CN109666545A - A kind of efficient cleaning toilet foam aerosol and preparation method thereof - Google Patents

A kind of efficient cleaning toilet foam aerosol and preparation method thereof Download PDF

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Publication number
CN109666545A
CN109666545A CN201811626909.2A CN201811626909A CN109666545A CN 109666545 A CN109666545 A CN 109666545A CN 201811626909 A CN201811626909 A CN 201811626909A CN 109666545 A CN109666545 A CN 109666545A
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China
Prior art keywords
cleaning toilet
aerosol
agent
foam aerosol
efficient cleaning
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CN201811626909.2A
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CN109666545B (en
Inventor
徐宇霖
余天才
温俊帆
梁高健
张为敬
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Zhongshan Tentop Fine Chemical Co Ltd
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Zhongshan Tentop Fine Chemical Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0068Deodorant compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0094High foaming compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2041Dihydric alcohols
    • C11D3/2055Dihydric alcohols unsaturated
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/24Organic compounds containing halogen
    • C11D3/245Organic compounds containing halogen containing fluorine
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/04Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D2111/42

Abstract

The invention belongs to the aerosol spray technique fields of daily necessities preparation, and in particular to a kind of efficient cleaning toilet foam aerosol and preparation method thereof.Aerosol provided by the invention includes following components and its weight percent: propellant 8~18%, foaming agent 5~10%, air cleaning agent 2~8%, thickener 0.1~0.6%, natural antibacterial agent 0.3~0.6%, preservative 0.2~0.4%, essence 0.2~0.4% and deionized water 62~84.2%.Efficient cleaning toilet foam aerosol provided by the invention, can effectively dispel and completely cut off stink, and foam exquisiteness is plentiful, be able to maintain the long period and be stabilized, and have many advantages, such as splash-proof, automatic toilet cleaning, save toilet paper, environment-friendly water-saving.

Description

A kind of efficient cleaning toilet foam aerosol and preparation method thereof
Technical field
The invention belongs to the aerosol spray technique fields of daily necessities preparation, and in particular to a kind of efficient cleaning toilet foaming aerosol Agent and preparation method thereof.
Background technique
With the development and continuous improvement of people's living standards of society, people have the hygienic quality of living environment more next Higher requirement especially has higher requirement to the sanitary standard of lavatory.Current either toilet seat or squatting pan, all use " S " curved design causes one " water seal ", for preventing the foul smell of sewer from flowing backwards.Just because of bottom, there are certain volumes Water, be seated or when couchant defecation is easy to splash dirt going to toilet, when diarrhea is especially serious.In addition, since user exists It is different using position on toilet seat or squatting pan, when using position far from " water seal ", it will lead to excreta and be stranded in toilet seat On device or squatting pan inner wall, " stink ", which can be discharged, in exposed excreta in air influences toilet air environment, meanwhile, closestool Inner wall is easy to attach dirt growth bacterium, and a large amount of bacteriums are just had when rushing closestool and are splashed to air, seriously affect the strong of people Health.Moreover, excreta is discharged water cleaning after going to the toilet, part residual is still suffered from, it is necessary to clean again using brush, very not side Just.The problem of this is all troublesome all the time.There is foam at water seal and can effectively prevent the excrement fallen into and splashes spray, There is also toilet seats or squatting pan that foam is generated by itself material both at home and abroad, but expensive, cannot generally be used, Do not received by the majority of consumers.
Chinese patent application CN105255603A discloses a kind of taste removal detergent for toilet and preparation method thereof, mainly by polyethylene Alcohol, stearic acid, calgon, ethoxylated dodecyl alcohol phosphate, sodium sulphate, propylene glycol monomethyl ether, hydrogen peroxide, different dragon Brain, 2- hydroxy-3-methyl methyl butyrate, glycine betaine, lauryl sodium sulfate, nonylphenol polyoxyethylene ether, water-soluble plant essence Oil, deionized water, taste removal auxiliary agent are made.Although this kind of detergent for toilet has the function of lubrication, blocks and cover peculiar smell, cleaning is removed The effect is relatively poor for dirt, is not easy to rinse, only plays the role of covering for peculiar smell, cannot eliminate peculiar smell.Chinese patent CN101239194B discloses a kind of deodorizing sterilizing foamed liquid for water closet for integrating sterilization, deodorization, cleaning, scale removal, foaming, should Although sterilizing foamed liquid for water bacteria-eliminating efficacy is preferable, the stability of its foam is not good enough, is easy defoaming, so can not eliminate when going to the toilet Splashing happens.
