CN102408951B - Disinfecting and deodorizing cleaning agent for refrigerator and preparation process thereof - Google Patents

Disinfecting and deodorizing cleaning agent for refrigerator and preparation process thereof Download PDF

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CN102408951B
CN102408951B CN 201110285435 CN201110285435A CN102408951B CN 102408951 B CN102408951 B CN 102408951B CN 201110285435 CN201110285435 CN 201110285435 CN 201110285435 A CN201110285435 A CN 201110285435A CN 102408951 B CN102408951 B CN 102408951B
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refrigerator
plant type
disinfecting
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CN102408951A (en
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刘雪玲
张清华
吕耀斌
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SHIJIAZHUANG BORIA DAILY CHEMICAL CO Ltd
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SHIJIAZHUANG BORIA DAILY CHEMICAL CO Ltd
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Abstract

The invention relates to a disinfecting and deodorizing cleaning agent for a refrigerator and a preparation process thereof. The cleaning agent comprises the following components in percentage by weight: 10-15% of APG (alkyl polyglucoside), 5-10% of plant bactericide, 0.05-0.1% of polyhexamethylene biguanidine, 2-5% of edible propylene, 0.2-0.5% of edible citric acid and the balance of water complementing to 100%, wherein the plant bactericide is prepared from the following raw materials by weight percent: 5-10% of kuh-seng, 25-30% of orange peel, 5-10% of wild chrysanthemum flower, 40-45% ofoleander leaves and 12-20% of red bayberry leaves. The preparation process comprises the steps of 1, preparing the plant bactericide; and 2, preparing the disinfecting and deodorizing cleaning agent for the refrigerator. The cleaning agent in the invention has the advantages of being natural and mild and obvious effect and the like, and meets the natural, no-stimulation, environmentally-friendly,green and low-carbon demands of people on a product.

Description

A kind of refrigerator disinfecting deodouring detergent and preparation technology
Technical field
The present invention relates to a kind of mainly by the disinfecting, deodorizing sanitising agent and the preparation technology that are used for refrigerator disinfecting cleaning of alkyl glycoside APG for short with the bactericide compounded green safety that forms of plant type of being made by extraction in the plant.
Background technology
Along with the raising of people's living standard, every household has refrigerator to store food basically now.The original idea that we use refrigerator is the quality guarantee period of wishing refrigerator energy food and extend, be conducive to us edible, but because many mistakes custom, often make refrigerator become the place of bacterium procreation, particularly store food at 4-6 degree centigrade cold compartment of refrigerator, not only do not have the effect of fresh-keeping food, this food can damage our health on the contrary.And because the amount reproduction of the interior bacterium of refrigerator, the insufferable unpleasant peculiar smell of people will appear allowing in use in refrigerator after for some time, many manufacturers have developed deodorant for refrigerator (or deodorant for refregerator sanitising agent) in the market to this, can remove these peculiar smell, certain sterilization effect can also be arranged.Existing deodorant for refrigerator (or deodorant for refregerator sanitising agent) probably has following a few class: a class is gac deodovization agent, tealeaves deodovization agent, lemon deodovization agent, these products all are to utilize trickle porous adsorption or distribute the peculiar smell that novel aroma is covered refrigerator, also can ooze out but shortcoming then is stink, this series products can be inreal fundamentally removes microorganism and peculiar smell in the refrigerator again; Another kind of reodorant is take hydrogen peroxide, dioxide peroxide as main component and the formulated compound of some other subsidiary, its principle is to utilize the strong oxidizing property kill bacteria of these materials to remove peculiar smell, but strong oxidized form reodorant has corrosion to body surface, thereby can certain damage be arranged to refrigerator inside; A class reodorant is to be the pure molten class disinfection deodorizer of main raw material by traditional Chinese medicine bactericide and ethanol again, adds a large amount of ethanol though this series products has in the bactericidal properties product, and smell is pungent, is difficult to obtain customer's approval.
Summary of the invention
It is a kind of mainly by the disinfecting, deodorizing sanitising agent and the preparation technology that are used for refrigerator disinfecting cleaning of alkyl glycoside APG for short with the bactericide compounded green safety that forms of plant type of being made by extract in the plant that purpose of the present invention just is to provide, it is for the defective of prior art, the advantage such as have and effect is remarkable natural, gentle, meet that people at present are natural, non-stimulated to product, the demand of environmental protection, green, low-carbon (LC).
Technical scheme of the present invention is.
