CN114686315B - Foam cleaning agent for closestool and preparation method thereof - Google Patents
Foam cleaning agent for closestool and preparation method thereof Download PDFInfo
- Publication number
- CN114686315B CN114686315B CN202111652429.5A CN202111652429A CN114686315B CN 114686315 B CN114686315 B CN 114686315B CN 202111652429 A CN202111652429 A CN 202111652429A CN 114686315 B CN114686315 B CN 114686315B
- Authority
- CN
- China
- Prior art keywords
- foam
- agent
- cleaning agent
- closestool
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000006260 foam Substances 0.000 title claims abstract description 122
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 78
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 81
- 239000000686 essence Substances 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000004088 foaming agent Substances 0.000 claims abstract description 20
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 19
- 239000003381 stabilizer Substances 0.000 claims abstract description 19
- 239000000022 bacteriostatic agent Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 78
- -1 alkenyl sulfonate Chemical compound 0.000 claims description 62
- 239000011734 sodium Substances 0.000 claims description 41
- 229910052708 sodium Inorganic materials 0.000 claims description 41
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical group CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 36
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 36
- 229930182470 glycoside Natural products 0.000 claims description 33
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 27
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 27
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical group CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims description 27
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 21
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical group [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 claims description 20
- 229940100530 zinc ricinoleate Drugs 0.000 claims description 20
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- 229940116335 lauramide Drugs 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 16
- JNGWKQJZIUZUPR-UHFFFAOYSA-N [3-(dodecanoylamino)propyl](hydroxy)dimethylammonium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)[O-] JNGWKQJZIUZUPR-UHFFFAOYSA-N 0.000 claims description 15
- 229940026210 lauramidopropylamine oxide Drugs 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- 239000002781 deodorant agent Substances 0.000 claims description 12
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 abstract description 15
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 6
- 230000001877 deodorizing effect Effects 0.000 abstract description 3
- 229960004106 citric acid Drugs 0.000 description 23
- 229940051841 polyoxyethylene ether Drugs 0.000 description 20
- 229920000056 polyoxyethylene ether Polymers 0.000 description 20
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 19
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 19
- 238000004140 cleaning Methods 0.000 description 17
- 229940061605 tetrasodium glutamate diacetate Drugs 0.000 description 16
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 16
- 230000000844 anti-bacterial effect Effects 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical group O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 12
- 150000002191 fatty alcohols Chemical class 0.000 description 12
- 238000005187 foaming Methods 0.000 description 12
- 229910052938 sodium sulfate Inorganic materials 0.000 description 12
- 235000011152 sodium sulphate Nutrition 0.000 description 12
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical group O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 10
- 229960000999 sodium citrate dihydrate Drugs 0.000 description 10
- 241000894006 Bacteria Species 0.000 description 9
- 239000008399 tap water Substances 0.000 description 9
- 235000020679 tap water Nutrition 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 244000005700 microbiome Species 0.000 description 7
- 210000002700 urine Anatomy 0.000 description 7
- 229920002125 Sokalan® Polymers 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 229960000587 glutaral Drugs 0.000 description 6
- 239000004584 polyacrylic acid Substances 0.000 description 6
- 159000000000 sodium salts Chemical class 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 108010077895 Sarcosine Proteins 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- MLDWGLQSBBCMMO-UHFFFAOYSA-N [Na].[Na].[Na].CNCC(=O)O Chemical compound [Na].[Na].[Na].CNCC(=O)O MLDWGLQSBBCMMO-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 4
- 239000000741 silica gel Substances 0.000 description 4
- 229910002027 silica gel Inorganic materials 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 241000588724 Escherichia coli Species 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 244000052616 bacterial pathogen Species 0.000 description 3
- 239000002738 chelating agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 210000003608 fece Anatomy 0.000 description 3
- 230000000968 intestinal effect Effects 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- QIAFMBKCNZACKA-UHFFFAOYSA-N N-benzoylglycine Chemical compound OC(=O)CNC(=O)C1=CC=CC=C1 QIAFMBKCNZACKA-UHFFFAOYSA-N 0.000 description 2
- 241001311547 Patina Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- GIYMJJRYEFFRKQ-UHFFFAOYSA-K [Na+].[Na+].[Na+].CNCC(=O)[O-].CNCC(=O)[O-].CNCC(=O)[O-] Chemical compound [Na+].[Na+].[Na+].CNCC(=O)[O-].CNCC(=O)[O-].CNCC(=O)[O-] GIYMJJRYEFFRKQ-UHFFFAOYSA-K 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- DDRJAANPRJIHGJ-UHFFFAOYSA-N creatinine Chemical compound CN1CC(=O)NC1=N DDRJAANPRJIHGJ-UHFFFAOYSA-N 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- CGWWRMKUJFUTPT-UHFFFAOYSA-N 3-methyl-1h-indole Chemical compound C1=CC=C2C(C)=CNC2=C1.C1=CC=C2C(C)=CNC2=C1 CGWWRMKUJFUTPT-UHFFFAOYSA-N 0.000 description 1
- 241000186000 Bifidobacterium Species 0.000 description 1
- 241000305071 Enterobacterales Species 0.000 description 1
- 241000186660 Lactobacillus Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000669298 Pseudaulacaspis pentagona Species 0.000 description 1
- 241000607142 Salmonella Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 1
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229940109239 creatinine Drugs 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002550 fecal effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 210000005239 tubule Anatomy 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a foam cleaning agent for a toilet and a preparation method thereof, wherein the raw materials for preparing the cleaning agent comprise a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, essence, water and/or a deodorizing agent; in addition, the foam cleaning agent can also remove scale or rust in the inner pipeline of the intelligent closestool or the closestool bubble machine, and prevent the inner pipeline from being blocked.
