CN106833439A - A kind of environmentally friendly paper tube adhesive and preparation method thereof - Google Patents
A kind of environmentally friendly paper tube adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106833439A CN106833439A CN201710150114.8A CN201710150114A CN106833439A CN 106833439 A CN106833439 A CN 106833439A CN 201710150114 A CN201710150114 A CN 201710150114A CN 106833439 A CN106833439 A CN 106833439A
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- China
- Prior art keywords
- parts
- paper tube
- environmentally friendly
- tube adhesive
- friendly paper
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/02—Homopolymers or copolymers of unsaturated alcohols
- C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of environmentally friendly paper tube adhesive, including following component by weight：56 parts of polyvinyl alcohol, 1 1.5 parts of cold cut converted starch, 15 18 parts of kaolin, 0.01 0.02 parts of defoamer, 0.13 0.15 parts of dispersant, 0.3 0.6 parts of tackifier, 0.017 0.03 parts of wetting agent, 0.3 0.5 parts of NMF, 0.17 0.2 parts of preservative, 75 82 parts of water；Environmental protection paper tube adhesive formula of the invention rationally, raw material be easy to get, it is with low cost, without formaldehyde, and preparation method is carried out under normal temperature condition, it is process is simple, easily operated, preparation process is without using boiler, environmental pollution is not resulted in, energy-conserving and environment-protective, obtained paper tube adhesive has that tack is good, just viscous the time is short, adhesive strength is high, bonds without premium properties such as alice, storage stabilizations.
Description
Technical field
The present invention relates to technical field of adhesive, more specifically, more particularly to a kind of environmentally friendly paper tube adhesive and its preparation side
Method.
Background technology
Paper tube adhesive is commonly called as paper tube adhesive, paper web glue etc., is to make various paper tubes, fiber drum, paper can and related paper products
A kind of special-purpose adhesive.In actual production, because the purposes of all kinds of paper products is different, requirement to paper tube also not phase
Together, and paper tube adhesive the performances such as the compressive strength of paper tube, hardness, toughness, water resistance, heat resistance and anti-creep deformation are played it is non-
Often important effect.
At present, in the market mainly has starch paper tube adhesive, white glue with vinyl, three kinds of glue for paper tube production of spinning of albumen paper tube adhesive
Stick.Wherein, the low production cost of starch paper tube adhesive, but there is low tack, slow drying speed and not humidity, hold after use
The shortcoming that easily mouldy, the chance water capacity is easily come unglued, greatly limit the use of starch paper tube adhesive；The water-tolerant of white glue with vinyl, but contain
There is formaldehyde, not environmentally, easily pollute working environment；And albumen paper tube adhesive is mainly by separation albumen (soybean bean powder refined product)
Raw material, though water resistance is good, production cost is high, expensive.
The content of the invention
It is an object of the invention to be directed to above-mentioned the deficiencies in the prior art, there is provided a kind of raw material is easy to get, it is with low cost, be free of
The environmentally friendly paper tube adhesive of formaldehyde, preparation process is simple, this environmentally friendly paper tube adhesive has that tack is good, just the viscous time is short, adhesive strength
High, bonding is without premium properties such as alice, storage stabilizations.
To achieve the above object, present invention employs following technical scheme：
A kind of environmentally friendly paper tube adhesive, including following component by weight：Polyvinyl alcohol 5-6 parts, cold cut converted starch 1-
1.5 parts, kaolin 15-18 parts, defoamer 0.01-0.02 parts, dispersant 0.13-0.15 parts, tackifier 0.3-0.6 parts, wetting
Agent 0.017-0.03 parts, NMF 0.3-0.5 parts, preservative 0.17-0.2 parts, water 75-82 parts.
In said components：The defoamer is octanol or tributyl phosphate；The dispersant be calgon or
Person's polycarboxylate；The tackifier are boric acid or borax；The wetting agent is TX-10 or OP-10；The NMF is sweet
Oil or urea；The preservative is Kathon CG or Sodium Benzoate.
