KR0148208B1 - Toilet soap composition having an excellent effect of removing a fishy-smell - Google Patents
Toilet soap composition having an excellent effect of removing a fishy-smellInfo
- Publication number
- KR0148208B1 KR0148208B1 KR1019950054319A KR19950054319A KR0148208B1 KR 0148208 B1 KR0148208 B1 KR 0148208B1 KR 1019950054319 A KR1019950054319 A KR 1019950054319A KR 19950054319 A KR19950054319 A KR 19950054319A KR 0148208 B1 KR0148208 B1 KR 0148208B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- parts
- extract
- soap
- skin
- Prior art date
Links
- 239000000344 soap Substances 0.000 title claims abstract description 42
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 230000000694 effects Effects 0.000 title description 22
- 239000000284 extract Substances 0.000 claims abstract description 33
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims abstract description 16
- 235000011613 Pinus brutia Nutrition 0.000 claims abstract description 16
- 241000018646 Pinus brutia Species 0.000 claims abstract description 16
- 239000000341 volatile oil Substances 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011435 rock Substances 0.000 claims abstract description 5
- 235000013339 cereals Nutrition 0.000 claims description 24
- 241000209094 Oryza Species 0.000 claims description 9
- 235000007164 Oryza sativa Nutrition 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 9
- 235000009566 rice Nutrition 0.000 claims description 9
- 239000004909 Moisturizer Substances 0.000 claims description 5
- 230000001333 moisturizer Effects 0.000 claims description 5
- 241000209140 Triticum Species 0.000 claims description 4
- 235000021307 Triticum Nutrition 0.000 claims description 4
- 239000002537 cosmetic Substances 0.000 abstract description 21
- 230000001877 deodorizing effect Effects 0.000 abstract description 18
- 235000019645 odor Nutrition 0.000 description 10
- 239000002781 deodorant agent Substances 0.000 description 8
- 230000000844 anti-bacterial effect Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 230000035943 smell Effects 0.000 description 7
- 239000004575 stone Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 150000001413 amino acids Chemical class 0.000 description 6
- 241000251468 Actinopterygii Species 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- 235000019688 fish Nutrition 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000003020 moisturizing effect Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 230000000845 anti-microbial effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VKPPFDPXZWFDFA-UHFFFAOYSA-N 2-chloroethanamine Chemical compound NCCCl VKPPFDPXZWFDFA-UHFFFAOYSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- 206010040880 Skin irritation Diseases 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 235000019462 natural additive Nutrition 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- 208000035143 Bacterial infection Diseases 0.000 description 1
- 241000218631 Coniferophyta Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 208000035859 Drug effect increased Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000269821 Scombridae Species 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229940069521 aloe extract Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 231100000676 disease causative agent Toxicity 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000010437 gem Substances 0.000 description 1
- 229910001751 gemstone Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 235000020640 mackerel Nutrition 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000037152 sensory function Effects 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9755—Gymnosperms [Coniferophyta]
- A61K8/9767—Pinaceae [Pine family], e.g. pine or cedar
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/18—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Botany (AREA)
- Biotechnology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dermatology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
1. 청구범위에 기재된 발명이 속한 기술분야1. TECHNICAL FIELD OF THE INVENTION
조성물Composition
2. 발명이 해결하려고 하는 기술적 과제2. The technical problem to be solved by the invention
화장비누의 소취효과 향상Improved deodorizing effect of cosmetic soap
3. 발명의 해결방법의 요지3. Summary of Solution to Invention
알콜농도 10%의 곡류엑기스 1 내지 3중량부, 맥반석 0.5 내지 1.5중량부와 솔잎정유 0.3 내지 1중량부가 잔여 중량부의 통상적인 비누분과 배합되어 있음을 특징으로하는 화장비누 조성물1 to 3 parts by weight of grain extract of 10% alcohol, 0.5 to 1.5 parts by weight of ganban rock and 0.3 to 1 parts by weight of pine needle essential oil are mixed with the remaining parts by weight of conventional soap powder.