A kind of refrigerator disinfecting deodouring detergent of natural, efficient, environmental protection, its component by following weight percent is formed: APG 10-15%, plant type sterilant 5-10%, poly hexamethylene biguanide 0.05-0.1%, food grade propylene glycol 2-5 %, edible citric acid 0.2-0.5% supplies the deionized water of surplus to 100%;
Wherein said plant type sterilant is the extracting solution of being produced by the plant material of following weight per-cent: kuh-seng 5-10% tangerine peel 25-30% Wild Chrysanthemum 5-10% Sweetscented Oleander Leaf 40-45% Folium Myricae rubrae 12-20%.
The preparation technology of above-mentioned refrigerator disinfecting deodouring detergent is:
One, at first carries out the preparation of plant type sterilant
With plant material: kuh-seng, tangerine peel, Wild Chrysanthemum, Sweetscented Oleander Leaf, Folium Myricae rubrae mix according to aforementioned proportion and clean up, add afterwards an amount of concentration and be 5% aqueous solution of propylene glycol, soaked first 6-8 hour, getting distillate with the electrically heated distillation gets final product, distillate is that faint yellow transparent water insoluble liquid is described plant type sterilant, and wherein active constituent content is at 10-15%;
Two, then carry out the preparation of refrigerator disinfecting deodouring detergent:
1, first deionized water is joined in the reactor, be heated to 65 ℃, open stirring and add APG after 5 minutes, be stirred to fully dissolving;
2, open water coolant, make feed liquid in the reactor cool to 35-45 ℃ after, add poly hexamethylene biguanide, propylene glycol and also stirred 20 minutes, add again citric acid the pH value be adjusted to 6.5-7.5;
3, add the plant type sterilant and stirred 10 minutes, left standstill afterwards 30 minutes, discharging is that colourless transparent liquid is described refrigerator disinfecting deodouring detergent, detects its pH value at 6.5-7.5, good water solubility.
Beneficial effect of the present invention is as follows:
Use product of the present invention spray on a small quantity inside and outside the refrigerator, again with a gently wiping of clean cloth, can kill the various bacteriums in the refrigerator, wipe gently just rapidly decontamination, deodorizing with clean cloth more afterwards.Peculiar smell, stink that it is removed from the source the refrigerator can also thoroughly clean refrigerator, without any corrosion, refrigerator are taken on an entirely new look.
One, research process of the present invention
(1) principle of formulating of recipe of the present invention is:
At first be to consult technical data and document, carried out widely market study, after the market requirement and location of this product, make the principles of formulation design of refrigerator sanitising agent.
1. used starting material are natural, green, nontoxic, safe raw materials in the prescription, and the effect excellent performance.
2. employed tensio-active agent emulsification greasy dirt is good in the prescription, and good water solubility will be made every effort to effective in the screening of sterilant.
3. product needed is neutral transparent liquid, without any corrosion, guarantees that product is not stratified, constant product quality.
4. controlling cost is a cardinal principle of component design.
5. require physical and chemical index to exceed standard-required, use properties reaches the like product top standard.
(2) selection of raw material
1. alkyl glycoside (APG0814), massfraction, total solid 〉=50% is provided by Shanghai Fakai Chemical Co., Ltd..
2. plant type sterilant, outward appearance: light yellow transparent liquid, it be kuh-seng (main component: matrine), tangerine peel (main component: obacalactone, orange peel element, naringin, limonene), Wild Chrysanthemum (main component: chrysanthemum glycosides, amino acid, flavones), Folium seu Cortex Nerii liquid (main component oleandrine, glucosides), Folium Myricae rubrae (main component myricetin) forms according to a certain percentage compound and makes an addition in the product compounding system.
3. the environmental protection and safety type poly hexamethylene biguanide belongs to nontoxic level, is a kind of water miscible sterilant, and without corrosion, scientific and technological Bioisystech Co., Ltd provides by the large life in Shaanxi to various materials.
4. other ancillary component, the food grade propylene glycol, they are good solvents, also are the crust protective materials, citric acid is pH value conditioning agent.
(3) determine the preparation method.
(4) experimental study of prescription.
The selection of tensio-active agent ratio
1, the decontamination in the refrigerator cleaner mainly is as main body take tensio-active agent, total amount is about 6%, consist of a kind of micelle solution of tensio-active agent, prescription for high-quality, not only good detersive power will be arranged, the transparency of product appearance also will have suitable cost, therefore by experiment, we have selected can adjust good outward appearance and detersive power with the APG adding.