Present invention also offers the preparation method of above-mentioned environmentally friendly paper tube adhesive, the method is carried out under normal temperature condition, technique
Simply, easily operated, preparation process does not result in environmental pollution, energy-conserving and environment-protective without using boiler.
The preparation method of the environmentally friendly paper tube adhesive specifically includes following steps：
(1) polyvinyl alcohol of formula ratio is ground into the fine particle material of 80-100 mesh, it is standby；
(2) defoamer for taking appropriate water and formula ratio adds mixing plant, under 1000-1200 revs/min of rotating speed, side
Stirring side is slowly added to the polyvinyl alcohol of step (1) crushing, after addition is finished, stirs 2-3 hours, until without particle in solution
Afterwards, cold cut converted starch is added, continues to stir 0.5-1 hours up to material is well mixed, obtain mixture I；
(3) water of the kaolin of formula ratio, dispersant, tackifier and surplus is mixed, with 600- in mixing plant
800 revs/min of rotating speed is stirred to well mixed, obtains mixture II；
(4) in mixture II obtained in step (3) being added into mixture I obtained in step (2), while adding formula ratio
Wetting agent, NMF and preservative, stir to well mixed under 1000-1200 revs/min of rotating speed, obtain final product environment protecting paper of the present invention
Pipe glue.
Compared with prior art, the advantage of the invention is that：
1st, prepare the raw material used by present invention environmental protection paper tube adhesive be easy to get, it is with low cost, without formaldehyde, obtained paper tube adhesive tool
Have that tack is good, just viscous the time is short, adhesive strength is high, bond without premium properties such as alice, storage stabilizations.
2nd, the preparation method of present invention environmental protection paper tube adhesive is carried out under normal temperature condition, process is simple, easily operated, preparation
Process does not result in environmental pollution, energy-conserving and environment-protective without using boiler.
Specific embodiment
For a better understanding of the present invention, it is with reference to the embodiment content that the present invention is furture elucidated but of the invention
Content is not limited solely to the following examples.
Embodiment 1
The preparation method of the environmentally friendly paper tube adhesive that the present embodiment is provided, comprises the following steps：
(1) 5 parts of the polyvinyl alcohol of alcoholysis degree 88% is weighed, the fine particle material of 80 mesh is ground into, it is standby；
(2) 0.01 part of addition mixing plant of 48 parts of water intaking and octanol, under 1000 revs/min of rotating speed, while stirring slowly
Add step (1) crush polyvinyl alcohol, addition finish after, stir 2 hours, until in solution without particle after, add cold cut become
Property 1 part of starch, continue stir 0.5 hour until material be well mixed, obtain mixture I；
(3) by 27 parts of 15 parts of kaolin, 0.13 part of calgon, 0.3 part of boric acid and water, with 600 in mixing plant
Rev/min rotating speed stir to well mixed, obtain mixture II；
(4) in mixture II obtained in step (3) being added into mixture I obtained in step (2), while adding TX-10
0.17 part of 0.017 part, 0.3 part of glycerine and Kathon CG, stir to well mixed under 1000 revs/min of rotating speed, obtain final product ring of the present invention
Protect paper tube adhesive.
Embodiment 2
The preparation method of the environmentally friendly paper tube adhesive that the present embodiment is provided, comprises the following steps：
(1) 5.5 parts of the polyvinyl alcohol of alcoholysis degree 88% is weighed, the fine particle material of 80 mesh is ground into, it is standby；
(2) 0.015 part of addition mixing plant of 50 parts of water intaking and octanol, under 1000 revs/min of rotating speed, while stirring slowly
Add step (1) crush polyvinyl alcohol, addition finish after, stir 3 hours, until in solution without particle after, add cold cut become
Property 1.2 parts of starch, continue stir 1 hour until material be well mixed, obtain mixture I；
(3) by 30 parts of 16 parts of kaolin, 0.14 part of calgon, 0.4 part of boric acid and water, with 700 in mixing plant
Rev/min rotating speed stir to well mixed, obtain mixture II；
(4) in mixture II obtained in step (3) being added into mixture I obtained in step (2), while adding TX-10
0.18 part of 0.02 part, 0.3 part of glycerine and Kathon CG, stir to well mixed under 1000 revs/min of rotating speed, obtain final product environmental protection of the invention
Paper tube adhesive.