Description
Technical Field
The invention belongs to the field of sanitary product cleaning and nursing, and particularly relates to a foam cleaning agent for a toilet and a preparation method thereof.
Background
The first intelligent toilet in the world was invented and patented by the united states of america in the 60 th century when caring for their own ill father, and then the intelligent toilet was widely used in the medical and health institutions as a medical device. In the 21 st century, with the development of chip technology, intelligent manufacturing technology endows new vitality for household products, and intelligent household products with full mesh in the industry are popular in people, especially in 80 th, 90 th and Z th generation people, and during new epidemic situation, people have higher requirements on sanitation, and epidemic situation causes the blocking of global supply chain, and the shortage of toilet paper increases the requirements of people on intelligent toilets. Compared with a common closestool, the intelligent closestool generally has the functions of automatically uncovering, cleaning a spray head, heating a seat ring, splashing prevention of a foam shield, deodorizing, fragrance retaining, drying, night lamp illumination, foot-feel turning or flushing and the like, and along with the continuous application of the novel technology on the intelligent closestool, the intelligent closestool greatly meets the demands of people on high-quality life. In addition, aiming at the existing non-intelligent closestool of a household, a closestool bubble machine also appears on the market, and the functions of splashing prevention, cleaning, deodorization and fragrance retention of a foam shield can be realized by installing the bubble machine on the non-intelligent closestool. And the foam cleaning agent for the closestool is needed for realizing the functions of splashing prevention, cleaning, deodorization, fragrance retention and the like of the foam shield.
The pollution sources in the toilet are mainly from four parts, namely tap water (reclaimed water), human excrement, human urine, intestinal gas and intestinal flora. Total hardness of tap water (CaCO) 3 Meter) the requirement is less than or equal to 450mg/L, the reclaimed water has no hardness requirement, the hardness of the water in different areas in China is greatly different, and tap water or reclaimed water in high hardness areas contains more Ca 2+ 、Mg 2+ 、Cu 2+ 、Fe 3+ And metal ions are easy to form white scale, reddish brown rust, green patina and other stains in the closestool after long-term use. Human manure is residues which are not absorbed and discharged out of the body after digestion, contains 70% -80% of water, and other food residues and microorganisms after digestion, and also contains a small amount of odorous substances such as skatole (3-methylindole), indole, hydrogen sulfide and the like. The human urine contains 95% of water, 1% -2% of urea and 1% of sodium chloride, and contains a small amount of uric acid, hippuric acid, creatinine, amino acid, phosphate, ammonium salt, trace elements and the like. The intestinal gas is mainly 60% nitrogen, 10% carbon dioxide, 25% methane, 5% hydrogen sulfide and a small amount of oxygen. 4600 bacteria have been found in the human gut, the gut flora being in order of more than a few in number: symbiotic bacteria, conditional pathogenic bacteria and harmful bacteria. Common symbiotic bacteria are bifidobacteria and lactobacilli. Common conditional pathogenic bacteria include enterobacteria, enterococci, etc. Common pathogenic bacteria include salmonella, pathogenic escherichia coli, and the like.
Due to the presence of these stains, toilets require periodic brushing after a period of use. Aiming at the stain condition on the closestool, the current commercial cleaning agent is mainly developed in the GB/T21241-2007 sanitary ware cleaning agent standard, wherein the total acidity (calculated by HCl) of the urinal and the special cleaning agent for the closestool is less than or equal to 12%, and the content of the surfactant is more than or equal to 0.5%. Therefore, the toilet cleaning agent developed in the market mainly comprises hydrochloric acid, citric acid, sulfamic acid, oxalic acid and the like, and a small amount of surfactant is used as an auxiliary cleaning agent, and the brush has good cleaning effect on scale, excretory stains, rust, patina and the like when being matched with the cleaning agent, but can cause unrecoverable damage on the surface of the toilet. Because the surfactant content of the cleaning agent is low, enough foam cannot be generated through the intelligent closestool or the closestool bubble machine to form a foam protection shield, and strong acid in the product can corrode parts in the intelligent closestool or the closestool bubble machine, the traditional closestool cleaning agent cannot meet the requirements of the intelligent closestool or the closestool bubble machine, and a brand new cleaning agent for the closestool needs to be developed.