Therefore, select APG amount ranges 10-15%, in this scope, just have after tested fine removal body surface spot ability.
2, the consumption of plant type sterilant and environment-friendly type sterilant
Their consumption will consider that at first its dosage in the refrigerator sanitising agent will reach sterilization, antibiotic amount, consider that again cost is suitable, also to meet safe dosage requirement, owing to having adopted plant type sterilant consumption 5-10% in this prescription, the consumption 0.05-0.1% of poly hexamethylene biguanide, both composite uses, germicidal action improves.
3, the dosage of propylene glycol and other compositions
Propylene glycol mainly is the synergism that increases the sterilant infiltration, can also protect crust, general dosage 2-5%.
Because the pH value of APG is alkalescence, so will add an amount of citric acid in the formula system product P H value is adjusted into 6.5-7.5 in addition.
(5) prescription determines
To sum up state some, according to the experience of producing and filling a prescription, successively determined the consumption of all raw materials, determine at last prescription.
The refrigerator disinfecting deodouring detergent outward appearance of formulated is colourless transparent liquid thus, good water solubility, and PH 6.5-7.5 has light citrus scented.
Because the raw material that adopts is green, safety, environmental protection, nontoxic raw material, to being that human body is without the auxiliary effect of any poison.
Two, security and effect assessment
1. employed tensio-active agent is natural, plant type raw material in the prescription, and it is nontoxic, harmless, safe and reliable to human body under specified volume.
2. by to product result of use and tracking, reflect that product is respond well.
3. the product of this formulated detects stabilizing effect, toxicity test effect through Hebei province Disease Control and Prevention Center, meets the disinfection technology standard requirement, belongs to nontoxic level.To pathogen enterobacteria, pyococcus, etc. common pathogen, killing rate is greater than 99.99%; To the body surface sterilizing rate greater than 99.8%
4. contrast with like product
? This product The A product The B product
Outward appearance Water white transparency Water white transparency The oyster white suspension
Security High Generally Generally
To production unit Without the burn into easy cleaning Perishable Easy cleaning not
Sterilization effect Excellent Very Very
Effects on surface corrodibility Nothing By force In
Environmental pollution Nothing In Nothing
Pungency Nothing Have Have
Long-lasting Good Generally Generally
Cleaning effect Good Generally Generally
Annotate: long-lasting referring to product refrigerator sanitising agent cleaning of the present invention still free from extraneous odour generation after 20 days.
Sum up: can show after deliberation, polysaccharide, flavones (flavonoid glycoside, cyanidin(e), flavonol etc.) polyphenol, saponins material, alkaloids in the plant, the materials such as organic acid have the restraining and sterilizing bacteria effect, on the other hand it and the composite use of environment-friendly type macromolecule polymer bactericide, action effect is more obvious, quicker.
Alkyl glycoside (APG for short) is a kind ofly to be prepared from by natural Fatty Alcohol(C12-C14 and C12-C18) and natural carbohydrate in addition, all be safe in many-sides such as ecology, toxicitys, to the organism action temperature and, nontoxic, moreover, alkyl glycoside has good surfactivity, readily biodegradable, thus it to be also referred to as be a kind of novel green surfactant.
So the present invention is exactly the technological deficiency that exists for the current refrigerator deodouring detergent; adopt natural green surfactant A PG; the natural plant type sterilant; be aided with again environment-friendly type without the neutral refrigerator disinfecting deodouring detergent that corrodes the preparation of high molecular polymer sterilant and body surface protective material and form; utilize its chemical performance and to human body; food and body surface wait safely characteristics; prepared and be different from the absorption class; cover class and other oxidation class and pure molten class deodouring detergent; prescription adopts the plant type raw material; the environmental protection and safety type raw material; have safe and efficient; fast; the characteristics such as lasting and easy to use; only need a spray one to wipe; not only can sterilization; can in several minutes, thoroughly decompose the odor causing substances such as Ammonia and sulfide, and can also remove fast in the refrigerator; the stupid dirty spot of outside surface.This technology can once be finished decontamination cleaning, sterilization, sterilization, the taste removal of refrigerator, guarantees absolutely safe.Prescription forms the natural green tensio-active agent in this product, adopts the bactericide of modern biotechnology preparation, environmental protection and safety type sterilant, the characteristics such as crust protective material etc. is made, and has a sterilizing power strong, and is safe and efficient.
