type cleaning toilet sanitising agent of table 5 embodiment 13 ~ 15
effect application test example
The performance test methods of the normal pressure foam type cleaning toilet sanitising agent of the embodiment of the present invention is as follows:
1, detersive power evaluation of measuring method
The making of rust deposite and cleaning: test with iron(ic) chloride to make rust deposite.By the boiling of ferric chloride in aqueous solution, be then evenly coated in ceramics and dry on the surface, put into 105 DEG C of oven ageings again.Use tap water after cleaning four times back and forth with scrubbing resistance instrument, evaluate clean front and back effect.
The making of calcium dirt makes and cleaning: hydrogenated lanolin and calcium stearate 95% alcohol mix, and be directly coated with stain after being heated to boiling state on ceramic tile surface, room temperature is dried, and treats that alcohol is evaporated completely.Then ceramic tile is put into 160 DEG C of oven ageings 1 hour, after taking out, room temperature places one day.Clean twice rear tap water back and forth with scrubbing resistance instrument, evaluate clean front and back effect.
Detersive power effect evaluation method: selected tested volunteer men and women totally 10 (22 years old-55 years old age), carries out sensory evaluation to cleaned ceramics, carries out scoring to evaluate detersive power effect: 10 points, cleaning performance is very clean by following 5 degree; 8 points, cleaning performance is cleaner; 6 points, cleaning performance is general; 4 points, cleaning performance is poor; 0 point, there is no cleaning effect.
2, the quantitative sterilize experiment of sterilization
The Guantitative bactericidal test of normal pressure foam type cleaning toilet sanitising agent is tested with reference to the requirement in Ministry of Health's " disinfection technology standard ".Test strain is common bacteria intestinal bacteria, streptococcus aureus.Fragrant atmosphere cleaning toilet foam cleaning agent is tested under the following conditions the killing rate of bacterium and is obtained: test fluid concentration is stoste, and action time is 10min.
Contrast commercially available cleaning toilet foam cleaner, carried out detergency test and sterilization test, experimental result is in table 6 ~ table 11.
Table 6 product of the present invention and control sample are to the detersive power test-results of rust deposite
Table 7 product of the present invention and control sample are to the detersive power test-results of rust deposite
Table 8 product of the present invention and control sample are to the detersive power test-results of calcium dirt
Table 9 product of the present invention and control sample are to the detersive power test-results of calcium dirt
As can be seen from table 6 ~ table 9, the clean effect of all embodiments to rust deposite and calcium dirt is all obviously better than commercially available prod.The clean effect of embodiment 3 and embodiment 12 pairs of rust deposites is optimum, and the clean effect of embodiment 3, embodiment 12 and embodiment 15 pairs of rust deposites is optimum.Foam type cleaning toilet sanitising agent, due to its abundant fine and smooth foam, can hang over for a long time on the wall of lavatory, functional component fully can be acted on dirt, make dirt be more prone to clean.
Table 10 sterilizing rate test-results
Table 11 sterilizing rate test-results
As can be seen from the result of above-mentioned table 10, table 11, the killing rate of all embodiments to the common intestinal bacteria of lavatory environment and streptococcus aureus reaches 99.9%, can solve peculiar smell source, lavatory from source---and bacterium, real sterilization eliminates the unusual smell.
In sum, normal pressure foam type cleaning toilet sanitising agent of the present invention is by cleaning toilet foam technology, and realization can wall built-up lastingly.Effective constituent durable attachment is on the wall of lavatory, and can disintegrate the rusty stain of the attachment on the wall of lavatory, stupid stain dirt such as urine alkali, incrustation scale etc., easy to use, safety non-toxic, has again effect of sterilization, taste removal.
The above, it is only preferred embodiment of the present invention, not any pro forma restriction is done to the present invention, therefore everyly do not depart from technical solution of the present invention content, the any simple modification done the above embodiment according to technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (10)
1. a normal pressure foam type cleaning toilet sanitising agent, is characterized in that: its recipe ingredient comprises the nonionic cellulose ether of weight percentage 0.01 ~ 2% as suds-stabilizing agent; The general structure of this nonionic cellulose ether is:
Wherein, R is-H ,-CH
3,-CH
2-CH
2-OH ,-CH
2-CH
2-CH
2-OH or be
the substitution value of this nonionic cellulose ether is 0.4 ~ 2.0, molecular weight ﹥ 10000.
2. the normal pressure foam type cleaning toilet sanitising agent according to right 1, it is characterized in that: by weight percentage, its feed composition comprises: suds-stabilizing agent 0.01 ~ 2%, whipping agent 1 ~ 15%, organic acid 0.5 ~ 15%, sterilant 0.1 ~ 5%, other components 0.1 ~ 5%, deionized water surplus.
3., according to the normal pressure foam type cleaning toilet sanitising agent that claim 2 is described, it is characterized in that: this nonionic cellulose ether be specially in Natvosol, hydroxypropylcellulose, methylcellulose gum, Vltra tears one or more; The preferred content of described nonionic cellulose ether is 0.1-0.6%.
4. normal pressure foam type cleaning toilet sanitising agent according to claim 2, it is characterized in that: this whipping agent is nonionogenic tenside or amphoterics, be specially fatty alcohol-polyoxyethylene ether-9, AMONYL 380LC, coconut oleoyl amine hydroxy sulfo lycine, any one of lauroylamidopropyl betaine or two or more mixtures; The preferred content of described whipping agent is 3-12.0%.
