CN103937351B - A kind of wallpaper basement membrane and preparation method thereof - Google Patents

A kind of wallpaper basement membrane and preparation method thereof Download PDF

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Publication number
CN103937351B
CN103937351B CN201410186683.4A CN201410186683A CN103937351B CN 103937351 B CN103937351 B CN 103937351B CN 201410186683 A CN201410186683 A CN 201410186683A CN 103937351 B CN103937351 B CN 103937351B
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weight portion
basement membrane
mildew
inorganic nano
wallpaper basement
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CN103937351A (en
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曹会玲
张树发
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Guangdong Lanyu New Material Technology Co ltd
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Abstract

The invention discloses a kind of wallpaper basement membrane, including deionized water, ethylene glycol, inorganic nano mildew-resistant powder, tourmaline powder, curing agent, soda acid controlling agent, clean taste emulsion and dispersant.The wallpaper basement membrane of the present invention can effectively suppress Wall paper adhesive to go mouldy, and reaches the most antibacterial, the effect of sterilization;It is applicable to various metope, especially obvious to the metope solidification effect that efflorescence is serious, solve body of wall pulverizing problem;Protection against the tide and alkali resistant excellent;Can with anion releasing, the anion discharged can decomposing organic gas, not only make the volatilizable organic matter amount in basement membrane reduce, it is also possible to decompose the organic gas in air, thus reach to purify for a long time the purpose of air.

Description

A kind of wallpaper basement membrane and preparation method thereof
Technical field
The present invention relates to wallpaper auxiliary material technical field, particularly relate to a kind of wallpaper basement membrane and preparation method thereof.
Background technology
In recent years, wallpaper, due to its characteristic such as easy-to-use, attractive in appearance, convenient, enjoys people to favor, but at present Wallpaper product in quality, there is the biggest defect, common wallpaper gas permeability, mildew resistant moistureproof performance are not Good, after Long-Time Service easy mildew rot, affect attractive in appearance.
Wallpaper basement membrane is the metope process material of a kind of special alkali resistant, protection against the tide, mildew-resistant, it is possible to effectively prevent Only moisture moisture and the alkaline matter of construction metope exosmoses, and prevents wall decorative material such as wallpaper, decoration The getting damp of plate, mouldy and turning black and changing color phenomenon occur.The effect of basement membrane has: solidification basic unit (i.e. putty layer), Effect that prevent mould from growing, preferably to play wallpaper and be connected with basic unit, it is easy to secondary paster.Making of basement membrane The simplest by method: with the cylinder of roller coating material, equably by basement membrane roller coating on metope, basement membrane is dried by the time After, just can be with wallpaper.
At present, wallpaper basement membrane effect on the market is single, it is impossible to the Wall paper adhesive suppressing the most mouldy occurs mould Become, there is no lasting bacteriostasis;And, common wallpaper basement membrane can not well play for the metope of efflorescence Effect, even has the opposite effect, causes wallpaper large area to come off;Further, common wallpaper basement membrane itself can discharge Some harmful organic gas, pollute living environment, and healthy to people brings harm.
Summary of the invention
For the defect existing for above-mentioned prior art, it is an object of the invention to propose a kind of combination property pole Good wallpaper basement membrane and preparation method thereof;The wallpaper basement membrane of the present invention can effectively suppress Wall paper adhesive to go mouldy, and Reach the most antibacterial, the effect of sterilization;It is applicable to various metope, especially serious to efflorescence metope solidification effect Fruit substantially, solves body of wall pulverizing problem;Protection against the tide and alkali resistant excellent;Can be released with anion releasing The anion put can decomposing organic gas, thus reach purify air purpose.
For reaching this purpose, the present invention by the following technical solutions:
First aspect, the invention provides a kind of wallpaper basement membrane, and this wallpaper basement membrane includes deionized water, second two Alcohol, inorganic nano mildew-resistant powder, tourmaline powder, curing agent, soda acid controlling agent, clean taste emulsion and dispersant.