In conclusion the lavatory clean aerosol in the prior art that is used for removes still there is also many shortcoming and defect Fungistatic effect is poor, can not dispelling abnormal flavor, foam is not abundant enough to stablize outer, the hair for the situation that can not also prevent from splashing during going to the toilet It is raw.
Summary of the invention
In order to solve the problems in the existing technology, the purpose of the present invention is to provide a kind of efficient cleaning toilet foaming aerosols Agent and preparation method thereof.Efficient cleaning toilet foam aerosol provided by the invention, can effectively dispel and completely cut off stink, foam is thin Greasy plentiful, being able to maintain the long period is stabilized, and has many advantages, such as splash-proof, automatic toilet cleaning, saves toilet paper, environment-friendly water-saving.
The technical scheme is that
A kind of efficient cleaning toilet foam aerosol, including following components and its weight percent composition: propellant 8~18%, Foaming agent 5~10%, air cleaning agent 2~8%, thickener 0.1~0.6%, natural antibacterial agent 0.3~0.6%, preservative 0.2~ 0.4%, essence 0.2~0.4% and deionized water 62~84.2%.
Further, the efficient cleaning toilet foam aerosol, is made of: propellant following components and its weight percent 12%, foaming agent 7%, air cleaning agent 4%, thickener 0.3%, natural antibacterial agent 0.4%, preservative 0.3%, 0.3% He of essence Deionized water 75.7%.
Further, the efficient cleaning toilet foam aerosol, the propellant are liquefied petroleum gas, 1,1- difluoro second One of alkane, 1,1,1,2- tetrafluoroethane, 1,3,3,3- tetrafluoropropene.
Further, the efficient cleaning toilet foam aerosol, the foaming agent are sodium sulfate of polyethenoxy ether of fatty alcohol It is formed with palmitinic acid by weight 7~16:2~5.
Further, the efficient cleaning toilet foam aerosol, the foaming agent are sodium sulfate of polyethenoxy ether of fatty alcohol It is formed with palmitinic acid by weight 13:3.
Further, the efficient cleaning toilet foam aerosol, the natural antibacterial agent are pot marigold essence, purple swallow grass extraction One of object, Fructus Gleditsiae Abnormalis extract are a variety of.
Further, the efficient cleaning toilet foam aerosol, the natural antibacterial agent are pot marigold essence, purple swallow grass extraction Object, Fructus Gleditsiae Abnormalis extract are formed by weight 5~11:2~7:1~4.
Further, the efficient cleaning toilet foam aerosol, the natural antibacterial agent are pot marigold essence, purple swallow grass extraction Object, Fructus Gleditsia extract are formed by weight 8:5:2.
Further, the efficient cleaning toilet foam aerosol, the air cleaning agent are coconut oil diethanol amide;The increasing Thick dose is hydroxypropyl methyl cellulose;The preservative sodium benzoate.
In addition, the present invention also provides a kind of preparation methods of efficient cleaning toilet foam aerosol, comprising the following steps:
Thickener is added in deionized water S1, and stirring and dissolving obtains thickener soln;
Preservative and foaming agent are added into the resulting thickener soln of step S1 by S2, stir 40-60min, keep solution mixed Air cleaning agent, essence and natural bacteriostatic agent are added after closing uniformly, are stirred 50-70min, are obtained intermixture liquid;
S3 pours into intermixture liquid obtained by step S2 in aerosol aluminium pot, installs valve, and sealing fills propellant, water-bath inspection Survey, tank bottom penetrates code, install nozzle to get.
