CN114686315A - Foam cleaning agent for toilet bowl and preparation method thereof - Google Patents
Foam cleaning agent for toilet bowl and preparation method thereof Download PDFInfo
- Publication number
- CN114686315A CN114686315A CN202111652429.5A CN202111652429A CN114686315A CN 114686315 A CN114686315 A CN 114686315A CN 202111652429 A CN202111652429 A CN 202111652429A CN 114686315 A CN114686315 A CN 114686315A
- Authority
- CN
- China
- Prior art keywords
- agent
- water
- sodium
- foam
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006260 foam Substances 0.000 title claims abstract description 140
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 84
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 108
- 239000000686 essence Substances 0.000 claims abstract description 44
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- 239000004088 foaming agent Substances 0.000 claims abstract description 32
- 239000003381 stabilizer Substances 0.000 claims abstract description 31
- 239000000022 bacteriostatic agent Substances 0.000 claims abstract description 29
- 239000002270 dispersing agent Substances 0.000 claims abstract description 27
- 239000002781 deodorant agent Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 99
- -1 alkyl glycoside Chemical class 0.000 claims description 67
- 239000011734 sodium Substances 0.000 claims description 47
- 229910052708 sodium Inorganic materials 0.000 claims description 47
- 229930182470 glycoside Natural products 0.000 claims description 46
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical group CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 40
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 40
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 37
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 37
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical group CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims description 37
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 37
- 229960004106 citric acid Drugs 0.000 claims description 33
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 28
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 28
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 27
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 27
- 235000011152 sodium sulphate Nutrition 0.000 claims description 27
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 26
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical group [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 claims description 26
- 229940100530 zinc ricinoleate Drugs 0.000 claims description 26
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 25
- 229940061605 tetrasodium glutamate diacetate Drugs 0.000 claims description 23
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 claims description 23
- 229940116335 lauramide Drugs 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 19
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 19
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical group O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 18
- JNGWKQJZIUZUPR-UHFFFAOYSA-N [3-(dodecanoylamino)propyl](hydroxy)dimethylammonium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)[O-] JNGWKQJZIUZUPR-UHFFFAOYSA-N 0.000 claims description 18
- 229940026210 lauramidopropylamine oxide Drugs 0.000 claims description 18
- 229920002125 Sokalan® Polymers 0.000 claims description 16
- 239000008367 deionised water Substances 0.000 claims description 16
- 229910021641 deionized water Inorganic materials 0.000 claims description 16
- 239000004584 polyacrylic acid Substances 0.000 claims description 16
- 159000000000 sodium salts Chemical class 0.000 claims description 16
- MLDWGLQSBBCMMO-UHFFFAOYSA-N [Na].[Na].[Na].CNCC(=O)O Chemical compound [Na].[Na].[Na].CNCC(=O)O MLDWGLQSBBCMMO-UHFFFAOYSA-N 0.000 claims description 14
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 14
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical group O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 14
- 229960000999 sodium citrate dihydrate Drugs 0.000 claims description 14
- 229960000587 glutaral Drugs 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 7
- 238000004140 cleaning Methods 0.000 description 16
- 238000000034 method Methods 0.000 description 14
- 230000003385 bacteriostatic effect Effects 0.000 description 12
- 238000005187 foaming Methods 0.000 description 12
- 241000894006 Bacteria Species 0.000 description 9
- BJEBSDPKCMJMEJ-UHFFFAOYSA-N 3-(dodecanoylamino)propyl-oxidoazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[NH2+][O-] BJEBSDPKCMJMEJ-UHFFFAOYSA-N 0.000 description 8
- 244000005700 microbiome Species 0.000 description 7
- 239000008399 tap water Substances 0.000 description 7
- 235000020679 tap water Nutrition 0.000 description 7
- 210000002700 urine Anatomy 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 230000009286 beneficial effect Effects 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 241000588724 Escherichia coli Species 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 4
- 244000052616 bacterial pathogen Species 0.000 description 4
- 229910001425 magnesium ion Inorganic materials 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- 239000002738 chelating agent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000000968 intestinal effect Effects 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- QIAFMBKCNZACKA-UHFFFAOYSA-N N-benzoylglycine Chemical compound OC(=O)CNC(=O)C1=CC=CC=C1 QIAFMBKCNZACKA-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- DDRJAANPRJIHGJ-UHFFFAOYSA-N creatinine Chemical compound CN1CC(=O)NC1=N DDRJAANPRJIHGJ-UHFFFAOYSA-N 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000029087 digestion Effects 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- CGWWRMKUJFUTPT-UHFFFAOYSA-N 3-methyl-1h-indole Chemical compound C1=CC=C2C(C)=CNC2=C1.C1=CC=C2C(C)=CNC2=C1 CGWWRMKUJFUTPT-UHFFFAOYSA-N 0.000 description 1
- 241000186000 Bifidobacterium Species 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000305071 Enterobacterales Species 0.000 description 1
- 241000194033 Enterococcus Species 0.000 description 1
- 241000186660 Lactobacillus Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241001311547 Patina Species 0.000 description 1
- 241000669298 Pseudaulacaspis pentagona Species 0.000 description 1
- 241000607142 Salmonella Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 1
- TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229940109239 creatinine Drugs 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000029142 excretion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 210000005239 tubule Anatomy 0.000 description 1
- 229940116269 uric acid Drugs 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a foam cleaning agent for a toilet and a preparation method thereof, wherein raw materials for preparing the cleaning agent comprise a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, essence, water and/or a deodorant; in addition, the foam cleaning agent can also remove scale or rust in the internal pipeline of the intelligent closestool or the closestool bubble machine, so that the internal pipeline is prevented from being blocked.