4. 발명의 중요한 용도4. Important uses of the invention
화장비누Toilet soap
Description
[발명의 명칭][Name of invention]
소취효과가 탁월한 화장비누 조성물Cosmetic soap composition with excellent deodorant effect
[발명의 상세한 설명]Detailed description of the invention
본 발명은 소취효과를 갖는 화장비누 조성물에 관한 것으로서, 더욱 상세하게는 통상의 화장비누에 소취효과를 줄수 있는 곡류엑기스와 함께 맥반석 및 솔잎정유를 배합하여 소취효과, 특히 비린내 제거효과를 크게 증대시킨 화장비누 조성물에 관한 것이다.The present invention relates to a cosmetic soap composition having a deodorizing effect, and more particularly, by combining ganban stone and pine needle essential oil with grain extract which can give a deodorizing effect to a conventional makeup soap, greatly increasing the deodorizing effect, in particular, the fishy removing effect. The present invention relates to a cosmetic soap composition.
일반적으로 화장비누라는 것은 지방산계의 각종 동식물 유지를 가성소다 등의 염기로 분해, 검화하여 제조하는 것으로서, 이때 피부 자극성을 줄이기 위하여 염기의 잔류량을 최소로 줄이고 지방산 특유의 냄새를 제거하기 위하여 향료를 소량 첨가하며, 피부 윤활성이나 보습성을 위하여 유연제나 보습제를 필요에 따라 첨가하여 적당한 형태를 갖는 고형으로 제조된 것을 말한다. 이러한 화장비누가 갖추어야 할 근본조건은 인체에 부착된 오염을 제거할 수 있는 세정성과 사용감을 부드럽게 할 수 있는 기포력 및 피부 자극성이 적고 사용후 미용효과가 있어야 한다. 최근에는 인체피부에 기생하는 각종 세균, 곰팡이등으로부터 기인하는 악취나 세균감염을 사전에 예방할수 있는 살균효과가 있는 위생용 화장비누에 대한 수요가 늘고 있으며 또한 냄새제거, 특히 비린내등과 같은 육류나 생선으로부터 기인하는 냄새를 제거할 수 있는 제품에 대한 수요가 늘고 있다. 그러나, 비누는 매우 강력한 계면활성제임에도 불구하고 비린내를 효과적으로 제거하지 못하고 있다. 이는 비린내의 원인물질이 피부에 강하게 흡착하여 단지 계면활성제의 세정작용으로는 완전히 흡착물질을 제거하지 못하기 때문이다.In general, cosmetic soap is produced by decomposing and saponifying fatty acid-based animal and vegetable fats and oils with a base such as caustic soda. At this time, perfumes are used to reduce the residual amount of bases and to remove fatty acid-specific odors to reduce skin irritation. Small amount is added, and softening agent or moisturizer is added as necessary for skin lubricity or moisturizing, and it is manufactured into solid having a suitable form. Fundamental conditions for these cosmetic soaps should be cleansing to remove contamination attached to the human body, less foaming and skin irritation to soften the feeling, and have a cosmetic effect after use. Recently, there is an increasing demand for hygienic cosmetic soaps having a sterilizing effect to prevent odors and bacterial infections caused by various bacteria and fungi that are parasitic on human skin, and also to remove odors, especially fish such as fishy smells. There is an increasing demand for products that can remove odors from fish. However, even though soap is a very powerful surfactant, it does not effectively remove fishy smell. This is because the causative agent of fishy is strongly adsorbed on the skin and only the cleaning action of the surfactant does not completely remove the adsorbent.