5. normal pressure foam type cleaning toilet sanitising agent according to claim 2, is characterized in that: this organic acid is any one in oxalic acid, citric acid, thionamic acid, acetic acid, tartrate or two or more mixture; Described organic acid preferred content is 2.0-8.0%.
6. normal pressure foam type cleaning toilet sanitising agent according to claim 2, is characterized in that: this sterilant is one or more mixtures in dodecyl benzyl dimethyl ammonium chloride, cetalkonium chloride, dodecyl dimethyl benzyl ammonium bromide; The preferred addition of described sterilant is 0.5-1.0%.
7. normal pressure foam type cleaning toilet sanitising agent according to claim 1, it is characterized in that: other components are essence and flavoring agent and pigment, these compositions are the general moiety of Betengent product, and kind does not do specific restriction.
8. the preparation method of the normal pressure foam type cleaning toilet sanitising agent according to any one of claim 2-7, is characterized in that comprising the following steps:
1) first the pH value of deionized water is adjusted to 8-10 scope, then suds-stabilizing agent is added to the water dispersed with stirring to clear transparent solutions;
2) organic acid is joined in solution be stirred to abundant dissolving;
3) whipping agent and sterilant are joined in solution be stirred to uniform solution;
4) essence and flavoring agent, pigment are added in solution, stir to abundant dissolving; Sampling detects, and carries out filling, packaging through after the assay was approved, i.e. obtained described normal pressure foam type cleaning toilet sanitising agent.
9. the preparation method of the normal pressure foam type cleaning toilet sanitising agent according to any one of claim 2-7, is characterized in that comprising the following steps:
1) first the pH value of deionized water is adjusted to 8-10 scope, then suds-stabilizing agent is added to the water dispersed with stirring to clear transparent solutions;
2) whipping agent and sterilant are joined in solution be stirred to uniform solution;
3) organic acid is joined in solution be stirred to abundant dissolving;
4) essence and flavoring agent, pigment are added in solution, stir to abundant dissolving; Sampling detects, and carries out filling, packaging through after the assay was approved, i.e. obtained described normal pressure foam type cleaning toilet sanitising agent.
10. the preparation method of normal pressure foam type cleaning toilet sanitising agent according to claim 8 or claim 9, it is characterized in that: above-mentioned normal pressure foam type cleaning toilet cleaner packing form is the packing bottle of band spray gun structure, the subsidiary reticular membrane of gun slot, reticular membrane pore size is 50 ~ 200 orders.
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| CN201510519812.1A CN105112182A (en) | 2015-08-21 | 2015-08-21 | Normal-pressure foam-type toilet cleaning agent and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109652216A (en) * | 2017-10-11 | 2019-04-19 | 信越化学工业株式会社 | Cleaning compositions |
| CN110846137A (en) * | 2019-11-22 | 2020-02-28 | 北京市家荣保洁服务有限公司 | Toilet cleaning composition and preparation method thereof |
| CN112029593A (en) * | 2020-07-21 | 2020-12-04 | 名臣健康用品股份有限公司 | Foam type toilet cleaning liquid composition and preparation method thereof |
| CN113652313A (en) * | 2021-08-12 | 2021-11-16 | 广东莱雅新化工科技有限公司 | Closestool bubble cleaning agent and preparation method thereof |
| CN113785844A (en) * | 2021-08-11 | 2021-12-14 | 中山市天图精细化工有限公司 | Aerosol for toilet disinfection foam and preparation method thereof |
| CN116179279A (en) * | 2022-12-28 | 2023-05-30 | 广州市爱家有方日用品有限公司 | Toilet cleaning block with low temperature influence and preparation method thereof |
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| WO2011009605A1 (en) * | 2009-07-21 | 2011-01-27 | Martin Miorin | Foam product |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109652216A (en) * | 2017-10-11 | 2019-04-19 | 信越化学工业株式会社 | Cleaning compositions |
| CN110846137A (en) * | 2019-11-22 | 2020-02-28 | 北京市家荣保洁服务有限公司 | Toilet cleaning composition and preparation method thereof |
| CN112029593A (en) * | 2020-07-21 | 2020-12-04 | 名臣健康用品股份有限公司 | Foam type toilet cleaning liquid composition and preparation method thereof |
| CN113785844A (en) * | 2021-08-11 | 2021-12-14 | 中山市天图精细化工有限公司 | Aerosol for toilet disinfection foam and preparation method thereof |
| CN113652313A (en) * | 2021-08-12 | 2021-11-16 | 广东莱雅新化工科技有限公司 | Closestool bubble cleaning agent and preparation method thereof |
| CN116179279A (en) * | 2022-12-28 | 2023-05-30 | 广州市爱家有方日用品有限公司 | Toilet cleaning block with low temperature influence and preparation method thereof |
| CN116179279B (en) * | 2022-12-28 | 2023-12-08 | 广州市爱家有方日用品有限公司 | Toilet cleaning block with low temperature influence and preparation method thereof |
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Effective date of registration: 20180723 Address after: 510370, four building, 97 Star Road, Liwan Road, Liwan District, Guangzhou, Guangdong. Applicant after: Guangzhou Chaowei chemical Limited by Share Ltd Address before: No. two, Liwan District Lu Ju Road, Guangzhou, Guangdong Province Applicant before: Guangzhou Liby Enterprise Group Co., Ltd. |
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Application publication date: 20151202 |