" inorganic nano mildew-resistant powder " used herein can be commercially available prod, and those skilled in the art can be led to Cross commercially available.Inventor is found by numerous studies, substitutes with inorganic nano mildew-resistant powder in wallpaper basement membrane Organic mould inhibitor, can reach the effect of long acting antibiotic, mildew-resistant, sterilization.
As preferably, described inorganic nano mildew-resistant powder is inorganic nano-silver mildew-proof powder, inorganic nano zinc mildew-resistant powder Or any one in inorganic nano copper mildew-resistant powder, or the most several compound.
The most several described compound, refer to by silver, zinc, copper Nano compound in any two kinds Or above doping crystallizes the inorganic nano mildew-resistant powder being composited, it it is a kind of high-effect anti-mould functional material.
" tourmaline powder " used herein is a kind of silicate compound containing many kinds of metal ions, electricity Gas is the strongest, it is possible to produce strong electric field, produces substantial amounts of anion with the hydrone effect in air, negative Ion can suppress the growth of bacterium, plays antibacterial, mildew-resistant, the effect of sterilization;Substantial amounts of anion is direct Act on organic matter, and make it decompose, thus eliminate pernicious gas, purify air;Tourmaline mineral resists Bacterium effective constituents A g+、Cu2+Dissolution can strengthen the antibacterial action of tourmaline.
Inventor finds, described inorganic nano mildew-resistant powder adapts to the collocation of tourmaline powder, both can add strong basis The sterilization of film, bacteriostasis, again can be with anion releasing, resolving harmful gas, purifies air.
As preferably, described curing agent is waterproofing agent of organosilicon, carbonic acid pick ammonium or potassium zirconium carbonate, preferably has Machine silicon waterproofing agent.
Described waterproofing agent of organosilicon, is a kind of organic-silicon-modified aqueous solution, can with in acrylic emulsion Some group crosslinks effect, improves the hardness of basement membrane itself, also can penetrate into body of wall, and wall well Body material generation chemical reaction, forms network structure.
In a preferred embodiment, described curing agent is commercially available prod, and its model is SILRES BS 16。
" soda acid controlling agent " used herein is also pH adjusting agent, and it can be by commercially available, it is possible to Prepared by method known to those skilled in the art.
As preferably, described soda acid controlling agent is AMP-95 multifunctional assistant, sodium hydrate aqueous solution or hydrogen The potassium oxide aqueous solution, preferably sodium hydrate aqueous solution.
In a preferred embodiment, described soda acid controlling agent is AMP-95 multifunctional assistant, and it can By commercially available.
As preferably, described clean taste emulsion is acrylic emulsion, silicone acrylic emulsion or styrene-acrylic emulsion, is preferably Acrylic emulsion.
In a preferred embodiment, described clean taste emulsion selects a kind of BASF acrylic emulsion, type Number it is ACRONALECO502ap, is the low smell emulsion for manufacturing coating for internal and external wall.
As preferably, described dispersant is Sodium Polyacrylate, polyacrylic acid or polymethylacrylic acid, is preferably Sodium Polyacrylate.Described dispersant can help inorganic nano mildew-resistant powder and tourmaline powder in clean taste emulsion more Disperse well.