이러한 화장비누의 단점을 극복하기 위하여 최근에는 살균력 및 탈취효과가 있는 천연 첨가물을 배합하거나 합성 항균물질로 화장비누에 항균력과 소취효과를 부여한 제품을 개발하려는 연구가 지속되었다. 냄새의 원인중 육류나 생선등 외부환경으로부터 기인한 것은 잘 씻어내면 제거할 수 있으나, 실제로는 그리 쉽게 제거되지 않으므로 소취효과를 갖는 천연물이나 특수 성분을 배합하여 냄새를 제거하려는 노력이 있어 왔다. 피부산재균이나 피지 등의 분비물이 부패하여 발생하는 경우는 씻어내도 또 발생하므로 근본적인 제거가 어렵기 때문에, 많은 연구자들은 합성 항균물질을 함께 배합하여 세정후 피부에 남아있는 일정농도의 항균물질이 피부산재균을 제거하여 소취효과를 갖도록 만든 제품을 개발중에 있다.In order to overcome the drawbacks of these cosmetic soaps, researches have recently been conducted to develop products that combine antibacterial and deodorizing effects with cosmetic antibacterial substances by combining natural additives having bactericidal and deodorizing effects. Among the causes of odors are those that originate from the external environment such as meat or fish, but can be removed by washing them well. However, since they are not so easily removed, there have been efforts to remove odors by combining natural products or special ingredients with deodorant effect. If the secretion of skin acid bacteria or sebum occurs due to decay, it may occur even after being washed away. Therefore, many researchers combine synthetic antimicrobial substances with a certain concentration of antimicrobial substances remaining on the skin after washing. The company is developing a product that has a deodorant effect by removing skin acid bacteria.
천연 첨가물중에서 한방성분을 사용한 예로는 한국특허공고제 83-385호에 공개된 맥반석이나 한국특허공고 제 90-2934호에 공개된 한방생약성분이 있지만 미용성분으로 효과만 강조하였고 살균력이나 소취효과는 입증하지 못하고 있다. 또한, 특허공고 제 90-2934호에는 토코페롤, 알로에 엑기스 등의 천연 약용물질과 함께 아미노 에틸 염산 글리신을 함께 사용하고 있으나, 이 경우 아미노에틸 염산 글리신의 살균작용 및 탈취효과가 매우 미약하며 기대한 만큼의 효과를 거두기 어렵다. 또한 피부 산재균을 제거하여 소취효과를 얻으려고 사용하는 합성 항균물질에는 여러 종류가 있지만 근본적으로 이와같은 물질은 사용하기에 너무 고가이고 실질적인 효과를 보기 위해서는 상당한 양을 요구하기 때문에 사용에 제약을 받는다.Among the natural additives, examples of using herbal ingredients include ganban stone disclosed in Korean Patent Publication No. 83-385 or herbal herbal ingredients disclosed in Korean Patent Publication No. 90-2934, but they emphasize only the effect as a cosmetic ingredient. It is not proven. In addition, in Patent Publication No. 90-2934, amino ethyl hydrochloride glycine is used together with natural medicinal substances such as tocopherol and aloe extract, but in this case, the bactericidal and deodorizing effect of aminoethyl hydrochloride glycine is very weak and as expected. It is hard to reap the effect. In addition, there are many kinds of synthetic antimicrobial agents used to remove skin scattering bacteria to achieve deodorizing effects, but they are fundamentally limited because they are too expensive to use and require a substantial amount for practical effects. .
따라서, 본 발명자들은 상기와 같은 항균물질을 사용하지 않고 소취효과, 특히 비린내 제거효과를 얻을 수 있는 제품을 개발하려고 노력한 바 기존 화장비누에 각종 곡류를 발효시켜 얻는 곡류 엑기스와 맥반석 및 솔잎정유를 함께 적절한 배합비율로 사용한 결과 소취효과, 특히 비린내 제거효과가 뛰어난 화장비누를 개발할 수 있었다.Therefore, the present inventors have tried to develop a product that can obtain a deodorizing effect, in particular, fishy removal effect without using the antimicrobial material as described above together with the grain extract obtained by fermenting various cereals in the existing cosmetic soap with ganban stone and pine needle essential oil. As a result of using an appropriate blending ratio, it was possible to develop a cosmetic soap with excellent deodorant effect, especially fishy removal effect.