Embodiment
Embodiment 1
Raw material is according to following weight percent proportioning APG 10%, plant type sterilant 5%, and poly hexamethylene biguanide 0.05%, food grade propylene glycol 2%, edible citric acid 0.2% is supplied the deionized water of surplus to 100%.Wherein said plant type sterilant is the extracting solution of being produced by the plant material of following weight per-cent: kuh-seng 8, tangerine peel 30, Wild Chrysanthemum 7, Sweetscented Oleander Leaf 42, Folium Myricae rubrae 13.
The preparation technology of above-mentioned refrigerator disinfecting deodouring detergent is:
One, at first carries out the preparation of plant type sterilant
With plant material: kuh-seng, tangerine peel, Wild Chrysanthemum, Sweetscented Oleander Leaf, Folium Myricae rubrae etc. mix according to above-mentioned percentage and clean up, adding afterwards a certain amount of concentration is 5% aqueous solution of propylene glycol, soaked first 6-8 hour, get final product with the electrically heated distillation, distillate is that faint yellow transparent water insoluble liquid is plant type sterilant of the present invention, and wherein active constituent content is at 10-15%;
Two, then carry out the preparation of refrigerator disinfecting deodouring detergent:
1, first appropriate amount of deionized water is joined in the reactor, be heated to 65 ℃, open stirring and add APG after 5 minutes, be stirred to fully dissolving.
2, open water coolant, make reactor cool to 35-45 ℃ after, add poly hexamethylene biguanide, propylene glycol and also stirred 20 minutes, add again citric acid the pH value be adjusted to 6.5-7.5.
3, add the plant type sterilant and stirred 10 minutes, then left standstill 30 minutes, discharging is that colourless transparent liquid is product refrigerator disinfecting deodouring detergent of the present invention, detects its pH value at 6.5-7.5, good water solubility.
Embodiment 2
Raw material is according to following weight percent proportioning APG12%, plant type sterilant 8%, and poly hexamethylene biguanide 0.08%, food grade propylene glycol 3.5%, edible citric acid 0.3% is supplied the deionized water of surplus to 100%.Wherein said plant type sterilant is the extracting solution of being produced by the plant material of following weight per-cent: kuh-seng 8, tangerine peel 30, Wild Chrysanthemum 7, Sweetscented Oleander Leaf 42, Folium Myricae rubrae 13.
The preparation technology of above-mentioned refrigerator disinfecting deodouring detergent is:
One, at first carries out the preparation of plant type sterilant
With plant material: kuh-seng, tangerine peel, Wild Chrysanthemum, Sweetscented Oleander Leaf, Folium Myricae rubrae etc. mix according to above-mentioned percentage and clean up, adding afterwards a certain amount of concentration is 5% aqueous solution of propylene glycol, soaked first 6-8 hour, get final product with the electrically heated distillation, distillate is that faint yellow transparent water insoluble liquid is plant type sterilant of the present invention, and wherein active constituent content is at 10-15%;
Two, then carry out the preparation of refrigerator disinfecting deodouring detergent:
1, first an amount of deionized water is joined in the reactor, be heated to 65 ℃, open stirring and add APG after 5 minutes, be stirred to fully dissolving.
2, open water coolant, make reactor cool to 35-45 ℃ after, add poly hexamethylene biguanide, propylene glycol and also stirred 20 minutes, add again citric acid the pH value be adjusted to 6.5-7.5.
3, add the plant type sterilant and stirred 10 minutes, left standstill afterwards 30 minutes, discharging is that colourless transparent liquid is product refrigerator disinfecting deodouring detergent of the present invention, detects its pH value at 6.5-7.5, good water solubility.
Embodiment 3
Raw material is according to following weight percent proportioning APG15%, plant type sterilant 10%, and poly hexamethylene biguanide 0.1%, food grade propylene glycol 5%, edible citric acid 0.5% is supplied the deionized water of surplus to 100%.Wherein said plant type sterilant is the extracting solution of being produced by the plant material of following weight per-cent: kuh-seng 8, tangerine peel 30, Wild Chrysanthemum 7, Sweetscented Oleander Leaf 42, Folium Myricae rubrae 13.
The preparation technology of above-mentioned refrigerator disinfecting deodouring detergent is:
One, at first carries out the preparation of plant type sterilant
With plant material: kuh-seng, tangerine peel, Wild Chrysanthemum, Sweetscented Oleander Leaf, Folium Myricae rubrae etc. mix according to above-mentioned percentage and clean up, add afterwards a certain amount of 5% concentration aqueous solution of propylene glycol, soaked first 6-8 hour, get final product with the electrically heated distillation, distillate is that faint yellow transparent water insoluble liquid is plant type sterilant of the present invention, and wherein active constituent content is at 10-15%;
Two, then carry out the preparation of refrigerator disinfecting deodouring detergent:
1, first an amount of deionized water is joined in the reactor, be heated to 65 ℃, open stirring and add APG after 5 minutes, be stirred to fully dissolving.