In efficient cleaning toilet foam aerosol prepared by the present invention, the foaming agent of addition is by sodium sulfate of polyethenoxy ether of fatty alcohol It is formed with palmitinic acid by weight 13:3.Sodium sulfate of polyethenoxy ether of fatty alcohol is anionic surfactant, soluble easily in water, tool There are excellent decontamination, emulsification, foam performance and hard water resistance performance.Many foams can be formed in a short time, and extension contains The brokenly bubble time of water bubble;The present invention is found surprisingly that, when addition palmitinic acid and sodium sulfate of polyethenoxy ether of fatty alcohol cooperation make The foam of used time, formation can be more stable for a long time, are easier to rinse well, water-saving and environmental protection.Meanwhile the foam of generation has more The good property of water-bearing and mobility, the foam for the lubrication that can be flowed into closet are covered with always closet inner face, effectively prevent Stink distributes.
In efficient cleaning toilet foam aerosol prepared by the present invention, the air cleaning agent of addition is coconut oil diethanol amide, is belonged to Nonionic surfactant, without cloud point.Character is faint yellow to amber thick liquid, soluble easily in water, with good hair The functions such as bubble, foam stabilizing, infiltration decontamination, hard water resistance.It is used cooperatively with the foaming agent of addition, thickening effect is obvious, while having good Good cleaning capacity and foam stabilizing ability, extends the holding time of foam, enhances using effect.
Efficient cleaning toilet foam aerosol prepared by the present invention in the natural bacteriostatic agent of addition, is mentioned by pot marigold essence, purple swallow grass Object, Fructus Gleditsia extract is taken to be composed by a certain percentage, each component is synergistic, has antibacterial, antiinflammation, effective to kill Toxic germ and can kill the detrimentals such as virus, roundworm egg in excrement because;It can be improved foam prepared by the present invention simultaneously The cleaning capacity of aerosol.
Material in efficient cleaning toilet foam aerosol prepared by the present invention, can be with abundant fine and smooth foam in conjunction with propellant Form release, while can according to the requirements such as different costs, environment, benefit adjust dosage and propellant selection, Wherein, 1,3,3,3- tetrafluoropropene (HFO-1234ze) of propellant used in the present invention is environmentally friendly propellant, makes tool of the present invention Have low GWP (global greenhouse potential), low VOC (volatile organic compounds), incombustibility environmental protection characteristic.
At home and abroad market has been very universal to the product of usual foam cleaning class, but foam is used for the splashproof that goes to the toilet The but rareness of water, isolation stink, the present invention is by conventional foamed cleaning class daily necessities combination aerosol packaging, by Material with exquisiteness The form of foam releases.The characteristics of the advantages of not only remaining conventional products, richer product.Traditional daily necessities are closed The aerosolization of reason is a direction of aerosol development, is aerosol market by the reasonable uniquenessization of Conventional aerosol daily necessities A certainty.Efficient cleaning toilet foam aerosol provided by the invention has the characteristics of daily necessities and aerosol, more there is uniqueness Isolation stink, splash-proof and other effects, create biggish market potential, have far-reaching promotional value.
Compared with prior art, efficient cleaning toilet foam aerosol provided by the invention has the advantage that
(1) foaming agent of efficient cleaning toilet foam aerosol provided by the invention, addition can be by feed liquid with the shape of fine and smooth foam Formula releases, and convenient for forming abundant fine and smooth foam inside closestool rapidly, the foam holding time is long, to reduce vision dirt Dye;Meanwhile splashing when can be reduced defecation, the sound to splash when also can eliminate defecation.
(2) efficient cleaning toilet foam aerosol provided by the invention has closed nature, cleans class product phase with regular-type foam Than ensure that content not by external environment secondary pollution, it is not easy to it is rotten, allow user to trust.