Disclosure of Invention
Aiming at the problems existing in the prior art, the invention aims to develop a foam cleaning agent for a closestool and a preparation method thereof aiming at the characteristics of a closestool foam machine or an intelligent closestool, and the foam cleaning agent has the characteristics of high foam, foam stabilization, cleaning, redeposition resistance, bacteriostasis, odor neutralization, lasting fragrance retention, safety, high efficiency, low corrosion, silica gel aging prevention and the like.
The invention aims at realizing the following technical scheme:
the foam cleaning agent for the closestool is prepared from the raw materials including a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate and fatty alcohol polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is sodium citrate dihydrate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostat is methyl chloroisothiazolinone and methyl isothiazolinone;
the composite material is prepared from the following components in percentage by weight: 5% of alpha-alkenyl sodium sulfonate, 20% of fatty alcohol polyoxyethylene ether sodium sulfate, 1% of lauramide propyl amine oxide, 10% of sodium citrate dihydrate, 1% of sodium polyacrylate, 4% of alkyl glycoside, 0.1% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.2% of essence, and the balance of water, wherein the pH is adjusted to 6-7 by citric acid.
Another aspect of the invention: the foam cleaning agent for the closestool comprises a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate and fatty alcohol polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is sodium citrate dihydrate and tetra sodium glutamate diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostat is glutaraldehyde, methyl chloroisothiazolinone and methyl isothiazolinone;
the composite material is prepared from the following components in percentage by weight: 10% of alpha-alkenyl sodium sulfonate, 15% of fatty alcohol polyoxyethylene ether sodium sulfate, 2% of lauramide propyl amine oxide, 5% of sodium citrate dihydrate, 5% of tetrasodium glutamate diacetate, 2% of sodium polyacrylate, 4% of alkyl glycoside, 5% of glutaraldehyde, 1% of methyl chloroisothiazolinone and methyl isothiazolinone, 1% of essence, adjusting the pH value to 6-7 by citric acid and the balance of water.
Another aspect of the invention: the foam cleaning agent for the closestool comprises a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, a deodorant, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate and fatty alcohol polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is tetrasodium glutamate diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostat is glutaraldehyde, methyl chloroisothiazolinone and methyl isothiazolinone;
the deodorant is zinc ricinoleate;
the composite material is prepared from the following components in percentage by weight: 20% of alpha-alkenyl sodium sulfonate, 10% of fatty alcohol polyoxyethylene ether sodium sulfate, 3% of lauramide propyl amine oxide, 10% of tetra sodium glutamate diacetate, 3% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 4% of glutaraldehyde, 2% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 2% of essence, and the balance of water, wherein the pH value is adjusted to 6-7 by citric acid.
Another aspect of the invention: the foam cleaning agent for the closestool comprises a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, a deodorant, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate and fatty alcohol polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is tetrasodium glutamate diacetate and trisodium methylglycine diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostat is glutaraldehyde, methyl chloroisothiazolinone and methyl isothiazolinone;
the deodorant is zinc ricinoleate;
the composite material is prepared from the following components in percentage by weight: 30% of alpha-alkenyl sodium sulfonate, 5% of fatty alcohol polyoxyethylene ether sodium sulfate, 4% of lauramide propyl amine oxide, 5% of tetra sodium glutamate diacetate, 5% of methyl glycine disodium, 4% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 3% of glutaraldehyde, 3% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 3% of essence, pH adjustment of citric acid between 6 and 7, and the balance of water.
Another aspect of the invention: the foam cleaning agent for the closestool comprises a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, a deodorant, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is tetrasodium glutamate diacetate and trisodium methylglycine diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostat is methyl chloroisothiazolinone and methyl isothiazolinone;
the deodorant is zinc ricinoleate;
the composite material is prepared from the following components in percentage by weight: 40% of alpha-alkenyl sodium sulfonate, 5% of lauramide propyl amine oxide, 10% of methyl glycine disodium acetate, 5% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 5% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 4% of essence, and the balance of water, wherein the pH is adjusted to 6-7 by citric acid.