본 발명에 사용하기 적합한 곡류 엑기스의 성분 및 제조방법은 한국특허공고 제 93-2848호에 자세히 기술되어 있다. 본 발명에 유용한 곡류 엑기스는 쌀, 쌀겨, 보리 및 밀 등을 바이오 기술을 이용하여 제조한 천연엑기스이므로 환경을 오염시키지 않고 세정효과를 높여주는 구실을 한다. 또한 곡류 엑기스는 천연보습인자의 주 성분인 아미노산을 다량 함유하여 피부의 거칠어짐을 방지함과 아울러 피부에 촉촉함을 유지시켜 준다. 피부의 천연보습인자 성분을 보면 아미노산류 40%, 피롤리돈카르복실산 12%, 요소 7%로 이루어져 이들 아미노산 관련 물질이 전체의 60% 가량 차지하고 있으며, 그 외에도 당, 유기산, 펩티드, 기타 염류등이 40%를 차지한다. 따라서, 아미노산 관련 물질이 피부에 적정수분을 유지함에 있어서 중요한 역할을 하는 것을 알 수 있다. 손경현 등의 연구문헌인 Kor. J. Appl. Microbiol. Biotechnol.,Vol 20, No 1, 85~90(1992)에 기술된 방법에 따르면 본 발명에서 제조된 곡류 엑기스중 특히 쌀겨 엑기스는 대략 다음과 같은 아미노산 조성을 갖는다.Ingredients and methods for preparing cereal extracts suitable for use in the present invention are described in detail in Korean Patent Publication No. 93-2848. Grain extract useful in the present invention is a natural extract manufactured by using biotechnology for rice, rice bran, barley and wheat, etc., and serves as an excuse to increase the cleaning effect without contaminating the environment. In addition, grain extract contains a large amount of amino acid, the main ingredient of natural moisturizing factor, to prevent roughness of the skin and to keep the skin moist. The natural moisturizing factor of skin consists of 40% of amino acids, 12% of pyrrolidonecarboxylic acid, and 7% of urea. These amino acid-related substances account for about 60% of the total. In addition, sugars, organic acids, peptides, and other salts The back accounts for 40%. Therefore, it can be seen that the amino acid-related substances play an important role in maintaining proper moisture in the skin. Son, Kyung-Hyun et al. Kor. J. Appl. Microbiol. According to the method described in Biotechnol., Vol 20, No 1, 85 to 90 (1992), among the grain extracts produced in the present invention, especially rice bran extract has approximately the following amino acid composition.
이처럼 곡류 엑기스에는 아미노산의 함량이 높기 때문에 생선 비린내의 주원인인 트리메칠아미노기를 쉽게 제거하는 소취효과가 있음을 기대할 수 있다. 그러나, 전술한 특허공고 제 93-2848호의 실시예Since the grain extract has a high amino acid content, it can be expected to have a deodorizing effect to easily remove trimethylamino group, which is the main cause of fish fish. However, the embodiment of the above-mentioned patent publication 93-2848
1, 실시예 2, 실시예 3에 명시된대로 제조된 곡물 엑기스는 미생물이 이용할 수 있는 영양분이 풍부하며 유통과정이나 보관중에 잡균에 오염될 가능성이 높기 때문에 이를 예방하는 것이 커다란 문제로 남아 있었다. 본 발명자들은 그러한 문제를 해결하기위하여 순수한 알콜을 여러농도로하여 선택적으로 사용하여 보았으나, 곡류 엑기스에 자체로 알콜을 함유하기 때문에 지나치게 과량 사용하면 계면활성제의 기포력을 저하시키는 소포작용과 고형 비누의 물성을 저하시켜 성형을 어렵게 하고 적은 양을 사용하면 소취효과가 나타나지 않는등 많은 곤란성을 겪으면서, 오랜기간의 연구결과 본 발명자들은 알콜농도가 10%로 조정된 곡류엑기스를 본 발명 조성물에 대해 1 내지 3중량부의 범위에서 사용했을 때 상기의 문제점들을 해결할 수 있음을 발견하였다.Cereal extracts prepared as specified in Examples 1, 2 and 3 are rich in nutrients that can be used by microorganisms and are highly contaminated with various germs during distribution and storage. In order to solve such a problem, the present inventors have selectively used pure alcohols in various concentrations, but since the grain extract itself contains alcohols, when excessively used, defoamers and solid soaps lower the foaming power of the surfactant. As a result of long-term research, the present inventors have found that grain extracts having an alcohol concentration adjusted to 10% are difficult to form due to the deterioration of physical properties and difficulty of molding, and the use of a small amount results in no deodorizing effect. It has been found that the above problems can be solved when used in the range of 1 to 3 parts by weight.