2, open water coolant, make reactor cool to 35-45 ℃ after, add poly hexamethylene biguanide, propylene glycol and also stirred 20 minutes, add again citric acid the pH value be adjusted to 6.5-7.5.
3, add the plant type sterilant and stirred 10 minutes, left standstill afterwards 30 minutes, discharging is that colourless transparent liquid is product refrigerator disinfecting deodouring detergent of the present invention, detects its pH value at 6.5-7.5, good water solubility.
Embodiment 4
Raw material is according to following weight percent proportioning APG12%, plant type sterilant 8%, and poly hexamethylene biguanide 0.08%, food grade propylene glycol 3.5%, edible citric acid 0.3% is supplied the deionized water of surplus to 100%.Wherein said plant type sterilant is the extracting solution of being produced by the plant material of following weight per-cent: kuh-seng 5 tangerine peels 25 Wild Chrysanthemums 9 Sweetscented Oleander Leafs 43 Folium Myricae rubrae 18.
The preparation technology of above-mentioned refrigerator disinfecting deodouring detergent is:
One, at first carries out the preparation of plant type sterilant
With plant material: kuh-seng, tangerine peel, Wild Chrysanthemum, Sweetscented Oleander Leaf, Folium Myricae rubrae etc. mix according to above-mentioned percentage and clean up, adding afterwards a certain amount of concentration is 5% aqueous solution of propylene glycol, soaked first 6-8 hour, get final product with the electrically heated distillation, distillate is that faint yellow transparent water insoluble liquid is plant type sterilant of the present invention, and wherein active constituent content is at 10-15%;
Two, then carry out the preparation of refrigerator disinfecting deodouring detergent:
1, first deionized water is joined in the reactor, be heated to 65 ℃, open stirring and add APG after 5 minutes, be stirred to fully dissolving.
2, open water coolant, make reactor cool to 35-45 ℃ after, add poly hexamethylene biguanide, propylene glycol and also stirred 20 minutes, add again citric acid the pH value be adjusted to 6.5-7.5.
3, add the plant type sterilant and stirred 10 minutes, left standstill afterwards 30 minutes, discharging is that colourless transparent liquid is product refrigerator disinfecting deodouring detergent of the present invention, detects its pH value at 6.5-7.5, good water solubility.
Embodiment 5
Raw material is according to following degree proportioning APG 12%, plant type sterilant 8%, and poly hexamethylene biguanide 0.08%, food grade propylene glycol 3.5%, edible citric acid 0.3% is supplied the deionized water of surplus to 100%; Wherein said plant type sterilant is the extracting solution of being produced by the plant material of following total amount portion rate: kuh-seng 8, tangerine peel 30, Wild Chrysanthemum 7, Sweetscented Oleander Leaf 42, Folium Myricae rubrae 13.
The preparation technology of above-mentioned refrigerator disinfecting deodouring detergent is:
One, at first carries out the preparation of plant type sterilant extracting solution
With plant material: kuh-seng, tangerine peel, Wild Chrysanthemum, Sweetscented Oleander Leaf, Folium Myricae rubrae etc. mix according to above-mentioned percentage and clean up, adding afterwards a certain amount of concentration is 5% aqueous solution of propylene glycol, soaked first 6-8 hour, get final product with the electrically heated distillation, distillate is that faint yellow transparent water insoluble liquid is plant type sterilant of the present invention, and wherein active constituent content is at 10-15%;
Two, then carry out the preparation of refrigerator disinfecting deodouring detergent:
1, first deionized water is joined in the reactor, be heated to 65 ℃, open stirring and add APG after 5 minutes, be stirred to fully dissolving.
2, open water coolant, make reactor cool to 35-45 ℃ after, add poly hexamethylene biguanide, propylene glycol and also stirred 20 minutes, add again citric acid the pH value be adjusted to 6.5-7.5.
3, add the plant type sterilant and stirred 10 minutes, left standstill afterwards 30 minutes, discharging is that colourless transparent liquid is product refrigerator disinfecting deodouring detergent of the present invention, detects its pH value at 6.5-7.5, good water solubility.
