CN105199648A - Solid wallpaper adhesive and preparation method thereof - Google Patents
Solid wallpaper adhesive and preparation method thereof Download PDFInfo
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- CN105199648A CN105199648A CN201510650613.4A CN201510650613A CN105199648A CN 105199648 A CN105199648 A CN 105199648A CN 201510650613 A CN201510650613 A CN 201510650613A CN 105199648 A CN105199648 A CN 105199648A
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- wall paper
- paper adhesive
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Abstract
The invention discloses a solid wallpaper adhesive which comprises the following components in percentage by mass: 40-55% of water-based resin, 20-30% of nano material dispersing agent, 20-30% of inorganic filler, 0.1-0.5% of defoaming agent, 2-5% of thickener and 0.002-0.003% of nano silver. The invention also discloses a preparation method of the solid wallpaper adhesive. The solid wallpaper adhesive effectively solves the problem of mildewing after use of amylan on the premise of not influencing the adhesiveness of the wallpaper, avoids the injuries of mildew to human health, greatly prolongs the service life of the wallpaper, and has great social benefit and economic benefit. The wallpaper adhesive is free of compounds capable of polluting the environment and hurting human health, and thus, is green and environment-friendly.
Description
Technical field
The present invention relates to a kind of Wall paper adhesive, specifically a kind of solid Wall paper adhesive and preparation method thereof.
Background technology
Wallpaper, also claims wallpaper, is the general designation of a class indoor wall finishing material.Because color is various, pattern enriches, luxurious style, safety and environmental protection, easy construction, moderate and be used widely, and has irreplaceable advantage.And wallpaper is attached to surface of wall, need use Wall paper adhesive, the current Wall paper adhesive overwhelming majority is amylan.Cheap with it, viscosity is high, environmental protection and being used widely.But amylan easily goes mouldy, after usage, often can there is mouldy phenomenon, thus cause wallpaper mildew, alice, have impact on the life-span of wallpaper; Mould also can damage HUMAN HEALTH.Many producers add formaldehyde in synthesis or use procedure, acetal, sanitas solve this kind of problem, and lasting effect is short, also can bring secondary pollution simultaneously, for this situation, need to develop a kind of novel solid Wall paper adhesive.
Summary of the invention
The object of this invention is to provide a kind of solid Wall paper adhesive.
Another object of the present invention is to provide the preparation method of this solid Wall paper adhesive.
For one of achieving the above object, the present invention by the following technical solutions:
A kind of solid Wall paper adhesive, according to mass percent, comprise the water-base resin of 40 ~ 55%, 20 ~ 30% nano material dispersion agent, 20 ~ 30% mineral filler, the defoamer of 0.1 ~ 0.5%, the thickening material of 2 ~ 5% and 0.002 ~ 0.003% nanometer silver.
Further, described water-base resin is at least one in vibrin, polyacrylic acid and polyvinyl alcohol.
Further, described nano material dispersion agent is at least one in nano aluminium oxide, nano silicon and nano-calcium carbonate.
Further, described mineral filler is at least one in calcium carbonate, magnesium aluminum silicate, titanium dioxide and silicon-dioxide.
Further, described calcium carbonate is fine particle calcium carbonate.
Described defoamer is the general defoamer in this area; Described thickening material is the general thickening material in this area.
The preparation method of solid Wall paper adhesive described in any one above, specifically: by water-base resin drying under reduced pressure, removes free monomer, mixes and get final product after cooling with nano material dispersion agent, mineral filler, defoamer, thickening material, nanometer silver in mixer.
The present invention has following beneficial effect:
Solid Wall paper adhesive of the present invention is not under affecting wallpaper and pasting the prerequisite of performance, efficiently solve the problem of going mouldy after amylan use, avoid the injury that mould is caused HUMAN HEALTH, also extend the work-ing life of wallpaper greatly, there is very large social benefit and economic benefit; Simultaneously Wall paper adhesive is not containing contaminate environment, the compound that is detrimental to health, environmental protection.
Embodiment
Below in conjunction with specific embodiment, the present invention is described further:
Per-cent in following examples is mass percent.
Embodiment 1
A kind of solid Wall paper adhesive, comprises 40% vibrin, 15% nano silicon, 15% nano aluminium oxide, 24.4975% fine particle calcium carbonate, 5% thickening material, 0.5% defoamer, 0.0025% nanometer silver.