또한, 본 발명자들은 곡류 엑기스가 세정 후에 피부에 남은 계면활성제 잔류분을 완벽하게 제거해 준 다는 사실을 알게되었으며, 이에따라, 곡류엑기스는 소취효과외에도 세정후 잔류 세제에 의하여 피부가 거칠어지는 것을 방지해 주는 역할도 기대된다.In addition, the present inventors have found that the grain extract completely removes the surfactant residues remaining on the skin after washing. Accordingly, the grain extract prevents the skin from being roughened by the residual detergent after washing in addition to the deodorizing effect. The role is also expected.
본 발명에서는 곡류 엑기스와 함께 맥반석을 사용하는 것이 필수적이다. 맥반석이란 석영반암에 속하는 암석으로 자연상태에서 장석과 석영의 결정으로 이루어져 있으며 본 발명에 사용한 것은 이 원석을 분쇄하고 다시 미분화하여 평균입자 크기가 320메쉬 이하인 것으로서 전남 노화도 광산에서 채취한 원석을 삼중세락믹사에서 가공한 제품이다. 본초강목 등에 따르면 맥반석은 인체의 신진대사를 원활히 하고 치료의 속도를 빠르게 하는 작용등이 보고되었으며, 최근 세라믹 산업등에서 널리 활용되고 있는 중이다. 동양에서 특히 잘 알려진 맥반석은 흡착, 수질조절, 산소 및 미네랄공급, 원적외선 방출 등 많은 특징이 있으나 특히 강력한 흡착작용은 맥반석내에 있는 미세한 구멍에 의해 생기는 것으로 믿어지며 이들 미세한 구멍이 모세관 현상을 일으켜 수증의 오염물질과 각종 공해물질 및 잡균을 흡착하는 것으로 추측된다. 이런 점에서 본 발명자들은 맥반석의 흡착작용을 이용하여 냄새제거를 위해 화장비누에 응용해 보았으나, 맥반석 함량이 지나치게 적으면 소취효과가 떨어지고 반대로 지나치게 많으면 고형비누의 응집력을 떨으뜨려 성형을 까다롭게 하여 곡류엑기스와 마찬가지로 많은 곤란성을 겪던중 만족할 만한 소취효과와 원하는 성형을 제공할 수 있는 맥반석의 가능한 사용량은 0.5 내지 1.5중량부임을 밝혀내었다.In the present invention, it is essential to use ganguerite together with the grain extract. Elvanite is a rock belonging to quartz rock, which is composed of feldspar and quartz crystal in natural state, and used in the present invention is pulverized and re-divided this gemstone, and the average particle size is 320 mesh or less. It is processed by MIX Corporation. According to the herbaceous tree, elvan has been reported to facilitate the metabolism of the human body and speed up the treatment, and is recently being widely used in the ceramic industry. Elvan, which is particularly well known in the Orient, has many features such as adsorption, water quality control, oxygen and mineral supply, and far-infrared emission, but especially strong adsorption is believed to be caused by micropores in the elvan, and these micropores cause capillary action. It is estimated to adsorb pollutants, various pollutants and various bacteria. In this regard, the present inventors have applied to the cosmetic soap to remove the odor by using the adsorbing action of elvan, but if the amount of the elvan is too small, the deodorizing effect is lowered. Like many extracts, it has been found that the possible use of elvan is 0.5 to 1.5 parts by weight, which can provide satisfactory deodorizing effects and desired moldings.