Another aspect of the invention: the foam cleaning agent for the enhanced closestool comprises a foaming agent, a foam stabilizer, a water softener, an anti-aging agent, a deodorizing agent, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is citric acid;
the anti-aging agent is alkyl glycoside;
the deodorant is zinc ricinoleate;
the reinforced foam cleaning agent for the closestool is solid-liquid 2-element package and is prepared from the following components in percentage by weight: the component A is citric acid 20%, the component B comprises alpha-sodium alkenyl sulfonate 40%, lauramidopropyl amine oxide 5%, alkyl glycoside 4%, zinc ricinoleate 0.5%, essence 5%, methyl chloroisothiazolinone and methyl isothiazolinone 0.1%, and the balance water.
Another aspect of the invention: the preparation method of the foam cleaning agent for the toilet comprises the following steps:
(1) Adding 1/3 of water into the reaction kettle, adding a water softener into deionized water, and stirring until the water softener is completely dissolved;
(2) Sequentially adding a foaming agent, a foam stabilizer and an anti-aging agent into the reaction kettle, and stirring until the foaming agent, the foam stabilizer and the anti-aging agent are completely dissolved;
if the raw materials contain dispersing agents, the dispersing agents are added into the system before the anti-aging agents are added;
(3) Finally, sequentially adding essence and the rest water into the reaction kettle, and stirring until the mixture is transparent to obtain the foam cleaning agent for the closestool;
if the raw materials contain a bacteriostatic agent and/or a deodorant, the bacteriostatic agent and/or the deodorant are added into the system after the pH is regulated by citric acid and before essence is added.
Another aspect of the invention: the preparation method of the foam cleaning agent for the enhanced closestool comprises the following steps of:
the component A is directly packaged with citric acid according to the weight percentage and is a solid component;
the component B is prepared as follows:
(1) According to the weight percentage, firstly adding 1/3 of water into a reaction kettle, then sequentially adding alpha-sodium alkenyl sulfonate, lauramidopropyl amine oxide and alkyl glycoside, and stirring until the mixture is completely dissolved;
(2) Finally, zinc ricinoleate, essence, methyl chloroisothiazolinone, methyl isothiazolinone and the rest deionized water are added, and the mixture is stirred until the mixture is transparent, so as to obtain a liquid component;
when the foam cleaning agent is used, the component A is added into the component B, and the foam cleaning agent for the enhanced closestool is obtained.
In the system of the foam cleaning agent for the closestool, the foaming agent mainly plays roles of foaming and forming a foam shield rapidly, so that excrement and urine are prevented from splashing, and meanwhile, the foaming agent has good cleaning effects of wetting, emulsifying and the like, can prevent stains from being adsorbed on the wall surface of the closestool, and keeps the closestool clean and tidy. The foam stabilizer mainly plays a role in stabilizing foam, and the durable foam shield is helpful for better preventionAnd (5) sputtering. The water softener mainly plays a role in removing Ca in tap water or reclaimed water 2+ 、Mg 2+ 、Fe 3+ 、Cu 2+ And the like, the softened water is favorable for decontamination and bacteriostasis and is favorable for stabilizing foam. The dispersant mainly plays a role in dispersing stains in water to prevent redeposition. The foam shield foaming component in the intelligent closestool comprises a silica gel pipe, and the anti-aging agent can form a protective layer on the surface of the silica gel pipe to slow down the aging effect of heat, light, mechanical stress, moisture and the like on the silica gel pipe. The bacteriostatic agent mainly inhibits the growth of microorganisms in urine or feces, eliminates harmful bacteria in the toilet, and makes the toilet cleaner. The deodorant is mainly used for removing peculiar smell molecules in urine or feces. The essence can mask the odor of the raw materials and neutralize the odor molecules to keep fragrance continuously, so that the mood of a user is relieved.
The foaming agent in the system is easy to excite the foam, but the foam stability is poor, and the foam is required to be stabilized by adding the foam stabilizer and the dispersing agent, so that the foam is kept stable in a reasonable time and is not defoamed rapidly, and the foam shield has better splash-proof and decontamination effects. The water softener can effectively remove calcium and magnesium ions in water, prevent the calcium and magnesium ions from reacting with the bacteriostatic agent to influence the bacteriostatic effect, and meanwhile, the chelating agent can change the permeability of cell membranes on the surface of bacteria, so that the bacteriostatic agent can enter the bacteria more easily to inhibit the growth and reproduction of the bacteria.
Compared with the prior art, the invention has the beneficial effects that:
1. the foam cleaning agent for the closestool can generate a large amount of foam in a short time after being mixed with water to form a foam shield, so that the splash of excrement and urine is effectively prevented, and meanwhile, the foam cleaning agent has the functions of cleaning the closestool, removing the existing peculiar smell and the like, can kill microorganisms possibly generating peculiar smell and has a good antibacterial function;
2. the foam cleaning agent for the closestool can also remove scale or rust in the inner pipeline of the intelligent closestool or the closestool bubble machine and prevent the inner pipeline from being blocked.