By vibrin drying under reduced pressure, remove free monomer, mix in mixer with all the other raw materials after cooling and get final product.
Embodiment 2
A kind of solid Wall paper adhesive, comprises 20% vibrin, 30% polyvinyl alcohol, 20% nano aluminium oxide, 7.897% magnesium aluminum silicate, 20% silicon-dioxide, 2% thickening material, 0.1% defoamer, 0.003% nanometer silver.
By vibrin, polyvinyl alcohol drying under reduced pressure, remove free monomer, mix in mixer with all the other raw materials after cooling and get final product.
Embodiment 3
A kind of solid Wall paper adhesive, comprises 20% polyacrylic acid, 25% polyvinyl alcohol, 21.698% nano-calcium carbonate, 10% fine particle calcium carbonate, 10% titanium dioxide, 10% magnesium aluminum silicate, 3% thickening material, 0.3% defoamer, 0.002% nanometer silver.
By polyacrylic acid, polyvinyl alcohol drying under reduced pressure, remove free monomer, mix in mixer with all the other raw materials after cooling and get final product.
Embodiment 4
A kind of solid Wall paper adhesive, comprises 30% vibrin, 25% polyacrylic acid, 20.597% nano aluminium oxide, 10% titanium dioxide, 10% silicon-dioxide, 4% thickening material, 0.4% defoamer, 0.003% nanometer silver.
By vibrin, polyacrylic acid drying under reduced pressure, remove free monomer, mix in mixer with all the other raw materials after cooling and get final product.
Performance test
Judge whether a kind of polymer substance easily goes mouldy with BOD5/CODCr (i.e. the ratio of 5 days biochemical oxygen demand (BOD)s and chemical oxygen demand), can think during BOD5/CODcr >=0.25 and easily go mouldy, containing starch in commercially available Wall paper adhesive, BOD5/CODcr usually >=0.3, the BOD5/CODcr of embodiment 1 ~ 4 is followed successively by 0.005,0.008,0.01,0.007, all≤0.01, illustrates that solid Wall paper adhesive of the present invention has good anti-mildew performance.
The anti-microbial property of embodiment 1 ~ 4 Wall paper adhesive is measured, with the commercially available Wall paper adhesive product as a comparison containing starch with reference to GB/T21866-2008.
Test bacterial classification: flavus, aspergillus niger, terreus, paecilomyces varioti, penicillium funiculosum, Aureobasidium pullulans, Chaetomium globosum.
Testing method: various mould is made into 10
5the bacterium liquid of cfu/mL, in bacterium liquid, often kind of mould quantity is identical.Respectively solid Wall paper adhesive made for embodiment 1 ~ 4 is coated on putty plate according to constructing operation, after drying, evenly sprays the aqueous solution of mould mixed solution.Be placed in the mold incubator of 37 DEG C, observe mouldy situation.After 60 days, mildew-resistant grade putty plate not having mould-growth is 0 grade, and the mildew-resistant grade having the mould-growth being less than 10% area is I level, has the mildew-resistant grade of the mould-growth of 10 ~ 20% areas to be II level.
Result: the mildew-resistant grade of embodiment 1 ~ 4 Wall paper adhesive be followed successively by 0 grade, I level, I level, 0 grade.Therefore, solid Wall paper adhesive of the present invention still effectively can suppress the growth of various mould in 60 days.The mildew-resistant grade of contrast product 30 days time is I level, becomes II level after 60 days.
The above; be only the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, anyly belongs to those skilled in the art in the technical scope that the present invention discloses; the change that can expect easily or replacement, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claim.
Claims (6)
1. a solid Wall paper adhesive, it is characterized in that, according to mass percent, comprise the water-base resin of 40 ~ 55%, 20 ~ 30% nano material dispersion agent, 20 ~ 30% mineral filler, the defoamer of 0.1 ~ 0.5%, the thickening material of 2 ~ 5% and 0.002 ~ 0.003% nanometer silver.
2. solid Wall paper adhesive according to claim 1, is characterized in that, described water-base resin is at least one in vibrin, polyacrylic acid and polyvinyl alcohol.
3. solid Wall paper adhesive according to claim 1, is characterized in that, described nano material dispersion agent is at least one in nano aluminium oxide, nano silicon and nano-calcium carbonate.
4. solid Wall paper adhesive according to claim 1, is characterized in that, described mineral filler is at least one in calcium carbonate, magnesium aluminum silicate, titanium dioxide and silicon-dioxide.