본 발명에서는 또한 솔잎정유(精油)를 사용하는 것이 필수적이다. 알려진 바와같이 소나무로 대표되는 몇가지 침엽수의 정유는 독특한 방향성(芳香成)과 함께 항균 및 소취효과를 갖고 있다. 이는 테르펜류와 식물성살균류 성분으로 대별되는 솔잎정유의 중요한 성분 때문에 나타나는 효과라고 이해된다. 본 발명에 사용된 솔잎정유의 제법과 특성은 강하영 등의 연구문헌인 임업연보 제49호, 177~185(1994)에 자세히 기술되어 있다. 일반적으로 기름성분을 지나치게 과량 사용하면 비누의 특성인 기포의 양이 과도하게 줄어드는 것으로 알려져 있다. 이러한 점을 감안하여 본 발명자들은 솔잎정유의 사용량을 신중히 고려하여 실험한 결과 가능한 사용량은 0.1 내지 2중량부임을 알게되었으나, 놀랍게도 본 발명에 따른 상기한 함량의 곡류 엑기스 및 맥반석과 함께 솔잎정유를 0.3 내지 1중량부로 사용했을 때 현저히 상승된 소취효과를 나타냄을 발견하였다.In the present invention, it is also essential to use pine needle essential oil (精油). As is known, the essential oils of some conifers, represented by pine trees, have antibacterial and deodorant effects with unique fragrance. This is understood to be due to the important components of pine needle essential oil, which is roughly divided into terpenes and vegetable fungicides. The preparation and properties of pine needle essential oil used in the present invention are described in detail in Forestry Yearbook No. 49, 177-185 (1994). In general, excessive use of oil components is known to reduce excessively the amount of bubbles that are characteristic of soap. In view of this, the present inventors have found that the possible amount of use is 0.1 to 2 parts by weight, and the inventors have carefully considered the amount of pine needle essential oil, but surprisingly, the pine needle extract oil with the above-mentioned grain extract and elvan is 0.3 When used in an amount of 1 to 1 part by weight was found to exhibit a markedly deodorant effect.
따라서, 본 발명은 통상의 화장비누 기재에 곡류를 효소반응시켜 얻은 에탄올 10%의 곡류엑기스 1 내지 3중량부, 맥반석0.5 내지 1.5 중량부 및 솔잎정유 0.3 내지 1중량부가 배합되어 있음을 특징으로 하는 화장비누 조성물을 제공한다.Therefore, the present invention is characterized in that 1 to 3 parts by weight of 10% ethanol grain extract, 0.5 to 1.5 parts by weight of ganban rock and 0.3 to 1 parts by weight of pine needle essential oil are formulated on a conventional soap base. Provides a cosmetic soap composition.
본 발명에 따른 화장비누 조성물에는 화장비누에 통상적으로 사용되는 피부유연제나 피부보습제를 함께 사용할 수 있다. 보통 화장비누에 광범위하게 사용되는 것들로서 솔비탄 에스테르류, 라놀린 혹은 그 유도체류, 각종오일류 및 고급 지방산 등을 사용할 수 있으며, 이들 물질을 사용하여도 본 발명의 특징인 살균력에는 전혀 문제가 없었다. 본 발명에서는 분말상의 맥반석이 첨가되어 고형비누를 제조하는 과정에서 비누의 살균력에는 전혀 문제가 없었다. 본 발명에서는 분말상의 맥반석이 첨가되어 고형비누를 제조하는 과정에서 비누의 응집력을 방해할 수 있기 때문에 상기 물질중 점도가 높은 것들은 피부 유연제나 보습제로서의 가치뿐 아니라 비누의 제조공정을 원활하게 해주는 역할도 함께하는 기대밖의 효과도 있다. 그러나, 이들 물질은 비누의 특성인 기포력을 감소시키는 악영향도 있기 때문에 본 발명에서는 0.5 내지 5중량부를 사용할 수 있고 비누의 세정성과 기포력 등을 고려할 때 바람직한 사용량은 0.5 내지 3중량부이다.The cosmetic soap composition according to the present invention may be used with a skin softener or skin moisturizer commonly used in cosmetic soap. As those commonly used in cosmetic soaps, sorbitan esters, lanolin or derivatives thereof, various oils and higher fatty acids may be used, and there is no problem in the bactericidal power which is a characteristic of the present invention even with these materials. In the present invention, there is no problem in the bactericidal power of the soap in the process of preparing a solid soap by the addition of powdery ganban stone. In the present invention, since the powdery elvan can be added to hinder the cohesion of the soap in the process of producing a solid soap, the high viscosity of the material is not only a value as a skin softener or moisturizing agent but also serves to smooth the soap manufacturing process. There are also unexpected effects to be together. However, since these substances also have a bad effect of reducing the foaming force, which is a characteristic of soap, 0.5 to 5 parts by weight can be used in the present invention, and the preferred amount is 0.5 to 3 parts by weight in consideration of the soap's detergency and foaming power.