(3) efficient cleaning toilet foam aerosol provided by the invention, the froth bed of generation can not only prevent bacterium disperse to In air, the chance of the parasitic nigh bath accessory of bacterium is reduced, and can also dispel and completely cut off the excretal odor, and The natural bacteriostatic of addition can effectively kill toxic germ and can kill the detrimentals such as virus, roundworm egg in excrement because;Together When can be more advantageous to cleaning and flushing, water-saving and environmental protection.
Specific embodiment
The following describes the present invention further through the description of specific embodiments, but it is to limit of the invention that this, which is not, System, those skilled in the art's basic thought according to the present invention can make various modifications or improvements, but without departing from this The basic thought of invention, it is within the scope of the present invention.
Pot marigold essence, No. CAS: 84776-23-8, it is purchased from Suzhou Fu Lu Biotechnology Co., Ltd;Purple swallow grass extract, Purchased from Xi'an Bioisystech Co., Ltd, Tianrui;Fructus Gleditsia extract is purchased from Zhong Shanlianjiu Biotechnology Co., Ltd.
A kind of efficient cleaning toilet foam aerosol of embodiment 1
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
The foaming agent is that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are formed by weight 7:5.
The natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsiae Abnormalis extract by weight 5:7:4 composition.
The preparation method of the efficient cleaning toilet foam aerosol, comprising the following steps:
Hydroxypropyl methyl cellulose is added in deionized water S1, and stirring and dissolving obtains Gonak;
Sodium benzoate and foaming agent are added into the resulting Gonak of step S1 by S2, stir 40min, So that solution is added coconut oil diethanol amide, essence and natural bacteriostatic agent after mixing, stirs 50-70min, obtain intermixture Liquid;
S3 pours into intermixture liquid obtained by step S2 in aerosol aluminium pot, installs valve, and sealing fills 1,1,1,2- tetrafluoro second Alkane, water-bath detection, tank bottom penetrate code, install nozzle to get.
A kind of efficient cleaning toilet foam aerosol of embodiment 2
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
The efficient cleaning toilet foam aerosol, the foaming agent are that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are pressed Weight ratio 13:3 composition.
The natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsia extract by weight 8:5:2 composition.
The preparation method of the efficient cleaning toilet foam aerosol, comprising the following steps:
Hydroxypropyl methyl cellulose is added in deionized water S1, and stirring and dissolving obtains Gonak;
Sodium benzoate and foaming agent are added into the resulting Gonak of step S1 by S2, stir 50min, So that solution is added coconut oil diethanol amide, essence and natural bacteriostatic agent after mixing, stirs 60min, obtain intermixture liquid;
S3 pours into intermixture liquid obtained by step S2 in aerosol aluminium pot, installs valve, and sealing fills 1,3,3,3- tetrafluoros third Alkene (HFO-1234ze), water-bath detection, tank bottom penetrate code, install nozzle to get.
A kind of efficient cleaning toilet foam aerosol of embodiment 3
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
Ingredient names Content (%, w/w)
1,1- Difluoroethane 18
Foaming agent 10
Coconut oil diethanol amide 8
Hydroxypropyl methyl cellulose 0.6
Natural antibacterial agent 0.6
Sodium benzoate 0.4
Essence 0.4
Deionized water 62
The foaming agent is that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are formed by weight 16:2.
The natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsiae Abnormalis extract by weight 11:2:1 composition.
The preparation method of the efficient cleaning toilet foam aerosol, comprising the following steps:
Hydroxypropyl methyl cellulose is added in deionized water S1, and stirring and dissolving obtains Gonak;
Sodium benzoate and foaming agent are added into the resulting Gonak of step S1 by S2, stir 60min, So that solution is added coconut oil diethanol amide, essence and natural bacteriostatic agent after mixing, stirs 70min, obtain intermixture liquid;
S3 pours into intermixture liquid obtained by step S2 in aerosol aluminium pot, installs valve, and sealing fills 1,1- Difluoroethane, Water-bath detection, tank bottom penetrate code, install nozzle to get.