5. solid Wall paper adhesive according to claim 4, is characterized in that, described calcium carbonate is fine particle calcium carbonate.
6. the preparation method of the solid Wall paper adhesive described in above-mentioned any one claim, it is characterized in that, by water-base resin drying under reduced pressure, remove free monomer, mix in mixer with nano material dispersion agent, mineral filler, defoamer, thickening material, nanometer silver after cooling and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510650613.4A CN105199648B (en) | 2015-10-08 | 2015-10-08 | A kind of solid Wall paper adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510650613.4A CN105199648B (en) | 2015-10-08 | 2015-10-08 | A kind of solid Wall paper adhesive and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN105199648A true CN105199648A (en) | 2015-12-30 |
| CN105199648B CN105199648B (en) | 2018-01-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510650613.4A Active CN105199648B (en) | 2015-10-08 | 2015-10-08 | A kind of solid Wall paper adhesive and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670537A (en) * | 2016-01-18 | 2016-06-15 | 常州大学 | Adhesive for buildings and preparation method of adhesive for buildings |
| CN106281148A (en) * | 2016-08-31 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | Cover quick permeation dry type wallpaper basement membrane and preparation method thereof |
| CN106833439A (en) * | 2017-03-14 | 2017-06-13 | 武汉市华林粘合剂有限公司 | A kind of environmentally friendly paper tube adhesive and preparation method thereof |
| CN109021905A (en) * | 2018-05-28 | 2018-12-18 | 成都市容德建筑劳务有限公司 | Moisture-proof adhesive and preparation method thereof |
Citations (4)
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|---|---|---|---|---|
| JPS55152770A (en) * | 1979-05-17 | 1980-11-28 | Denki Kagaku Kogyo Kk | Rewettable adhesive for wall paper |
| CN103980833A (en) * | 2014-05-05 | 2014-08-13 | 张树发 | Long-acting antibacterial wet adhesive for wallpaper and preparation method thereof |
| CN104004473A (en) * | 2014-05-20 | 2014-08-27 | 佛山市三水灏诚合成树脂有限公司 | Foam coating glue of water-based wallpaper, preparation method thereof and wallpaper |
| CN104449153A (en) * | 2014-12-01 | 2015-03-25 | 鹤山市顺鑫实业有限公司 | Solid wall protecting agent and preparation method thereof |
-
2015
- 2015-10-08 CN CN201510650613.4A patent/CN105199648B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55152770A (en) * | 1979-05-17 | 1980-11-28 | Denki Kagaku Kogyo Kk | Rewettable adhesive for wall paper |
| CN103980833A (en) * | 2014-05-05 | 2014-08-13 | 张树发 | Long-acting antibacterial wet adhesive for wallpaper and preparation method thereof |
| CN104004473A (en) * | 2014-05-20 | 2014-08-27 | 佛山市三水灏诚合成树脂有限公司 | Foam coating glue of water-based wallpaper, preparation method thereof and wallpaper |
| CN104449153A (en) * | 2014-12-01 | 2015-03-25 | 鹤山市顺鑫实业有限公司 | Solid wall protecting agent and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105670537A (en) * | 2016-01-18 | 2016-06-15 | 常州大学 | Adhesive for buildings and preparation method of adhesive for buildings |
| CN106281148A (en) * | 2016-08-31 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | Cover quick permeation dry type wallpaper basement membrane and preparation method thereof |
| CN106281148B (en) * | 2016-08-31 | 2018-11-20 | 嘉力丰科技股份有限公司 | Covering infiltration quick-dry type wallpaper basement membrane and preparation method thereof |
| CN106833439A (en) * | 2017-03-14 | 2017-06-13 | 武汉市华林粘合剂有限公司 | A kind of environmentally friendly paper tube adhesive and preparation method thereof |
| CN109021905A (en) * | 2018-05-28 | 2018-12-18 | 成都市容德建筑劳务有限公司 | Moisture-proof adhesive and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105199648B (en) | 2018-01-16 |
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Effective date of registration: 20180605 Address after: 529000 1-209, 8 of 10 West Zhuang Road West, Pengjiang, Jiangmen, Guangdong. Patentee after: Three new Mstar Technology Ltd in Jiangmen Address before: 529726 industrial zone three, Hezhen Town, Heshan, Jiangmen, Guangdong Patentee before: Heshan Shunxin Industrial Co.,Ltd. |