Detailed Description
The disclosure of the present invention will be further understood in conjunction with the following detailed description of the preferred embodiments of the invention, including examples. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. If the definition of a particular term disclosed in the prior art is inconsistent with any definition mentioned in this application, the definition of that term provided in this application controls.
See table 1 for sources of raw materials for the specific examples section.
Example 1
The embodiment provides a foam cleaning agent for a basic toilet, which is prepared from the following components in percentage by weight: 5% of alpha-alkenyl sodium sulfonate, 20% of fatty alcohol polyoxyethylene ether sodium sulfate, 1% of lauramide propyl amine oxide, 10% of sodium citrate dihydrate, 1% of sodium polyacrylate, 4% of alkyl glycoside, 0.1% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.2% of essence and the balance of water to 100.
The method for preparing the foam cleanser for the toilet comprises the following steps:
(1) According to the weight percentage, firstly adding 1/3 of deionized water into a reaction kettle, adding sodium citrate dihydrate, and stirring until the sodium citrate dihydrate is completely dissolved;
(2) Sequentially adding alpha-sodium alkenyl sulfonate, sodium fatty alcohol polyoxyethylene ether sulfate, lauramidopropyl amine oxide, sodium polyacrylate and alkyl glycoside into a reaction kettle, and stirring until the alpha-sodium alkenyl sulfonate, the sodium fatty alcohol polyoxyethylene ether sulfate, the lauramidopropyl amine oxide, the sodium polyacrylate and the alkyl glycoside are completely dissolved; and adjusting the pH value to be 6-7 by citric acid.
(3) And finally, adding methyl chloroisothiazolinone, methyl isothiazolinone, essence and the rest deionized water, and stirring until the mixture is transparent to obtain the foam cleaning agent for the toilet bowl according to the basic mode.
The using method of the foam cleaning agent for the basic type closestool comprises the following steps: pouring foam cleaning agent for a closestool into a cleaning agent box in an intelligent closestool or a closestool bubble machine, pressing a starting key on the closestool, and pumping cleaning agent and tap water (reclaimed water) into a foam generator by a pump in the closestool, wherein the cleaning agent and the tap water are prepared according to the following ratio of 1:100 The mass ratio of (or prescribed mass ratio) mixes and generates a large amount of foam that is sprayed into the bowl of the toilet through the spray head in the toilet, and the large amount of foam forms a foam shield in the bowl that prevents fecal/urine from splashing.
The foam cleaning agent for the basic type closestool mainly meets the basic functions of foam shield, cleaning, removing the existing peculiar smell and the like.
Example 2
The embodiment provides an upgraded foam cleaning agent for a toilet, which is prepared from the following components in percentage by weight: 10% of alpha-alkenyl sodium sulfonate, 15% of fatty alcohol polyoxyethylene ether sodium sulfate, 2% of lauramide propyl amine oxide, 5% of sodium citrate dihydrate, 5% of tetrasodium glutamate diacetate, 2% of sodium polyacrylate, 4% of alkyl glycoside, 5% of glutaraldehyde, 1% of methyl chloroisothiazolinone and methyl isothiazolinone, 1% of essence and the balance of water.
The method for preparing the foam cleanser for the toilet comprises the following steps:
(1) According to the weight percentage, firstly adding 1/3 of deionized water into a reaction kettle, adding sodium citrate dihydrate and tetra sodium glutamate diacetate, and stirring until the sodium citrate dihydrate and the tetra sodium glutamate diacetate are completely dissolved;
(2) Sequentially adding alpha-sodium alkenyl sulfonate, sodium fatty alcohol polyoxyethylene ether sulfate, lauramidopropyl amine oxide, sodium polyacrylate and alkyl glycoside into a reaction kettle, and stirring until the alpha-sodium alkenyl sulfonate, the sodium fatty alcohol polyoxyethylene ether sulfate, the lauramidopropyl amine oxide, the sodium polyacrylate and the alkyl glycoside are completely dissolved; and adjusting the pH value to be 6-7 by citric acid.
(3) And finally, glutaraldehyde, methyl chloroisothiazolinone, methyl isothiazolinone, essence and the rest deionized water are added, and the mixture is stirred until the mixture is transparent, so that the updated foam cleaning agent for the toilet bowl is obtained.
The method of using the upgraded foam cleaning agent for toilets described in this example is described in example 1.