Embodiment 3
The preparation method of the environmentally friendly paper tube adhesive that the present embodiment is provided, comprises the following steps：
(1) 6 parts of the polyvinyl alcohol of alcoholysis degree 88% is weighed, the fine particle material of 100 mesh is ground into, it is standby；
(2) 0.02 part of addition mixing plant of 52 parts of water intaking and tributyl phosphate, under 1200 revs/min of rotating speed, side stirring
While be slowly added to step (1) crushing polyvinyl alcohol, addition finish after, stir 3 hours, until in solution without particle after, add
1.5 parts of cold cut converted starch, continues to stir 1 hour up to material is well mixed, and obtains mixture I；
(3) by 30 parts of 16 parts of kaolin, 0.14 part of polycarboxylate, 0.5 part of borax and water, in mixing plant with 750 turns/
The rotating speed for dividing is stirred to well mixed, obtains mixture II；
(4) in mixture II obtained in step (3) being added into mixture I obtained in step (2), while adding OP-10
0.18 part of 0.025 part, 0.4 part of urea and Sodium Benzoate, stir to well mixed under 1200 revs/min of rotating speed, obtain final product this hair
Bright environmentally friendly paper tube adhesive.
Embodiment 4
The preparation method of the environmentally friendly paper tube adhesive that the present embodiment is provided, comprises the following steps：
(1) 6 parts of the polyvinyl alcohol of alcoholysis degree 88% is weighed, the fine particle material of 100 mesh is ground into, it is standby；
(2) 0.015 part of addition mixing plant of 48 parts of water intaking and tributyl phosphate, under 1200 revs/min of rotating speed, side stirring
While be slowly added to step (1) crushing polyvinyl alcohol, addition finish after, stir 2 hours, until in solution without particle after, add
1.2 parts of cold cut converted starch, continues to stir 1 hour up to material is well mixed, and obtains mixture I；
(3) by 34 parts of 18 parts of kaolin, 0.15 part of polycarboxylate, 0.6 part of borax and water, in mixing plant with 800 turns/
The rotating speed for dividing is stirred to well mixed, obtains mixture II；
(4) in mixture II obtained in step (3) being added into mixture I obtained in step (2), while adding OP-10
0.2 part of 0.03 part, 0.5 part of urea and Sodium Benzoate, stir to well mixed under 1200 revs/min of rotating speed, obtain final product the present invention
Environmentally friendly paper tube adhesive.
Environmentally friendly paper tube adhesive, outward appearance obtained in above-described embodiment 1-4：Be creamy white uniform sticky glue, and the quality for measuring refers to
Mark is as shown in the table：
Claims (8)
1. a kind of environmentally friendly paper tube adhesive, it is characterised in that：Including following component by weight：
Polyvinyl alcohol 5-6 parts
1-1.5 parts of cold cut converted starch
Kaolin 15-18 parts
Defoamer 0.01-0.02 parts
Dispersant 0.13-0.15 parts
Tackifier 0.3-0.6 parts
Wetting agent 0.017-0.03 parts
NMF 0.3-0.5 parts
Preservative 0.17-0.2 parts
Water 75-82 parts.
2. environmentally friendly paper tube adhesive according to claim 1, it is characterised in that：The defoamer is octanol or tricresyl phosphate fourth
Ester.
3. environmentally friendly paper tube adhesive according to claim 1, it is characterised in that：The dispersant is calgon or poly- carboxylic
Hydrochlorate.
4. environmentally friendly paper tube adhesive according to claim 1, it is characterised in that：The tackifier are boric acid or borax.