Embodiment 6
Raw material is according to following degree proportioning APG 12%, plant type sterilant 8%, and poly hexamethylene biguanide 0.08%, food grade propylene glycol 3.5%, edible citric acid 0.3% is supplied the deionized water of surplus to 100%; Wherein said plant type sterilant is the extracting solution of being produced by the plant material of following total amount portion rate: kuh-seng 7 tangerine peels 27 Wild Chrysanthemums 10 Sweetscented Oleander Leafs 40 Folium Myricae rubrae 16.
The preparation technology of above-mentioned refrigerator disinfecting deodouring detergent is:
One, at first carries out the preparation of plant type sterilant extracting solution
With plant material: kuh-seng, tangerine peel, Wild Chrysanthemum, Sweetscented Oleander Leaf, Folium Myricae rubrae etc. mix according to above-mentioned percentage and clean up, adding afterwards a certain amount of concentration is 5% aqueous solution of propylene glycol, soaked first 6-8 hour, get final product with the electrically heated distillation, distillate is that faint yellow transparent water insoluble liquid is plant type sterilant of the present invention, and wherein active constituent content is at 10-15%;
Two, then carry out the preparation of refrigerator disinfecting deodouring detergent:
1, first deionized water is joined in the reactor, be heated to 65 ℃, open stirring and add APG after 5 minutes, be stirred to fully dissolving.
2, open water coolant, make reactor cool to 35-45 ℃ after, add poly hexamethylene biguanide, propylene glycol and also stirred 20 minutes, add again citric acid the pH value be adjusted to 6.5-7.5.
3, add the plant type sterilant and stirred 10 minutes, left standstill afterwards 30 minutes, discharging is that colourless transparent liquid is product refrigerator disinfecting deodouring detergent of the present invention, detects its pH value at 6.5-7.5, good water solubility.

Claims (2)

1. refrigerator disinfecting deodouring detergent, it is characterized in that its component by following weight percent is formed: APG 10-15%, plant type sterilant 5-10%, poly hexamethylene biguanide 0.05-0.1%, food grade propylene glycol 2-5 %, edible citric acid 0.2-0.5% supplies the deionized water of surplus to 100%;
Wherein said plant type sterilant is the extracting solution of being produced by the plant material of following weight per-cent: kuh-seng 5-10% tangerine peel 25-30% Wild Chrysanthemum 5-10% Sweetscented Oleander Leaf 40-45% Folium Myricae rubrae 12-20%; Its making method is with plant material: kuh-seng, tangerine peel, Wild Chrysanthemum, Sweetscented Oleander Leaf, Folium Myricae rubrae mix according to aforementioned proportion and clean up, add afterwards an amount of concentration and be 5% aqueous solution of propylene glycol, soaked first 6-8 hour, getting distillate with the electrically heated distillation gets final product, distillate is that faint yellow transparent water insoluble liquid is described plant type sterilant, and wherein active constituent content is at 10-15%.
2. the preparation technology of a kind of refrigerator disinfecting deodouring detergent claimed in claim 1 is characterized in that its processing step is as follows:
(1), at first carries out the preparation of plant type sterilant
With plant material: kuh-seng, tangerine peel, Wild Chrysanthemum, Sweetscented Oleander Leaf, Folium Myricae rubrae mix according to aforementioned proportion and clean up, add afterwards an amount of concentration and be 5% aqueous solution of propylene glycol, soaked first 6-8 hour, getting distillate with the electrically heated distillation gets final product, distillate is that faint yellow transparent water insoluble liquid is described plant type sterilant, and wherein active constituent content is at 10-15%;
(2), then carry out the preparation of refrigerator disinfecting deodouring detergent
A, first deionized water is joined in the reactor, be heated to 65 ℃, open to stir after 5 minutes and add APG, be stirred to fully dissolving;
B, open water coolant, make feed liquid in the reactor cool to 35-45 ℃ after, add poly hexamethylene biguanide, propylene glycol and also stirred 20 minutes, add again citric acid the pH value be adjusted to 6.5-7.5;
C, adding plant type sterilant stirred 10 minutes, left standstill afterwards 30 minutes, and discharging is that colourless transparent liquid is described refrigerator disinfecting deodouring detergent, detects its pH value at 6.5-7.5, good water solubility.
CN 201110285435 2011-09-23 2011-09-23 Disinfecting and deodorizing cleaning agent for refrigerator and preparation process thereof Active CN102408951B (en)

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植物源杀菌剂研究进展;杨玉萍 等;《中国农业科技导报》;20061231;第08卷(第01期);第49-53页 *

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