The upgraded foam cleaning agent for the closestool can meet better basic functions (such as the basic functions of foam shield, cleaning and removing the existing peculiar smell and the like as described in the embodiment 1), has a good antibacterial function, and can kill microorganisms possibly generating the peculiar smell while removing the existing peculiar smell.
Example 3
The embodiment provides an upgraded foam cleaning agent for a toilet, which is prepared from the following components in percentage by weight: 20% of alpha-alkenyl sodium sulfonate, 10% of fatty alcohol polyoxyethylene ether sodium sulfate, 3% of lauramide propyl amine oxide, 10% of tetra sodium glutamate diacetate, 3% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 4% of glutaraldehyde, 2% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 2% of essence and the balance of water.
The method for preparing the foam cleanser for the toilet comprises the following steps:
(1) According to the weight percentage, firstly adding 1/3 of deionized water into a reaction kettle, adding tetra sodium glutamate diacetate, and stirring until the tetra sodium glutamate diacetate is completely dissolved;
(2) Sequentially adding alpha-sodium alkenyl sulfonate, sodium fatty alcohol polyoxyethylene ether sulfate, lauramidopropyl amine oxide, sodium polyacrylate and alkyl glycoside into a reaction kettle, and stirring until the alpha-sodium alkenyl sulfonate, the sodium fatty alcohol polyoxyethylene ether sulfate, the lauramidopropyl amine oxide, the sodium polyacrylate and the alkyl glycoside are completely dissolved; the pH value of the citric acid is regulated to be between 6 and 7
(3) And finally, glutaraldehyde, methyl chloroisothiazolinone, methyl isothiazolinone, zinc ricinoleate, essence and the rest deionized water are added, and stirring is carried out until the mixture is transparent, so that the updated foam cleaning agent for the toilet bowl is obtained.
The method of using the upgraded foam cleaning agent for toilets described in this example is described in example 1.
The upgraded foam cleaning agent for the closestool can meet better basic functions (such as the basic functions of foam shield, cleaning and removing the existing peculiar smell and the like as described in the embodiment 1), has a good antibacterial function, and can kill microorganisms possibly generating the peculiar smell while removing the existing peculiar smell.
Example 4
The embodiment provides an upgraded foam cleaning agent for a toilet, which is prepared from the following components in percentage by weight: 30% of alpha-alkenyl sodium sulfonate, 5% of fatty alcohol polyoxyethylene ether sodium sulfate, 4% of lauramide propyl amine oxide, 5% of tetra sodium glutamate diacetate, 5% of methyl glycine disodium, 4% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 3% of glutaraldehyde, 3% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 3% of essence and the balance of water.
The method for preparing the foam cleanser for the toilet comprises the following steps:
(1) According to the weight percentage, firstly adding 1/3 of deionized water into a reaction kettle, adding tetra sodium glutamate diacetate and trisodium methylglycine diacetate, and stirring until the tetra sodium glutamate diacetate and trisodium methylglycine diacetate are completely dissolved;
(2) Sequentially adding alpha-sodium alkenyl sulfonate, sodium fatty alcohol polyoxyethylene ether sulfate, lauramidopropyl amine oxide, sodium polyacrylate and alkyl glycoside into a reaction kettle, and stirring until the alpha-sodium alkenyl sulfonate, the sodium fatty alcohol polyoxyethylene ether sulfate, the lauramidopropyl amine oxide, the sodium polyacrylate and the alkyl glycoside are completely dissolved; and adjusting the pH value to be 6-7 by citric acid.
(3) And finally, glutaraldehyde, methyl chloroisothiazolinone, methyl isothiazolinone, zinc ricinoleate, essence and the rest deionized water are added, and stirring is carried out until the mixture is transparent, so that the updated foam cleaning agent for the toilet bowl is obtained.
The method of using the upgraded foam cleaning agent for toilets described in this example is described in example 1.
The upgraded foam cleaning agent for the closestool can meet better basic functions (such as the basic functions of foam shield, cleaning and removing the existing peculiar smell and the like as described in the embodiment 1), has a good antibacterial function, and can kill microorganisms possibly generating the peculiar smell while removing the existing peculiar smell.
Example 5
The embodiment provides an upgraded foam cleaning agent for a toilet, which is prepared from the following components in percentage by weight: 40% of alpha-alkenyl sodium sulfonate, 5% of lauramide propyl amine oxide, 10% of methyl glycine disodium acetate, 5% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 5% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 4% of essence and the balance of water.
The method for preparing the foam cleanser for the toilet comprises the following steps:
(1) According to the weight percentage, firstly adding 1/3 of deionized water into a reaction kettle, adding trisodium methylglycinate, and stirring until the trisodium methylglycinate is completely dissolved;
(2) Sequentially adding alpha-sodium alkenyl sulfonate, lauramidopropyl amine oxide, sodium polyacrylate and alkyl glycoside into a reaction kettle, and stirring until the alpha-sodium alkenyl sulfonate, the lauramidopropyl amine oxide, the sodium polyacrylate and the alkyl glycoside are completely dissolved; and adjusting the pH value to be 6-7 by citric acid.