5. environmentally friendly paper tube adhesive according to claim 1, it is characterised in that：The wetting agent is TX-10 or OP-10.
6. environmentally friendly paper tube adhesive according to claim 1, it is characterised in that：The NMF is glycerine or urea.
7. environmentally friendly paper tube adhesive according to claim 1, it is characterised in that：The preservative is Kathon CG or Sodium Benzoate.
8. a kind of preparation method of environmentally friendly paper tube adhesive as claimed in claim 1, it is characterised in that：Including following preparation process：
（1）The polyvinyl alcohol of formula ratio is ground into the fine particle material of 80-100 mesh, it is standby；
（2）The defoamer for taking appropriate water and formula ratio adds mixing plant, under 1000-1200 revs/min of rotating speed, side stirring
While being slowly added to step（1）The polyvinyl alcohol of crushing, addition finish after, stir 2-3 hours, until in solution without particle after, plus
Enter cold cut converted starch, continue to stir 0.5-1 hours up to material is well mixed, obtain mixture I；
（3）The water of the kaolin of formula ratio, dispersant, tackifier and surplus is mixed, with 600-800 in mixing plant
Rev/min rotating speed stir to well mixed, obtain mixture II；
（4）By step（3）Obtained mixture II adds step（2）In obtained mixture I, while adding the wetting of formula ratio
Agent, NMF and preservative, stir to well mixed under 1000-1200 revs/min of rotating speed, obtain final product environmentally friendly paper tube adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710150114.8A CN106833439A (en) | 2017-03-14 | 2017-03-14 | A kind of environmentally friendly paper tube adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710150114.8A CN106833439A (en) | 2017-03-14 | 2017-03-14 | A kind of environmentally friendly paper tube adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106833439A true CN106833439A (en) | 2017-06-13 |
Family
ID=59144447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710150114.8A Pending CN106833439A (en) | 2017-03-14 | 2017-03-14 | A kind of environmentally friendly paper tube adhesive and preparation method thereof |
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| CN (1) | CN106833439A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110079246A (en) * | 2019-04-24 | 2019-08-02 | 中山市旭森涂层材料有限公司 | A kind of water seep through and preparation method thereof for Sticky Note |
| CN110343491A (en) * | 2018-04-02 | 2019-10-18 | 青岛海恒源科技有限公司 | A kind of water-fast trade mark adhesive of crystal plastics and preparation method thereof |
| CN113861849A (en) * | 2021-09-30 | 2021-12-31 | 厦门维邦科技有限公司 | Powdery paper tube adhesive |
| CN114106707A (en) * | 2021-10-29 | 2022-03-01 | 新乡县博大绒业有限公司 | High-strength paper tube adhesive and preparation method thereof |
| CN114591705A (en) * | 2020-12-07 | 2022-06-07 | 如东县凤阳纺织器材有限公司 | Environment-friendly pollution-free glue |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110343491A (en) * | 2018-04-02 | 2019-10-18 | 青岛海恒源科技有限公司 | A kind of water-fast trade mark adhesive of crystal plastics and preparation method thereof |
| CN110343491B (en) * | 2018-04-02 | 2021-04-23 | 青岛海恒源科技有限公司 | Water-resistant crystal plastic trademark adhesive and preparation method thereof |
| CN110079246A (en) * | 2019-04-24 | 2019-08-02 | 中山市旭森涂层材料有限公司 | A kind of water seep through and preparation method thereof for Sticky Note |
| CN114591705A (en) * | 2020-12-07 | 2022-06-07 | 如东县凤阳纺织器材有限公司 | Environment-friendly pollution-free glue |
| CN113861849A (en) * | 2021-09-30 | 2021-12-31 | 厦门维邦科技有限公司 | Powdery paper tube adhesive |
| CN114106707A (en) * | 2021-10-29 | 2022-03-01 | 新乡县博大绒业有限公司 | High-strength paper tube adhesive and preparation method thereof |
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Application publication date: 20170613 |