As preferably, described wallpaper basement membrane includes: deionized water 10-15 weight portion, ethylene glycol 3-5 weight Part, inorganic nano mildew-resistant powder 0.5-2 weight portion, tourmaline powder 3-5 weight portion, curing agent 3-7 weight portion, Soda acid controlling agent 0.05-0.5 weight portion, clean taste emulsion 100-150 weight portion, dispersant 0.1-0.3 weight Part;
In a preferred embodiment, described wallpaper basement membrane includes: deionized water 10 weight portion, second Glycol 3 weight portion, inorganic nano mildew-resistant powder 0.5 weight portion, tourmaline powder 3 weight portion, curing agent 3 weight Amount part, soda acid controlling agent 0.2 weight portion, clean taste emulsion 120 weight portion, dispersant 0.2 weight portion;
In another preferred embodiment, described wallpaper basement membrane includes: deionized water 10 weight portion, Ethylene glycol 3 weight portion, inorganic nano mildew-resistant powder 1 weight portion, tourmaline powder 4 weight portion, curing agent 5 weight Amount part, soda acid controlling agent 0.1 weight portion, clean taste emulsion 120 weight portion, dispersant 0.2 weight portion;
In another preferred embodiment, described wallpaper basement membrane includes: deionized water 15 weight portion, Ethylene glycol 3 weight portion, inorganic nano mildew-resistant powder 2 weight portion, tourmaline powder 5 weight portion, curing agent 7 weight Amount part, soda acid controlling agent 0.05 weight portion, clean taste emulsion 120 weight portion, dispersant 0.3 weight portion.
Second aspect, the invention provides the preparation method of wallpaper basement membrane as described in relation to the first aspect, and this is prepared Method is: filters and get final product after being mixed by various raw materials.
Preferably, various raw materials are added in container, filters after being uniformly dispersed by high speed dispersor and get final product. Preferably, the addition order of various raw materials is: deionized water, dispersant, inorganic nano mildew-resistant powder, electrically Stone flour, clean taste emulsion, curing agent, soda acid controlling agent, ethylene glycol.
The wallpaper basement membrane of the present invention uses inorganic nano mildew-resistant powder to use with tourmaline powder collocation, can be by many Plant sterilization mechanism and reach and reach the most antibacterial, the effect of sterilization, it is possible to effectively suppression Wall paper adhesive goes mouldy;Ratio As, antibiotic effective ingredient Ag in tourmaline mineral+、Cu2+Dissolution can strengthen the antibacterial work of tourmaline With, and the anion of tourmaline powder release can be with decomposing organic matter, and thoroughly elimination microorganism remains, reach Sterilization, bacteriostasis thoroughly.
Additionally, the anion of tourmaline powder release can not only make waving in basement membrane with resolving harmful gas Send out organic matter amount to reduce, it is also possible to decompose the organic gas in air, thus reach to purify for a long time the mesh of air 's.
It addition, the wallpaper basement membrane of the present invention can infiltrate into body of wall well, in surface of wall and internal generation Solidification crosslinked action, the problem solving metope efflorescence well.
Detailed description of the invention
Technical scheme is further illustrated below in conjunction with specific embodiment.Should be appreciated that the present invention Enforcement be not limited to following example, those skilled in the art can carry out various changing based on this Entering, these also each fall within protection scope of the present invention.
In following example, the source of primary raw material used is as follows:
Inorganic nano mildew-resistant powder: model 421, Shanghai Shizhan Chemical Technology Co., Ltd. produces;
Tourmaline powder: nanoscale, Lingshou County, Shijiazhuang Jin An mineral products processing factory produces;
Curing agent: the organic-silicon-modified aqueous solution, model SILRES BS16, Guangdong Long Hu science and technology share is limited Company;
Soda acid controlling agent: AMP-95 multifunctional assistant, Nanjing Wei Gao Chemical Co., Ltd. produces;
Clean taste emulsion: model ACRONALECO502ap, Shanghai BASF China is raw Produce;
Dispersant: Sodium Polyacrylate, active ingredient 30%, Guangzhou towing force spy Chemical Co., Ltd. produces.
The preparation of embodiment 1 wallpaper of the present invention basement membrane
Composition of raw materials:
Deionized water 10 weight portion, ethylene glycol 3 weight portion, inorganic nano mildew-resistant powder 0.5 weight portion, electrically Stone flour 3 weight portion, curing agent 3 weight portion, soda acid controlling agent 0.2 weight portion, clean taste emulsion 120 weight Part, dispersant 0.2 weight portion.