Description
Technical Field
The invention belongs to the field of cleaning and nursing of bathroom products, and particularly relates to a foam cleaning agent for a closestool and a preparation method thereof.
Background
In the 60 th century, the Americans Arnold Cohen invented the first intelligent closestool in the world and obtained the patent when caring the father of their own disease, and then the intelligent closestool was widely used in medical health institutions as medical equipment. Since the 21 st century, along with the development of chip technology, the intelligent manufacturing technology endows household products with new vitality, and the intelligent household products full of enamel are popular with people's lives, especially people who are 80 th, 90 th and Z generations, and during the new crown epidemic situation, people have higher requirements for sanitation, and the global supply chain is blocked due to the epidemic situation, and the demand of people on intelligent toilets is increased due to the shortage of toilet paper. Compared with the common closestool, the intelligent closestool generally has the functions of automatically opening the cover, cleaning the spray head, heating the seat ring, preventing splashing by the foam shield, deodorizing, reserving fragrance, drying, illuminating the night light, turning over the ring by foot feeling or flushing and the like, and the intelligent closestool greatly meets the requirements of people on high-quality life along with the continuous application of new technology on the intelligent closestool. In addition, for the existing non-intelligent toilet in the family, a toilet bubble machine is also appeared in the market, and the bubble machine can also realize the functions of foam shield anti-splash, cleaning and deodorization fragrance retention by being installed on the non-intelligent toilet. The foam cleaning agent for the toilet bowl is needed for realizing the functions of splashing prevention, cleaning, deodorization, fragrance retention and the like of the foam shield.
The pollution source in the closestool mainly comes from four parts, namely tap water (reclaimed water), human excrement, human urine, intestinal gas and intestinal flora. Total hardness of tap water (as CaCO) in China3Measured) is less than or equal to 450mg/L, the reclaimed water has no hardness requirement, the hardness of the water in different regions at home is greatly different, and the tap water or the reclaimed water in high-hardness regions contains more Ca2+、Mg2+、Cu2+、Fe3+And the metal ions are easy to form white scale, red brown rust, green rust and other stains in the toilet bowl after long-term use. Human excrement is discharged from the body of food after digestion and unabsorbedThe residue contains 70-80% of water, and other food residues and microorganisms after digestion, and also contains a small amount of odor substances such as skatole (3-methylindole), indole, hydrogen sulfide and the like. Human urine contains 95% of water, 1% -2% of urea, 1% of sodium chloride, and a small amount of uric acid, hippuric acid, creatinine, amino acid, phosphate, ammonium salt, trace elements and the like. Intestinal gas is mainly 60% nitrogen, 10% carbon dioxide, 25% methane, 5% hydrogen sulfide and a small amount of oxygen. A 4600 variety of bacteria have been found in the human gut, and the gut flora is quantitatively, from many to many times: symbiotic bacteria, conditional pathogenic bacteria and harmful bacteria. The common symbiotic bacteria include bifidobacteria and lactobacilli. Common pathogenic bacteria include enterobacteria, enterococcus and the like. Common pathogenic bacteria include salmonella, pathogenic escherichia coli and the like.
Due to the presence of these stains, toilets require regular brushing after a period of use. Aiming at the stain condition on the toilet, the current commercially available cleaning agent is mainly developed according to GB/T21241-. Therefore, the toilet cleaning agent developed on the market mainly takes hydrochloric acid, citric acid, sulfamic acid, oxalic acid and the like as main cleaning agents, takes a small amount of surfactant as auxiliary cleaning agents, and the hairbrush has good cleaning effect on scale, excretion stains, rust, patina and the like by matching with the cleaning agents, but can cause unrecoverable damage to the surface of the toilet. Because the surfactant content of the cleaning agent is low, the cleaning agent cannot generate enough foam to form a foam shield through the intelligent closestool or the closestool bubble machine, and the strong acid in the product can corrode parts in the intelligent closestool or the closestool bubble machine, the traditional closestool cleaning agent cannot meet the requirement of the intelligent closestool or the closestool bubble machine, and a brand-new cleaning agent for the closestool needs to be developed.
Disclosure of Invention
Aiming at the problems in the prior art, the invention aims to develop a foam cleaning agent for a closestool and a preparation method thereof aiming at the characteristics of a closestool bubble machine or an intelligent closestool, and the foam cleaning agent has the characteristics of high foam, foam stabilization, cleaning, redeposition resistance, bacteriostasis, odor neutralization, lasting fragrance, safety, high efficiency, low corrosion, silica gel aging prevention and the like.
The purpose of the invention is realized by the following technical scheme:
a foam cleaning agent for a toilet bowl is prepared from raw materials including a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, essence and water;
the foaming agent is alpha-alkenyl sodium sulfonate and fatty alcohol-polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is sodium citrate dihydrate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is methyl chloroisothiazolinone and methyl isothiazolinone;
the composition is prepared from the following components in percentage by weight: 5% of alpha-sodium alkenyl sulfonate, 20% of fatty alcohol-polyoxyethylene ether sodium sulfate, 1% of lauramidopropyl amine oxide, 10% of sodium citrate dihydrate, 1% of sodium polyacrylate, 4% of alkyl glycoside, 0.1% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.2% of essence, citric acid with the pH adjusted to be 6-7, and the balance of water.