A kind of efficient cleaning toilet foam aerosol of embodiment 4
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
Ingredient names Content (%, w/w)
Liquefied petroleum gas 10
Foaming agent 7
Coconut oil diethanol amide 4
Hydroxypropyl methyl cellulose 0.3
Natural antibacterial agent 0.4
Sodium benzoate 0.2
Essence 0.3
Deionized water 77.8
The efficient cleaning toilet foam aerosol, the foaming agent are that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are pressed Weight ratio 13:3 composition.
The natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsia extract by weight 8:5:2 composition.
The preparation method of the efficient cleaning toilet foam aerosol, comprising the following steps:
Hydroxypropyl methyl cellulose is added in deionized water S1, and stirring and dissolving obtains Gonak;
Sodium benzoate and foaming agent are added into the resulting Gonak of step S1 by S2, stir 50min, So that solution is added coconut oil diethanol amide, essence and natural bacteriostatic agent after mixing, stirs 60min, obtain intermixture liquid;
S3 pours into intermixture liquid obtained by step S2 in aerosol aluminium pot, installs valve, and sealing fills liquefied petroleum gas, water Bath detection, tank bottom penetrate code, install nozzle to get.
A kind of efficient cleaning toilet foam aerosol of embodiment 5
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
Ingredient names Content (%, w/w)
Liquefied petroleum gas 15
Foaming agent 4.1
Coconut oil diethanol amide 7
Hydroxypropyl methyl cellulose 0.4
Natural antibacterial agent 0.4
Sodium benzoate 0.3
Essence 0.2
Deionized water 72.6
The efficient cleaning toilet foam aerosol, the foaming agent are that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are pressed Weight ratio 13:3 composition.
The natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsia extract by weight 8:5:2 composition.
The preparation method of the efficient cleaning toilet foam aerosol, comprising the following steps:
Hydroxypropyl methyl cellulose is added in deionized water S1, and stirring and dissolving obtains Gonak;
Sodium benzoate and foaming agent are added into the resulting Gonak of step S1 by S2, stir 50min, So that solution is added coconut oil diethanol amide, essence and natural bacteriostatic agent after mixing, stirs 60min, obtain intermixture liquid;
S3 pours into intermixture liquid obtained by step S2 in aerosol aluminium pot, installs valve, and sealing fills liquefied petroleum gas, water Bath detection, tank bottom penetrate code, install nozzle to get.
A kind of efficient cleaning toilet foam aerosol of embodiment 6
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
The efficient cleaning toilet foam aerosol, the foaming agent are that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are pressed Weight ratio 13:3 composition.
The natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsia extract by weight 8:5:2 composition.
The preparation method of the efficient cleaning toilet foam aerosol, comprising the following steps:
Hydroxypropyl methyl cellulose is added in deionized water S1, and stirring and dissolving obtains Gonak;
Sodium benzoate and foaming agent are added into the resulting Gonak of step S1 by S2, stir 50min, So that solution is added coconut oil diethanol amide, essence and natural bacteriostatic agent after mixing, stirs 60min, obtain intermixture liquid;
S3 pours into intermixture liquid obtained by step S2 in aerosol aluminium pot, installs valve, and sealing fills 1,3,3,3- tetrafluoros third Alkene (HFO-1234ze), water-bath detection, tank bottom penetrate code, install nozzle to get.
A kind of efficient cleaning toilet foam aerosol of embodiment 7
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
The efficient cleaning toilet foam aerosol, the foaming agent are that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are pressed Weight ratio 13:3 composition.
The efficient cleaning toilet foam aerosol, for pot marigold, smart, purple swallow grass extract, Chinese honey locust mention the natural antibacterial agent Object is taken to form by weight 8:5:2.
The preparation method of the efficient cleaning toilet foam aerosol, comprising the following steps:
Hydroxypropyl methyl cellulose is added in deionized water S1, and stirring and dissolving obtains Gonak;
Sodium benzoate and foaming agent are added into the resulting Gonak of step S1 by S2, stir 50min, So that solution is added coconut oil diethanol amide, essence and natural bacteriostatic agent after mixing, stirs 60min, obtain intermixture liquid;
S3 pours into intermixture liquid obtained by step S2 in aerosol aluminium pot, installs valve, and sealing fills 1,1,1,2- tetrafluoro second Alkane, water-bath detection, tank bottom penetrate code, install nozzle to get.