Prepare by the following method:
Above-mentioned raw materials is sequentially added in reaction vessel, by the rotating speed high-speed stirred 30 points of 800-1000rpm Clock, filters and packages after stirring and gets final product finished product.
Preservation is deposited in the cool and sealed to the product that the present embodiment obtains, and the phase that stores under normal temperature is 1 year.
The preparation of embodiment 2 wallpaper of the present invention basement membrane
Composition of raw materials:
Deionized water 10 weight portion, ethylene glycol 3 weight portion, inorganic nano mildew-resistant powder 1 weight portion, tourmaline Powder 4 weight portion, curing agent 5 weight portion, soda acid controlling agent 0.1 weight portion, clean taste emulsion 120 weight portion, Dispersant 0.2 weight portion.
Prepare by the following method:
Above-mentioned raw materials is sequentially added in reaction vessel, by the rotating speed high-speed stirred 30 points of 800-1000rpm Clock, filters and packages after stirring and gets final product finished product.
Preservation is deposited in the cool and sealed to the product that the present embodiment obtains, and the phase that stores under normal temperature is 1 year.
The preparation of embodiment 3 wallpaper of the present invention basement membrane
Composition of raw materials:
Deionized water 15 weight portion, ethylene glycol 3 weight portion, inorganic nano mildew-resistant powder 2 weight portion, tourmaline Powder 5 weight portion, curing agent 7 weight portion, soda acid controlling agent 0.05 weight portion, clean taste emulsion 120 weight Part, dispersant 0.3 weight portion.
Prepare by the following method:
Above-mentioned raw materials is sequentially added in reaction vessel, by the rotating speed high-speed stirred 30 points of 800-1000rpm Clock, filters and packages after stirring and gets final product finished product.
Preservation is deposited in the cool and sealed to the product that the present embodiment obtains, and the phase that stores under normal temperature is 1 year.
The hardness test of embodiment 4 wallpaper of the present invention basement membrane
For testing the wallpaper basement membrane of the present invention effect in terms of solidification metope, raising metope hardness, reference GB/T6739-2006 paint and varnish pencil method measures hardness of film standard, made to embodiment 1,2,3 Standby wallpaper basement membrane of the present invention carries out hardness test.Its result is as shown in the following Table 1:
Table 1, the hardness test result of wallpaper basement membrane of the present invention
Embodiment is numbered 1 2 3
Hardness 3B HB H
In table 1, B represents blackness, and B number means that color is the most black, hardness is the least;H represents hardness, H number means that hardness is the biggest, color is the most shallow;It is medium that HB then represents that hardness and blackness are.
As seen from the results in Table 1, the wallpaper basement membrane of the present invention is helpful to for solidification efflorescence metope;And And, along with the increasing of curing agent content in formula, base membrane layer hardness improves.
The antibacterial effect test of embodiment 5 wallpaper of the present invention basement membrane
The antibacterial test of wallpaper basement membrane of the present invention is with reference to GB/T21866-2008 antibiotic paint (paint film) antibiotic property Pipette method and antibacterial effect standard.
Test bacterial classification: aspergillus flavus, aspergillus niger, Aspergillus terreus, paecilomyces varioti, penicillium funiculosum, sprout short stalk Mould, Chaetomium globosum;
Method of testing: various moulds are configured to 105Cfu/ml bacterium solution, every kind of mould quantity phase in the aqueous solution With.Respectively wallpaper basement membrane made for above three embodiment is coated on putty plate according to constructing operation, is dried After the aqueous solution of mould mixed liquor is uniformly sprayed.It is placed in the mold incubator of about 37 DEG C, observes and send out Mould situation.After 28 days, putty plate does not has fungus growth mildew-resistant grade be 0 grade, have less than 10% area Fungus growth mildew-resistant grade be I grade.