Another aspect of the invention: a foam cleaning agent for a closestool comprises a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, essence and water;
the foaming agent is alpha-alkenyl sodium sulfonate and fatty alcohol-polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is sodium citrate dihydrate and tetrasodium glutamate diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is glutaraldehyde, methyl chloroisothiazolinone and methyl isothiazolinone;
the composition is prepared from the following components in percentage by weight: 10% of alpha-sodium alkenyl sulfonate, 15% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2% of lauramidopropyl amine oxide, 5% of sodium citrate dihydrate, 5% of tetrasodium glutamate diacetate, 2% of sodium polyacrylate salt, 4% of alkyl glycoside, 5% of glutaraldehyde, 1% of methyl chloroisothiazolinone and methyl isothiazolinone, 1% of essence, citric acid for adjusting the pH value to be 6-7, and the balance of water.
Another aspect of the invention: a foam cleaning agent for a closestool comprises a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, a deodorant, essence and water;
the foaming agent is alpha-alkenyl sodium sulfonate and fatty alcohol-polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is tetrasodium glutamate diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is glutaraldehyde, methyl chloroisothiazolinone and methyl isothiazolinone;
the deodorant is zinc ricinoleate;
the composition is prepared from the following components in percentage by weight: 20% of alpha-sodium alkenyl sulfonate, 10% of fatty alcohol-polyoxyethylene ether sodium sulfate, 3% of lauramidopropyl amine oxide, 10% of tetrasodium glutamate diacetate, 3% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 4% of glutaraldehyde, 2% of methyl chloro isothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 2% of essence, citric acid for adjusting the pH value to be 6-7, and the balance of water.
Another aspect of the invention: a foam cleaning agent for a closestool comprises a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, a deodorant, essence and water;
the foaming agent is alpha-alkenyl sodium sulfonate and fatty alcohol-polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is tetrasodium glutamate diacetate and trisodium methylglycine diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is glutaraldehyde, methyl chloroisothiazolinone and methyl isothiazolinone;
the deodorant is zinc ricinoleate;
the composition is prepared from the following components in percentage by weight: 30% of alpha-sodium alkenyl sulfonate, 5% of fatty alcohol-polyoxyethylene ether sodium sulfate, 4% of lauramidopropyl amine oxide, 5% of tetrasodium glutamate diacetate, 5% of trisodium methylglycine diacetate, 4% of sodium polyacrylate salt, 4% of alkyl glycoside, 3% of glutaraldehyde, 3% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 3% of essence, citric acid with the pH adjusted to be 6-7, and the balance of water.
Another aspect of the invention: a foam cleaning agent for a closestool comprises a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, a deodorant, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is tetrasodium glutamate diacetate and trisodium methylglycine diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is methyl chloroisothiazolinone and methyl isothiazolinone;
the deodorant is zinc ricinoleate;
the composition is prepared from the following components in percentage by weight: 40% of alpha-sodium alkenyl sulfonate, 5% of lauramidopropyl amine oxide, 10% of trisodium methylglycine diacetate, 5% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 5% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 4% of essence, citric acid with the pH adjusted to be 6-7, and the balance of water.
Another aspect of the invention: a foam cleaning agent for a reinforced closestool comprises a foaming agent, a foam stabilizer, a water softener, an anti-aging agent, a deodorant, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is citric acid;
the anti-aging agent is alkyl glycoside;
the deodorant is zinc ricinoleate;
the reinforced foam cleaning agent for the closestool is a solid-liquid 2-yuan package and is prepared from the following components in percentage by weight: the component A is 20 percent of citric acid, the component B comprises 40 percent of alpha-sodium alkenyl sulfonate, 5 percent of lauramidopropyl amine oxide, 4 percent of alkyl glycoside, 0.5 percent of zinc ricinoleate, 5 percent of essence, 0.1 percent of methyl chloroisothiazolinone and methyl isothiazolinone, and the balance of water.
Another aspect of the invention: the preparation method of the foam cleaning agent for the closestool comprises the following steps:
(1) adding 1/3 water into a reaction kettle, adding a water softener into deionized water, and stirring until the water softener is completely dissolved;
(2) sequentially adding a foaming agent, a foam stabilizer and an anti-aging agent into the reaction kettle, and stirring until the foaming agent, the foam stabilizer and the anti-aging agent are completely dissolved;
if the raw materials contain the dispersing agent, the dispersing agent is added into the system before the anti-aging agent is added;
(3) finally, sequentially adding essence and the rest water into the reaction kettle, and stirring until the mixture is transparent to obtain the foam cleaning agent for the closestool;
if the raw materials contain the bacteriostatic agent and/or the deodorant, the bacteriostatic agent and/or the deodorant is added into the system after the pH is adjusted by the citric acid and before the essence is added.
Another aspect of the invention: the preparation method of the foam cleaning agent for the reinforced closestool comprises the following steps:
the component A is directly subpackaged with citric acid according to the weight percentage to be solid component;
the component B is prepared as follows:
(1) according to the weight percentage, firstly adding 1/3 water into a reaction kettle, then sequentially adding alpha-alkenyl sodium sulfonate, lauramide propyl amine oxide and alkyl glycoside, and stirring until the alpha-alkenyl sodium sulfonate, the lauramide propyl amine oxide and the alkyl glycoside are completely dissolved;
(2) finally, adding zinc ricinoleate, essence, methyl chloro isothiazolinone, methyl isothiazolinone and the rest deionized water, and stirring until the mixture is transparent to obtain a liquid component;
when the foam cleaning agent is used, the component A is added into the component B, and the foam cleaning agent for the reinforced toilet bowl is obtained.