본 발명의 화장비누 조성물은 통상의 지방산계 화장비누 제조 장치에 의해 용이하게 제조할 수 있다. 곡류 엑기스, 맥반석, 솔잎정유 및 피부유연제나 보습제등은 전부 후첨가하여 제조할 수 있으며, 자세한 제조방법은 이 분야에서는 아주 일반적인 공지의 사실이므로 본원에서 자세하게 설명하지 않더라도 당업자라면 용이하게 제조할 수 있음은 자명하다.The cosmetic soap composition of the present invention can be easily produced by a conventional fatty acid-based cosmetic soap manufacturing apparatus. Cereal extract, elvan, pine needle essential oil and skin softener or moisturizer can all be prepared by post-addition, and detailed manufacturing methods are well known in the art and can be easily manufactured by those skilled in the art without detailed description. Is self explanatory.
하기 실시예로 본 발명의 화장비누 조성물에 대한 효과는 입증된다. 이들 실시예에서 비누분은 우지 지방산 70중량부와 야자 지방산 30중량부의 혼합 지방산을 수산화 나트륨으로 검화하여 칩상태로 제조사용하였으며 평균수분함량은 최대 10%이었다. 그러나, 이와 같은 비누분은 본 발명을 구체적으로 예시하기위하여 제조한 것이며, 당업자라면 널리 알려진 많은 공지의 방법에 따라 다른 비누분을 제조하여 본 발명의 특징을 마찬가지로 적용할 수 있을 것으로 이해할 것이다.The following examples demonstrate the effect on the cosmetic soap composition of the present invention. In these examples, the soap powder was prepared by using a mixture of fatty acid 70 parts by weight of fatty acid and 30 parts by weight of palm fatty acid with sodium hydroxide in a chip state, and the average moisture content was up to 10%. However, such soap powder is prepared to specifically illustrate the present invention, those skilled in the art will understand that it is possible to apply the features of the present invention by preparing other soap powder according to many well-known methods.
또한, 하기 실시예에서 소취효과를 내는 물질인 곡류엑기스는 전술한 특허공고 제 93-2848호의 실시예 1, 실시예 2, 실시예3에 명시된 쌀, 쌀겨 및 밀엑기스를 그대로 사용하였다. 기타 맥반석과 솔잎정유등도 본문에서 언급한 바와 같이 제조하여 사용하였다. 기타향료, 색소 및 피부보습제를 가한후 시험용 바아를 제조하여 소취효과를 평가하였다.In addition, in the following examples, the grain extract, which has a deodorizing effect, was used as the rice, rice bran and wheat extract described in Examples 1, 2, and 3 of Patent Publication No. 93-2848. Other elvan and pine needle essential oils were prepared and used as mentioned in the text. After adding other fragrances, pigments and skin moisturizers, a test bar was prepared to evaluate the deodorizing effect.
마지막으로, 하기 실시예에서는 달리 특정적으로 언급되지 않으면 성분의 함량은 최종 조성물에 대한 중량부로 나타난다.Finally, in the examples below, the content of components is expressed in parts by weight relative to the final composition, unless specifically stated otherwise.
[실시예 1 내지 26][Examples 1 to 26]
상기한 바와 같이 먼저 비누분을 제조하고 본 발명에서 특징적으로 사용된 곡류엑기스 및/또는 맥반석 및/또는 솔잎정유, 및 첨가제를 하기 표 2 및 3에 나타낸 바와 같은 양으로 혼합하여 화장비누 조성물을 제조하였다.As described above, the soap powder is first prepared, and the cereal extract and / or ganban stone and / or pine needle essential oil, and additives, which are characteristically used in the present invention, are mixed in an amount as shown in Tables 2 and 3 to prepare a cosmetic soap composition. It was.