A kind of efficient cleaning toilet foam aerosol of comparative example 1
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
The efficient cleaning toilet foam aerosol, the foaming agent are that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are pressed Weight ratio 13:3 composition.
The natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsia extract by weight 8:5:2 composition.
The preparation method of the efficient cleaning toilet foam aerosol is similar to Example 2.
The difference from example 2 is that being not added with palmitinic acid in the foaming agent.
A kind of efficient cleaning toilet foam aerosol of comparative example 2
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
The efficient cleaning toilet foam aerosol, the foaming agent are that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are pressed Weight ratio 1:1 composition.
The natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsia extract by weight 8:5:2 composition.
The preparation method of the efficient cleaning toilet foam aerosol is similar to Example 2.
The difference from example 2 is that the foaming agent be sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid by weight It is formed than 1:1.
A kind of efficient cleaning toilet foam aerosol of comparative example 3
The efficient cleaning toilet foam aerosol, is made of following components and its weight percent:
The efficient cleaning toilet foam aerosol, the foaming agent are that sodium sulfate of polyethenoxy ether of fatty alcohol and palmitinic acid are pressed Weight ratio 13:3 composition.
The natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsia extract by weight 1:1:1 composition.
The preparation method of the efficient cleaning toilet foam aerosol is similar to Example 2.
The difference from example 2 is that the natural antibacterial agent is pot marigold essence, purple swallow grass extract, Fructus Gleditsia extract It is formed by weight 1:1:1.
Test example one, foaming capacity and foam stability test
1, test material: the efficient cleaning toilet foam aerosol of embodiment 1-7, comparative example 1-3 preparation.
2, test method: by embodiment 1-7, the efficient cleaning toilet foam aerosol Continued depression spray head of comparative example 1-3 preparation 3s reads foam volume into 2L graduated cylinder, and investigates its foaming capacity and foam stability.
Wherein, foaming power: the foam of sending pours into measurement foam volume V, the foaming power as foam aerosol in graduated cylinder. Stability: time, the referred to as half-life period (t of foam needed for recording above-mentioned foam volume decaying half1/2v), to measure foam Stability, t1/2vLonger, surfactant foam liquid more stability is better.
3, test result
Test result is as shown in table 1.
1 foaming capacity of table and foam stability test result
As shown in Table 1, compared with the control group, the foaming capacity and foam of the efficient cleaning toilet aerosol of embodiment 1-7 preparation Stability is excellent, and wherein 2 groups of effects of embodiment are best, is highly preferred embodiment of the present invention.And comparative example 1-3 group and embodiment Test result show in efficient cleaning toilet aerosol provided by the invention that the foaming agent and each group distribution ratio of addition are reasonable, cooperate with Effect is obvious.Proportion due to comparative example 1 and 2 due to changing foaming agent, so its foaming capacity is decreased obviously, and foam Stability is also poor compared with the effect of embodiment.
Test example two, anti-microbial property test
1. test material: embodiment 2, the efficient cleaning toilet foam aerosol of comparative example 1-3 preparation.
2. subjects: Escherichia coli, Candida albicans, staphylococcus aureus.
3. test method: antibacterial experiment: efficient cleaning toilet foam aerosol 5mL prepared by embodiment 2 and comparative example 1-3 being set In sterile conical flask, it is separately added into 70mL phosphate buffer (0.03molL-1) and 5mL bacterium solution, culture medium is penetrated into liquid In after, 37 DEG C culture for 24 hours after, carry out bacterium colony counting.
Bacteriostasis rate calculation formula: X=(A-B)/A × 100%, wherein X is bacteriostasis rate, and A is average colony before sample vibrates Number, B are average colony number after test agent oscillation.
4. test result
Test result is as shown in table 2.