In the system of the foam cleaning agent for the closestool, the foaming agent mainly plays a role in foaming and quickly forming a foam shield to prevent excrement/urine from splashing, and meanwhile, the foaming agent has good cleaning effects of wetting, emulsifying and the like, can prevent stains from being adsorbed on the wall surface of the closestool, and keeps the closestool clean and tidy. The foam stabilizer mainly plays a role in stabilizing foam, and the durable foam shield is favorable for better splash prevention. The water softener mainly plays a role in removing Ca in tap water or reclaimed water2+、Mg2+、Fe3+、Cu2+And the softened water is not only beneficial to decontamination and bacteriostasis, but also beneficial to stabilizing foam. The dispersant primarily serves to disperse soil in the water to prevent redeposition. The foam shield foaming component in the intelligent closestool comprises a silicone tube, and the anti-aging agent can form a protective layer on the surface of the silicone tube to slow down the aging effect of heat, light, mechanical stress, water and the like on the silicone tube. The bacteriostatic agent mainly inhibits the growth of microorganisms in urine or excrement, removes harmful germs in the toilet bowl and enables the toilet bowl to be cleaner. The deodorant mainly removes peculiar smell molecules in urine or feces. The essence can cover the odor of the raw materials and neutralize the peculiar smell molecules to keep the fragrance continuously, thereby relieving the mood of a user.
The foaming agent in the system is easy to excite foam, but the foam stability is poor, and a foam stabilizer and a dispersing agent are required to be added to stabilize the foam, so that the foam is kept stable within a reasonable time and is not quickly defoamed, and the foam shield has better splash-proof and decontamination effects. The water softener can effectively remove calcium and magnesium ions in water, prevent the calcium and magnesium ions from reacting with the bacteriostatic agent to influence the bacteriostatic effect, and meanwhile, the chelating agent can change the permeability of cell membranes on the surface of bacteria, so that the bacteriostatic agent can easily enter the bacteria to inhibit the growth and reproduction of the bacteria.
Compared with the prior art, the invention has the beneficial effects that:
1. the foam cleaning agent for the closestool can generate a large amount of foam in a short time after being mixed with water to form a foam shield, effectively prevents excrement/urine from splashing, has the functions of cleaning the closestool, removing the existing peculiar smell and the like, can kill microorganisms which possibly generate peculiar smell, and has a good bacteriostatic function;
2. the foam cleaning agent for the closestool can also remove scale or rust in the internal pipeline of the intelligent closestool or the closestool bubble machine and prevent the internal pipeline from being blocked.
Detailed Description
The invention will be further understood by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs. To the extent that a definition of a particular term disclosed in the prior art is inconsistent with any definitions set forth herein, the definition of that term provided herein controls.
See table 1 for some of the raw material sources for the specific examples.
Example 1
The embodiment provides a basic type foam cleaning agent for a toilet, which is prepared from the following components in percentage by weight: 5% of alpha-sodium alkenyl sulfonate, 20% of fatty alcohol-polyoxyethylene ether sodium sulfate, 1% of lauramidopropyl amine oxide, 10% of sodium citrate dihydrate, 1% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 0.1% of methylchloroisothiazolinone and methylisothiazolinone, 0.2% of essence and the balance of water to 100%.
The method for preparing the foam cleanser for the closestool comprises the following steps:
(1) according to the weight percentage, 1/3 deionized water is added into a reaction kettle, sodium citrate dihydrate is added, and the mixture is stirred until the sodium citrate dihydrate is completely dissolved;
(2) sequentially adding alpha-alkenyl sodium sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, laurylamidopropyl amine oxide, polyacrylic acid sodium salt and alkyl glycoside into a reaction kettle, and stirring until the alpha-alkenyl sodium sulfonate, the fatty alcohol-polyoxyethylene ether sodium sulfate, the laurylamidopropyl amine oxide, the polyacrylic acid sodium salt and the alkyl glycoside are completely dissolved; adjusting the pH value to be 6-7 by using citric acid.
(3) And finally, adding methyl chloroisothiazolinone, methyl isothiazolinone, essence and the rest deionized water, and stirring until the mixture is transparent to obtain the basic foam cleaning agent for the toilet bowl.
The use method of the foam cleaning agent for the basic closestool comprises the following steps: pour into the detergent box among intelligent closestool or the closestool bubble machine with the foam cleaner for the closestool in, press the start button on the closestool, pump in the closestool can extract cleaner and running water (normal water) to the foam generator in, cleaner and running water are according to 1: 100 (or a specified mass ratio) and generates a large amount of foam to be sprayed into a sink of the toilet through a spray head in the toilet, and the large amount of foam forms a foam shield in the sink to prevent the feces/urine from splashing.
This embodiment the foam cleaning agent for closestool of basic style mainly satisfies basic functions such as foam shield, cleanness and clearance existing peculiar smell.
Example 2
The embodiment provides an upgraded foam cleaning agent for a toilet, which is prepared from the following components in percentage by weight: 10% of alpha-sodium alkenyl sulfonate, 15% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2% of lauramidopropyl amine oxide, 5% of sodium citrate dihydrate, 5% of tetrasodium glutamate diacetate, 2% of sodium polyacrylate salt, 4% of alkyl glycoside, 5% of glutaraldehyde, 1% of methyl chloroisothiazolinone and methyl isothiazolinone, 1% of essence and the balance of water.