(3) And finally, adding methyl chloroisothiazolinone, methyl isothiazolinone, zinc ricinoleate, essence and the rest deionized water, and stirring to be transparent to obtain the updated foam cleaning agent for the toilet bowl.
The method of using the upgraded foam cleaning agent for toilets described in this example is described in example 1.
The upgraded foam cleaning agent for the closestool can meet better basic functions (such as the basic functions of foam shield, cleaning and removing the existing peculiar smell and the like as described in the embodiment 1), has a good antibacterial function, and can kill microorganisms possibly generating the peculiar smell while removing the existing peculiar smell.
Example 6
The embodiment provides a reinforced foam cleaning agent for a toilet, which is a solid-liquid 2-element package and is prepared from the following components in percentage by weight: the component A is 20% of citric acid, the component B is 40% of alpha-alkenyl sodium sulfonate, 5% of lauramidopropyl amine oxide, 4% of alkyl glycoside, 0.5% of zinc ricinoleate, 5% of essence, 0.1% of methyl chloroisothiazolinone and methyl isothiazolinone, and the balance of water.
The method for preparing the foam cleanser for the toilet comprises the following steps:
the component A is directly packaged with citric acid according to the weight percentage.
The component B is prepared as follows:
(1) According to the weight percentage, firstly adding 1/3 of deionized water into a reaction kettle, then sequentially adding alpha-sodium alkenyl sulfonate, lauramidopropyl amine oxide and alkyl glycoside, and stirring until the mixture is completely dissolved;
(2) Finally, zinc ricinoleate, essence, methyl chloroisothiazolinone, methyl isothiazolinone and the rest deionized water are added, and stirring is carried out until the mixture is transparent, so that the enhanced foam cleaning agent for the toilet bowl is obtained.
The use method of the enhanced foam cleaning agent for the toilet bowl comprises the following steps: the component A is added to the component B and mixed uniformly for use (this is because citric acid and other components are mixed and have stability problems in long-term storage and have no stability problems in short-term storage), and the subsequent use method is described in example 1.
Because the foaming device pipelines inside the closestool bubble machine or the intelligent closestool are mostly pipelines with the inner diameter of 2 mm, and the long-term use of the tubules in areas with poor water quality has the risk of blockage, the foam cleaning agent for the enhanced closestool is developed to have various functions of basic type and upgrading type, and can remove scale or rust in the pipelines inside the intelligent closestool or the closestool bubble machine and prevent the pipelines inside the intelligent closestool or the closestool bubble machine from being blocked.
20% citric acid in the formulation was found to be 1: the pH after 100 dilution is about 3, which is lower than the pH suitable for growth of most bacteria, so the antibacterial effect can be good. The enhanced foam cleaning agent formula for the toilet is mainly used for cleaning the toilet in areas with harder water quality or cleaning dirt in the toilet pipeline.
Considering that the foam cleaning agent for the closestool is directly connected with the tap water of a toilet pipeline when being applied, the water quality supplied by the pipeline has influence on the performance of products. The areas of China are wide, the water quality difference is large, namely 30-450ppm, and a large amount of calcium scale and water rust can be deposited in old and old pipelines. The citric acid in the raw material of the embodiment 6 can react with calcium, magnesium and iron plasma in water to reduce the hardness of the water, so that the surfactant can improve detergency and foaming power and stabilize foam, and can dissolve scale and scale deposited in a pipeline to facilitate maintenance of the pipeline. The chelating agent in examples 1-5 also has the effect of softening water quality to reduce the hardness of water, and the citric acid has the effect of the chelating agent and has the function of being added, so that the requirements of users with poor water quality are met.
1. Measurement of foaming ability of foam cleaning agent:
the suction pipe in the foaming device in the closestool is respectively inserted into the foam cleaning agent for the closestool and tap water in the embodiments 1-6, the spray head is placed into the measuring cylinder, the starting device observes the foaming capacity of different embodiments, and the volumes of the foams in 0 min and 5 min are respectively recorded. And the amounts of foam generated by actually measuring 3g of the foam cleaning agent for a toilet and 300g of tap water are shown in the following table 2 by comparing the commercial HCl toilet cleaner with the commercial citric acid toilet cleaner:
TABLE 2 foaming Properties of the different examples and comparative examples
| Foaming amount | 1# | 2# | 3# | 4# | 5# | 6# | Commercial HCl toilet cleaner | Commercial citric acid toilet cleaner |
| Foam amount (ml) for 0 min | 800 | 850 | 870 | 920 | 950 | 930 | 90 | 120 |
| Foam amount (ml) for 5 minutes | 690 | 770 | 810 | 870 | 920 | 900 | 0 | 0 |
From the foaming property results in Table 2, it can be seen that: examples 4-6 all have good foaming effect and have good foam stabilizing effect within 5 minutes, and the foaming amount and the foam stability of the cleaning of examples 1-6 are obviously better than those of the conventional commercial toilet cleaning products.