The antifungi test result of wallpaper basement membrane of the present invention is as shown in table 2:
Table 2, the antifungi test result of wallpaper basement membrane of the present invention
Embodiment is numbered 1 2 3
Mildewing grade I grade I grade 0 grade
As seen from the results in Table 2, wallpaper basement membrane of the present invention can effectively suppress the growth of various mould.
Applicant states, the present invention illustrates the present invention by above-described embodiment, but the invention is not limited in Above-mentioned, i.e. do not mean that the present invention has to rely on and above-mentioned could implement.Person of ordinary skill in the field should This understands, any improvement in the present invention, and the equivalence to raw material selected by the present invention is replaced and auxiliary element Interpolation, concrete way choice etc., within the scope of all falling within protection scope of the present invention and disclosure.

Claims (8)

1. a wallpaper basement membrane, it is characterised in that described wallpaper basement membrane is made up of following raw material: deionized water 10-15 weight portion, ethylene glycol 3-5 weight portion, inorganic nano mildew-resistant powder 0.5-2 weight portion, tourmaline powder 3-5 Weight portion, curing agent 3-7 weight portion, soda acid controlling agent 0.05-0.5 weight portion, clean taste emulsion 100-150 weight Amount part, dispersant 0.1-0.3 weight portion;
Described inorganic nano mildew-resistant powder is inorganic nano-silver mildew-proof powder, inorganic nano zinc mildew-resistant powder or inorganic nano Any one in copper mildew-resistant powder, or the most several compounds;Described curing agent is waterproofing agent of organosilicon; Described soda acid controlling agent is AMP-95 multifunctional assistant, sodium hydrate aqueous solution or potassium hydroxide aqueous solution; Described clean taste emulsion is acrylic emulsion;Described dispersant is Sodium Polyacrylate, polyacrylic acid or poly-methyl-prop Olefin(e) acid.
Wallpaper basement membrane the most according to claim 1, it is characterised in that described soda acid controlling agent is hydrogen-oxygen Change sodium water solution.
Wallpaper basement membrane the most according to claim 1, it is characterised in that described dispersant is polyacrylic acid Sodium.
Wallpaper basement membrane the most according to claim 1, it is characterised in that described wallpaper basement membrane is by following Raw material is made: deionized water 10 weight portion, ethylene glycol 3 weight portion, inorganic nano mildew-resistant powder 0.5 weight portion, Tourmaline powder 3 weight portion, curing agent 3 weight portion, soda acid controlling agent 0.2 weight portion, clean taste emulsion 120 Weight portion, dispersant 0.2 weight portion.
Wallpaper basement membrane the most according to claim 1, it is characterised in that described wallpaper basement membrane is by following former Material is made: deionized water 10 weight portion, ethylene glycol 3 weight portion, inorganic nano mildew-resistant powder 1 weight portion, electricity Gas stone flour 4 weight portion, curing agent 5 weight portion, soda acid controlling agent 0.1 weight portion, clean taste emulsion 120 weight Amount part, dispersant 0.2 weight portion.
Wallpaper basement membrane the most according to claim 1, it is characterised in that described wallpaper basement membrane is by following former Material is made: deionized water 15 weight portion, ethylene glycol 3 weight portion, inorganic nano mildew-resistant powder 2 weight portion, electricity Gas stone flour 5 weight portion, curing agent 7 weight portion, soda acid controlling agent 0.05 weight portion, clean taste emulsion 120 weight Amount part, dispersant 0.3 weight portion.
7. the preparation method of the wallpaper basement membrane as described in any one of claim 1-6, it is characterised in that will be each Plant raw material mixing, filter and get final product.
Preparation method the most according to claim 7, it is characterised in that various raw materials are added container In, filter after being uniformly dispersed by high speed dispersor and get final product.
CN201410186683.4A 2014-05-05 2014-05-05 A kind of wallpaper basement membrane and preparation method thereof Active CN103937351B (en)

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