The method for preparing the foam cleanser for the closestool comprises the following steps:
(1) according to the weight percentage, firstly adding 1/3 deionized water into a reaction kettle, adding sodium citrate dihydrate and tetrasodium glutamate diacetate, and stirring until the sodium citrate dihydrate and the tetrasodium glutamate diacetate are completely dissolved;
(2) sequentially adding alpha-alkenyl sodium sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, laurylamidopropyl amine oxide, polyacrylic acid sodium salt and alkyl glycoside into a reaction kettle, and stirring until the alpha-alkenyl sodium sulfonate, the fatty alcohol-polyoxyethylene ether sodium sulfate, the laurylamidopropyl amine oxide, the polyacrylic acid sodium salt and the alkyl glycoside are completely dissolved; adjusting the pH value to be 6-7 by using citric acid.
(3) And finally, adding glutaraldehyde, methyl chloroisothiazolinone, methyl isothiazolinone, essence and the rest deionized water, and stirring until the mixture is transparent to obtain the upgraded foam cleaning agent for the toilet bowl.
The application method of the upgraded foam cleaning agent for the toilet bowl is described in the embodiment 1.
The upgraded foam cleaning agent for the toilet bowl can meet better basic functions (such as basic functions of foam shield, cleaning and removing existing peculiar smell and the like in embodiment 1), has a good bacteriostatic function, and can kill microorganisms which may generate peculiar smell while removing the existing peculiar smell.
Example 3
The embodiment provides an upgraded foam cleaning agent for a toilet, which is prepared from the following components in percentage by weight: 20% of alpha-sodium alkenyl sulfonate, 10% of sodium fatty alcohol-polyoxyethylene ether sulfate, 3% of lauramidopropyl amine oxide, 10% of tetrasodium glutamate diacetate, 3% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 4% of glutaraldehyde, 2% of methyl chloro isothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 2% of essence and the balance of water.
The method for preparing the foam cleanser for the closestool comprises the following steps:
(1) according to the weight percentage, 1/3 deionized water is added into a reaction kettle, tetrasodium glutamate diacetate is added, and the mixture is stirred until the tetrasodium glutamate diacetate is completely dissolved;
(2) sequentially adding alpha-alkenyl sodium sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, laurylamidopropyl amine oxide, polyacrylic acid sodium salt and alkyl glycoside into a reaction kettle, and stirring until the alpha-alkenyl sodium sulfonate, the fatty alcohol-polyoxyethylene ether sodium sulfate, the laurylamidopropyl amine oxide, the polyacrylic acid sodium salt and the alkyl glycoside are completely dissolved; adjusting the pH value to 6-7 by citric acid
(3) And finally adding glutaraldehyde, methyl chloroisothiazolinone, methyl isothiazolinone, zinc ricinoleate, essence and the rest of deionized water, and stirring until the mixture is transparent to obtain the upgraded foam cleaning agent for the toilet bowl.
The application method of the upgraded foam cleaning agent for the toilet bowl is described in the embodiment 1.
The upgraded foam cleaning agent for the toilet bowl can meet better basic functions (such as basic functions of foam shield, cleaning and removing existing peculiar smell and the like in embodiment 1), has a good bacteriostatic function, and can kill microorganisms which may generate peculiar smell while removing the existing peculiar smell.
Example 4
The embodiment provides an upgraded foam cleaning agent for a toilet, which is prepared from the following components in percentage by weight: 30% of alpha-sodium alkenyl sulfonate, 5% of fatty alcohol-polyoxyethylene ether sodium sulfate, 4% of lauramidopropyl amine oxide, 5% of tetrasodium glutamate diacetate, 5% of trisodium methylglycine diacetate, 4% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 3% of glutaraldehyde, 3% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 3% of essence and the balance of water.
The method for preparing the foam cleanser for the closestool comprises the following steps:
(1) according to the weight percentage, 1/3 deionized water is added into a reaction kettle, tetrasodium glutamate diacetate and trisodium methylglycine diacetate are added, and the mixture is stirred until the tetrasodium glutamate diacetate and the trisodium methylglycine diacetate are completely dissolved;
(2) sequentially adding alpha-alkenyl sodium sulfonate, fatty alcohol-polyoxyethylene ether sodium sulfate, laurylamidopropyl amine oxide, polyacrylic acid sodium salt and alkyl glycoside into a reaction kettle, and stirring until the alpha-alkenyl sodium sulfonate, the fatty alcohol-polyoxyethylene ether sodium sulfate, the laurylamidopropyl amine oxide, the polyacrylic acid sodium salt and the alkyl glycoside are completely dissolved; adjusting the pH value to be 6-7 by using citric acid.
(3) And finally adding glutaraldehyde, methyl chloroisothiazolinone, methyl isothiazolinone, zinc ricinoleate, essence and the rest of deionized water, and stirring until the mixture is transparent to obtain the upgraded foam cleaning agent for the toilet bowl.
The application method of the upgraded foam cleaning agent for the toilet bowl is described in the embodiment and refers to the embodiment 1.
The upgraded foam cleaning agent for the toilet bowl can meet better basic functions (such as basic functions of foam shield, cleaning and removing existing peculiar smell and the like in embodiment 1), has a good bacteriostatic function, and can kill microorganisms which may generate peculiar smell while removing the existing peculiar smell.