2 antibacterial tests result of table
By the anti-microbial property test of table 2 as the result is shown it is found that a kind of efficient cleaning toilet foam gas prepared by the embodiment of the present invention 2 To Escherichia coli, the inhibitory effect of Candida albicans and Staphylococcus aureus is significant for mist agent, the bacteriostasis rate after contact 24 hours 98% or more, the efficient cleaning toilet foam aerosol fungistatic effect of comparative example 1-3 preparation is relatively weak, and comparative example 3 and reality The comparing result for applying example 2 shows the natural bacteriostatic agent added in efficient cleaning toilet foam aerosol prepared by the present invention according to certain For ratio with being combined into, each component is synergistic, has wide spectrum and potent anti-microbial property, can effectively kill toxic germ and energy Kill detrimentals such as virus, roundworm egg in excrement because.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as At all equivalent modifications or change, should be covered by the claims of the present invention.

Claims (10)

1. a kind of efficient cleaning toilet foam aerosol, which is characterized in that including following components and its weight percent: propellant 8~ 18%, foaming agent 5~10%, air cleaning agent 2~8%, thickener 0.1~0.6%, natural antibacterial agent 0.3~0.6%, preservative 0.2~0.4%, essence 0.2~0.4% and deionized water 62~84.2%.
2. efficiently cleaning toilet foam aerosol as described in claim 1, which is characterized in that by following components and its weight percent Composition: propellant 12%, foaming agent 7%, air cleaning agent 4%, thickener 0.3%, natural antibacterial agent 0.4%, preservative 0.3%, Essence 0.3% and deionized water 75.7%.
3. efficiently cleaning toilet foam aerosol as claimed in claim 1 or 2, which is characterized in that the propellant is liquefied petroleum One of gas, 1,1- Difluoroethane, 1,1,1,2- tetrafluoroethane, 1,3,3,3- tetrafluoropropene.
4. efficiently cleaning toilet foam aerosol as claimed in claim 1 or 2, which is characterized in that the foaming agent is poly alkyl alcohol Ethylene oxide ether sodium sulfate and palmitinic acid are formed by weight 7~16:2~5.
5. efficiently cleaning toilet foam aerosol as claimed in claim 4, which is characterized in that the foaming agent is fatty alcohol polyoxy second Alkene ether sodium sulfate and palmitinic acid are formed by weight 13:3.
6. efficiently cleaning toilet foam aerosol as claimed in claim 1 or 2, which is characterized in that the natural antibacterial agent is golden small cup One of anthosin, purple swallow grass extract, Fructus Gleditsiae Abnormalis extract are a variety of.
7. efficiently cleaning toilet foam aerosol as claimed in claim 6, which is characterized in that the natural antibacterial agent is pot marigold Essence, purple swallow grass extract, Fructus Gleditsiae Abnormalis extract are formed by weight 5~11:2~7:1~4.
8. efficiently cleaning toilet foam aerosol as claimed in claim 7, which is characterized in that the natural antibacterial agent is pot marigold Essence, purple swallow grass extract, Fructus Gleditsiae Abnormalis extract are formed by weight 8:5:2.
9. efficiently cleaning toilet foam aerosol as claimed in claim 1 or 2, which is characterized in that the air cleaning agent is coconut oil two Glycollic amide;The thickener is hydroxypropyl methyl cellulose;The preservative sodium benzoate.
10. a kind of preparation method of such as described in any item efficient cleaning toilet foam aerosols of claim 1-9, which is characterized in that The following steps are included:
Thickener is added in deionized water S1, and stirring and dissolving obtains thickener soln;
Preservative and foaming agent are added into the resulting thickener soln of step S1 by S2, stir 40-60min, keep solution mixing equal Air cleaning agent, essence and natural bacteriostatic agent are added after even, are stirred 50-70min, are obtained intermixture liquid;
S3 pours into intermixture liquid obtained by step S2 in aerosol aluminium pot, installs valve, and sealing fills propellant, water-bath detection, tank Code is penetrated at bottom, install nozzle to get.
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Denomination of invention: A highly effective toilet cleaning foam aerosol and its preparation method

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