2. Antibacterial effect of the cleaning agent
According to the method of quantitative antibacterial test of 5.1.1 suspension in WS/T650-2019 antibacterial and bacteriostatic effect evaluation method, the concentration is 1:100 (mass ratio of cleaning agent to hard water) for 5 minutes, the antibacterial ratio against staphylococcus aureus (ATCC 6538) and escherichia coli (8099) is shown in table 3 below:
TABLE 3 antibacterial Properties of the different examples
| Antibacterial rate | 1# | 2# | 3# | 4# | 5# | 6# |
| Golden yellow grape ball (ATCC 6538) | 0 | 99.9% | 99.9% | 99.9% | 99.9% | 99.9% |
| Coli (8099) | 0 | 99.9% | 99.9% | 99.9% | 99.9% | 99.9% |
From the results of the antibacterial properties shown in Table 3, it can be seen that: the foam cleaning agent for the toilet bowl has strong antibacterial effect on staphylococcus aureus (ATCC 6538) and escherichia coli (8099) in examples 2-6.
3. Descaling effect of cleaning agent
According to laboratory test results: 100 Example 6 enhanced foam cleaning agent stock solution for toilet bowl 6.57g CaCO was dissolved 3 。
Claims (1)
1. The foam cleaning agent for the enhanced closestool is characterized in that the raw materials for preparing the cleaning agent comprise a foaming agent, a foam stabilizer, a water softener, an anti-aging agent, a deodorant, a bacteriostatic agent, essence and deionized water;
the foaming agent is alpha-sodium alkenyl sulfonate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is citric acid;
the anti-aging agent is alkyl glycoside;
the deodorant is zinc ricinoleate;
the bacteriostat is methyl chloroisothiazolinone and methyl isothiazolinone;
the foam cleaning agent for the enhanced closestool is a solid-liquid 2-element package and is prepared from the following components in percentage by weight: the component A is citric acid 20%; the component B comprises 40% of alpha-alkenyl sodium sulfonate, 5% of lauramide propyl amine oxide, 4% of alkyl glycoside, 0.5% of zinc ricinoleate, 5% of essence, 0.1% of methyl chloroisothiazolinone and methyl isothiazolinone, and the balance of deionized water;
the preparation method of the foam cleaning agent for the toilet comprises the following steps:
the component A is directly packaged with citric acid according to the weight percentage and is a solid component;
the component B is prepared as follows:
(1) According to the weight percentage, firstly adding 1/3 of deionized water into a reaction kettle, then sequentially adding alpha-sodium alkenyl sulfonate, lauramidopropyl amine oxide and alkyl glycoside, and stirring until the mixture is completely dissolved;
(2) Finally, zinc ricinoleate, essence, methyl chloroisothiazolinone, methyl isothiazolinone and the rest deionized water are added, and the mixture is stirred until the mixture is transparent, so as to obtain a liquid component;
when the foam cleaning agent is used, the component A is added into the component B, and the foam cleaning agent for the enhanced closestool is obtained.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101818104A (en) * | 2010-05-17 | 2010-09-01 | 北京绿伞化学股份有限公司 | Neutral cleaning agent for bathroom equipment and preparation method thereof |
| CN104629688A (en) * | 2015-03-05 | 2015-05-20 | 李震 | Closestool splash-proof foam aerosol and preparation method thereof |
| CN105199865A (en) * | 2015-10-16 | 2015-12-30 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN112029593A (en) * | 2020-07-21 | 2020-12-04 | 名臣健康用品股份有限公司 | Foam type toilet cleaning liquid composition and preparation method thereof |
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- 2021-12-31 CN CN202111652429.5A patent/CN114686315B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101818104A (en) * | 2010-05-17 | 2010-09-01 | 北京绿伞化学股份有限公司 | Neutral cleaning agent for bathroom equipment and preparation method thereof |
| CN104629688A (en) * | 2015-03-05 | 2015-05-20 | 李震 | Closestool splash-proof foam aerosol and preparation method thereof |
| CN105199865A (en) * | 2015-10-16 | 2015-12-30 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN112029593A (en) * | 2020-07-21 | 2020-12-04 | 名臣健康用品股份有限公司 | Foam type toilet cleaning liquid composition and preparation method thereof |
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