Example 5
The embodiment provides an upgraded foam cleaning agent for a toilet, which is prepared from the following components in percentage by weight: 40% of alpha-sodium alkenyl sulfonate, 5% of lauramidopropyl amine oxide, 10% of trisodium methylglycine diacetate, 5% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 5% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 4% of essence and the balance of water.
The method for preparing the foam cleanser for the closestool comprises the following steps:
(1) according to the weight percentage, 1/3 deionized water is added into a reaction kettle, and trisodium methylglycine diacetate is added and stirred until the trisodium methylglycine diacetate is completely dissolved;
(2) sequentially adding alpha-alkenyl sodium sulfonate, lauramide propyl amine oxide, sodium polyacrylate and alkyl glycoside into a reaction kettle, and stirring until the alpha-alkenyl sodium sulfonate, the lauramide propyl amine oxide, the sodium polyacrylate and the alkyl glycoside are completely dissolved; adjusting the pH value to be 6-7 by using citric acid.
(3) And finally, adding methyl chloroisothiazolinone, methyl isothiazolinone, zinc ricinoleate, essence and the rest deionized water, and stirring until the mixture is transparent to obtain the upgraded foam cleaning agent for the toilet bowl.
The application method of the upgraded foam cleaning agent for the toilet bowl is described in the embodiment 1.
The upgraded foam cleaning agent for the toilet can meet better basic functions (such as basic functions of foam shield, cleaning, removing existing peculiar smell and the like in embodiment 1), has a good bacteriostatic function, and can kill microorganisms which may generate peculiar smell while removing the existing peculiar smell.
Example 6
The embodiment provides a reinforced foam cleaning agent for a toilet, which is a solid-liquid 2-element package and is prepared from the following components in percentage by weight: the component A is 20 percent of citric acid, the component B is 40 percent of alpha-sodium alkenyl sulfonate, 5 percent of lauramidopropyl amine oxide, 4 percent of alkyl glycoside, 0.5 percent of zinc ricinoleate, 5 percent of essence, 0.1 percent of methyl chloroisothiazolinone and methyl isothiazolinone, and the balance of water.
The method for preparing the foam cleanser for the closestool comprises the following steps:
the component A is directly packaged with citric acid according to the weight percentage.
The component B is prepared as follows:
(1) according to the weight percentage, 1/3 deionized water is added into a reaction kettle, then alpha-alkenyl sodium sulfonate, lauramide propyl amine oxide and alkyl glycoside are sequentially added, and the mixture is stirred until the alpha-alkenyl sodium sulfonate, the lauramide propyl amine oxide and the alkyl glycoside are completely dissolved;
(2) finally, zinc ricinoleate, essence, methyl chloro isothiazolinone, methyl isothiazolinone and the rest deionized water are added, and the mixture is stirred until the mixture is transparent, so that the enhanced toilet foam cleaning agent is obtained.
The use method of the enhanced foam cleaning agent for the toilet bowl comprises the following steps: the component A is added into the component B and uniformly mixed for use (because the citric acid and other components are mixed and have stability problems for a long time, but have no stability problems for a short time), and the subsequent use method refers to example 1.
Because the inside foaming device pipeline of closestool bubble machine or intelligent closestool is mostly the pipeline that the internal diameter is 2 mm, these tubules use for a long time in the bad area of quality of water and have the risk of jam, so the development the foam cleaning agent for closestool of reinforcing money can also clear away incrustation scale or rust stain in intelligent closestool or the inside pipeline of closestool bubble machine except having each item function of basic money, upgrading money, prevents that its inside pipeline from blockking up.
The formulation has 20% citric acid in the ratio of 1: the pH value after 100 dilution is about 3, which is lower than the proper growth pH value of most bacteria, so the bacteriostatic effect can be good. The enhanced foam cleaning agent formula for the toilet is mainly used for cleaning the toilet in the area with hard water quality or cleaning stains on the toilet pipeline.
Considering that when the foam cleaning agent for the closestool is directly butted with tap water in a pipeline of a toilet when the foam cleaning agent for the closestool is applied, the quality of water supplied by the pipeline has influence on the performance of the product. China has wide territory and great water quality difference of-30-450 ppm, and a great amount of calcium scale and water rust can be deposited in old and old pipelines. In example 6, the citric acid in the raw material can react with calcium, magnesium, iron and the like in water to reduce the hardness of water, which is beneficial to the improvement of detergency and foaming power by the surfactant and the stabilization of foam, and can dissolve scale and scale deposited in the pipeline to be beneficial to the maintenance of the pipeline. The chelating agent in the embodiments 1 to 5 also has the function of softening water and reducing the hardness of water, and the citric acid has the efficacy of the chelating agent and also has the function of increasing, thereby meeting the requirements of users with poor water quality.
Firstly, measuring the foaming capacity of the foam cleaning agent:
the suction pipe in the foaming device in the closestool is respectively inserted into the foam cleaning agent for the closestool and tap water described in the embodiments 1-6, the spray head is placed into the measuring cylinder, the starting device is used for observing the foaming capacity of different embodiments, and the volumes of the foam in 0 minute and 5 minutes are respectively recorded. And the actual measurement of the amount of foam generated by 3g of foam cleaner for toilets and 300g of tap water, as compared to commercially available HCl toilet cleaner and commercially available citric acid toilet cleaner, is shown in Table 2 below:
TABLE 2 foaming Properties of the different examples and comparative examples
| Amount of foaming | 1# | 2# | 3# | 4# | 5# | 6# | Commercial HCl toilet cleaner | Commercial citric acid toilet cleaner |
| Foam amount (ml) at 0 minute | 800 | 850 | 870 | 920 | 950 | 930 | 90 | 120 |
| 5 minute foam volume (ml) | 690 | 770 | 810 | 870 | 920 | 900 | 0 | 0 |
From the results of the foaming properties of Table 2, it can be seen that: examples 4 to 6 all have good foaming effect and good foam stabilizing effect within 5 minutes, and the foaming amount and the foam stability of the cleaning of examples 1 to 6 are obviously superior to those of the existing commercial toilet cleaning products.