[소취효과 실험][Deodorant effect experiment]
1. 냄새오염포 제조: 시중에서 구입할 수 있는 무게 약 600g의 고등어를 가로, 세로 30cm인 면수건으로 감싸서 비닐에 밀봉한 상태로 1일간 냉장고 냉동실에 보관하여 비린내가 수건에 충분히 흡착되도록 한다.1. Odor Pollution Preparation: A commercially available mackerel weighing about 600g is wrapped in a cotton towel 30 cm long and 30 cm wide, and sealed in a plastic bag and stored in the refrigerator freezer for 1 day so that the fishy smell is sufficiently adsorbed on the towel.
2. 소취효과 비교2. Comparison of deodorant effect
방법: 상기 오염포를 각각의 시험품과 표준품 용액에서 다음 조건으로 세척하여 관능에 의해 냄새를 비교하였다.Methods: The stain was washed in each test and standard solution under the following conditions to compare odors by sensory function.
오염포: 상기 방법으로 만든 오염포를 가로, 세로 각 5cm로 잘라서 사용한다.Contaminated cloth: The contaminated cloth made by the above method is cut into 5 cm horizontally and vertically.
측정기계: TERGOTOMETERMeasuring Machine: TERGOTOMETER
측정온도: 25℃Measuring temperature: 25 ℃
세정수: 수도물(경도 53ppm)Washing water: tap water (hardness 53ppm)
비누농도: 1gr/1세정수Soap Concentration: 1gr / 1
욕비: 30:1Bath expenses: 30: 1
세탁시간: 5분Laundry time: 5 minutes
헹굼시간:3분Rinsing time: 3 minutes
평가: 세척된 오염포 냄새를 표준품에서 세척한 것과 시험품에서 세척한 것을 다음 조건에 따라 50명 판넬에게 비교 평가하였다.Evaluation: The washed stained odors were washed in the standard and the washed in the test sample, and compared to 50 panelists under the following conditions.
※표준품과 같은 정도의 비린내가 난다······0점※ It smells like fish as standard product 0 points
※표준품과 비교하여 약한 비린내가 난다·····1점※ We smell weak fishy in comparison with standard product ... one point
※표준품과 비교하여 극히 약한 냄새가 난다···2점* Smells very weak compared to the standard product
※표준품과 비교하여 거의 냄새가 나지 않는다··3점* Almost no smell compared to standard products
평가결과는 하기 표 4 및 표 5에 나타낸 바와 같다.Evaluation results are as shown in Table 4 and Table 5.
이상과 같이 쌀, 쌀겨 및 밀 엑기스간 소취효과 차이는 뚜렷하지 않고 다만 사용량이 증가함에 따라 소취효과가 증가하였으며, 곡류 엑기스가 1중량부미만일때는 뚜렷한 소취효과는 없고 3중량부 이상일지라도 증가폭이 크지 않으며 제조공정이 어렵기 때문에 실제적으로 사용할 수 없다. 또한 일정량의 곡류 엑기스에 맥반석과 솔잎정유(精油)를 함께 사용하면 뛰어난 상승효과를 볼수 있으며, 곡류 엑기스를 최대로 사용하여도 맥반석이나 솔잎정유(精油)의 함량이 낮으면 뚜렷한 상승효과가 없으며 지나치게 높은 것은 효과에 비하여 비효율적임을 알 수 있다.As described above, the difference in deodorization effect between rice, rice bran and wheat extract was not obvious, but the deodorizing effect increased as the amount of use increased. When the grain extract was less than 1 part by weight, there was no obvious deodorizing effect and the increase was large even if it was more than 3 parts by weight. And because the manufacturing process is difficult, it can not be used practically. In addition, the use of ganban stone and pine needle essential oil (精油) together with a certain amount of grain extract shows excellent synergistic effect. Even if the maximum amount of grain extract is low, the amount of ganban stone or pine needle essential oil (精油) has no obvious synergistic effect. It can be seen that the higher one is inefficient compared to the effect.
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