Secondly, the bacteriostatic effect of the cleaning agent
According to the method of the 5.1.1 suspension quantitative bacteriostasis test in WS/T650-containing 2019 antibacterial and bacteriostasis effect evaluation method, the use concentration is 1: 100 (mass ratio of cleaning agent to hard water), 5 minutes action time, and the bacteriostatic ratio to staphylococcus aureus (ATCC 6538) and escherichia coli (8099) are shown in table 3 below:
TABLE 3 bacteriostatic Properties of the different examples
| Rate of inhibition of bacteria | 1# | 2# | 3# | 4# | 5# | 6# |
| Golden yellow grape ball (ATCC 6538) | 0 | 99.9% | 99.9% | 99.9% | 99.9% | 99.9% |
| Escherichia coli (8099) | 0 | 99.9% | 99.9% | 99.9% | 99.9% | 99.9% |
The results of the bacteriostatic performance shown in table 3 show that: the foam cleaning agent for the toilet bowl, which is disclosed in the embodiment 2-6, has a strong bacteriostatic action on staphylococcus aureus (ATCC 6538) and escherichia coli (8099).
Thirdly, the descaling effect of the cleaning agent
According to the laboratory test results: 100 g of the enhanced foam cleanser stock solution for toilet bowl of example 6 dissolved 6.57g of CaCO3。
Claims (8)
1. A foam cleaning agent for a toilet is characterized in that raw materials for preparing the cleaning agent comprise a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, essence and water;
the foaming agent is alpha-alkenyl sodium sulfonate and fatty alcohol-polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is sodium citrate dihydrate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is methyl chloroisothiazolinone and methyl isothiazolinone;
the composition is prepared from the following components in percentage by weight: 5% of alpha-sodium alkenyl sulfonate, 20% of fatty alcohol-polyoxyethylene ether sodium sulfate, 1% of lauramidopropyl amine oxide, 10% of sodium citrate dihydrate, 1% of sodium polyacrylate, 4% of alkyl glycoside, 0.1% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.2% of essence, citric acid with the pH adjusted to be 6-7, and the balance of water.
2. A foam cleaning agent for a toilet is characterized in that raw materials for preparing the cleaning agent comprise a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, essence and water;
the foaming agent is alpha-alkenyl sodium sulfonate and fatty alcohol-polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is sodium citrate dihydrate and tetrasodium glutamate diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is glutaraldehyde, methyl chloroisothiazolinone and methyl isothiazolinone;
the composition is prepared from the following components in percentage by weight: 10% of alpha-sodium alkenyl sulfonate, 15% of fatty alcohol-polyoxyethylene ether sodium sulfate, 2% of lauramidopropyl amine oxide, 5% of sodium citrate dihydrate, 5% of tetrasodium glutamate diacetate, 2% of sodium polyacrylate salt, 4% of alkyl glycoside, 5% of glutaraldehyde, 1% of methyl chloroisothiazolinone and methyl isothiazolinone, 1% of essence, citric acid for adjusting the pH value to be 6-7, and the balance of water.
3. A foam cleaning agent for a closestool is characterized in that raw materials for preparing the cleaning agent comprise a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, a deodorant, essence and water;
the foaming agent is alpha-alkenyl sodium sulfonate and fatty alcohol-polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is tetrasodium glutamate diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is glutaraldehyde, methyl chloroisothiazolinone and methyl isothiazolinone;
the deodorant is zinc ricinoleate;
the composition is prepared from the following components in percentage by weight: 20% of alpha-sodium alkenyl sulfonate, 10% of fatty alcohol-polyoxyethylene ether sodium sulfate, 3% of lauramidopropyl amine oxide, 10% of tetrasodium glutamate diacetate, 3% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 4% of glutaraldehyde, 2% of methyl chloro isothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 2% of essence, citric acid for adjusting the pH value to be 6-7, and the balance of water.
4. A foam cleaning agent for a toilet is characterized in that raw materials for preparing the cleaning agent comprise a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, a deodorant, essence and water;
the foaming agent is alpha-alkenyl sodium sulfonate and fatty alcohol-polyoxyethylene ether sodium sulfate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is tetrasodium glutamate diacetate and trisodium methylglycine diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is glutaraldehyde, methyl chloroisothiazolinone and methyl isothiazolinone;
the deodorant is zinc ricinoleate;
the composition is prepared from the following components in percentage by weight: 30% of alpha-sodium alkenyl sulfonate, 5% of fatty alcohol-polyoxyethylene ether sodium sulfate, 4% of lauramidopropyl amine oxide, 5% of tetrasodium glutamate diacetate, 5% of trisodium methylglycine diacetate, 4% of sodium polyacrylate salt, 4% of alkyl glycoside, 3% of glutaraldehyde, 3% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 3% of essence, citric acid with the pH adjusted to be 6-7, and the balance of water.
5. A foam cleaning agent for a toilet is characterized in that raw materials for preparing the cleaning agent comprise a foaming agent, a foam stabilizer, a water softener, a dispersing agent, an anti-aging agent, a bacteriostatic agent, a deodorant, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is tetrasodium glutamate diacetate and trisodium methylglycine diacetate;
the dispersing agent is sodium polyacrylate;
the anti-aging agent is alkyl glycoside;
the bacteriostatic agent is methyl chloroisothiazolinone and methyl isothiazolinone;
the deodorant is zinc ricinoleate;
the composition is prepared from the following components in percentage by weight: 40% of alpha-sodium alkenyl sulfonate, 5% of lauramidopropyl amine oxide, 10% of trisodium methylglycine diacetate, 5% of polyacrylic acid sodium salt, 4% of alkyl glycoside, 5% of methyl chloroisothiazolinone and methyl isothiazolinone, 0.5% of zinc ricinoleate, 4% of essence, citric acid with the pH adjusted to be 6-7, and the balance of water.
6. A reinforced foam cleaning agent for a toilet is characterized in that raw materials for preparing the cleaning agent comprise a foaming agent, a foam stabilizer, a water softener, an anti-aging agent, a deodorant, essence and water;
the foaming agent is alpha-sodium alkenyl sulfonate;
the foam stabilizer is lauramide propyl amine oxide;
the water softener is citric acid;
the anti-aging agent is alkyl glycoside;
the deodorant is zinc ricinoleate;
the bacteriostatic agent is methyl chloroisothiazolinone and methyl isothiazolinone;
the foam cleaning agent for the reinforced closestool is a solid-liquid 2-yuan package and is prepared from the following components in percentage by weight: the component A is 20 percent of citric acid; the component B comprises 40 percent of alpha-alkenyl sodium sulfonate, 5 percent of lauramidopropyl amine oxide, 4 percent of alkyl glycoside, 0.5 percent of zinc ricinoleate, 5 percent of essence, 0.1 percent of methyl chloroisothiazolinone and methyl isothiazolinone, and the balance of water.
7. A preparation method of the foam cleaning agent for the toilet bowl as claimed in any one of claims 1 to 5, characterized by comprising the following steps:
(1) adding 1/3 water into a reaction kettle, adding a water softener into deionized water, and stirring until the water softener is completely dissolved;
(2) sequentially adding a foaming agent, a foam stabilizer and an anti-aging agent into the reaction kettle, and stirring until the foaming agent, the foam stabilizer and the anti-aging agent are completely dissolved;
if the raw materials contain the dispersing agent, the dispersing agent is added into the system before the anti-aging agent is added;
(3) adjusting the pH value of the system to 6-7 by using citric acid; finally, sequentially adding essence and the rest water into the reaction kettle, and stirring until the mixture is transparent to obtain the foam cleaning agent for the closestool;
if the raw materials contain the bacteriostatic agent and/or the deodorant, the bacteriostatic agent and/or the deodorant is added into the system after the pH is adjusted by the citric acid and before the essence is added.
8. The preparation method of the enhanced foam cleaning agent for the toilet bowl as claimed in claim 6, wherein the preparation method comprises the following steps:
the component A is directly subpackaged with citric acid according to the weight percentage to be solid component;
the component B is prepared as follows:
(1) according to the weight percentage of claim 6, 1/3 water is added into a reaction kettle, then alpha-alkenyl sodium sulfonate, lauramide propyl amine oxide and alkyl glycoside are added in sequence, and the mixture is stirred until the alpha-alkenyl sodium sulfonate, the lauramide propyl amine oxide and the alkyl glycoside are completely dissolved;
(2) finally, adding zinc ricinoleate, essence, methyl chloro isothiazolinone, methyl isothiazolinone and the rest deionized water, and stirring until the mixture is transparent to obtain a liquid component;
when the foam cleaning agent is used, the component A is added into the component B, and the foam cleaning agent for the reinforced toilet bowl is obtained.
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| CN202111652429.5A CN114686315B (en) | 2021-12-31 | 2021-12-31 | Foam cleaning agent for closestool and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202111652429.5A CN114686315B (en) | 2021-12-31 | 2021-12-31 | Foam cleaning agent for closestool and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101818104A (en) * | 2010-05-17 | 2010-09-01 | 北京绿伞化学股份有限公司 | Neutral cleaning agent for bathroom equipment and preparation method thereof |
| CN104629688A (en) * | 2015-03-05 | 2015-05-20 | 李震 | Closestool splash-proof foam aerosol and preparation method thereof |
| CN105199865A (en) * | 2015-10-16 | 2015-12-30 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN112029593A (en) * | 2020-07-21 | 2020-12-04 | 名臣健康用品股份有限公司 | Foam type toilet cleaning liquid composition and preparation method thereof |
-
2021
- 2021-12-31 CN CN202111652429.5A patent/CN114686315B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101818104A (en) * | 2010-05-17 | 2010-09-01 | 北京绿伞化学股份有限公司 | Neutral cleaning agent for bathroom equipment and preparation method thereof |
| CN104629688A (en) * | 2015-03-05 | 2015-05-20 | 李震 | Closestool splash-proof foam aerosol and preparation method thereof |
| CN105199865A (en) * | 2015-10-16 | 2015-12-30 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN112029593A (en) * | 2020-07-21 | 2020-12-04 | 名臣健康用品股份有限公司 | Foam type toilet cleaning liquid composition and preparation method thereof |
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| CN114686315B (en) | 2024-04-12 |
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